• Title/Summary/Keyword: 광물조성 변화

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Effect of Clay Mineral Pegmatite and Vitamin A and Supplements on the Physico-Chemical Characteristics of Fattening Hanwoo Steers (거정석과 비타민 A 급여가 거세한우 등심육의 이화학적 특성에 미치는 영향)

  • Kim Byung-Ki;Go Si-Jang
    • Food Science of Animal Resources
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    • v.25 no.2
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    • pp.156-161
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    • 2005
  • This study was conducted to detennine the effect of dietary supplements of mineral powder (pegmatite) on the physico-chemical properties of M longissimuss for 24 Hanwoo steers. Each eight Hanwoo steers were randomly allotted to three treatments ; Control $(0\%)$, T1 (supplemented with pegmatite $2.0\%$ and vitamin A $0.2\%)$, T2 (supplemented with pegmatite $2.0\%$). Cooking loss was highest in control, while water holding capacity (WHC) was the highest in T2 (56.38) than the others. However, effect of the diets on meat color was not significantly different (p>0.05) Panel test scores of juiciness, tenderness and flavor of M longissinus were the highest for T1 $(4.6\~5.0)$ between the treatment group (p<0.05). The content of total fatty acid in M longissimus was the highest in T2 $(50.80\%)$ among the treatment group. Palmitic acid and oleic acid were siginificantly higher in T1 and control than those for the others(p<0.05). Unsaturated fatty acid (UFA) was highest in T2 $(58.57\%)$ than the others$(55.09\~55.64\%)$ (p<0.05).

A Study on the Consistency Measurement of Weathered Granite Soil (화강암질풍화토(花崗岩質風化土)의 Consistency 측정(測定)에 관한 연구(硏究))

  • Kang, Yea Mook;Cho, Seung Seup;Hong, Soon Pil
    • Korean Journal of Agricultural Science
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    • v.7 no.2
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    • pp.109-118
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    • 1980
  • This test was carried out to present criterion to measure the liquid limit of weathered granite soil by using the flow-table method whose operation is easier and more convenient than slump test. The results are as follows. 1. Since liquid limit of weathered granite soil depends upon the particle size distribution, weatheredness and content of colored minerals, maximum particle size should be prescribed when the testing rule of liquid limit by flow-table method is enacted. 2. If take the averaged water content as liquid limit where the height and width of flow are 1 cm respectively by 10 times dropping, this liquid limit is slightly less than the one by slump test. The differance of liquid limit between flow table method and slump test is about 10%. 3. Correlation curves of flow width-water content and flow hight-water content show similar shapes. Those are straight lines in semi-logarithm paper just as liquid limit test. 4. This flow-table method is more convenient and has less personal error of measurement than slump test does. So flow-table method would be favourably utilized for judging the engineering properties of soil.

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Fluid Inclusion and Stable Isotope Studies of Mesothermal Gold Vein Deposits in Metamorphic Rocks of Central Sobaegsan Massif, Korea: Youngdong Area (소백산 육괴 중부 지역의 변성암에서 산출되는 중온형 금광상에 대한 유체 포유물 및 안정동위원소 연구. 영동지역)

  • Chip-Sup So
    • Economic and Environmental Geology
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    • v.32 no.6
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    • pp.561-573
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    • 1999
  • Mesothermal gold deposits of the Heungdeok, Daewon and Ilsaeng mines in the Youngdong area occur in fault shear zones in Precambrian metamorphic rocks of central Sobaegsan Massif, Korea, and formed in single stage of massive quartz veins (0.3 to 3 m thick). Ore mineralogy is simple, consisting dominantly of pyrrhotite, sphalerite and galena with subordinate pyrite, chalcopyrite, electrum, tetrahedrite and native bismuth. Fluid inclusion data indicate that hydrothermal mineralization occurred at high temperatures (>240$^{\circ}$ to 400$^{\circ}$C) from $H_{2}O-CO_{2}(-CH_{4})$-NaCI fluids with salinities less than 12 wt. % equiv. NaC!. Fluid inclusions in vein quartz comprise two main types. These are, in decreasing order of abundance, type I (aqueous liquid-rich) and type II (carbonic). Volumetric proportion of the carbonic phase in type II inclusions varies widely in a single quartz grain. Estimated $CH_4$ contents in the carbonic phase of type II inclusions are 2 to 20 mole %. Relationship between homogenization temperature and salinity of fluid inclusions suggests a complex history of fluid evolution, comprising the early fluid's unmixing accompanying $CO_2$ effervescence and later cooling. Estimated pressures of vein filling are at least 2 kbars. The ore mineralization formed from a magmatic fluid with the ${\delta}^{34}S_{{\Sigma}S}$, ${\delta}^{18}O_{water}$ and ${\delta}D_{water}$ values of -2.1 to 2.2$\textperthousand$, 4.7 to 9.3$\textperthousand$ and -63 to -79$\textperthousand$, respectively. This study validates the application of a magmatic model for the genesis of mesothermal gold deposits in Youngdong area.

