• Title/Summary/Keyword: 고도산화

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A Study on the Effect of Chemical Pretreatment for Livestock Wastewater on the Linked Treatment of Sewage (축산폐수 처리 시 화학적 전처리가 연계처리에 미치는 영향 연구)

  • Han, Jun-Suk;Han, Gee-Bong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.1
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    • pp.89-97
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    • 2010
  • In this study, to investigate the effect of chemical pretreatment for livestock wastewater, laboratory scale test for ozonation and linked treatment of sewage were conducted. and the results were obtained as follows. The ozonation of livestock wastewater showed the COD removal rate per hour to be 17%, 78% and 62% at each pH 4, 7 and 10, respectively. With transformation of NBDCOD to biodegradable BDCOD by ozonation, the ratio of SCODcr/TCODcr was increased from 26% to 38%. Accordingly, pretreatment of livestock wastewater affected to the biological post treatment process to elevate removal efficiency by transformation of nonbiodegradable mass to biodegradable mass. As the results of linked treatment of pre-ozonated livestock wastewater and sewage in the MLE process, the treatment efficiencies of TCODcr 93.8%, T-N 74.3%, T-P 89.7%, SS 97.5% were earned at 100% of internal recycle rate. When the internal recycle rate was increased to 150%, the treatment efficiencies of TCODcr 94.5%, T-N 54.5%, T-P 70.8%, SS 98.5% were earned. Also the removal efficiencies of TCODcr 92.6%, T-N 83.1%, T-P 81.9%, SS 98.5% were earned as the internal recycle rate was increased to 200%. Especially, nitrogen removal efficiency in the linked treatment showed 74.3%, 54.5%, 83.1% at 100%, 150% and 200% of internal recycle ratio, respectively, which revealed the tendency of higher removal efficiency than that of sewage treatment.

Design Of 2-Stage Rocket Using Hybrid Rocket Motor and Solid Rocket Motor (하이브리드로켓 모터 및 고체로켓 모터를 이용한 2단 로켓 설계)

  • Go, Su-Han;Kim, Yeong-Jin;Mun, Seong-Gyun;Byeon, Min-Uk;Yu, Ji-Seung;Kim, Ga-Ram;Kim, Min-Cheol;Park, Jong-Su;Mun, Hui-Jang;Kim, Jin-Gon
    • 한국항공운항학회:학술대회논문집
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    • 2016.05a
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    • pp.14-18
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    • 2016
  • 본 연구에서는 하이브리드로켓 모터와 고체로켓 모터를 이용하여 목표 고도 1km인 2단 로켓 설계를 수행하였다. 비행 시나리오는 총 비행시간 51.59초, 1단부 로켓 연소시간은 3초이며 연소 종료 후 3초 뒤 단 분리를 수행하여 2단부 로켓 점화가 이루어져 총 3초간 연소가 진행된다. 1단부 모터는 하이브리드로켓으로써 5port의 HDPE를 연료 그레인으로 사용하였고 $LN_2O$를 산화제로 사용하였다. 2단부 모터는 고체로켓으로 KNSB(Sorbitol/$KNO_3$)추진제를 사용하였다. 단 분리는 영전자석을 이용하여 분리하며 2단부 모터의 점화는 광학 센서와 니크롬선 점화방식을 이용하여 점화하도록 설계하였다. 비행하는 동안 AVR를 이용해 압력, 가속도, GPS 등의 자료를 수집할 수 있도록 설계하였다.

