• Title/Summary/Keyword: 광변색

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Optical Patterning and Applications of Photo-chromic Polymers (광변색 고분자의 광학적 패터닝과 응용)

  • Kim, Jun-Young;Fukuda, Takashi
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.76-76
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    • 2007
  • Several kinds of photo-chromic polymers containing push-pull structure were synthesized and investigated on optical patterning by photo-induced surface relief gratings (SRG) technique. The azobenzene segment was introduced as a functional group for a photo-triggered tran-cis isomerization. Consequently, we have fabricated micro-size regular pattern by one-step process without photo-mask.

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직업환경을 위한 TLV의 근거 - PHENOTHIAZINE

  • Kim, Chi-Nyeon
    • 월간산업보건
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    • s.295
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    • pp.11-14
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    • 2012
  • Phenothiazine의 직업적 노출기준(TLV-TWA)은 $5mg/m^3$으로 권고되었다. TLV-TWA의 수준은 피부자극과 변색, 각막염 그리고 태양광에 직접 노출되었을 때 나타나는 광감작반응의 가능성을 최소화하기 위해 설정되었다. 고용량의 phenothiazine을 경구 투여하면 간과 신장이 손상되며 용혈성의 빈혈이 발생한다. Phenothiazine의 피부흡수에 의한 전신 독성이 증명되어 피부흡수 "Skin" 경고주석을 권고하였다. 감작제(SEN)와 발암성 경고주석 그리고 TLV-STEL을 설정하기에는 유용한 자료가 부족하다.

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New Evaluation Method for the Lightfastness of Colored Papers by Radiant Energy (광방사에 의한 채색지의 새로운 내광성 평가 방법)

  • Kim, Hoon;Kim, Hong-Bum;Kwon, Sae-Hyuk
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.6
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    • pp.37-43
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    • 1997
  • Density of a dye or pigment teduces by radiant energym and dinsity change induces color change. In this paper, we habe worked out an equation to predict the color change by the radiant energy under the assumption of colorant density changing pattern by radiant energy and the color changing pattern by colorant density chane. And the damaging factors in the equation was established by experiments. To evaluate the efectiveness of the equation and the method, several samples were irradiated by common light source and color change was measured. Good coincidence between the ceasured and the calculated color change was found. And it was also found that there is a close relationhaip between the spectral damaging factor and the spectral absorptance in visible wavelength range.

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Effects of Blackout Certain to Improve Quality of Onion(Allium cepa. L) under Room Temperature (양파 간이 저장시 차광조건이 품질에 미치는 영향)

  • 이찬중;김희대;정은호;하인종;서전규
    • Food Science and Preservation
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    • v.8 no.4
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    • pp.362-366
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    • 2001
  • This study was conducted to reduce degradation of marketability by the rot and discolor of onion bulbs under room temperature from 1977 to 1998. Allium cepa cv. Changnyungdeago, late strain, was used for the test at the storage condition of non-shading, 55% and 95% shadings. The results obtained are as follows: The mean temperature was maintained lowly 1.0∼2.9$\^{C}$ in 55% and 2.0∼3.8$\^{C}$ in 95% shadings in contrast to nun-shading, but the relative humidity was a tittle higher in high shading than other shading condition. The illumination and color density maintained lowly in high shading. After 21 days of storage, the rate of discolored onion bulbs was significantly higher in non-shading(90.0%) than 55%(35.7%) and 95%(13.3%) shadings. The rotting rate by the end of August was a little decreased at 55%(25.4%) and 95% shadings(26.5%) in contrast to non-shading(28.9%), and total weight loss was maintained lowly in high shading.

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Photochromic Properties of Cellulose Derivatives Having Spirobenzopyran Group (스피로벤조피란을 포함하는 셀룰로오스 유도체의 광변색 특성)

  • Xiangdan, Li;Kim, Eun-Kyoung;Lee, Myong-Hoon
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.25-31
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    • 2005
  • Cellulose acetate derivatives containing 6-(p-hexyloxyphenyl)carbonyl spirobenzopyran (CA-COSP) were prepared from base-catalyzed etherification of cellulose acetate, and their physical and photochromic properties were characterized. The degree of substitution of COSP was calculated from the amount of residual hydroxyl groups in cellulose acetate measured by the $^1H$-NMR and UV spectrometric data. It was ranging from 0.87 to 45.5% depending on the reaction condition. UV/vis spectrometry of the resulting CA-COSP revealed that the polymer shows a reversible color change by changing its color from colorless to blue upon UV irradiation forming a merocyanine structure, and returning back again to colorless spiropyran structure by visible light or by heat. The rate of color change was faster in solution than in the film. In the more polar solvent, the more stable was the resulting merocyanine, and the slower was the rate of reverse reaction to spiropyran. Compared to COSP blended with cellulose acetate, in which a phase separation was observed for samples containing more than 0.9 wt% of COSP, up to 48 wt% of COSP could be blended in CA-COSP without phase separation.

