• Journal of the Institute of Electronics Engineers of Korea SD
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• v.41 no.6
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• pp.53-58
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• 2004

A novel UV sensor was manufactured and characterized using evanescent field coupling between photochromic dye dispersed polymer waveguide and side polished fiber. The spiroxazine (photochromic dye) dispersed polymer was used as planar waveguides. The resonant wavelength was shifted owing to refractive index variation of planar waveguide on exposed UV because of its photo-functional properties. The sensitivities are $1.21{\mu}W/mw$ and $2.75{\mu}W/mw$ when UV intensities increased after exposure times were fixed at 3 seconds and 5 seconds, respectively. Output optical power according to UV intensity increases and saturation time decreases as the intensity of UV radiations increases.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.131-131
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• 2019

최근 기후변화와 여름철 고온 등으로 인한 녹조현상, 각종 사고로 인한 화학물질 및 유류 유출 등 수질오염과 관련된 사회적 관심이 높아지고 있다. 특히, 화학사고로 인한 유해화학물질 유출은 접촉시 인체에 악영향을 끼치며, 대기 수질 토양을 오염시키고 주변 농작물의 변색이나 괴사를 유발하는 등 발생 시 적절한 조치와 대응이 필요하다. 환경부에서는 유해화학물질 유출사고로 인한 국민건강 및 환경상의 위해를 예방하기 위해 화학물질관리법과 화학물질 등록 및 평가에 관한 법률을 제정하여 유해화학물질을 관리하고 사고에 대응하고 있다. 그러나, 화학사고 발생 시 현장인력에 의존해 공장 인근의 먼지, 악취 등을 감시하거나 화학물질의 유출이 우려되는 곳에 제한적으로 검출센서를 설치해 사고를 감시하고 있으나 미설치 지역에 대한 능동적 탐지가 어렵고, 공간적 분포 탐지가 불가능하여 초동 대응에 한계가 있다. 한편 최근 초분광 영상을 활용하여 물질 고유의 특성을 분석함으로써 토지피복, 식생, 수질 등의 식별에 활용되고 있어 화학물질 감지 가능성도 보여주고 있다. 하지만, 초분광 센서를 활용한 하천의 화학물질 감지를 위한 연구는 아직 미비한 실정이다. 이에 본 연구에서는 우선 유해화학물질의 일종인 황산, 염화티오닐, 톨루엔을 대상으로 지점 분광복사계로 촬영하여 각각의 화학물질이 갖는 분광특성을 수집하여 초분광 영상으로 상호 구분이 가능한 지 확인하고자 하였다. 이상치 검출 및 신뢰도 높은 자료를 구축하기 위해 다회 반복촬영하였으며 반사도의 표준화를 위해 백색판을 동시에 측정하고 이를 정규화하여 분광 라이브러리를 구축한 결과, 대상 화학물질 별 식별이 가능하다는 결과를 도출하였다. 이러한 가능성에 기반하여 추가적인 유해화학물질 분광 라이브러리 데이터베이스를 구축하면, 사고물질의 식별 및 농도를 즉각적으로 확인하고 실시간 모니터링에 적용하여 신속하게 화학사고 발생여부 감지 및 대응에 활용될 것으로 기대한다.

• Journal of the korean academy of Pediatric Dentistry
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• v.37 no.1
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• pp.73-81
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• 2010

