• Korean Chemical Engineering Research
• /
• v.47 no.5
• /
• pp.580-586
• /
• 2009

In this study, co-combustion characteristics of Chinese bituminous coal and North Korean anthracite were investigated using a 2 MWe scale circulating fluidized bed power plant. At first, the combustion efficiency of bituminous coal of China and Australia as a function of excess air ratio and temperature were observed. The results showed that the combustion efficiency was influenced by particle size and volatile content of coal, the combustion efficiency of Chinese bituminous coal was over 99.5%. The unburned carbon particles from fly ash and bottom ash were a content 5~7% and 0.3%, respectively. The combustion efficiency with the mixture ratio 20% of bituminous coal and anthracite decreased over 5% because of the increase of entrained particles by a small average particle size of anthracite in the combustor. However, the outlet concentration of $SO_2$ and $NO_x$ was not changed remarkably. The concentrations of the typical air pollutants such as $NO_x$ and $SO_2$ were 200~250 ppm($O_2$ 6%), 100~320 ppm($O_2$ 6%) respectively. The outlet concentration of $NO_x$ was decreased to 30~65% with $NH_3$ supplying rate of 2~13 l/min in SCR process. The $SO_x$ removal efficiency was up to 70% by in-furnace desulfurization using limestone with Ca/S molar of approximately 6.5. With wet scrubbing using $Mg(OH)_2$ as absorbent, the $SO_x$ removal efficiency reached 100% under near pH 5.0 of scrubbing liquid.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.24 no.4
• /
• pp.436-445
• /
• 2014

Objectives: Time-activity studies have become an integral part of comprehensive exposure assessment and personal exposure modeling. The aims of this study were to estimate exposure levels to nitrogen dioxide($NO_2$) and volatile organic compounds(VOCs), and to compare estimated exposures by using time-activity patterns and indoor air concentrations. Methods: The major microenvironments for office workers were selected using the Time-Use Survey conducted by the National Statistical Office in Korea in 2009. A total of 9,194 and 6,130 workers were recruited for weekdays and weekends, respectively, from the Time-Use Survey. It appears that workers were spending about 50% of their time in the house and about 30% of their time in other indoor areas during the weekdays. In addition, we analyzed the time-activity patterns of 20 office workers and indoor air concentrations in Daegu using a questionnaire and time-activity diary. Estimated exposures were compared with measured concentrations using the time-weighted average analysis of air pollutants. Conclusions: According to the time-activity pattern for the office workers, time spent in the residence indoors during the summer and winter have been shown as $11.12{\pm}2.20$ hours and $12.48{\pm}1.77$ hours, respectively, which indicates higher hours in the winter. Time spent in the office in the summer has been shown to be 1.5 hours higher than in the winter. The target pollutants demonstrate a positive correlation ($R^2=0.076{\sim}0.553$)in the personal exposure results derived from direct measurement and estimated personal exposure concentrations by applying the time activity pattern, as well as measured concentration of the partial environment to the TWA model. However, these correlations were not statistically significant. This may be explained by the difference being caused by other indoor environments, such as a bar, cafe, or diner.

• Clean Technology
• /
• v.26 no.1
• /
• pp.72-78
• /
• 2020

The use of fossil fuel and biogas production causes air pollution and climate change problems. Research endeavors continue to focus on converting methane and carbon dioxide, which are the major causes of climate change, into quality energy sources. In this study, a novel plasma-carbon converter was proposed to convert biogas into high quality gas, which is linked to photovoltaic and wind power and which poses a problem on generating electric power continuously. The characteristics of conversion and gas production were investigated to find a possibility for biogas conversion, involving parametric tests according to the change in the main influence variables, such as O₂/C ratio, total gas feed rate, and CO₂/CH₄ ratio. A higher O₂/C ratio gave higher conversions of methane and carbon dioxide. Total gas feed rate showed maximum conversion at a certain specified value. When CO₂/CH₄ feed ratio was decreased, both conversions increased. As a result, the production of solar fuel by plasma oxidation destruction-carbon material gasification conversion, which was newly suggested in this study, could be known as a possibly useful technology. When O₂/C ratio was 0.8 and CO₂/CH₄ was 0.67 while the total gas supply was at 40 L min^-1 (VHSV = 1.37), the maximum conversions of carbon dioxide and methane were achieved. The results gave the highest production for hydrogen and carbon dioxide which were high-quality fuel.

• Korean Journal of Plant Resources
• /
• v.29 no.5
• /
• pp.579-587
• /
• 2016

The final goal of this research is to develop a miniaturized botanical biofilter using a wick-typed automatic humidifier for stabilizing soil moisture content (SMC) and purifying indoor air pollutants by the biofilter. This new biofilter equipped with wick-typed automatic humidifier was manufactured as more compacted design removing an absorption tower-typed humidifier compared with the previous big-sized biofilter made in 2015. This study was performed to compare changes of SMCs among floors depending on the number of wicks installed on the humidifier within the novel biofilter, and to compare changes of SMCs and plant growth parameters before and after planting Spathiphyllum wallisii ‘Mauna Loa’ on the biofilter. SMCs among floors depending on the number of wicks were similar, and all regression lines of SMCs showed almost horizontal lines because of long-term stability on SMCs. Comparing plant growth parameters of S. wallisii ‘Mauna Loa’ before planting and at 30 days after planting on the biofilter, all growth parameters were not statistically significant. Thus, SMCs of the biofilter were more stabilized using this humidifying apparatus regardless of the number of wicks than the previous biofilter using absorption tower-typed humidifying apparatus.

