• Membrane Journal
• /
• v.21 no.4
• /
• pp.360-366
• /
• 2011

The effect of cross-flow velocity and transmembrane pressure (TMP) on membrane fouling was observed from pilot-scale operation of thermophilic anaerobic membrane bioreactor (AnMBR) treating food waste leachate. It was found that fouling rate was reduced significantly as cross-flow velocity increased at constant TMP mode of operation while this effectiveness was more pronounced at lower TMP. Higher TMP resulted in less permeable fouling layer possibly due to compressibility of foulant material on membrane surface. Particle sizes of membrane concentrate ranged from 10 to $100{\mu}m$, implying that shear-induced diffusion enhance back transport of these particle sizes away from the membrane effectively. From the continuous operation of AnMBR, it was confirmed that shear rate played an important role in the reduction of membrane fouling. Membrane autopsy works at the end of operation of AnMBR showed clearly that both organic and inorganic fouling were significant on membrane surface. Surface shear by cross-flow velocity was expected to be less effective to remove irreversible fouling which can be mainly caused by the adsorption of organic colloidal materials into membrane pores.

• Membrane Journal
• /
• v.21 no.4
• /
• pp.377-388
• /
• 2011

Flat sheet microfiltration membranes were prepared with polysulfone (PSF), polyethersulfone (PES), and polyphenylsulfone (PPS) by an immersion precipitation phase inversion method. In this method, dimethyl formamide (DMF) and polyvinylpyrrolidone (PVP) were used as a solvent and a wetting polymer additive, respectively. 2-butoxyethanol (BE) was used as a nonsolvent additive catalyst to form pore. The morphology of membranes was investigated by scanning electron microscopy and micropermporometer. The permeability of the membranes was evaluated with the flux of pure water. When the BE was added, the pore size of membranes became larger than blank membranes. The changes in the morphology of membrane due to the BE addition depend on polymer structure. All membranes have similar mean pore size and porosity. The mean pore sizes of PSF, PES, and PPS membranes were 0.282, 0.330 $0.308{\mu}m$, respectively. The porosities of PSF, PES and PPS membranes were 68.5, 66.1, 66.4%, respectively. However, the PPS membrane showed higher pore density on surface and narrower pore size distribution than PSF or PES membrane does. As a result, the pure water flux of PPS membrane ($357L/m^2\;hr$) was higher than that of PSF ($196L/m^2\;hr$) or PES membrane ($214L/m^2\;hr$).

• Journal of the Korea Institute of Building Construction
• /
• v.17 no.3
• /
• pp.211-217
• /
• 2017

The objective of this study is to seek a reliable mixture proportion for magnesium potassium phosphate composite(MKPC) mortars with a near-neutral pH value (below 9.5) and a relatively good compressive strength exceeding 30MPa. The main parameter selected was the molar ratios($M_{mp}$) of $MgO-to-KH_2PO_4$ which varied from 30.4 to 3.4. The setting time of the MKPC mortars tended to shorten with a decrease in $M_{mp}$ value. With regard to the strength development ratio normalized by the 28-day strength, the ranges measured in the mortars with an $M_{mp}$ below 7.9 were 50~61% at 1 day and 60~73% at 3 days, indicating a highly rapid early-strength development. With a decrease in $M_{mp}$, the formation of struvite-K crystal identified as a primary hydration product increased, which led to the decrease of the macro-capillary pores in micro-structures. For achieving the targeted requirements for pH value and compressive strength, the $M_{mp}$ needs to be selected as below 5.1.

