• Title/Summary/Keyword: 고온상

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Zircon Morphology and Petrochemistry of Mesozoic Plutonic rocks in Seonsan Area, Korea (선산 지역 중생대 심성암류의 저어콘 헝태 및 암석화학)

  • 이윤종;박순자;장용성;정원우;김중욱;황상구;윤성효
    • The Journal of the Petrological Society of Korea
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    • v.13 no.2
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    • pp.81-102
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    • 2004
  • The plutonic rocks in Seonsan area are divided into dioritic-syenitic rock, gneissose granite, biotite granite and fine grained biotite granite. These rocks intruded into the Pre-cambrian metamorphic complex and are all covered by the Cretaceous Nakdong formation. According to modal minerals, dioritic-syenitic rock corresponds to quartz monzonite, granodiorite, tonalite fields, whereas all the other plutonic rocks fall in granite field. Petrochemically the dioritic-syenitic rock is lower in SiO$_2$ content, differentiation index and Larsen index than all the other plutonic rocks. About the zircon morphology, dioritic-syenitic rock shows (100) dominant type but other granitic rocks exhibit mixed types between (100) and (110) type. The dioritic-syenitic rock could be crystallized in higher temperature than the other plutonic rocks. The plutonic rocks correspond to calc-alkaline rock series, and belong to I-type granite and mostly magnetite-series in magmatic origin. In plutonic processes, the dioritic-syenitic rock with 5kb vapor pressure could intrude into the metamorphic batement at 17km deep below the surface. Later the gneissose granite with lower 3kb vapor pressure could intrude at 10km deep. Sequentially the biotite granite with 0.7kb could intrude at 2km deep. Finally the fine grained biotite granite with 3kb vapor pressure could intrude at 10km deep.

Induction Heating of Cylinderical MoSi2-based Susceptor (실린더형 MoSi2계 발열체의 유도가열 적용)

  • Lee, Sung-Chul;Kim, Yo Han;Myung, Jae-ha;Kim, Bae-Yeon
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.553-558
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    • 2019
  • In present study, the cylindrical susceptor by the slip casting method was designed to apply high-temperature induction heating by using $(Mo,W)Si_2$ ceramics. $MoSi_2$-based materials were synthesized by SHS (Self-propagating High-temperature Synthesis) method. The phase and crystal structure of $MoSi_2$-based materials were confirmed by XRD analysis. The shape of cylindrical mold was synthesized for various thickness by using the slip casting method. Finally, the susceptor for induction heating was processed by sintering and heat treatment to form $SiO_2$ layer, which was confirmed on the surface of susceptor by SEM/EDS analysis. To evaluate the heating performance of $(Mo,W)Si_2$ cylinder susceptor, we measured the maximum surface temperature and heating rate in comparison with the rod heating element under constantly applied power. The induction heating of the $(Mo,W)Si_2$ cylinder showed excellent heating performance, reaches the maximum temperature of $1457^{\circ}C$, with the average heating rate of $19^{\circ}C/s$ at 2 kW

A Study on the Evaluation of Adsorption Characteristics of VOCs on TiO2 and Al2O3 and Investigation of the Thermal Durability by Molding Various Structures (TiO2와 Al2O3의 기상 VOCs 흡착 특성 평가 및 다양한 구조체로의 성형을 통한 열적 내구성 확보에 관한 연구)

  • Hwang, In-Hyuck;Lee, Sang Moon;Kim, Sung Su
    • Clean Technology
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    • v.24 no.4
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    • pp.280-286
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    • 2018
  • In this study, the adsorption performance of vapor phase VOCs under dry conditions was evaluated by using two metal oxides, $TiO_2$ powder and $Al_2O_3$ powder. BET analysis and ammonia in-situ FT-IR analysis were used to analyze specific surface area and surface acid site. As a result, $TiO_2$ powder and $Al_2O_3$ powder had a specific surface area of $317.6m^2\;g^{-1}$ and $64m^2\;g^{-1}$, respectively. In the case of $TiO_2$ powder, many acid sites were observed on the surface. As a result of evaluating the vapor phase VOCs adsorption performance using two metal oxide powders, $TiO_2$ powder having a relatively large specific surface area and a large number of acid sites exhibited relatively good adsorption performance. In particular, it is considered that the specific surface area directly affects the adsorption performance, and further study on the effect of the acid site is required. Based on the $TiO_2$ exhibited excellent adsorption performance, it manufactured into various forms of honeycomb, hollow fiber and disc. As a result, the adsorption performance was lower than that of the powder, but it is advantageous in view of applicability. In addition, it was confirmed that the disc adsorbent having excellent thermal durability due to the characteristics of the manufacturing process stably maintains adsorption performance even at a high temperature desorption process several times.

