• Journal of Energy Engineering
• /
• v.28 no.1
• /
• pp.17-21
• /
• 2019

Calcium sulfaluminate (CSA) was synthesized to improve the shrinkage of OPC. In this study, the setting time, the compressive strength and the length change ratio were confirmed by replacing the synthesized CSA with OPC by 10% and 13% by 16%. In the case of shrinkage-reducing type cement, formation of Ca-Al-$H_2$-based hydrate was activated. Therefore, the setting time was shortened. The compressive strength of the shrinkage - reducing type cement is comparable to that of OPC after 7 days' strength. However, shrinkage reducing type cement showed improved initial strength compared to OPC. The length change ratio was found to be improved by drying shrinkage from -0.075% to -0.047% on the 28th day.

• The Journal of the Petrological Society of Korea
• /
• v.15 no.2 s.44
• /
• pp.81-89
• /
• 2006

Pb isotopic compositions were determined from the ore deposits of Beonam, Dongjin, Jeoksang and Bukchang mines distributed within Jeolabuk-do. As a result, individual mine shows significantly different values of Pb isotopic compositions from each other. Pb isotopic values of the Beonam, Bukchang and Dongjin mines altogether from linear variation, but it is too steep to represent their formation age. Instead, such trend suggests that these ore leads were originated from binary mixing. Precambrian basement rocks and Mesozoic granitoids are suggested for such two end-members. The relative contribution of lead from each source seems to be quite different for each ore deposit, implying that the circulation of the ore-forming fluid was very localized when they were formed. In the case of Dongjin mine it seems significant portion of the ore leads were originated from the basement rocks, which suggests that related igneous rock seems to have acted as heat source to generate circulation of the fluid rather than the source of the ore-forming elements.

• Korean Journal of Mineralogy and Petrology
• /
• v.33 no.1
• /
• pp.53-64
• /
• 2020

The Samgwang deposit has been one of the largest deposits in Korea. The deposit consists of series of host rocks including Precambrian metasedimentary rocks and Jurassic Baegunsa formation, which unconformably overlies the Precambrian metasedimentary rocks. The deposit consists of eight lens-shaped quartz veins which filled fractures along fault zones in Precambrian metasedimentary rock, which feature suggest that it is an orogenic-type deposit. Laminated quartz veins are common in the deposit which contain minerals including quartz, ankerite, white mica, chlorite, apatite, rutile, arsenopyrite, sphalerite, chalcopyrite and galena. The structural formulars of white micas from laminated quartz vein and wallrock alteration are determined to be (K_1.02-0.82Na_0.02-0.00Ca_0.00)(Al_1.73-1.58Mg_0.26-0.16Fe_0.23-0.10Mn_0.00Ti_0.03-0.01Cr_0.01-0.00)(Si_3.35-3.22Al_0.79-0.65)O₁₀(OH)₂ and (K_0.75-0.67Na_0.01Ca_0.00) (Al_1.78-1.74Mg_0.16-0.15Fe_0.15-0.13Mn_0.00Ti_0.04-0.02Cr_0.01-0.00)(Si_3.33-3.26Al_0.74-0.67)O₁₀(OH)₂, respectively. It suggest that white mica from laminated quartz vein has higher interlayer cation (K+Na+Ca) and Fe+Mg+Mn+Ti content in octahedral site compared to the white mica from the wallrock alteration. Compositional variations in white mica from laminated quartz vein can be caused by phengitic or Tschermark substitution ((Al³⁺)^VI+(Al³⁺)^IV <-> (Fe²⁺ or Mg²⁺)^VI)+(Si⁴⁺)^IV) and (Fe³⁺)^VI <-> (Al³⁺)^VI substitution. Ankerite from laminated quartz vein has compositional variations of FeO and MgO contents along crystal growth direction. The geochemical and textural features suggest that laminated quartz vein from the Samgwang gold-silver deposit was formed during ductile shear stage, which is an important main gold-silver ore-forming event in orogeinc deposit.

