• Polymer(Korea)
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• v.36 no.6
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• pp.822-830
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• 2012

We used dipodal type bis[3-(trimethoxysilyl)propyl]amine (BTMA) silane coupling agent to modify silica nanoparticles to introduce secondary amino groups on the silica surface. These N-H groups were reacted with three different molecular weights (M.W. = 258, 575, and 700) of poly(ethylene glycol) diacrylates to introduce different attached layer thicknesses on the silica surface by Michael addition reaction. After Michael addition reaction, we used several analytical techniques such as fourier transform infrared spectroscopy (FTIR), elemental analysis (EA) and solid state $^{13}C$ cross-polarization magic angle spinning (CP/MAS) nuclear magnetic resonance spectroscopy to characterize introduced structures. We found almost complete Michael addition reaction of both two acrylate groups of PDGDA with N-H groups of BTMA modified silica to form ${\beta}$-amino acid esters. Between equimolar ratio of pure BTMA and pure PEGDA reaction, only one acrylate group of two acrylate groups of PEGDA reacted with N-H groups of pure BTMA to form ${\beta}$-amino acid ester and the other remaining acrylate group can be used to form a polymer later.

• Analytical Science and Technology
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• v.28 no.1
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• pp.40-46
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• 2015

Hydrochar has been generated from food waste via hydrothermal carbonization (HTC) reaction. As a solid product of HTC reaction, hydrochar has a great potential as an adsorbent of pollutants from the various media. The surface area and pore volumes are very important parameters to be served as an adsorbent. It requires an expensive equipment and consumes time to measure those parameter. Therefore, titration methods including iodine and methylene blue adsorption were evaluated to be correlated with that of BET analysis. Even though the absolute values of the computed surface area and pore volumes were not able to be matched directly, the patterns of change were successfully correlated. Among the reaction conditions, the reaction time and temperature at $230^{\circ}C$ for 4 h was determined as an optimization condition, which confirmed by titration method and BET analysis. Titration method for surface area and pore volumes computed by combination of iodine and methylene blue adsorbing values would be a simple and fast way of determining the optimization condition for hydrochar as an adsorbent produced by HTC reaction.

• Applied Chemistry for Engineering
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• v.17 no.5
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• pp.451-457
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• 2006

We synthesized phase pure CrN having surface areas up to $47m^2/g$ starting from $CrCl_{3}$ with $NH_{3}$. Thermal Gravimetric Analysis coupled with X-ray diffraction was carried out to identify solid state transition temperatures and the phase after each transition. In addition, the BET surface areas, pore size distributions, and crystalline diameters for the synthesized materials were analyzed. Space velocity influenced a little to the surface areas of the prepared materials, while heating rate did not. We believe it is due to the fast removal of reaction by-products from the system. Temperature programmed reduction results revealed that the CrN was hardly passivated by 1% $O_{2}$. Molecular nitrogen was detected from CrN at 700 and $950^{\circ}C$, which may be from lattice nitrogen. In temperature programmed oxidation with heating rate of 10 K/min in flowing air, oxidation started at or higher than $300^{\circ}C$ and resulting $Cr_{2}O_{3}$ phase was observed with XRD at around $800^{\circ}C$. However the oxidation was not completed even at $900^{\circ}C$. CrN catalysts were highly active for n-butane dehydrogenation reaction. Their activity is even higher than that of a commercial $Pt-Sn/Al_{2}O_{3}$ dehydrogenation catalyst in terms of volumetric reaction rate. However, CrN was not active in pyridine hydrodenitrogenation.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.7
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• pp.652-659
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• 2011

A computational system to predict flowfield and infrared signature in aircraft exhaust system is developed. As the first step, a virtual mission profile is considered and an engine is selected through a performance analysis. Then a nozzle that meets the requirement of each mission is designed. The internal flow in the exhaustion nozzle at the maximum thrust is analyzed using a state-of-the-art CFD code. In addition, a system to combine information of the skin temperature distribution of the nozzle and after-body surface with an infrared prediction code is developed. Finally, qualitative results for the infrared signature reduction design are obtained by investigating the infrared signature level under various conditions.

• Journal for History of Mathematics
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• v.21 no.3
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• pp.1-30
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• 2008

The success of Newton's Gravitational Theory has influenced the theory of capillarity, beginning in the early nineteenth century, by providing a major model of molecular attraction. He used the equation of the attraction of spheroids, which is expressed by second order partial differential equations, to utilize this analogy as the same kind of a particle's force, between gravitational, refractive force of light, and capillarity. The solution of the differential equation corresponds to the geometrical figure of the vessel and the contact angle which is made by the fluid. Unknown abstract functions $\varphi(f)$ represent interaction forces between molecules, giving their potential functions. By conducting several kinds of experimental conditions, it was found that the height of the ascending fluid in the tube is inversely proportional to the rayon of the tube or the distance of the plate. This model is an essential element in the theory of capillarity. Laplace has brought Newtonian mechanics to completion, which relates to the standard model of gravitational theory. Laplace-Young's equation of capillarity is applicable to minimal surfaces in mathematics, to surface tensional phenomena in physics, and to soap bubble experiments.