• Korean Chemical Engineering Research
• /
• v.45 no.3
• /
• pp.242-248
• /
• 2007

For an optimal design of automotive electric system, it is important to have a reliable modeling tool to predict the charge-discharge behaviors of the automotive battery. In this work, a two-dimensional modeling was carried out to predict the charge-discharge behaviors of a 12-V automotive lead-acid battery. The model accounted for electrochemical kinetics and ionic mass transfer in a battery cell. In order to validate the modeling, modeling results were compared with the experimental data of the charge-discharge behaviors of a lead-acid battery. The discharge behaviors were measured with three different discharge rates of C/5, C/10, and C/20 at operating temperature of $25^{\circ}C$. The batteries were charged with constant current of 30A until the charging voltage reached to a predetermined value of 14.24 V and then the charging voltage was kept constant. The discharge and charge curves from the measurements and modeling were in good agreement. Based on the modeling, the distributions of the electrical potentials of the solid and solution phases, the porosity of the electrodes, and the current density within the electrodes as well as the acid concentration can be predicted as a function of charge and discharge time.

• Journal of the Korean Geographical Society
• /
• v.41 no.4 s.115
• /
• pp.404-417
• /
• 2006

In order to clarify some characteristics of hydrological cycle in the subalpine zone of Mt. Halla, water balance has been analysed using hydrological data of a first-order drainage basin around Mansedongsan and meterological data of Odeung AWS. The experimental basin extends from 1,595 m to 1,645 m in altitude and has an catchment area of 1.34 ha. It is largely underlain by trachybasalt and covered with sasa bamboo and sedges. Hydrological observations were carried out every 20 minutes from April 15 to September 19, 2004. The basin shows the total precipitation of 3,074 m that is 1.6 to 3 times of those in coastal and intermontane regions. Surface runoff amounts to 850 mm that is equivalent to 27.6% of the precipitation. By contrast, evapotranspiration only accounts for 14.2% of the precipitation, and the remnant of 1,790 m penetrates underground through a basement. The basin is located in the subalpine zone and then it has a high rainfall intensity as well as a large rainfall due to frequent orographic precipitation. But surface runoff usually dose not exceed 30% of the rainfall while Percolation demonstrates about 2 times of the runoff. Compared with granite or gneiss basins in Korea Peninsula, the experimental basin is characterized by a higher portion of percolation in water balance. And it is probably related to the highly permeable basaltic lavas in Jeju Island which are also overlain by porous volcanic soils.

• 한국해양학회지
• /
• v.26 no.3
• /
• pp.193-203
• /
• 1991

KODOS (Korea Deep ocean Study)-89 sediments, recovered from western part of Clarion-Clipperton fracture zone in north Pacific, show two distinctly colored layer zones: surface yellow brown layer (unit A) and subsurface dark brown layer (unit B), and roughly recognized as Quaternary and Tertiary in age, respectively. Geochemical characteristics are also different in those two units. Smectite, water, micronodule, and heavy metal contents are higher in unit B, while POC content is higher in unit A. High smectite and low POC contents in unit B are due to the longer formation period of smectite, almost decomposition of labile organic matter in unit B relative to unit A. High water content in unit B is caused by coarse fabric which results from higher content of spicules and spines. Additionally, stronger electrostatic repulsion force caused by high smectite content also supports high water content in unit B relative to unit A. Variations in heavy metal contents are closely related to the amount of micronodule, which has higher metal contents than that of sediment. Therefore, we conclude that the differences of geochemical characteristics in unit A and unit B are resulted from the different diagenetic durations of unit A and unit B.

• Journal of the Korean Geosynthetics Society
• /
• v.18 no.3
• /
• pp.33-44
• /
• 2019

Clinker layer is a stratum structure distributed in volcanic area such as Jeju Island. The clinker layers were formed in between the repetitive action of eruption and solidification of lava flows. Since the clinker layer contains a large amount of voids accompanied by the lava gas ejection process, there is a possibility of inducing overall stability of the ground due to the low stiffness and strength of the clinker layer. Therefore, in this study, site investigation was carried out at both ends of the 00 bridge where the clinker layers exist. And, based on the ground survey results, the behavior of shallow foundations was analyzed numerically. In addition, the improved shallow foundation behavior in grouting substitution using the chemical injection method of the clinker layer was compared with the shallow foundation behavior in the ground, and the grouting substitution efficiency of each layer was analyzed. As a result, the bearing capacity, the replacement efficiency and elastic settlement were different according to the presence or absence of the sediment layer. This is because the sediment layer has a lower stiffness and density than the clinker layer.