The objective of this study was to evaluate the color stability of new silorane-based composite resin compared with methacrylate-based composite resins after immersion in 3 staining solutions. One silorane-based composite(Filtek P90) and 3 methacrylate -based composites(Filtek Z250, Filtek Z350, Tetric Ceram) were evaluated. Twenty disk-shaped specimens($10{\times}2mm$) of each of 4 composite resins were prepared. The specimens were then divided into 4 groups of 5 specimens each and immersed in 3 staining solutions( coffee, red wine, curry solution) or distilled water(control) for 28-day test period. Color of the specimens was measured with a spectrophotometer(Color Eye 7000A) using CIE $L^*a^*b^*$ color space relative to CIE standard illuminant D65 at baseline, 1day, 3days, 7days, 14days, 21days and 28days after staining. The color differences( ${\Delta}{E^*}_{ab}$) were calculated. The results were obtained as follows ; 1. The mean color changes(${\Delta}{E^*}_{ab}$) of the composites were greatest in curry solution, then red wine, coffee and distilled water, in decreasing order. 2. The mean color changes(${\Delta}{E^*}_{ab}$) of the composites were greatest in Z350, Z250, Tetric Ceram and P90, in decreasing order.

• FLOWER RESEARCH JOURNAL
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• v.16 no.1
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• pp.49-56
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• 2008

Typical rose flowers, 'Red Corvette (red)', 'Nobless (pink)', 'Golden Metal (yellow)', and 'Rose Yumi (white)', were used as experimental materials to examine flower color changes as affected by pressing method and light treatment for four weeks and eight weeks by 2,000 lux fluorescent light at a 16 hours daylength. Pressing materials in silicagel mat resulted in the least change after pressing and light treatment for all kinds. On the contrary, an electric pressing device caused color to change to brown. Flower colors deteriorated the most by an electric pressing device made in Korea for pink rose; an electric pressing device made in Japan for white rose; and paper sheet made in Korea for red rose. The sequence of degree in severity of color change after pressing was pink, yellow, and white roses. Light treatment brought about the most extreme color change in yellow 'Nobless' rose, while other three cultivars were rather stable in change of color.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.494.1-494.1
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• 2014

태양광은 세계적으로 유망한 에너지 중의 하나이며, 태양광 모듈은 실제 옥외 조건에 따라 다르지만 장기 신뢰성과 수명을 보장하기 위해 최소 20년 이상을 안정적으로 작동될 필요성이 있다. 하지만 실제 태양전지는 옥외에 장기 노출됨에 따라 성능이 저하되며, 그 원인으로는 셀 균열, 부식, 접착 강도 손실 및 박리, 그리고 변색 등이 있다. 본 논문에서는 부식으로 인한 성능 저하를 완화하기 위해 희생금속을 이용하여 태양전지 모듈의 성능 향상에 대해 연구하였다. 태양전지는 4 cell 결정질 실리콘 태양전지 미니 모듈을 이용하였고, 희생금속의 영향을 확인하기 위해 두 종류의 시료를 준비하였다. 한 시료에는 Al 희생금속을 태양전지 리본 위에 부착하였으며, 나머지 한 시료는 비교 시료로 Al 희생금속을 부착하지 않았다. 시료는 $85^{\circ}C$ 85%의 상대습도인 고온고습 조건에서 2500시간을 진행하였다. 그리고 2500시간의 고온고습 시험이 진행된 시료의 전기적 특성을 분석하였다. 시험 결과, 희생금속이 없을 경우 28.8%의 출력 저하가 있었으며, 희생금속이 있을 경우 19.3%의 출력 저하가 확인되었다. 또한, 희생금속이 없을 경우, 충실도는 21.5% 감소하였으며, 단락전류 역시 약 6% 정도 감소하였다. 반면, 희생금속이 있을 경우, 충실도는 16.1%로 감소하였고, 단락전류는 거의 변화가 없었다.

• Transactions of the Society of Information Storage Systems
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• v.3 no.4
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• pp.173-177
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• 2007

A photo-reactive methacrylate monomer having triazine as a core component was examined for photochromic diffractive image formation. Photochromic photopolymer films as a recording media contained a monomer mixture of triazine difunctional metharylate (DT) and ethylene glycol phenyl ether acrylate, binder polymer, photo initiator, and a photochromic spiro-oxazine dye. The content of photochromic dye was changed to examine the effect of photochromophore on diffraction efficiency and real holographic image formation. Holographic recording was performed on the photopolymer film by the combination of reference and probe beam. The diffraction efficiency of the photopolymer film in real-time measurement reached a maximum of $\sim90%$ within 30s. It was highly dependent on the photochromophore contents. After holographic recording, the color of the recorded area was changed under UV light (365 nm) and reversibly bleached to original color upon exposure to a visible light source. Films containing only photochromophore without monomer mixture were not reactive under the recording beam (491nm). Diffractive image formation and mechanism of the holographic recording in the presence of photochromophore will be presented.

