• Title/Summary/Keyword: 광물조성 변화

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Petrology of Charnockite in Sancheong Area (산청지역에 분포하는 챠노카이트의 암석학적 연구)

  • Lee, Sang-Won;Ock, Soo-Seck;Lee, Young-Taek
    • Journal of the Korean earth science society
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    • v.25 no.4
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    • pp.251-264
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    • 2004
  • The Charnockite in Sancheong region is quarzofeldspathic rock containing orthopyroxene and garnet with a color dark than common granitic rocks. The Chamockite are mostly massive and medium to coarse-grained with K-feldspar phenocryst, but reveal weak foliation. The rock consist mainly of quartz, K-feldspar, plagioclase and orhopyroxene, with biotite, garnet, and anthophyllite. In petrochemistry, the Chamockite has 61-65% $SiO_2$ contents, varying gradually into the margin contacted with orthogneiss, which have compositions of felsic igneous rocks. Major element show almost systematical variation with those of the marginal orthogneisses, except the hornblende gneiss and anorthosite. The Charnockite and orthogneisses show the tholeiitic differentiational trend. Trace and rare earth element abundance patterns in the Charnockite show remarkable negative Sr and Eu anomalies similar to orthogneisses, but different from the hornblende gneiss and anorthosite. Eu contents of the Charnockite are richer than that of orthogneisses. The metamorphic condition of the Charnockite were tested by an orthopyroxene-garnet geotherrnorneter and a plagioclase-garnet geobarometer. Estimated P-T conditions are about $761^{\circ}C$ and 7 kbar at peak metamorphism, but $653^{\circ}C$ and 6.4 kbar at retrograde metamorphism. This suggests that the Charnockite have from an early stage of high-grade metamorphism to represent the granulite facies and then to a late stage medium-grade metamorphism belonging to the amphibolite facies.

Soil Genesis on the King Muryung's Tomb of the Ancient Baegje Dynasty in Korea (백제(百濟) 무령왕능(武寧王陵) 봉분(封墳)의 토양생성화(土壤生成化) 작용(作用)에 관(關)한 연구(硏究))

  • Shin, Young-Hwa;Choi, Dae-Ung;Jung, Pil-Kyun;Lee, Dong-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.3
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    • pp.191-194
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    • 1992
  • The tomb of the king Muryung, the 25th king of ancient Baegje dynasity in Korea, was proved to be constructed about 1500 years ago. The Physico-chemical characteristics were determined in order to investigate the pedogenic process for tomb soils. Clay and silt content inclosed down to 30~40cm soil depth. The increase of clay was 13.4% in the 10cm surface soil and the estimated time for 1% increase of clay in the profile was about 112 years. There were great changes in chemical properties in the 10cm surface soil, and considerable accumiration of salts and increase of catiom exchange capacity(CEC) down to 30cm depth. The alteration of primary minerals and formation of clay minerals were great in the 10cm surface soil and considerably reconized down to 50~60cm. The result suggested that the development of soil profile from the tomb parent material for the period was 10cm under the forest environment in Korea. The parent material of tomb soil was considered to be transported greyish green clored diorite from other place.