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Characterization of crystal phase evolution in cordierite honeycomb for diesel particulate filter by using rietveld refinement and SEM-EDS methods (Rietveld 정밀화법과 SEM-EDS 분석에 의한 DPF용 코디어라이트 하니컴 세라믹스의 결정성장 과정 분석)

  • Chae, Ki-Woong;Kim, Kang San;Kim, Jeong Seog;Kim, Shin-Han
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.3
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    • pp.116-126
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    • 2021
  • Diesel particulate filter (DPF) is a typical application field of cordierite (Mg2Al4Si5O18) honeycomb. Green body for DPF honeycomb was extruded using slurry paste and sintered at the temperature range of 980~1450℃. Quantitative crystal phase analysis was carried out by using Rietveld refinement method for powder XRD data. In conjunction with the quantitative Rietveld analysis, SEM-EDS analysis was carried for the crystal phases (indialite, cordierite, cristobalite, alumina, spinel, mullite, pro-enstatite). After removing amorphous phase on the sintered surfaces by chemical etching method, the shape and composition of the crystal phases can be clearly identified by SEM-EDS method. By combining the Rietveld refinement method and SEM-EDS analysis, crystal phase evolution process in DPF cordierite ceramics could be clarified. In addition, the coefficient of thermal expansion (CTE) of the DPF honeycombs were measured and compared with the calculated CTEs based on the quantitative crystal phase analysis results.

Modeling of Geochemical Variations and Weathering Depth on the Surface of Pelitic Rocks in Periodical Submerging Zone: Bangudae Petroglyphs (주기적 침수구역 이질암 표면의 지구화학적 변화와 풍화심도 모델링: 반구대 암각화)

  • Chan Hee Lee;Yu Gun Chun
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.583-596
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    • 2022
  • The rock surface of Bangudae petroglyphs is mainly dark brown hornfelsified shales by contact metamorphism. The surface form a weathered layer of a invariable depth, and there is a difference with mineral and chemical composition between weathered and non-weathered layers. Surface of the petroglyphs has been discolored to light brown over the face due to biological and chemical weathering. As the measuring chromaticity based on the non-weathered layer, the whiteness and yellowness increased in the weathered layer, and the color difference (ΔE) was 5.54 to 36.89 (mean 17.26). In the weathered layer of the petroglyph surface, the CaO content was reduced by about 90% compared to the non-weathered layer, and Sr also showed the same trend. In particular, the mean porosity of the non-weathered layer was 0.4%, but it was estimated as 25.0% in the weathered layer. This is interpreted as the fact that calcite reacts with water, and forms a weathered layer from the surface as it is eluted. Based on the weathering depth modeling of the petroglyphs using the penetration characteristics of X-rays, the weathering depth of rock faces was found to be 1 to 2mm. However, the area classified as 2mm or more estimated to be a maximum of 3 to 4mm, considering the weathering depth around the petroglyphs surface.

Geochemistry of tourmalines in the Ilgwang Cu-W breccia-pipe deposit, Southeastern Gyeongsang Basin (경상남도 일광의 각력파이프형 구리(Cu)광상에서 산출되는 전기석의 지구화학)