• Journal of Energy Engineering
• /
• v.19 no.4
• /
• pp.228-233
• /
• 2010

About 55% of total energy is consumed in the industrial division. The industrial heat pump application will show magnificent energy saving effect as well as higher cost efficiency because of larger energy consuming volume of each facility and longer operation hour and higher stability against seasonal temperature change. Over 90% of dryer for industrial usage has hot wind heat source and hot wind dryer is the representative type covering 68.7% while its 30 ~ 50% lower heat efficiency causes lots of energy loss by exhaust air. Re-usage of exhaust air can improve energy efficiency of dryer because 68% heat energy or 78% of hot air lose in exhaust air. Therefore, high temperature heat pump dryer can be the best alternative. Comparing to the existing dryer with 30% ~ 50% energy efficiency, newly developing high temperature heat pump dryer will enhance energy efficiency up to 60% ~ 80% efficiency. In this paper, heat pump system for high temperature was designed, constructed and tested. The results have shown that system COPh is estimated as 3.3.

• Journal of Korean Society for Atmospheric Environment
• /
• v.12 no.4
• /
• pp.429-439
• /
• 1996

A comprehensive air quality monitoring was carried out in this study to investigate the concentrations of criteria air pollutants in indoor and outdoor air of public facilities in Taegu area. Four different kinds of public facilities were seleced as sampling sites, which are underground stores, stations & terminals, general hospitals, and department stores. Each group of the public facilities was consisted of three different sampling sites. As a consequence, a total of 12 different sampling sites were surveyed throughout this study. Sampling was conducted simultaneously indoors, three times per day (in the morning, afternoon, and evening) and four times per year (spring, summer, fall, and winter) at each sampling site during the period of October 1994 to July 1995. A range of criteria pollutants were measured in order to obtain a broad profile of indoor and ambient air quality, including total suspended particles (TSP), carbon monoxide (CO), carbon dioxide ($CO_2$), formaldehyde (HCHO), sulfur dioxide ($SO_2$), and nitrogen dioxide ($NO_2$). In addition, temperature, relative humidity, and air current were measured on site together with those air pollutants. Results of this study indicated that the indoor levels of TSP, CO, $SO_2, and NO_2$ appeared to be generally higher in stations/terminals and underground stores than those in department stores and hospitals. However, HCHO and $CO_2$ were found to have higher levels in the department stores and hospitals than other places, indicating that the effects of indoor sources for these pollutants are significantly different from other combustion related pollutants such as TSP, CO, and $SO_2$. It was also found that there are marked seasonal and daily variations both in indoor and outdoor air quality. In general, combustion related pollutants such as CO, $SO_2$ and $NO_2$ showed a typical pattern of higher levels in winter than insummer, and also higher in the morning and/or in the evening than in the afternoon. However, the seasonal and daily patterns of HCHO appeared to be opposite to the combustion related pollutants, i.e., higher both in summer and in the afternoon, implying the effect of temperature on the volatilization from indoor sources of HCHO. Results of correlation analyses between indoor and outdoor air quality also indicated that the effects of outdoor sources on the indoor levels of TSP, $SO_2$, CO, and $NO_2$ and much significant, whilst no significant correlations between indoor and outdoor levels were found for HCHO and $CO_2$.

• 보존과학연구
• /
• s.28
• /
• pp.91-104
• /
• 2007

The goal of this study was to provide basic data for arrangement of management in museum environment. We investigated characteristics of distribution on indoor air pollutants at exhibition halls and storages in museums between July and August, 2007. The monitoring carried out at three cultural sites, Pusan, Daejeon and Kyungjoo which is possessed their own exhibition hall and storage in Museums. We adopt the several pollutants for this survey such as $PM_{10}$, $PM_{2.5}$ $CO_2$, Formaldehyde, TBC, CO, $NO_2$, Rn, VOCs, $O_3$ and followed the standard method of Ministry of Environment, Korea for sampling and analysis, respectively. The results of this survey revealed that average concentration of $PM_{10}$ and $PM_{2.5}$ in storages were $117.3{\mu}g/m^3$ and $92.6{\mu}g/m^3$, respectively. The average concentration in storages of gases pollutants and microorganism such as $CO_2$, Formaldehyde, $NO_2$, Rn, TVOC, $O_3$, and TBC showed as: 788.8ppm, $30.7{\mu}g/m^3$, 0.4ppm, 6.4ppb, $1.3pCi/{\ell}$, $1,374.9{\mu}g/m^3$, 2.4ppb, and $119.4cfu/m^3$, respectively. In addition, average concentration of $PM_{10}$ and $PM_{2.5}$ in exhibition halls were $49.5{\mu}g/m^3$ and $56.1{\mu}g/m^3$, respectively. The average concentration in exhibition halls of gases pollutants and microorganism such as $CO_2$, Formaldehyde, $NO_2$, Rn, TVOC, $O_3$, and TBC showed as: 475.2ppm, $94.1{\mu}g/m^3$, 0.3ppm, 12.4ppb, $0.3pCi/{\ell}$, $1,179.1{\mu}g/m^3$, 5.2ppb, 2.4ppb, and $24.8cfu/m^3$, respectively.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.9
• /
• pp.279-287
• /
• 2018