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태양계의 물: 기원과 진화

  • Choe, Byeon-Gak;Choe, Hye-Rim
    • 한국지구과학회:학술대회논문집
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    • 2005.09a
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    • pp.3-8
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    • 2005
  • 지구는 현재 태양계에서 액체 상태의 물이 표면에 존재하는 유일한 천체이다. 하지만, 고체 또는 기체 상태의 물은 태양계의 다른 행성이나, 위성, 소행성, 혜성 등에도 풍부하게 존재하고 있다. 풍부한 액체 상태의 물은 지구 표면에서 일어나고 있는 기후의 변화, 해류의 이동, 퇴적 및 침식 작용, 화산활동과 같은 여러 지구과학적 현상에 밀접하게 관여하고 있을 뿐 아니라 생명의 탄생과 진화에도 매우 중요한 역할을 하였다. 현재 지구 표면에 액체 상태의 물이 존재할 수 있는 이유는 태양으로부터의 거리, 지구의 조성 및 크기 등과 관련된 지구 표면의 물리-화학적 조건이 액체 상태의 물이 존재할 수 있는 조건과 일치하고 있기 때문이다. 이와는 달리 지구보다 태양에 더 가깝게 위치하고 있고, 두터운 이산화탄소 대기를 갖고 있어 표면의 온도가 매우 높은 금성의 경우 H2O는 기체 상태로 존재하며, 지구보다 더 멀리 떨어져 있고 희박한 대기를 갖고 있는 화성의 경우에는 현재 H2O가 고체 즉 얼음의 형태로 존재한다. 태양계를 탄생시킨 태양계 성운에서는 압력이 너무 낮아 액체 상태의 물이 존재할 수 없으며, 고온에서는 기체 상태로 매우 낮은 저온에서는 얼음의 형태, 또는 함수 광물 내에 포함되어 존재할 수 있다. 지구와 같은 규모의 행성은 비교적 중력이 작아 태양계 성운의 기체를 거의 끌어들이지 못했다. 따라서 현재 지구에 존재하는 물은 대부분은 고체 상태로 지구에 집적되었을 것이다. 하지만 지구가 탄생한 위치에서 초기 태양계의 온도는 얼음이 형성되기에는 너무 높았기 때문에 좀 더 먼 곳에서(현재의 목성 위치보다 바깥쪽)에서 생성된 얼음 즉, 혜성이 태양계 안쪽으로 들어와 지구에 물을 공급했거나 함수광물을 포함하고 있는 소행성(예를 들어 CI chondrites와 같은 조성의)이 물을 가져왔을 것으로 생각되고 있다.서의 활성화는 어미 변환과 관련된 영역이라기보다는 산출시 관련되는 articulation, motor coordinate관련 영역으로 추정되고, 측두엽의 활성화는 형태소, 의미 관련 지식의 data base로 추정된다. 또한 우반구 전두엽 부분에서 관찰된 활성화는 억제관련 영역으로 짐작된다.러한 동물실험이 그 기초를 제공해 줄 수 있을 것이다. 또한 행동성향 및 기억의 종류에 따른 약물효과의 차이는 기억과 관련된 질병인 알츠하이머 환자에 있어 개개인에게 맞는 적절한 특징적인 치료약물이 존재할 것이라는 가능성을 제공해줄 뿐만 아니라 학습과 기억력 증진 효과를 기대해 볼 수 있을 것이라고 생각된다. 및 지역산업발전의 기획${\sim}$조정기구로서, 선진국의 지역발전기구(Regional Development Agency : RDA)인 지역전략산업기획단이 2002년도부터 산업자원부와 9개 시도에 의해 설립되어 지역네트워크의 활성화와 클러스터의 형성 촉진을 하게 되었고 2004년도에는 13개시도로 확대${\sim}$운영되고 있고, 지역특화사업(H/W)과 지역산업기술개발과제(S/W)와 함께 패케지 형태로 지원되며, 주요역할은 크게 지역산업의 정책기획 분야와 평가관리, 지역혁신역량 조사 및 DB구축 등으로 구분된다. 그중에서도 권역별, 지역별, 지역산업진흥사업 육성과 중장기 산업발전계획을 수립하기 위하여 지역혁신역량을 바탕으로 한 지역 Technology Road Map(TRM)작성사업은 전국공통의 1단계 사업으로 실시 ?榮쨉?, 2005년 3월 기준으로 9개 지역(강원, 대전, 충남, 충북, 경북, 울산, 전남, 전북, 제주) 26개 산업분야를 대상으로 23개가 완료된 상황이다. 이를 근거로 한 지역정책과 R&D 과제 및 필요 인프라의 도출이 체계적으로 구축되어 지역산업 발전을 위한

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Effect of Physiochemical Properties of Seokganju on Functionality and Light Fastness (석간주의 이화학적 특성이 기능성 및 내광성에 미치는 영향 연구)

  • Park, Ju Hyun;Jeong, Hye Yeong;Mun, Seong Woo;Woo, In Suk
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.485-495
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    • 2017
  • The purpose of this study is to evaluate the functionality and lightfastness of the natural pigments according to the type of Seokganju used as Dancheong. The commercially available red iron-oxide-based natural pigments that are called Seokganju and Daija manufactured by traditional methods in Korea and Japan were selected. The analysis of the constituent minerals and constituents of 8 kinds of collected Seokganju showed that most of them contained hematite. There are two types of Seokganju according to the $Fe_2O_3$ contents. The type of Seokganju can be characterized not only using the main component but also from the burn-out processing. The chromaticity results for Seokganju with a high $Fe_2O_3$ concentration indicate dark red or grayish brown, while those for Seokganju with a low $Fe_2O_3$ concentration indicate yellowish red or yellowish brown. Samples were prepared by mixing with a glue solution and functional properties were evaluated based on the opacity and spreadability. Coated samples were used in the lightfastness test. The spreadability and opacity of the pigments were measured differently depending on the main component. Most Seokganju samples a showed slight color change until $9,000kJ/m^2$ but rapid color changes were detected after $18,000kJ/m^2$. In particular, burnt Seokganju showed superior lightfastness.