• Journal of the korean academy of Pediatric Dentistry
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• v.44 no.1
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• pp.28-37
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• 2017

Mineral trioxide aggregate have been used for many years as a pulp therapy material. The most widely used product, Proroot white $MTA^{(R)}$ has a major drawback that it causes tooth discoloration. This study assessed discoloration of crown when various MTA-based materials were placed in the coronal aspect of the root canal. Seventy-five single-rooted, unrestored premolar teeth were selected. The teeth were randomly assigned to four experimental groups, each of $Biodentine^{(R)}$, Proroot $wMTA^{(R)}$, $Endocem^{(R)}$, $RetroMTA^{(R)}$ and one negative control groups. Color measurements were utilized by the Commission International de I'Eclairage's L*a*b* system with spectrophotometer. The color was assessed eight times : initial, 1 day, 1 week, 2 weeks, 4 weeks, 8 weeks, 12 weeks, and 16 weeks after the placement. Statistical analysis was performed using the 2-way repeated analysis of variance and Bonferroni's method with p < 0.05. Proroot $wMTA^{(R)}$ induced significant decreases in $L^*$ values during experiment period. Tooth samples from the $Endocem^{(R)}$ group presented indistinct grayish color changes. The $Biodentine^{(R)}$ and $RetroMTA^{(R)}$ showed color stability. Consequently, while Proroot $wMTA^{(R)}$ and $Endocem^{(R)}$ that contain bismuth oxide as a radiopacifier showed tooth discoloration, displayed no sign of discoloration $Biodentine^{(R)}$ and $RetroMTA^{(R)}$ that contain zirconium oxide as a radiopacifier.

• Journal of the Korean Society of Clothing and Textiles
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• v.18 no.1
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• pp.15-22
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• 1994

The formation of carbonyl group was dominant to other functional groups. Concentrations of both carboxyl and peroxide groups were found to rapidly reach low steady state values that increased slightly with increa-sing temperature and relatice humidity. Since the deg-radation of cellulose samples was in the initial stage and the conversion of glycosidic bonds and hydroxyl groups were very small, it was found that changes in the physical and chemical properties could be fitted to a first-order reaction model.

• Journal of the Korean Chemical Society
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• v.37 no.5
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• pp.523-526
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• 1993

Absorption spectra of photochromic spironaphthoxazine dye in various solvents were examined and exhibited a positive solvatochromism. The positive solvatochromism of this dye strongly suggests that the structure of open chain forms is keto type structure, 4a. The effect of structural change on the electronic spectra, on replacement of the C=C bond by C=N bond, is discussed.

• Journal of the Korean Chemical Society
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• v.46 no.5
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• pp.407-411
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• 2002

A method to determine lead ion in aqueous media using an optical sensor loaded on a fluorescent optode membrane incoporating a metal ion-selective ionophore, a proton-selective chromoionophore and lipophilic anionic sites has been studied. The effects of pH and thickness of membrane on the fluorescence intensity were investigated. The effects of foreign ions such as $Na^+$, $K^+$, $Mn^{2+}$ and $Zn^{2+}$ on the determination of lead ion were also studied. The linear range in the calibration curve for the determination of lead ion was found to be 5.0${\times}10^-7$ to 5.0${\times}$$10^-3$M and the correlation coefficient in this range was -0.99107 under the optimal experimental conditions. The relative standard deviation of the blank signals was 3.0% and the detection limit of lead ion was 5.0${\times}$$10^-9$M.