• Proceedings of the Materials Research Society of Korea Conference
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• 2007.05a
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• pp.39.2-39.2
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• 2007

• Proceedings of the Korean Nuclear Society Conference
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• 1999.10a
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• pp.379.2-379
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• 1999

• Elastomers and Composites
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• v.43 no.4
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• pp.281-287
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• 2008

Using solid state $^{13}C$ NMR, polybutadiene rubber vulcanizates were qualitatively and quantitatively analyzed. In the filled conventional system of BR vulcanizate accelerated with TBBS, addition to the olefinic double bond and substitution in the $\alpha$ position to the double bond occurred simultaneously. Also the latter $\alpha$ substitution reaction was faster than the former addition reaction at initial reaction time. In addition, it was suggested that double bond-addition-polysulfide structures might be modified into 5-membered and 6-membered cyclic structures in overcure time. These chain modifications were correlated with the decrease in the chemical crosslink density in overcure time.

• Journal of the Korean Chemical Society
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• v.17 no.6
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• pp.450-454
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• 1973

The afterpolymerization and depolymerization of poly-${\varepsilon}$-caproamide in solid state have been studied under two different reaction conditions, nitrogen flow and sealed state. The degree of polymerization ($\bar{P}$) of nylon 6 increased with the increase in reaction time and temperature, and then reacted finally an equilibrium. In the presence of oxygen, $\bar{P}$ decreased by increasing the reaction time due to the oxidation reaction. Under certain reaction condition, the change of $\bar{P}$ for different initial degree of polymerization ($\bar{P}_0$) tendered toward unity in equilibrium.

• The Journal of Natural Sciences
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• v.1
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• pp.33-45
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• 1987

$BaCO_3$ 와 다양한 입자크기의 $TiO_2$ 의 고체상태 반응을 산소 ( 혹은 공기 ) 와 이산화탄소 중에서 열중량 분석법 (TG) 과 시차 열분석법 (DTA) 를 이용하여 반응속도론 및 반응기구를 조사하였다. 중간생성물과 최종생성물의 확인은 X-ray 회절 분석법 (XRD) 을 이용하였다. $TiO_2$ 의 반응성은 입자의 크기가 $0.15\mum$이하일 때 현저히 증가하였다. 반응초기에 $BaTiO_3$ 는 반응물의 접촉표면에서 생기기 시작하며 반응의 진행과정은 Jander 에 따라 확산조절과정이 된다. 반응과정에서 BaO-$TiO_2$ 의 상평형도에 기술된 화합물들이 중간물질로써 나타난다. 공기중에서는 상당한 양의 $Ba_2$$TiO_4$ 가 생성되지만 $CO_2$ 의 분위기에서는 약 $1100^{\circ}C$까지 억제된다. 이 온도는 열역학적 계산치인 $1060\pm$ $50^{\circ}C$와 잘 일치하고 있다. 확산과정의 활성화 에너지 값은 공기중에서는 56.4Kcal/mol 이었으며 이산화탄소의 경우에서는 79.6Kacl/mol 이었다.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.04a
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• pp.112-115
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• 2011

본 연구는 고체가연물의 초기 점화 및 화재성장과정에서의 발열량을 대형화재발열량계(large scale fire calorimeter)를 이용하여 정량적으로 측정하고 화재발생 초기에 화재성장특성 파악하고자 한다. 실험에 적용된 고체가연물 화재는 단일/이중 목재화재, 폴리프로필렌 소재의 쿠션화재, 목재 및 폴리프로필렌 소재의 카페트 화재이며 화재발달 단계에서의 화재성장특성을 시간 제곱 화재성장 시나리오와 비교분석하고 고체 기본가연물의 화재성장과정을 이해한다. 구획조건이 화재발열량에 미치는 영향을 파악하기 위하여 자유연소상태와 ISO-9705 화재실 내부에서 화재실험이 수행되었으며 화재성장특성과 최대발열량등을 비교하였다. 본 연구는 설계화재와 화재시나리오를 설정하는데 있어서 고체가연물의 발열량 데이터 및 화재성장에 대한 정보를 제공하고 공간조건에 따른 발열량 측정데이터의 신뢰성 분석을 위한 기초연구로 활용될 수 있다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.05a
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• pp.203-206
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• 2008

In this study, we focused on development of the adhesive insulator using the case for solid rocket motors. Material of insulator used unvulcanized rubber based on EPDM/kevlar. In case of front insulator, preforms was made by using hot press molding, and then modified nylon film was inserted between two preforms for boots manufacturing. Rear insulator included cylinder part was embodied by only one mold with special designed and manufactured shape in the process. Boots part of rear insulator was obtained by cutting machine with hard-metal cemented carbide.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.6
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• pp.505-511
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• 2015

Solid oxide fuel cell operate at high temperature ($800{\sim}1000^{\circ}C$). High temperature have an advantage of system efficiency, but a weak durability. In this study, linear state space controller is designed to handle the temperature of solid oxide fuel cell system for proper thermal management. System model is developed under simulink environment with Thermolib$^{(R)}$. Since the thermally optimal system integration improves efficiency, very complicated thermal integration approach is selected for system integration. It shows that temperature response of fuel cell stack and catalytic burner are operated at severe non-linearity. To control non-linear temperature response of SOFC system, gain scheduled linear quadratic regulator is designed. Results shows that the temperature response of stack and catalytic burner follows the command over whole ranges of operations.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.2
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• pp.332-341
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• 1998

Reaction kinetics for the solid - state reaction of ${\alpha}-Al_2O_3$with amorphous $SiO_2$to produce mullite ($3Al_2O_3;{cdot};2SiO_2$) was studied in the temperature range of 1450~$1480^{\circ}C$. Rate of kinetic reaction were determined by using $SiO_2$- coated $Al_2O_3$ compact containing 28.16 wt.% $SiO_2$and heating the reactant mixtures in MgO at definite temperature for various times. Amount of products and unreacted reactants were determined by X-ray diffractometry. Data from the volume fraction and ratio of peak intensities of mullite indicated that the reaction of ${\alpha}-;Al_2O_3$ with $SiO_2$to form $3Al_2O_3\;{\cdot}\;2SiO_2$ start between 1450 and $1480^{\circ}C$. The activation energy for solid-state reaction was determined by using the Arrhenius equation; The activation energy was 31.9 kJ/mol.

• Polymer(Korea)
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• v.29 no.6
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• pp.549-556
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• 2005

Effects of the dimensionless variables on the heat transport phenomena in the extrusion process of a single screw extruder have been studied numerically. Based on the understanding of the solids conveying related to the geometrical structure and characteristics of the screw, the heat balance equation for the solids conveying zone was established and normalized. The finite volume method and power-law scheme were applied to derive a discretized equation and the equation was solved using the alternating direction iterative method with relaxation. Effects of the dimensionless parameters, Biot and Peclet numbers, that define the heat transfer characteristics of the solids conveying zone have been investigated with respect to the temperature of the feeding zone and the length of the solids conveying zone. As the Biot number is increased, the heat loss by cooling dominates to decrease the temperature of the barrel but it has little effects on the temperature of the solids bed and the length of the solids conveying zone. On the other hand, if the Peclet number is increased, the convection term dominates to decrease the temperature of the solids bed and it results in an increase in the length of the solids conveying zone.