• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.200-204
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• 2008

The curing kinetics of diglycidyl ether of bisphenol F (DGEBF) with an asymmetric cycloaliphatic amine curing agent were examined by thermal analysis in both isothermal and dynamic curing conditions. From the residual curing of the samples partially cured in isothermal condition and from the dynamic curing with various heating rates, it was found that there exist two kinds of reactions such as at low temperature and at high temperature regions. It was thus also found that the cure parameters obtained from the isothermal curing kinetic model hardly estimate experimental results for a degree of cure larger than 0.6. The activation energies and frequency factors of these two kinds of reactions were obtained from the dynamic curing experiments with various heating rates. From the curing analysis, it was verified that the total cure kinetics for low degrees of cure is dominated by the cure reaction in the low temperature region.

• Journal of IKEEE
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• v.15 no.4
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• pp.313-318
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• 2011

The effects of external continuous wave optical injection on spectral comb of a 10 GHz harmonically mode-locked semiconductor fiber ring laser have been studied. Greater than 40 dB spectral deeps in the spectral comb and greater than 30 dB reduction of supermode beating noise are achieved by injecting coherent light with ~ 100 KHz spectral width. To examine the possibility of using a low-cost seed source, we replace the seed source by a DFB laser with ~ 10 MHz spectral width. It shows similar spectral deeps, however supermode beating noise enhancement, rather than reduction, is observed.

• The Journal of the Acoustical Society of Korea
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• v.15 no.6
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• pp.52-58
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• 1996

Using the acoustic resonances and oscillatory pulsations considered as the branch of wave technologies, the concept of the acoustic resonance diffusers for waste water treatment which maximize the oxygen transfer efficiency in gas-liquid two phase medium have been proposed, and studies for the principles and performance tests were accomplished. Besides, the design concepts for the low pressure Helmholtz resonator, cylinder and annular type reflection resonator and combined type resonance system have been implemented. The acoustic resonance energy which can speed up the mass transfer process increase the oxygen transfer efficiency, and periodic pulsations generated from the instability of air jet from nozzle make very small air bubbles. Then, the annular type jet resonator(AJR) applying these two principles successfully was evalulated as the most promising device and also the efficiency showing $20{\sim}30%$ better than conventional diffusers has been verified experimentally.

• Journal of the Korean Chemical Society
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• v.35 no.6
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• pp.636-644
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• 1991

The cationic polymerization of substituted oxethanes which have pendant energetic groups such as methoxy, azido, and nitrato are investigated theoretically using the semiempirical MINDO/3, MNDO, and AM1 methods. The nucleophilicity and basicity of substituted oxethanes can be explained by the negative charge on oxygen atom of oxetanes. The reactivity of propagation in the polymerization of oxetanes can be represented by the positive charge on carbon atom and the low LUMO energy of active species of oxetanes. The reaction of the energetic cyclic oxonium ion forms to the open chain carbenium ion forms is expected by computational stability energy of the oxonium and carbenium ion (about 10~20 kcal/mole) favoring the carbenium ion. The relative equilibrium concentration of cyclic oxonium and open carbenium ions is found to be a major determinant of mechanism, owing to the rapid equilibrium of these cation forms and the expectation based on clauclation that the prepolymer propagation step SN1 mechanism will be at least as fast as that for SN2 mechanism.

• Applied Chemistry for Engineering
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• v.21 no.3
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• pp.278-283
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• 2010

The cationic polymerization of oxolane high explosives which have pendant explosive groups such as azido, nitrato and hydrazino is investigated theoretically using the semiempirical MINDO/3, MNDO and AM1 methods. The nucleophilicity and basicity of oxolane high explosives can be explained by the negative charge on oxygen atom of oxolane. The reactivity of propagation in the polymerization of oxolane can be represented by the positive charge on carbon atom and the low LUMO energy of active species of oxolane. The reaction of the oxolane high explosives in oxonium ion form to the open chain carbenium ion form is expected by computational stability energy (17.950~30.197 kcal/mol) of the oxonium ion and carbenium ion favoring the carbenium ion. The relative equilibrium concentration of cyclic oxonium ion and carbenium ion is found to be a major determinant of mechanism, owing to the rapid equilibrium of these catoinic forms. Based on calculation, in the prepolymer propagation step, $S_N1$ mechanism will be at least as fast as that for $S_N2$ mechanism.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.11a
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• pp.463-466
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• 2008

The weapon systems with a liquid propulsion engine have been used for various purposes and demands of the liquid fuel with variety of properties for its operational purposes and environment. The cyclic hydrocarbons including norbornane or dicyclopentane structures have many applications to the guided weapon systems due to the high density and high energy characteristics, also efforts have been given in many fields. In this study, the cyclic hydrocarbons that we designed and fabricated were investigated to obtain tendency on the structures.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2014.05a
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• pp.130-131
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• 2014