Sealants are an important element of modern architecture and serve as a building protection against weathering by providing barriers against ingress of moisture, air, and other materials. Exposure to a variety of environments often reduces lifespan due to changes in physical, chemical and mechanical characteristics, and UV, humidity, and temperature expansion are important issues that are directly related to durability. In this study, a combined deterioration test chamber was developed to simulate the environment of the open air as an instrument for verifying the durability of structural sealing materials indoors. In order to replicate special weather conditions, such as yellow dust, acid rain, and contamination by microorganisms, it was deemed impossible to replicate the outdoor environment by 100 %, and the results of the results of the results of the external exposure test of the structural sealant and the combined deterioration testing device. As a result of the displacement test of the outdoor exposure test, it was determined that the sealant was breaking apart and that it would be smooth, and the displacement would be up to three times greater than the initial material value of 1 year. The displacement test results of the combined deterioration test device show the tendency to deteriorate, decreasing the elasticity and tensile characteristics. In the case of denatured silicon, the current 400 cycles have been completed to confirm 12 months of degradation of the external exposure. The deformation of the test specimen cannot be verified with the naked eye, so it is considered that the conditions of the specimen are more stable than the silicon sealant. As a result of the outdoor exposure test, if the combined deterioration test device is structured and proposed in the relevant guidance or specification, the anticipated lifespan of 12 months in the actual use environment can be verified indoors and below 3 months later, economically.

• Clean Technology
• /
• v.27 no.4
• /
• pp.367-371
• /
• 2021

The oxy-combustion system is one of the carbon recovery and storage technologies (CCS: Carbon capture & storage) that performs coal combustion using pure oxygen and recirculated flue gas. This is a technology that facilitates storage of carbon dioxide by generating an exhaust gas consisting of only carbon dioxide without a process of separating carbon dioxide and nitrogen when coal is burned using pure oxygen and recirculated flue gas mixture instead of a conventional air combustion system that produces carbon dioxide and nitrogen mixed exhaust gas. In this study, the characteristics of generated NO and SO₂ as atmospheric pollutants during oxy-combustion were examined using O₂/CO₂ mixed simulation gas. The reaction temperature was varied from 900 ℃ to 1200 ℃ and oxygen partial pressure was varied from 30% to 50%. The results showed that NO and SO₂ concentrations in flue gas increased as the oxygen concentration and the reaction temperature in the furnace increased. The partial pressure of CO₂ in flue gas also increased as the oxygen concentration and the reaction temperature in the furnace increased. As a results of comparing NO production of 30% O₂/CO₂ oxy-combustion with air combustion, NO in flue gas increased with reaction temperature in both experiments and NO of oxy-combustion was 40 ~ 80 ppm lower than that of air combustion.

• Korean Journal of Remote Sensing
• /
• v.39 no.2
• /
• pp.129-142
• /
• 2023

This study analyzed the ratio of carbon monoxide (CO) and carbon dioxide (CO₂), CO and nitrogen dioxide (NO₂) for cities and regionsin Korea and China using column-averaged carbon dioxide dry-air mole fraction (XCO₂) of the Orbiting Carbon Observatory-2/3, CO and NO₂ vertical column density (named XCO, XNO₂ in thisstudy) of TROPOspheric monitoring instrument from April 2018 to April 2022, and presented the relationship between socioeconomic indicators (population, number of vehicles, Gross Regional Domestic Product) and ratio, and differences in characteristics between Korea and China. First, CO₂ and CO were analyzed after calculating ΔXCO₂ and ΔXCO removing the background value and trend line due to the difference in atmospheric residence time of three gaseous substances (CO₂, CO, and NO₂). Comparing the three values by regions, ΔXCO and ΔXCO₂ were relatively higher in China and XNO₂ were higher in Korea and the ratio of both values (ΔXCO/ΔXCO₂, ΔXCO/XNO₂) was higher in China than in Korea. ΔXCO/ΔXCO₂, ΔXCO/XNO₂ and socioeconomic indicators have a positive correlation suggesting that the concentration of air pollutants and greenhouse gases is higher as the city is large and the economic activity is active. Regarding the differences in the ratio characteristics of Korea and China, the relationship between ΔXCO and ΔXCO₂ showed a negative correlation in Korea and a positive correlation in China. When the relationship between ΔXCO and XNO₂ was examined for summer and winter, the change of ΔXCO by season was not significant in Korea, whereasthe change of ΔXCO and XNO₂ by season waslarge in China resulting in the relationship between two countries appeared differently. These results suggest that seasonal variability and national emission characteristics should be considered in the process of analyzing the ratio of greenhouse gases to air pollutants.