  • 양경희;장주연
    • The Journal of the Petrological Society of Korea
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    • v.11 no.3_4
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    • pp.259-270
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    • 2002
  • A small granodiorite-quartz monzonitic stock containing sericitic and propylitic alteration assemblages hosts a Cu-W breccia-pipe deposit in the southeastern Cyeongsang basin. The mineralized breccia-pipe contains angular to subangular brecciated fragments of granitic rocks showing clast-supported textures. An assemblage of quartz, tourmalines, sulfide minerals (mainly chalcopyrite, arsenopyrite and pyrrhotite) and calcite was precipitated as a hydrothermal cement between the brecciated fragments. A tourmaline aureole surrounds the breccia pipe. Extensive tourmalinization of the granitic rocks near and within the pipe and no tourmalinization in the sedimentary and volcanic rocks. The tourmalines are marked by Fe-rich, black charcoal-like schorl (80 mol% schorl relative) nearer the schorl-dravite solid solution. The chemical changes in the hydrothermal fluid are reflected by variations in compositional Boning from cores to rims. They generally contain cores with low values of Fe/(Fe+Mg) and high values of Na/(Na+ca) relative to rims. This is because of an increase Fe and Ca contents toward rims. The main trend of these variations is a combination of the exchange vectors Ca(Fe, Mg) $(NaAl)_{- }$ $_1$ and $Fe^{3}^{+}$ $Al_{[-10]}$ $_1$ It is thought that boiling causes the loss of $H_2$ into the vapor phase resulting in the oxidation of Fe in the aqueous phase. pH of the melt would be one of important controlling factors for the tourmaline stability. The tourmalines could be precipitated when the system evolved to the acidic hydrothermal regime as most hydrothermal brines and acidic gases exsolved from the magma. The Ilgwang tourmaline crystallization is products of hypogene orthomagmatic hydrothermal processes that were strongly pipe-controlled.

Effect of Boron Content on Atomic Structure of Boron-bearing Multicomponent Oxide Glasses: A View from Solid-state NMR (비정질 소듐 보레이트와 붕소를 함유한 다성분계 규산염 용융체의 붕소의 함량에 따른 원자 구조에 대한 고상 핵자기 공명 분광분석 연구)

  • Lee, A Chim;Lee, Sung Keun
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.3
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    • pp.155-165
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    • 2016
  • Understanding the effect of boron content on atomic structures of boron-bearing multicomponent silicate melts is essential to reveal the atomistic origins of diverse geochemical processes involving silica-rich magmas, such as explosive volcanic eruption. The detailed atomic environments around B and Al in boron-bearing complex aluminosilicate glasses yield atomistic insights into reactivity of nuclear waste glasses in contact with aqueous solutions. We report experimental results on the effect of boron content on the atomic structures of sodium borate glasses and boron-bearing multicomponent silicate melts [malinkoite ($NaBSiO_4$)-nepheline ($NaAlSiO_4$) pseudo-binary glasses] using the high-resolution solid-state NMR ($^{11}B$ and $^{27}Al$). The $^{11}B$ MAS NMR spectra of sodium borate glasses show that three-coodrinated boron ($^{[3]}B$) increases with increasing $B_2O_3$ content. While the spectra imply that the fraction of non-ring species decreases with decreasing boron content, peak position of the species is expected to vary with Na content. Therefore, the quantitative estimation of the fractions of the ring/non-ring species remains to be explored. The $^{11}B$ MAS NMR spectra of the glasses in the malinkoite-nepheline join show that four-coordinated boron ($^{[4]}B$) increases as $X_{Ma}$ [$=NaBSiO_4/(NaBSiO_4+NaAlSiO_4)$] increases while $^{[3]}B$ decreases. $^{27}Al$ MAS NMR spectra of the multicomponent glasses confirm that four-coordinated aluminum ($^{[4]}Al$) is dominant. It is also observed that a drastic decrease in the peak widths (full-width at half-maximum, FWHM) of $^{[4]}Al$ with an addition of boron ($X_{Ma}=0.25$) in nepheline glasses. This indicates a decrease in structural and topological disorder around $^{[4]}Al$ in the glasses with increasing boron content. The quantitative atomic environments around boron of both binary and multicomponent glasses were estimated from the simulation results of $^{11}B$ MAS NMR spectra, revealing complex-nonlinear variation of boron topology with varying composition. The current results can be potentially used to account for the structural origins of the change in macroscopic properties of boron-bearing oxide melts with varying boron content.

Analysis of Test Items of Earth Science and the Applicants' Responses on the Items in the College Scholastic Ability Test (대학수학능력시험의 지구과학영역 문항 및 응시자 반응 분석)

  • Lee, Yang-Rak
    • Journal of the Korean earth science society
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    • v.22 no.6
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    • pp.469-479
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    • 2001
  • This study investigated the trends in the number of applicants and mean score and applicants’ responses on the test items of Earth Science in the College Scholastic Ability Test (CSAT) implemented for 3 years (1999-2001). The percentage of applicants of science track were 43.14% in 1995, but reduced through 29.5% in 2001 to 26.92% in 2002 CSAT For elective subject, about 22% of science track students applied to Earth Science II which ranked third to Biology II and Chemistry II. In 1999, test items were developed to have the expected difficulty 40 ${\sim}$ 59% (6 items) to 60 ${\sim}$ 79% (10 items). But in 2001 every 16 items were developed to have difficulty 60 ${\sim}$ 79%, which was caused by the policy of so called ‘easy CSAT’. Thus the mean score of ‘Earth Science II’ was increased from 50.26 in 1999 through 64.47 in 2000, to 67.58 in 2001. Applicants were generally very good at solving test items focusing on process skills only and familar items but poor at solving test items related to the motion of the earth and planets and sea wave, especially items calling two or more concepts. Thus special measures to cope with the decrease in applicants of science track should be provided. And it is recommended to develop test items with wider range of difficulty and to reduce test items calling process skills only. And special consideration should be given to teaching the content area with poor achievement and high actual difficulty compared to the expected.