• Journal of Soil and Groundwater Environment
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• v.12 no.5
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• pp.73-85
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• 2007

In this study, the experiment of solid-phase microextraction (SPME) technique using GC/FID was conducted as a possible alternative to liquid-liquid extraction for the analysis of EGBE, DGBE, DBM and TGME in water, and also, an optimization condition of trace analysis for disel oxygenates including EGBE by the design of experiment (DOE) was described. Experiments used a fractional factorial design method followed by central composite design allowing optimization of a number of factors as well as statistical analysis of the results. The response surface analysis showed that the extraction efficiency could be represented by a second-order polynomial equation in which the salts concentration, extraction temperature, extraction time and sonication time are the major influences. Using DOE method, a new datadependent method was developed to improve the quantity of confidently analyzed disel oxygenates in water samples.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.25 no.4
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• pp.200-208
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• 1989

To the purpose of preparation for investigating aspect of material that not revealed by the light microscope and extending our knowledge in applicable field, a scanning acoustic microscope system of 200MHz was organized and appraised its performance with experiments. Professor N.CHUBACHI in Tohoku University in Sendai, Japan provided the ZnO transducer with lens. The system for transmitting and receiving ultrasonic pulses of 200nsec was organized with a rectangular audio wave generator for modulation of 200MHz carrier wave, gating system for transmitting and receiving, mixer for converting intermediate frequency, a directional coupler, ZnO transducer, radio frequency amplifiers. detecter and personal computer. The Scanning system was driven in micro steps with three stepping motors in the direction of x, y and z axes. The system was a reflecting type scanning acoustic microscope and the operation program processed graphics data from receiving echo intensities. Photograph of fish scale obtained by optical microscope was compared with its image by the scanning acoustic microscope organized here. The result was satisfiable.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.10
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• pp.779-787
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• 2013

The effects of various nozzle configurations on infrared signature are investigated for the purpose of analysing the infrared signature level of aircraft propulsion system. A virtual subsonic aircraft is selected and then a circular convergent nozzle, which meets the mission requirements, is designed. Convergent nozzles of different configurations are designed with different geometric profiles. Using a compressible Navier-Stokes-Fourier CFD code, an analysis of thermal flow field and nozzle surface temperature distribution is conducted. From the information of plume flow field and nozzle surface temperature distribution, IR signature of plume and nozzle surface is calculated through the narrow-band model and the RadThermIR code. Finally, qualitative information for IR signature reduction is obtained through the analysis of the effects of various nozzle configurations on IR signature.

• Journal of the Korean institute of surface engineering
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• v.27 no.2
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• pp.65-73
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• 1994

Effects of deposition parameter on the ionic conductivity and structural change of the Lithium borosili-cate solid electrolyte films, prepared by rf sputtering using 7$LI_2O-3B_2O_3-1SiO_2$ single phase target and also a mosaic target enriched with $LI_2O$, were analyzed by measuring AC impedance and IR absorption spectra for the films. Thed solid electrolyte film deposited from the single phase target exhibited very low ionic conductivi-ty of $10^{-10}{\Omega}^{-1}cm{-1}$ at room temperature, a result of low $Li^+$ ion content(7.52 at%) in the film. The $Li^+$ con-ductivity for the films deposited from the mosaic target, however, significantly increased to $10^{-7}{\Omega}^{-1}cm{-1}$ due to both an increased $Li^+$content (14.75 at %) and a structural change of the films. The increased ionic conduc-tivity of the film appears to be associated with an easiness of ionic mobility by structural change of glassy film from a some close packed network structure to a open one. These structural changes of film were found to be closely related to the increase in the peak intensity at~$960cm^{-1}$ of IR absorption spectra for the glassy films. With increasing either argon pressure from 3 to 21 mtorr or rf power from 2 to 3 W/$cm^2$, the $Li^+$ conduc-tivity for the films significantly increased to an order of $10^{-6}{\Omega}^{-1}cm{-1}$ due to an increase in openness of film structure, as confirmed by both an increase in the IR absorption peak intensity at ~$960cm^{-1}$ and a resultant reduction of activation energy for mobility of $Li^+$ ion.

• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.617-621
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• 2009

Zinc oxide (ZnO) nanorods were grown on the pre-oxidized silicon substrate with the assistance of Au and the fluorine-doped tin oxide (FTO) based on the catalysts by vapor-liquid-solid (VLS) synthesis. Two types of ZnO powder particle size, 20nm, $20{\mu}m$, were used as a source material, respectively The properties of the nanorods such as morphological characteristics, chemical composition and crystalline properties were examined by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX) and field-emission scanning electron microscope (FE-SEM). The particle size of ZnO source strongly affected the growth of ZnO nanostructures as well as the crystallographic structure. All the ZnO nanostructures are hexagonal and single crystal in nature. It is found that $1030^{\circ}C$ is a suitable optimum growth temperature and 20 nm is a optimum ZnO powder particle size. Nanorods were fabricated on the FTO deposition with large electronegativity and we found that the electric potential of nanorods rises as the ratio of current rises, there is direct relationship with the catalysts, Therefore, it was considered that Sn can be the alternative material of Au in the formation of ZnO nanostructures.