• The Journal of the Petrological Society of Korea
• /
• v.21 no.2
• /
• pp.263-275
• /
• 2012

Jurassic Daebo biotite granites, known as one of the main stone resources in the country, are widely and away distributed in the Pocheon and Yangju areas of the mid Gyeonggi massif. The objects of the study are mainly to reveal the unique characteristics of grain size, rock color, mineral composition, physical property and fracture system from the above biotite granites. Biotite granites from the Pocheon area (PG) and Yangju area (YG) are represented by coarse-grained and light gray, and medium to coarse-grained and grayish to light gray, respectively. In modes, main minerals of Qz+Af+Pl (quartz+alkali feldspar+plagioclase) are more increased in the PG, and accessories of biotite are more increased in the YG, which differences can cause the PG more bright light gray than the YG. Specific gravity (SG) shows somewhat more increasing in the YG than the PG. These differences can be caused by more increasing in biotite contents of higher specific gravity compared to the major minerals in the former than the latter. Absorption ratio (AR) and porosity (PR) of the PG and YG show the same values of 0.33 % and 0.86 %, respectively. In the correlations, PR vs SG and AR vs PR show gradually negative and distinctly positive trends, respectively. Compressive strength (CS) and tensile strength (TS) show increasing in the PG (CS: 1,775 $kg/cm^2$, TS: 87 $kg/cm^2$) than the YG (CS: 1,647 $kg/cm^2$, TS: 79 $kg/cm^2$). These strength characteristics could be attributed to the inherent rock textures of them. Abrasive hardness (AH) also shows a little increasing in PG, which can be caused by increase in quartz contents having higher hardness than the other major minerals. Orientations of fracture sets from the PG and YG were compared with those of vertical rift and grain planes in Mesozoic granites of the country. From the overlapped diagram, the distribution pattern between fracture sets and above vertical planes suggests that microcrack systems developed in Mesozoic granites in Korea occur also in the Daebo biotite granite bodies of the mid Gyeonggi massif. From the relation diagram showing the characteristics of fracture patterns for the above two area, PG and YG may have more potentiality for dimension and non-dimension stone resources, respectively.

• Economic and Environmental Geology
• /
• v.25 no.3
• /
• pp.259-273
• /
• 1992

The Seongsan mine is one of the largest dickite deposits in the southwestern part of the Korean Peninsula. The main constithent minerals of the ore are dickite and quartz with accessory alunite, kaolinite and sericite. The geology around the Seongsan mine consists mainly of the late Cretaceous felsic volcanic rocks. In the studied area, these rocks make a synclinal structure with an axis of E-W direction plunging to the east. Most of the felsic volcanic rocks have undergone extensive hydrothermal alteration. The hydrothermally altered rocks can be classified into the following zones: Dickite, Dickite-Quartz, Quartz, Sericite, Albite and Chlorite zones, from the center to the margin of the alteration mass. Such zonal arrangement of altered rocks suggests that the country rocks, most of which are upper part of the rhyolite and welded tuff, were altered by strongly acid hydrothermal solutions. It is reasonable to consider that initial gas and solution containing $H_2S$ and other compounds were oxidized near the surface, and formed hydrothermal sulfuric acid solutions. The mineralogical and chemical changes of the altered rocks were investigated using various methods, and chemical composition of fifty-six samples of the altered rocks were obtained by wet chemical analysis and X.R.F. methods. On the basis of these analyses, it was found that some components such as $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO, MgO, $K_2O$, $Na_2O$ and $TiO_2$ were mobilized considerably from the original rocks. The formation temperature of the deposits was estimated as higher than $200^{\circ}C$ from fluid inclusion study of samples taken from the Quartz zone. On the basis of the chemical composition data on rocks and minerals and estimated temperatures, the hydrothermal solutions responsible for the formation of the Seongsan dickite deposits were estimated to have the composition: $m_{K^+}=0.003$, $m_{Na^+}=0.097$, $m_{SiO_2(aq.)}=0.008$ and pH=5.0, here "m" represents the molality (mole/kg $H_2O$).