• Applied Chemistry for Engineering
• /
• v.33 no.3
• /
• pp.296-301
• /
• 2022

Due to the fact that zirconium based metal-organic frameworks (Zr-MOFs), such as UiO-66, have a large specific surface area and excellent selective adsorption capacity, Zr-MOFs are gaining attention as materials that can provide protection from the attack of chemical warfare agents in battleground. However, most of the metal-organic frameworks have an issue of selective adsorption capacity degraded by water molecules when exposed to the atmosphere, because of the weak metal-organic ligand bonds and the presence of voids. Therefore, polydimethylsiloxane (PDMS), a representative hydrophobic polymer material, was coated on the surface of UiO-66 to enhance the sustainability of the diisopropyl methylphosphonate (DIMP) sorption capacity in the battleground condition. Through the analysis of surface structure and organic functional group distribution of PDMS coated UiO-66, silicon was confirmed to be evenly coated. The contact angle increased by over 30° for the PDMS coated UiO-66, indicating that the hydrophobicity was improved. In addition, both the UiO-66 and PDMS coated UiO-66 were used as adsorbents for DIMP, a similar chemical warfare agent, to investigate the durability of adsorption capacity in a high humidity environment. The PDMS coated UiO-66 showed higher durability of adsorption capacity for 20 days than that of pristine UiO-66.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.31 no.3
• /
• pp.260-269
• /
• 1986

This experiment was conducted to investigate the effect of mulching materials on the emergence rate, root dry weight and grain weight of sesame using variety Poong Nyun Ggae and also their effects on physical properties of soil, evapotranspiration and weed growth on the respective plots were studied. The effect of soil water holding capacity at mulching with polyethylene film and straw increased 5.4%, 2.8% to non-mulched plot respectively. The maximum soil temperature was raised up to 4$^{\circ}C$ by applying clear film and was dropped down to 7$^{\circ}C$ by straw. The minimum soil temperature was raised up to 2$^{\circ}C$ by clear film and was dropped down to 3$^{\circ}C$ by straw. In the early stage, the soil physical properties of clear film mulching were better than those of non mulching, and so was in emergence rate. In the late stage, soil strength was high at non mulching, and soil porosity, soil aeration and water infiltration rate were high at film and straw mulchings. Total root dry weight was great at clear film mulching, and root dry weight was concentrated mainly in the upper 10 cm of soil profile. The amount of weeds collected was the least at black film mulching. There were of little difference in evapotranspiration among treatments. The grain yield of sesame was increased to 57% by polyethylene film and 25% by straw mulching.

• Journal of the Korean Geotechnical Society
• /
• v.25 no.11
• /
• pp.105-115
• /
• 2009

The Jeju sand was sampled from the beach in Jeju Island and its basic properties were analyzed. The cementation effect of Jeju coastal sediments was evaluated from in-situ tests such as SPT, CPT, and the Suspension-PS test. It was shown from test results that the Jeju sand has high extreme void ratios due to the angularity of grains and the intra-particle voids of hollow particles, similar to typical calcareous sands. From cone penetration test in the calibration chamber, it was found that the cone resistance($q_c$)-relative density($D_R$)-vertical effective stress(${\sigma}_v'$) relation of Jeju sand almost matches that of high compressible quartz sand. However, the $q_C-D_R-{\sigma}_v'$ correlation suggested for uncemented Jeju sand overestimates the relative density of coastal sediments of Jeju Island due to the cementation effect. From the analysis of the relation of cone resistance, N value, and small strain shear modulus measured in-situ, it seems reasonable to assume that the coastal sediment of Jeju Island is a naturally cemented one.