시맨틱 웹은 1998년 웹의 창시자인 Tim Berners Lee가 제안을 한 웹 기술로써 인간의 언어를 이해하고 인간과 쉽게 의사소통이 가능한 네트워크를 말한다. 즉 컴퓨터 스스로 웹에 연결된 정보의 의미를 인식하고 사용자가 필요로 하는 정보를 검색하며 검색된 정보에서 지식을 유추할 수 있는 기능을 제공하는 지능형 웹 환경이다. 이런 시맨틱 웹 개념을 적용한 사례로는 네이버 시맨틱 웹 영화검색 이있다. 본 논문에서는 네이버 시맨틱 웹 영화검색 시스템을 벤치마킹한 도서검색 서비스 설계를 제안하고자 한다. 본 도서검색 서비스는 온톨로지 개념을 적용하여 도서와 관련된 검색 카테고리를 설정하며, 간단한 시나리오는 다음과 같다. 한 권의 책을 검색하면 해당 책과 연관된 첫 번째 카테고리로 출판사, 제작한 년도, 저자, 장르, 관련 검색 도서 등의 데이터들이 상단에 제시된다. 제시된 카테고리에서 임의의 항목을 선택하면 그 하단 공백에 선택된 항목과 연관된 카테고리에 해당하는 항목들이 제시된다. 예를 들어, 출판사를 선택한다면 해당 출판사에서 출간된 도서들이 하단 공백에 열거가 되고 상단 두 번째 카테고리에 원작국가, 저자 관련 책, 수상정보, 공동 집필자, 책을 원작으로 확장된 컨텐츠 등 또 다른 카테고리가 우측으로 생성이 되며 선택을 할 수 있게 된다. 본 논문에서 제안하는 시맨틱 웹 기반 도서검색 서비스는 사용자가 검색하고자 하는 정보를 보다 효율적이고 사용자 중심에서 제공할 수 있다고 사료된다.

• Explosives and Blasting
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• v.38 no.1
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• pp.30-37
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• 2020

In this study the split ring (SR) test was investigated for its applicability to the measurement of the tensile strength of rock specimen of NX size. The concept of the SR test is the same as the half ring (HR) test (Choi et al., 2019) except that the expected fracture plane is perpendicular to the loading direction. Because of this perpendicularity, however, it was believed that the SR test could be more accurate than the HR test. Like the HR specimen, the SR specimen is a curved prismatic bar with a uniform section. Appealing to a basic bending theory in strength of materials, the tensile strength for the special bar can be calculated analytically. Numerical simulations using LS-DYNA revealed, as expected, that the strength errors were 1% and 5% for the tensional and compressional SR tests, respectively, which were much lower than that (12%) of the HR test. To identify the performance of the two SR tests, laboratory experiments were conducted. The HR and Brazilian tests were also performed for comparison. The experiments showed that the ratios of the tensional and compressional SR to Brazilian strengths were 1.2~1.4 and 1.1~1.2, respectively, which are too small compared to empirical values in ordinary bend tests. Consequently, it is concluded that the SR test is not appropriate for use in tensile strength test of rock specimen of NX size. But the ratio of the HR to Brazilian strengths was within 1.7~2.0 for both the previous and present studies, showing a good consistency in their test results.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05b
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• pp.543-548
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• 1996

이 연구의 목적은 고리 3/4호기 및 영광 1/2호기의 음의 중성자속 변화율에 의한 원자로 트립(NFRT) 설정치를 제거하여 불의의 제어봉 낙하 사고시에 원자로 트립을 방지하는 것이다. 현재의 인허가된 안전해석 방법론에 의하면 제어봉 낙하사고시에 NFRT에 의하여 원자로가 트립되고 결국 발전소의 이용율이 감소하게 되는데 본 연구에서 적용된 새로운 방법론으로는 이 NFRT 보호신호 없이도 제어봉 낙하사고시에 발전소의 안전성을 입증할 수 있다. 안전분석은 주기별로 다른 핵설계 자료 즉, 냉각재 온도상수, 전출력에서의 제어봉가 및 제어봉 삽입한계 등을 이용하여 수행되었다. 웨스팅하우스형 연료인 OFA 및 V5H에 대하여 고리 4호기 6주기외 3개 주기에 대하여 분석되었다. 분석된 주기들에 대해서 NFRT 신호 없이도 핵비등 이탈률(DNBR) 설계기준을 모두 만족하였다. 그러므로 고리 3/4호기 및 영광 1/2호기의 NFRT 신호는 제거할수 있고 이로써 제어봉 낙하사고시의 발전소 불시정지를 방지할수 있다.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.516-520
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• 2012

홍수시 유속 및 유량을 직접 측정하기 어려우므로 수위-유량 관계식을 이용하면 편리하다. 그러나 수위-유량 관계는 유량 및 하도조건에 따라 변화하므로 매년 갱신하여 사용하는 것을 권장하고 있다. 본 연구에서는 초음파유속계 (Ultrasonic Velocity Meter: UVM)에 의한 연속적인 수위 및 유량 측정자료를 이용하여 수위-유량 관계를 구축하고 제시된 수위-유량 관계식을 적용하여 정확도를 분석하였다. 측정자료는 임진강 적성지점으로 2008년부터 2010년까지 7월 및 8월 자료를 대상으로 하였다. 초음파유속계는 홍수기 연속적인 수위와 유량의 측정이 가능하므로 측정자료에 의한 수위-유량 관계는 일반적으로 단일 홍수사상에 대해 고리 (loop) 모양을 보였다. 또한, 초음파유속계에 의한 수위 및 유량 측정이 안정된 경우 수위-유량 관계식은 고리 형태의 수위-유량 관계의 중앙을 관통하는 것으로 나타났다. 수위유량 관계식의 정확도는 당해 연도 측정자료에 대한 오차가 가장 작았으며, 오차의 크기가 차년도 자료 그리고 전년도 자료 순으로 나타났다. 이는 하천에 홍수 유과 이후 수위-유량 관계식을 개선해 주어야 하는 필요성을 제시한다.