Characteristics of Gwanbuk-ri remains, Buyeo, inferred from the analysis of iron artifacts from District "Na" (부여 관북리 유적 "나" 지구 출토 제철유물의 분석을 통한 제철유적의 성격 추론)

  • Hong, Ju-Hyun;Han, Song-I;Kim, So-Jin;Han, Woo-Rim;Jo, Nam-Cheol
    • Korean Journal of Heritage: History & Science
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    • v.50 no.1
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    • pp.4-17
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    • 2017
  • In this research, the chemical composition of the iron artifacts from the late 6th-century to early 7thcentury Baekje remains in Gwanbuk-ri, Buyeo, specifically of the nine iron artifacts including slags, furnace walls and ingot iron excavated in the District "Na", were examined by observing their chemical compounds and microstructures. As a result, GB1 and GB6 were determined to be proto-reduction lumps whereas GB2, GB3, GB4 and GB5 were determined to be tempered slags, respectively. Also, he furnace wall GB7 were containing mullite and cristobalite, which are high temperature index minerals, The extrusion temperature was found out to be about $1200{\sim}1300^{\circ}C$, and it is most likely that the smelting temperature in the furnace was in that temperature range. GB8 ingot iron was determined to be a forged ironware. This ingot iron was an intermediary product for making ironware and its nonmetallic inclusions displayed similar microstructure and contents compared to the forged iron. Because of the existence of proto-reduction lumps and forged iron, the iron making facility located in District "Na" most likely had a small-scale iron making facility that handled iron bloom smelting and refining processes.

Properties of quasi-noncombustible ultra-lightweight geopolymer (준불연 초경량 지오폴리머의 물성)

  • Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.3
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    • pp.132-139
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    • 2019
  • EPS (expanded polystyrene) is one of the most used building materials for insulation that is favored by its excellent heat insulation, economical efficiency and lightweight characteristics. However, EPS is vulnerable to the fire and producing large amount of toxic gases in case of fire. Therefore, ultra-lightweight geopolymer which can replace EPS is fabricated by using IGCC (integrated gasification combined cycle) fused slag and Si sludge as raw materials and the possibility of replacement on ultra-lightweight geopolymer for EPS as an insulation building material was evaluated in this study. Ultra-lightweight geopolymer can be fabricated with the pulverized IGCC fused slag having low carbon content and density, compressive strength, thermal conductivity were $0.064g/cm^3$, 0.04 MPa, and 0.072 W/mK, respectively. The thermal conductivity of ultra-lightweight geopolymer is 1.5~2.0 times higher than that of EPS suggested in the KS M 3808; however, the thermal conductivity value of geopolymer is meaningful and competitive to that of EPS in the market. Therefore, ultralightweight geopolymer can be applicable to the building material for thermal insulation purpose and have an enough possibility to replace EPS in the future because it is not only much safer than EPS in case of fire but also it can be fabricate by using waste materials from the industry.

Hexagonal shape Si crystal grown by mixed-source HVPE method (혼합소스 HVPE 방법에 의해 성장된 육각형 Si 결정)

  • Lee, Gang Seok;Kim, Kyoung Hwa;Park, Jung Hyun;Kim, So Yoon;Lee, Ha Young;Ahn, Hyung Soo;Lee, Jae Hak;Chun, Young Tea;Yang, Min;Yi, Sam Nyung;Jeon, Injun;Cho, Chae Ryong;Kim, Suck-Whan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.3
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    • pp.103-111
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    • 2021
  • Hexagonal shape Si crystals were grown by the mixed-source hydride vapor phase epitaxy (HVPE) method of mixing solid materials such as Si, Al and Ga. In the newly designed atmospheric pressure mixed-source HVPE method, nuclei are formed by the interaction between GaCln, AlCln and SiCln gases at a high temperature of 1200℃. In addition, it is designed to generate a precursor gas with a high partial pressure due to the rapid reaction of Si and HCl gas. The properties of hexagonal Si crystals were investigated through scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), high-resolution X-ray diffraction (HR-XRD), and Raman spectrum. From these results, it is expected to be applied as a new material in the Si industry.

Preparation of NH4+-β"-alumina as a Protonic Solid Electrolyte by Ion Exchange Reaction (이온교환반응에 의한 양성자 고체 전해질 NH4+-β"-alumina의 제조)

  • Lee, Jun-Hee;Han, Choon-Soo;Lee, Sung-Tae;Lee, Ki-Moon;Lee, Dae-Han;Lim, Sung-Ki
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.255-260
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    • 2011
  • $NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina which is expected to an inorganic solid electrolyte of high temperature polymer electrolyte membrane fuel cells (PEMFC) was prepared by ion-exchange reaction of $K^{+}-{\beta}^{{\prime}{\prime}}$-alumina pellet with $NH_4NO_3$ aqueous solution and molten $NH_4NO_3$ salts as an ion-exchange medium in the autoclave and the heating mentle reaction. In the autoclave reaction, the concentrations of $NH_4NO_3$ solution was chosen at 5 and 10 M. Each ion-exchange reaction was carried out at 130, 150, 170, and $200^{\circ}C$ for 2, 4, 6 and 8 h. In the heating mentle reaction, ion-exchange was performed at $200^{\circ}C$ for 2, 4, 6 and 8 h with molten $NH_4NO_3$ salts. In order to determine the effect of reaction times, each ion-exchange reaction was repeated 3 times. The phase stability and the ion-exchange rate of $NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina were analyzed by XRD and ICP.