A Study on the Dental Discolouration Measurement due to the Temperature Variation (온도 변화에 따른 치아 변색 측정에 관한 연구)

  • Oh, Se-Yong;Lee, Young-Woo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.123-125
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    • 2008
  • Enamel layer consists of carbonated hydroxyapatite of 85%, water of 12% and protein of 3% and lipid and tentin consists of carbonated hydroxyapatite of 47%, water of 20% and protein of 33% and lipid so if heat is increased in teeth and then teeth color is discolor. In case high temperature is applied in teeth, teeth color changed quality is measured about change of time for minimize teeth change of color. Spectroscopic light intensity special quality by change of time rise at specification temperature.

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Development of Pore-filled Polymer Electrolyte Membranes for Flexible Electrochromic Devices (유연한 전기변색 소자를 위한 세공충진 고분자 전해질 멤브레인의 개발)

  • Park, Hyeon-Jung;Lee, Ji-Hyeon;Kang, Moon-Sung
    • Membrane Journal
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    • v.31 no.5
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    • pp.333-342
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    • 2021
  • A flexible electrochromic device (ECD) is a promising technology that is expected to be applied in various fields such as smart windows. Polymer electrolyte is an important component that determines the bleaching-coloration performance and physical stability of flexible ECDs. In this study, a pore-filled polymer electrolyte membrane (PFPEM) with excellent dimensional stability was developed to effectively fabricate flexible ECDs and improve durability. Polyvinyl acetate, which has excellent adhesion, and polyethylene glycol, which can improve ionic conductivity, were filled in the pores of a porous substrate made of polyethylene, which is inexpensive and has excellent physical and chemical stability. The optimal lithium salt (LiTFSI) content of the prepared PFPEM was determined at about 27 wt%, and it was confirmed to possess excellent dimensional stability, adhesive strength, and ion conductivity close to that of conventional polymer electrolytes. Although the visible light transmittance was lowered by the use of the porous substrate, it was expected to act as an advantage in the colored state.

Chemical Stimuli-Responsible Characteristics of Polymer Films Using PMMA Containing Styryl Dye (Styryl계 PMMA를 이용한 고분자 필름의 화학적 자극-응답 특성)

  • 이선화;이범훈;정재윤;윤기종;조재환
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.60-63
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    • 2003
  • Smart 재료는 외부의 환경으로부터 자극을 받을 경우 형상, 색, 전기적 또는 광학적 특성 등이 변할 수 있는 소재를 말한다. 기존의 재료들은 단지 주어진 환경변화를 수동적으로 받아들이는 데 대하여 smart 재료는 이런 한계를 넘어 생물체처럼 환경에 반응한다는 점에서 앞으로 새로운 소재로 각광받을 수 있을 것이다. 변색성 재료도 이와 같은 중요한 smart 소재에 해당하는데, 물질에 따라 광, 온도, 화학물질, 전기장 등의 외부 환경조건에 응답할 수 있다. (중략)

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Syntheses and Characterisitics of New Photochromic Spiroxazine Dyes (새로운 광변색성 Spiroxazine색소의 합성과 특성)

  • 김성훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.159-168
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    • 1994
  • The Aggregation State of thin vapor deposite Film made by Cyanine Dye were changed into Monomeric molecular state(M) and Dimeric Aggregation(D) at the acidic treatment, into reversible H-Aggregation (H) at alkalic gas or heat treatment. Photo-electric properties were higher H than D and M, this stats were effective in enhancing Photoelectric-conversion characteristic. Substitute group of Meso-Position being stronger electronic Donors, Electronic density is higher and Electric conductivity is enhanced, we confirmed Oscillator Strength calculated by PPP-Molecular Orbital Calculation and Absorption Spectra at solvent stats were agreed good.

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