• Title/Summary/Keyword: 고체탄소

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Characteristics of Submerged and Solid-State Fermentations for Production of Arachidonic Acid Mortierella alpina (Arachidonic Acid 생산을 위한 Mortierella alpina 곰팡이의 심부 및 고체 발효 특성 연구)

  • Shin Hyung Tai;Lee Soo Won;Park Ki Moon;Song Jae Whan;Suh Dong Sang;Lee Jae Heung
    • KSBB Journal
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    • v.20 no.1 s.90
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    • pp.60-65
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    • 2005
  • The objective of this work was to evaluate a solid-state fermentation process for the practical production of arachidonic acid(AA) by Mortierella alpina ATCC 32222. In the present investigation, batch culture kinetics for both submerged- and solid-state fermentations was carried out at $25^{\circ}C$ to identify the relationship between growth and arachidonic acid (AA) production. Glucose and yeast extract were used in submerged fermentations by using flasks, while rice bran was used as a sole raw material in the other type of fermentations by using a series of Petri dishes. It was evident that a mixed-growth associated pattern existed between the two variables, irrespective of modes of fermentations. The effect of carbon to nitrogen (CfN) ratio on AA production in solid-state fermentation was studied in the range of 6.5 - 20. As a result, an optimum condition was found to be 6.5. Supplementary carbon source was not necessary to meet the optimum C/N ratio. Unlike the Previous results obtained by other researchers, a supplement of sodium glutamate up to $4\%$ (w/w) to the rice bran medium did not have a positive effect on the AA productivity. However, an increase in AA productivity was obtained with the rice bran medium supplemented with sesame oil.

Development of Combustion System for Solid Oxide Fuel Cell System (고체산화물 연료전지용 예혼합 연소시스템 개발)

  • Jo, Soonhye;Lee, Pilhyong;Cha, Chunloon;Hong, Seongweon;Hwang, Sangsoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.96.1-96.1
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    • 2011
  • Solid oxide fuel cells(SOFCs) can convert the chemical energy of fuel into electricity directly. With the rising fuel prices and stricter emission requirement, SOFCs have been widely recognized as a promising technology in the near future. In this study, lean premixed flame using the orifice swirl burner was analyzed numerically and experimentally. We used the program CHEMKIN and the GRI 3.0 chemical reaction mechanism for the calculation of burning velocity and adiabatic flame temperature to investigate the effects of equivalence ratio on the adiabatic flame temperature and burning velocity respectively. Burning velocity of hydrogen was calculated by CHEMKIN simulation was 325cm/s, which was faster than that of methane having 42 cm/s at the same equivalence ratio. Also Ansys Fluent was used so as to analysis the performance with alteration of swirl structure and orifice mixer structure. This experimental study focused on stability and emission characteristics and the influence of swirl and orifice mixer in Solid Oxide Fuel Cell Systme burner. The results show that the stable blue flame with different equivalence ratio. NOx was measured below 20 ppm from equivalence ratios 0.72 to 0.84 and CO which is a very important emission index in combustor was observed below 160 ppm under the same equivalence region.

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Voltage-Current Profiles of Hydrogen-Oxygen Mixture Gas at Polymer Electrolyte Interface (고체고분자전해질 계면에 접한 수소 산소 혼합 가스의 전압전류 특성)

  • Cha, Suk-Yeul;Song, Jung-Min;Lee, Woong-Moo
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.2
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    • pp.129-135
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    • 1996
  • Voltage-current profiles are measured when hydrogen-oxygen gas is in contact with solid polymer membrane ($Nafion^{(R)}$) as the electrolyte. The feed gas is prepared by mixing hydrogen and oxygen gas in various ratios. The carbon gas diffusion electrodes contacting the electrolyte are treated by platinum catalyst. The platinum surface is impregnated with a 5% $Nafion^{(R)}$ solution to ensure its good surface contact with the electrolyte. The constant voltage between anode and cathode was applied by a DC power supply. The results on the profiles show that the energy efficiency critically depends on the hydrogen concentration in $H_2/O_2$ mixture gas.

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A Study on the Suppression of Carbon Deposition in Solid Oxide Fuel Cells Through Methane Internal Reforming (메탄 내부개질 반응을 통한 고체산화물 연료전지의 탄소침적 억제에 관한 연구)

  • Kang, Yun-Hyeok;Lim, Sung-Kwang;Yoo, Yung-Sung;Park, Jin-Woo;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.5
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    • pp.473-481
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    • 2007
  • Compared to other types of fuel cells, SOFC has advantages like a wide output range and the direct use of hydrocarbon fuel without the process of external reforming. Particularly because the direct use of fuel without reforming reaction is closely linked to overall system efficiency, it is a very attractive advantage. We tried the operation with methane. However, although methane has a small number of carbons compared to other hydrocarbon fuels, our experiment found the deposition of carbon on the surface of the SOFC electrode. To overcome the problem, we tried the operation through activating internal reforming. The reason that internal reforming was possible was that SOFC runs at high temperature compared to other fuel cells and its electrode is made of Ni, which functions as a catalyst favorable for steam reforming.

A Parametric Study on Double-Slit-Type Rupture Disc of Pulse Separation Device (펄스분리장치의 이중 슬릿형 파열판 매개변수 연구)

  • Han, Houk-Seop;Cho, Won-Man;Lee, Won-Bok;Koo, Song-Hoe;Lee, Bang-Eop
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.5
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    • pp.101-110
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    • 2010
  • Dual pulse rocket motor is a solid motor with two grains separated by a bulkhead and rupture disc. The elasto-plastic explicit dynamic analysis for the rupture disc was conducted by finite element method. The effect of the slit geometry of a rupture disc was parametrically analyzed in terms of rupture time and shape. The results can be used to control the rupture pressure by changing the slit geometry of rupture disc.