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Biogeochemical Remediation of Cr(VI)-Contaminated Groundwater using MMPH-0 (Enterobacter aerogenes) (MMPH-0 (Enterobacter aerogenes)에 의한 6가 크롬 오염 지하수의 생지화학적 정화)

  • Seo, Hyun-Hee;Rhee, Sung-Keun;Kim, Kang-Joo;Park, Eun-Gyu;Kim, Yeong-Kyoo;Chon, Chul-Min;Moon, Ji-Won;Roh, Yul
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.105-119
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    • 2012
  • Indigenous bacteria isolated from contaminated sites play important roles to remediate contaminated groundwater. Chromium has the most stable oxidation states. Cr(VI) is toxic, carcinogenic, and mobile, but Cr(III) is less toxic and immobile. In this study, indigenous microorganism (MMPH-0) was enriched from Cr(VI) contaminated groundwater, and identified by 16S rRNA gene analysis. Using MMPH-0, the effect of stimulating with e-donors (glucose, lactate, acetate, and no e-donor control), respiration conditions, biomass, tolerance, and geochemical changes on Cr(VI) reduction were investigated in batch experiments for 4 weeks. The changes of Cr(VI) concentration and geochemical conditions were monitored using UV-vis-spectrophotometer and Eh-pH meter. And the morphological and chemical characteristics of MMPH-0 and precipitates in the effluents were characterized by TEM-EDS and SEM-EDS analyses. MMPH-0 (Enterobacter aerogenes) was able to tolerate up to 2000 mg/L Cr(VI) and reduce Cr(VI) under aerobic and anaerobic conditions. MMPH-0 performed faster and higher efficiency of Cr(VI) reduction with electron donors (over 70% after 1 week with e-donor, 10-20% after 4 weeks without e-donor). The changes of Eh-pH in effluents showing the tendency from oxidizing to reducing condition and a bit of acidic change in pH due to microbial oxidation of organic matters donating electrons and protons suggested the roles of MMPH-0 on Cr(VI) in the contaminated water catalyzing to transit geochemical stable zone for more stable $Cr(OH)_3$ or Cr(III) precipitates. TEM/SEM-EDS analyses of MMPH-0 and precipitates indicate direct and indirect Cr(VI) reduction: extracellular polymers capturing Cr component outside cells. These results suggested diverse indigenous bacteria and their biogeochemical reactions might enhance more effective and feasible remediation technology of redox sensitive heavy metals in metal-contaminated in groundwater.

Development of Theme-Based Integrated Unit in the Middle School Science and Analysis of it's Effects (중학교 과학수업을 위한 주제중심 통합단원의 개발 및 효과 분석)

  • Park, Soo-Kyong;Kim, Sang-Dal;Ju, Gook-Yong;Nam, Youn-Kyong
    • Journal of the Korean earth science society
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    • v.22 no.5
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    • pp.350-359
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    • 2001
  • The purpose of this study is to develop theme-based integrated science unit by the interdisciplinary approach and to analyze it's effects on the science achievement and the attitude towards science learning. 'Interaction' and 'Stability' were selected as the integrated themes, and the main concept and subconcept in relation to the themes were extracted from the four areas of science, and the learning contents were constructed in the integrated ways. While the main concept have relevance to subconcept in the interaction, the main concept have little relevance to subconcept in the stability. Therefore, the stability was to fit with middle school integrated science theme, but the interaction was not. The theme-based integrated science units developed was implemented in middle school, and the results are follows. First, the science achievement of group of theme-based integrated science teaching is significantly higher than those of group of traditional teaching. Second, the scores of the test of attitude toward science learning of the group of theme-based integrated science teaching is significantly higher than those of group of traditional teaching. Third, the students' perception of theme-based integrated science teaching was positive. The students have participation, interest, motivation in theme-based integrated science teaching, and students have difficulty in learning theme-based integrated science teaching.

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