Oxygen Sites in Quaternary Ca-Na Aluminosilicate Classes : O-17 Solid-State NMR Study (사성분계 비정질 Ca-Na 알루미노규산염의 산소주변의 원자구조 : O-17 고상핵자기 공명분광학분석)

  • Sung, So-Young;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.347-353
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    • 2006
  • The atomic-nano scale structures of multi-component aluminosilicate glasses have not been well understood in spite of its implications fur dynamics and generation of magma in the natural system due to lack of suitable spectroscopic and scattering experiments. Here, we report O-17 MAS and isotropic projection of 3QMAS NMR spectra for quaternary Na-Ca silicate glasses $[(CaO)_x(Na_2O)_{1-x}]\;(A1_2O_3)_{0.5}(SiO_2)_6,\;CNAS)$ at 14.1 Tesla where atomic configurations around bridging oxygen (Si-O-Si, Si-O-Al) and non bridging oxygen (Na-O-Si, Ca-O-Si, (Na, Ca)-O-Si) are partially resolved. With increasing Na content, the fraction of Na-O-Si increases while those for bridging oxygens remain constant. The Na/Ca ratio apparently affects the peak widths of bridging oxygen peaks (e.g., Si-O-Si)) and thus the topological entropy as well as chemical shifts of the bridging oxygen peaks, implying that both BOs and NBOs are strongly interacting with network modifying cations The effect of cation field strength on the degree of Al-avoidance was also discussed.

A study of push core sediments and topographical controls around the shallow gas hydrate site in the Ulleung Basin, East Sea (울릉분지 천부 가스하이드레이트 부존지역에서의 해저지형변화에 따른 퇴적물 특성 연구)

  • Chun, Jong-Hwa;Lee, Joo-Yong;Kim, Hak-Joo;Kang, Nyeon-Keon;Nam, Sung-Il
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.200-202
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    • 2008
  • 동해 울릉분지에서는 시추선 RemEtive를 사용하여 UBGH-X-01 가스하이드레이트 탐사가 2007년에 실시되었다. 본 연구에서는 천부 가스하이드레이트가 확인된 UBGH1-10 정점에서 무인잠수정(Quantam WROV)을 사용하여 획득된 푸쉬코어와 해저지형 분석을 수행되었다.UBGH1-10 정점은 seismic chimneys의 탄성파 특성이 발달된 지역이다. 이곳에서는 해저표면으로부터 수 m 하부에서 가스하이드레이트가 발견되었다. 이 정점은 수 m 높이의 얕은 둔덕들이 무인잠수정에 부착된 비디오 카메라에 의해서 관찰되었다.이곳에서 채취된 길이 약40 cm의 푸쉬코어는 생물교란된 뻘질 퇴적물로 구성되어 있으며, 가스하이드레이트와 chemosynthetic community는 관찰되지 않았다. 푸쉬코어는 X-ray fluorescence scanner를 사용하여 퇴적물의 26가지 원소 조성을 분석하였다. UBGH1-10 정점의 산화환원환경은 Mo/Al과 Mn/Ti 원소비를 이용하여 천부 가스하이드레이트가 발견되지 않은 UBGH1-9와 UBGH1-1 정점과 대비하였다. 이 정점의 일차생산력은 Ba/Al 원소비를 이용하여 다른 정점과 대비하였다. 천부 가스하이드레이트가 발견된 UBGH1-10 정점은 활발한 가스방출과 관련된 생물집단 서식 또는 자생광물 형성의 흔적이 발견되지 않으며, 퇴적물에서도 산화환원환경과 일차생산력의 큰 차이가 관찰되지 않는다.

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Mineralogical and chemical characterization of arsenic solid phases in weath-ered mine tailings and their leaching potential (풍화광미내 고상 비소의 광물학적${\cdot}$화학적 특성 및 용출 가능성 평가)

  • 안주성;김주용;전철민;문희수
    • Economic and Environmental Geology
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    • v.36 no.1
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    • pp.27-38
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    • 2003
  • Arsenic contamination around Au-Ag mining areas occurs mainly from the oxidation of arsenopyrite which is frequently contained in mine tailings. In weathered tailings, oxidation of sulfide minerals typically results in the formation of abundant ferric (oxy)hydroxides or (oxy)hydroxysulfates near the tailings surface, and arsenic may be associated with these secondary precipitates. In this study, solid phases of arsenic in weathered tailings of some Au-Ag mines were investigated through the SEM/EDS and sequential extraction analyses. The stability of As solid phases and the leaching potential were assessed with the variation of pH and Eh conditions. Oxidation of sulfides in the tailings samples was indicated by depletion of S molar concentrations compared to As and heavy metals. Under XRD examinations, jarosite as an Fe-oxyhydroxysulfate was found in the tailings of Deokeum, Dongil and Dadeok, and scorodite as an As-bearing crystalline mineral was identified from Dadeok which has the highest concentration of As (4.36 wt.%). Beudantite-like phases and some Pb-arsenates were also found under SEM/EDS analysis, and most of As phases were associated with Fe-(oxy)hydroxides and (oxy)hydroxysulfates despite a few arsenopyrite from Samgwang and Gubong. Sequential extraction analysis also showed that As was present predominantly as coprecipitated with Fe hydroxides from Dongil, Dadeok and Myungbong (72∼99%), and as sulfides (58%) and Fe hydroxide-associated forms (40%) from Samgwang and Gubong. In the tailings leaching experiment, As was released with high amounts by the dissolution of As-bearing Fe(oxy)hydroxysulfates in the lowest pH (2.7) conditions of Deokeum, and by desorption under alkaline conditions of Samgwang and Gubong. Higher leaching rates of arsenite(+3) were found under acidic conditions, which pose a higher risk to water quality. Changes in pH and Eh conditions coupled with microbial processes could influence the stabilities of the As solid phases, and thus, time amendments or landfilling of weathered tailings may result in enhanced As mobilization.