Design and Implementation K-Band EWRG Transceiver for High-Resolution Rainfall Observation (고해상도 강수 관측을 위한 K-대역 전파강수계 송수신기 설계 및 구현)

  • Choi, Jeong-Ho;Lim, Sang-Hun;Park, Hyeong-Sam;Lee, Bae-Kyu
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.24 no.5
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    • pp.646-654
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    • 2020
  • This paper is to develop an electromagnetic wave-based sensor that can measure the spatial distribution of precipitation, and to a electromagnetic wave rain gauge (hereinafter, "EWRG") capable of simultaneously measuring rainfall, snowfall, and wind field, which are the core of heavy rain observation. Through this study, the LFM transmission and reception signals were theoretically analyzed. In addition, In order to develop a radar transceiver, LFM transceiver design and simulation were conducted. In this paper, we developed a K-BAND pulse-driven 6W SSPA(Solid State Power Amplifiers) transceiver using a small HMIC(Hybrid Microwave Integrated Circuit). It has more than 6W of output power and less than 5dB of receiving NF(Noise Figure) with short duty of 1% in high temperature environment of 65 degrees. The manufactured module emits LFM and Square Pulse waveform with the built-in waveform generator, and the receiver has more than 40dB of gain. The transceiver developed in this paper can be applied to the other small weather radar.

Au-Ag-bearing Ore Mineralization at the Geochang Hydrothermal Vein Deposit (거창 열수 맥상광상의 함 금-은 광화작용)

  • Hong, Seok Jin;Lee, Sunjin;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.55 no.2
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    • pp.171-181
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    • 2022
  • The Geochang Au-Ag deposit is located within the Yeongnam Massif. Within the area a number of hydrothermal quartz and calcite veins were formed by narrow open-space filling of parallel and subparallel fractures in the granitic gneiss and/or gneissic granite. Mineral paragenesis can be divided into two stages (stage I, ore-bearing quartz vein; stage II, barren calcite vein) by major tectonic fracturing. Stage I, at which the precipitation of major ore minerals occurred, is further divided into three substages (early, middle and late) with paragenetic time based on minor fractures and discernible mineral assemblages: early, marked by deposition of pyrite with minor pyrrhotite and arsenopyrite; middle, characterized by introduction of electrum and base-metal sulfides with minor sulfosalts; late, marked by hematite with base-metal sulfides. Fluid inclusion data show that stage I ore mineralization was deposited between initial high temperatures (≥380℃ ) and later lower temperatures (≤210℃ ) from H2O-CO2-NaCl fluids with salinities between 7.0 to 0.7 equiv. wt. % NaCl of Geochang hydrothermal system. The relationship between salinity and homogenization temperature indicates a complex history of boiling, fluid unmixing (CO2 effervescence), cooling and dilution via influx of cooler, more dilute meteoric waters over the temperature range ≥380℃ to ≤210℃. Changes in stage I vein mineralogy reflect decreasing temperature and fugacity of sulfur by evolution of the Geochang hydrothermal system with increasing paragenetic time. The Geochang deposit may represents a mesothermal gold-silver deposit.

Effect of Frost Injury in Harvest Season and Temperature Condition of Orchard on Storage Characteristics of Persimmon (Diospyros kaki 'Fuyu') Fruit (단감 '부유' 과실의 저장특성에 미치는 수확기 동상해 및 과수원 온도조건의 영향)

  • Kwack, Y.B.;Kim, S.H.;Ahn, K.H.;Lee, C.H.;Kang, S.K.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.23 no.1
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    • pp.67-80
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    • 2021
  • We analyzed the effect of planting site (elevation: high, middle, low) and temperature condition of orchard on the frost injury occurrence and storage characteristics of persimmon (Diospyros kaki cv. 'Fuyu) fruits under an early fall frost at two orchards, Changwon (A) and Changnyeong (B), Gyeongsangnam-do Korea. Also, the fruits picked at Nov. 5 and Nov. 20 were MA stored to investigate the quality and chilling injury of fruits. On 2-way factor analysis, both planting elevation and orchard factor had not a significant effect on fruit characteristics (weight, firmness, soluble solid), while planting elevation factor did on the skin color (hunter 'a')(p<0.05). A fruit skin coloration at orchard A was faster than that at orchard B. At low elevation of orchard B, 2% fruits were frost injured at harvest season. On LDPE film MA storage with the fruits harvested at Nov. 5 and Nov. 20, the fruits at orchard A had higher fruit firmness than those of orchard B during storage. In addition, the 73% (orchard A) and 85%(orchard B) fruits harvested at Nov. 5 showed no chilling injury 80 days after storage. However, At harvest of Nov, 20 (after incidence of frost), only the 14% fruits of orchard B had no the chilling disorder 80 days after storage, even though 76% fruits at orchard A did.