A Parametric Study on Rupture Disc with Radial Slit of Pulse Separation Device (원주방향 슬릿을 가진 파열판의 매개변수 연구)

  • Han, Houk-Seop;Cho, Won-Man;Lee, Won-Bok;Koo, Song-Hoe;Lee, Bang-Eop
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.261-264
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    • 2010
  • Dual Pulse Rocket Motor is a solid rocket motor with two grains separated by a bulkhead and rupture disc. The elasto-plastic explicit dynamic analysis of rupture disc was conducted by the finite element method. The effect of the slit geometry of rupture disc with radial slit was parametrically analyzed in terms of rupture time and shape. The results can be used to control the rupture pressure by changing the slit geometry of rupture disc.

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A Parametric Sturdy on Double Slit Type Rupture Disc of Pulse Separation Device (펄스분리장치의 이중 슬릿형 파열판 매개변수 연구)

  • Han, Houk-Seop;Cho, Won-Man;Koo, Song-Hoe;Lee, Bang-Eop
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.05a
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    • pp.105-112
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    • 2010
  • Dual Pulse Rocket Motor is a solid rocket motor with two grains separated by a bulkhead and rupture disc. The elasto-plastic explicit dynamic analysis of rupture disc was conducted by finite element method. The effect of the slit geometry of a rupture disc was analyzed for rupture time and shape by the parametric study. The results can be used to control the rupture pressure by the change the slit geometry of a rupture disc.

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Carbothermal Reduction of Oxide Powder Prepared from Waste WC/Co Hardmetal by Solid Carbon (WC/Co 초경 스크랩 산화물의 고체탄소에 의한 환원/침탄)

  • Lee Gil-Geun;Ha Gook-Hyun
    • Journal of Powder Materials
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    • v.12 no.2 s.49
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    • pp.112-116
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    • 2005
  • In the present study, the focus is on the analysis of carbothermal reduction of oxide powder prepared from waste WC/Co hardmetal by solid carbon under a stream of argon for the recycling of the WC/Co hard-metal. The oxide powder was prepared by the combination of the oxidation and crushing processes using the waste $WC-8 wt.\%Co$ hardmetal as the raw material. This oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and gases discharge of the mixture during carbothermal reduction was analysed using XRD and gas analyzer. The oxide powder prepared from waste $WC-8wt.\%Co$ hardmetal has a mixture of $WO_{3} and CoWO_{4}$. This oxide powder reduced at about $850^{\circ}C$, formed tungsten carbides at about $950^{\circ}C$, and then fully transformed to a mixed state of tungsten carbide (WC) and cobalt at about $1100^{\circ}C$ by solid carbon under a stream of argon. The WC/Co composite powder synthesized at $1000^{\circ}C$ for 6 hours from oxide powder of waste $WC-8wt.\%Co$ hardmetal has an average particle size of $0.3 {\mu}m$.

Analysis of Methane Conversion Rate and Selectivity of Methane Pyrolysis Reaction in Ceramic Tube According to Temperature and Reaction Time (온도와 반응 시간에 따른 세라믹 튜브 내 메탄 열분해 반응의 메탄 전환율과 선택도 분석)

  • LEE, DONGKEUN;KIM, YOUNGSANG;AHN, KOOKYOUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.1
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    • pp.1-7
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    • 2022
  • Interest in hydrogen productions that do not emit carbon dioxide and can produce hydrogen at a low price is increasing. Reforming and electrolysis are widely used, but they have limitations, such as carbon dioxide problems and costs. The methane can be decomposed as hydrogen and solid carbon without carbon dioxide emission at high temperatures. In this research, the methane pyrolysis experiment was conducted at 1,200℃ and 1,400℃ in a ceramic tube. The composition of the produced gas was measured by gas chromatography before carbon blocked the tube. The methane conversion rate and hydrogen selectivity were calculated based on the results. The hydrogen selectivity was derived as 60% and 55% at the highest point at 1,200℃ and 1,400℃, respectively. The produced solid carbon was expected to be carbon black and was analyzed using scanning electron microscope.

Numerical Modeling of Anodic Reaction of Carbon-Rich Fuel at Solid Oxide Fuel Cell (탄소연료를 이용하는 고체 산화물 연료전지의 연료극 반응 수치해석)

  • Lim, Ho;Kim, Jong-Pil;Song, Ju-Hun;Chang, Young-June;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.19 no.3
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    • pp.188-194
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    • 2010
  • Direct Carbon Fuel Cell(DCFC), unlike gas turbines or engines, is a kind of fuel cell which directly generates electricity by electrochemical reaction from a carbon fuel. The advantages of DCFC are higher efficiency and lower emission in comparison with existing power generation facilities. In this study, the effects of CO and $CO_2$ on theoretical potential are examined using the thermodynamic equilibrium method, and the dependence of product on operating temperature is examined via two dimensional CFD method. As a result, when the reaction of CO production (Boudouard reaction) considered, theoretical potential is higher than that in only $CO_2$ reactions, and its value increases as temperature increases. Two dimensional results of computational fluid dynamics(CFD) confirm that the Boudouard reaction becomes more important to be considered as temperature increases and inert gas affects the equilibrium composition of the Boudouard reaction.