• Economic and Environmental Geology
• /
• v.47 no.4
• /
• pp.363-379
• /
• 2014

The Haenam Pb-Zn skarn deposit is located at the Hwawon peninsula in the southwestern part of the Ogcheon Metamorphic Belt. The deposit is developed along the contact between limestone of the Ogcheon group and Cretaceous quartz porphyry. Petrography of ore samples, chemical composition of skarn and ore minerals, and geochemistry of the related igneous rocks were investigated to understand the characteristics of the skarn mineralization. Skarn zonation consists of garnet${\pm}$pyroxene${\pm}$calcite${\pm}$quartz zone, pyroxene+garnet+quartz${\pm}$calcite zone, calcite+pyroxene${\pm}$garnet zone, quartz+calcite${\pm}$pyroxene zone, and calcite${\pm}$chlorite zone in succession toward carbonate rock. Garnet commonly shows zonal texture comprised of andradite and grossular. Pyroxene varies from Mn-hedenbergite to diopside as away from the intrusive rock. Chalcopyrite occurs as major ore mineral near the intrusive rock, and sphalerite and galena tend to increase as going away. Electron probe microanalyses revealed that FeS contents of sphalerite become decreased from 5.17 mole % for garnet${\pm}$pyroxene${\pm}$calcite${\pm}$quartz zone to 2.93 mole %, and to 0.40 mole % for calcite+pyroxene${\pm}$garnet zone, gradually. Ag and Bi contents also decreased from 0.72 wt.% and 1.62 wt.% to <0.01 wt.% and 0.11 wt.%, respectively. Thus, the Haenam deposit shows systematic variation of species and chemical compositions of ore minerals with skarn zoned texture. The related intrusive rock, quartz porphyry, expresses more differentiated characteristics than Zn-skarn deposit of Meinert(1995), and has relatively high$SiO_2$ concentration of 72.76~75.38 wt.% and shows geochemical features classified as calc-alkaline, peraluminous igneous rock and volcanic arc tectonic setting.

• Korean Journal of Mineralogy and Petrology
• /
• v.35 no.2
• /
• pp.125-140
• /
• 2022

The Xiquegou Pb-Zn deposit is located at the Qingchengzi orefield which is one of the largest Pb-Zn mineralized zone in the northeast of China. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite, Paleo-Mesoproterozoic sodic granite, Paleoproterozoic Liaohe group, Mesozoic diorite and Mesozoic monzoritic granite. The Xiquegou deposit which is a Triassic magma-hydrothermal type deposit occurs as vein ore filled fractures along fault zone in unit 3 (dolomitic marble and schist) of Dashiqiao formation of the Paleoproterozoic Liaohe group. Xiquegou Pb-Zn deposit consists of quartz, apatite, calcite, pyrite, arsenopyrite, pyrrhotite, marcasite, sphalerite, chalcopyrite, stannite, galena, tetrahedrite, electrum, argentite, native silver and pyrargyrite. Wallrock alteration of this deposit contains silicification, pyritization, dolomitization, chloritization and sericitization. Based on mineral petrography and paragenesis, dolomites from this deposit are classified two type (1. dolomite (D₀) as wallrock, 2. dolomite (D₁) as wallrock alteration in Pb-Zn mineralization quartz vein ore). The structural formulars of dolomites are determined to be Ca_1.03-1.01Mg_0.95-0.83Fe_0.12-0.02Mn_0.02-0.00(CO₃)₂(D₀) and Ca_1.16-1.00Mg_0.79-0.44Fe_0.53-0.13Mn_0.03-0.00As_0.01-0.00(CO₃)₂(D₁), respectively. It means that dolomites from the Xiquegou deposit have higher content of trace elements compared to the theoretical composition of dolomite. The dolomite (D₁) from quartz vein ore has higher content of these trace elements (FeO, PbO, Sb₂O₅ and As₂O₅) than dolomite (D₀) from wallrock. Dolomites correspond to Ferroan dolomite (D₀), and ankerite and Ferroan dolomite (D₁), respectively. The structural formular of chlorite from quartz vein ore is (Mg_1.65-1.08Fe_2.94-2.50Mn_0.01-0.00Zn_0.01-0.00Ni_0.01-0.00Cr_0.02-0.00V_0.01-0.00Hf_0.01-0.00Pb_0.01-0.00Cu_0.01-0.00As_0.03-0.00Ca_0.02-0.01Al_1.68-1.61)_5.77-5.73(Si_2.84-2.76Al_1.24-1.16)_4.00O₁₀(OH)₈. It indicated that chlorite of quartz vein ore is similar with theoretical chlorite and corresponds to Fe-rich chlorite. Compositional variations in chlorite from quartz vein ore are caused by mainly octahedral Fe²⁺ <-> Mg²⁺ (Mn²⁺) substitution and partly phengitic or Tschermark substitution (Al^3+,VI+Al^3+,IV <-> (Fe²⁺ 또는 Mg²⁺)^VI+(Si⁴⁺)^IV).