Petrology and Geochemistry of the Cretaceous Palgongsan Granite, Southern Korea (백악기(白堊紀) 팔공산(八公山) 화강암(花崗岩)의 암석학적(岩石學的) 및 지구화학적(地球化學的) 연구(硏究))

  • Hong, Young Kook
    • Economic and Environmental Geology
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    • v.16 no.2
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    • pp.83-109
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    • 1983
  • The Cretaceous Palgongsan granite is a typical, calc-alkaline, subsolvus monzogranite and shows characteristics of "I-type" granite by mineralogy and chemical composition. Many of the major and trace element characteristics of the Palgongsan granite are consistent with a relationship by fractional crystallisation to form a chemically zoned pattern. The granite show light REE enrichment with (Ce/Yb)N ratios of 5.78-9.50. All the REE patterns show Eu negative anomalies which become larger from the margin ($Eu/Eu^*=0.75$) to the core ($Eu/Eu^*=0.24$) of the pluton, mainly due to feldspar fractionation. Mineral geochemistry (alkali-feldspar, plagioclase & biotite) studies also show the zonal structure of the Palgongsan granite. The two-feldspar geothermometer shows that the temperature difference between the margin and the core part of the pluton is about $200^{\circ}C$ at various assumed pressures.

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Mineralogy of Alunite from the Sungsan Mine (성산광산(聲山鑛山) 명반석(明礬石)의 광물학적(鑛物學的) 특성(特性))

  • Cho, Hyen Goo;Kim, Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.2 no.2
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    • pp.81-89
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    • 1989
  • Alunite occurs as massive, cavity-filling and veinlets in the Cretaceous Hwangsan Formation in the Sungsan mine, Korea. It is a hydrothermal alteration product of rhyolitic tuffs, and associated with dickite, quartz and barite. The average chemical formula of alunite in the mine is $(K_{0.93}Na_{0.07})_{1.00}Al_{3.00}(SO_4)_{2.00}(OH)_6$. Atomic percentage of Na substituting for K in A site of the alunite structure varies from 5.9 to 9.2. Unit-cell volume and c dimension decrease with increasing Na atomic percentage. On the basis of thermal and high temperature XRD analyses, the decomposition of alunite into $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ concomitant with the liberation of structural water (12.86%) occurs at about $550^{\circ}C$. The reconstruction of $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ to $Al_2(SO_4)_3$, arcanite and thenardite, and the crystallization of ${\gamma}-Al_2O_3$ take place at about $720^{\circ}C$. The destruction of $Al_2(SO_4)_3$ structure takes place at about $760^{\circ}C$ removing 3/4 of total $SO_3$ (27.32%).

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Characteristics and depositional environment of paleosol layers developed on top of the terrace in the Jeongdongjin area, East Coast, Korea (강릉 정동진 지역 단구 고토양층의 특징과 퇴적 환경)

  • Yi, Seon-Bok;Lee, Yong-Il;Lim, Hyun-Soo
    • The Korean Journal of Quaternary Research
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    • v.23 no.1
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    • pp.1-24
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    • 2009
  • Paleosol layers lying on top of the terrace in Jeongdongjin area appear to have been deposited under generally well-drained condition with periodic waterlogging. From a 4.5m-long profile observed, a total of 6 stratigraphic units were identified. Grain-size analysis indicates the dominance of silty and clay materials with some portions with high sand content. Major mineralogical elements are quartz, feldspar, mica and chlorite. Geo-chemical composition shows little change throughout the stratigraphy with some fluctuation in chemical weathering index. Marked increase in magnetic susceptibility is recognizable where stratigraphic unit changes. Soil- wedge layer is developed around 50cm below the surface with concentration of grains of AT tephra (c. 25,000 BP). An OSL date of c. 110,000 BP was obtained from a sand layer lying below the paleosol.

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