• 한국해양학회지
• /
• v.27 no.4
• /
• pp.277-289
• /
• 1992

Kyeonggi Bay, a macrotidal coastal embayment in the Yellow Sea coast of central korea, is fringed by vastly developed tidal flats. About 400 surface sediment samples were collected from the intertidal and subtidal zones of Kyeonggi Bay for a study of the sediment distribution pattern and the surface sediment characteristics of this environment. The kyeonggi Bay surface sediment becomes progressively finer in the shoreward direction, from offshore sand to shoreward silty sand and sandy silt. This shoreward-fining trend is repeated again on the tidal flat and, as a consequence, a grain-size break occurs near the low-water line which separates the intertidal area from the subtidal one. The intertidal and subtidal sediments differ from each other in textural characteristics such as mean grain size and skewness and this can be interpreted to result from differences in hydraulic energy and morphology between the two environments. The mineral and chemical compositions of the Kyeonggi Bay sediments are largely controlled by the sediment grain size. Smectite was nearly absent in the clay mineral assemblage of Kyeonggi Bay sediment. The contents of Co, Cu and Ni were high in the Banweol tidal flat, which suggests a continuous process of accumulation of these metals. the intertidal environment appears to respond rapidly to artificial coastal modifications, the effects of which should be taken into consideration when planning a dam construction or coastal reclamation.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.4 no.4
• /
• pp.338-348
• /
• 1999

Physical properties of mudbelt sediments in the southeastern inner shelf of Korea are studied from 14 cores. Physical properties, compressional wave velocity, and sediment texture for core sediments are analyzed. The major source of sediment in the study area is the Nakdong River. Fine-grained sediments from the river are transported northeastward by coastal circulation and the Tsushima Current, resulting in a gradual northeastward increase in porosity and a decrease in wet bulk density and velocity. The trend matches well with the bathymetry. The mean grain size appears to be the most important variable to determine the physical properties and velocity. The variations of physical properties with burial depth are dependent more strongly on sediment texture than compaction and/or consolidation. Correlations between the physical properties and the sediment texture show slight deviations from those of the continental terrace sediment in the North Pacific and inner shelf sediment in the South Sea of Korea. The velocity is higher than that of the North Pacific and the South Sea sediments between these areas. This is probably due to differences in sedimentary, environment and mineral compositions. The higher sediment velocity in the study area may also be attributed to the escape of gas from pore space which decreases void ratio.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.5 no.4
• /
• pp.335-345
• /
• 2000

Physical and acoustic properties of the Southeastern Yellow Sea Mud (SEYSM) of Korea were studied by using 10 piston cores. The data were also compared with mudbelt sediments in the South Sea and the East Sea (southeastern inner shelf) of Korea. The sediments were mainly composed of homogeneous silt. Sandy mud and mud were minor components. The major source of sediment in the study area is probably the Keum River. Finegrained sediments discharged from the river are transported southward by coastal current, resulting in a gradual southward increase in porosity and a decrease in wet bulk density and sound velocity. The mean grain size especially appears to be the most important variable to determine the physical properties and velocity. The variations of physical properties with burial depth are dependent more strongly on sediment texture (especially, silt content) than compaction and/or consolidation. Correlations between the physical properties and the sediment texture show slight deviations from those of the East Sea and the South Sea of Korea in spite of similar pattern within the limiting values. This is probably due to the differences in silt contents, sedimentary environments, mineral compositions, and gas contents.