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Superconductivity and physics (초전도와 물리학)

  • 오범환
    • Electrical & Electronic Materials
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    • v.9 no.3
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    • pp.304-309
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    • 1996
  • 본 고에서는 초전도에 관한 학문적 연구내용의 추이와 그 응용기술의 개발내용을 간략히 살펴보았다. 고온 초전도의 형성원리에 대한 학문적 관심과 응용기술 개발사이의 괴리를 이해하려는 노력의 일환으로 고온 초전도체를 주대상으로 한 각종 연구결과들을 소개하면서 순수학문과 공학기술과의 긴밀한 연관성을 찾았다. 전자와 정공의 도핑 대칭성을 확립한 Nd-Ce-Cu-O의 발견은 물성의 정확한 이해에 기초한 성공이었고, 산화물 고온 초전도체들의 전자쌍 파동함수의 대칭성에 관한 논의들에서 최근 연구의 주종을 이루고 있는 Josephson-coupling과 Photoemission등의 직관적인 결과를 주는 측정 실험들은 고도의 첨단기술과 죠셉슨 접합 등의 새로운 초전도 물성개념의 정확한 이해를 요하는 연구들이었다. 이러한 새로운 초전도 개념들의 토대위에 현 응용분야들의 추세를 대략 살핌으로써 부실하나마 미래의 차원 높은 수요에 대비한 학문적, 기술적 준비를 시도해 보았다.

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영산강 유역 생활하수처리장 방류수중의 유기오염물질 특성 규명

  • Lee, Mun-Hui;Park, Ji-Yeong;Han, Sang-Guk
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.05a
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    • pp.183-185
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    • 2005
  • 영산강 유역 생활하수처리장의 방류수의 분석 결과, 일일 처리량이 타지점들에 비해 다량이며 인구수가 많고 산업이 발달되어 있는 광주지역에 위치해 있는 광주 하수처리장과 송대 하수처리장에서 다종의 유기화합물이 검출되었다. 특히 polycyclic compounds, phenols, phthalates, pesticides는 여름철에 다종 고농도로 검출되어 여름철 영산강 유역 방류수의 주 오염물질로 판단된다. 이들 광주 하수처리장 방류수와 송대 하수처리장 방류수에서는 내분비계 장애물질인 diethylph thalate와 bis(2-ethyhexyl)phthalate가 4회 이상 검출되었다. 또한 송대, 장성 하수처리장에서 고농도로 검출된 물질이 대부분 산업용 화학물질이나 반응에 의해 2차로 생성되는 화학물질들이 다종으로 검출되었다. 따라서 이들 지점의 영향은 산업폐수에 의한 것으로 판단된다. 현재 각 하수처리장에서 실시하는 표준활성오니법, 회전원판접촉식 처리공정으로는 본 연구에서 검출된 물질과 같이 생태계나 인간의 건강에 유해한 유기화합물을 처리하기에는 역부족이라고 판단된다. 따라서 영산강 유역 수질 안정성을 확보하기 위해서는 polycycli compounds, phenols, phthalates, pesticides와 같은 난분해성 유기 화합물질을 처리할 수 있는 고도산화처리 시스템 도입이 필요하다.

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Design and Manufacture Hybrid Rocket for Measuring Atmospheric Fine Dust (대기 중 미세먼지 농도 측정을 위한 하이브리드 로켓 설계 및 제작)

  • Park, Yeong-Hun;Kim, Gi-Mun;Lee, Dong-Wan;Mun, Hui-Jang;Kim, Jin-Gon
    • 한국항공운항학회:학술대회논문집
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    • 2015.11a
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    • pp.13-19
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    • 2015
  • 본 연구의 목적은 자체 설계 제작한 하이브리드 발사체를 이용하여 대기 중의 미세먼지를 측정하는데 있다. 대기 중의 미세먼지를 측정하기 위한 방법으로는 중량농도법을 이용하였으며, 미세먼지 측정을 위한 포집장치를 자체 제작하였다. 엔진은 5port의 HDPE(High Density Polyethylene)를 연료 그레인으로 사용하였고 $LN_2O$(Liquefied Nitrous Oxide)를 산화제로 사용하였다. 압력, 가속도, GPS 등을 수집하며, 하이브리드 발사체의 동체는 FRP(Fiberglass Reinforced Plastics)로 제작한다. 전체 비행시간은 총 95초로 예상되며. 연소시간은 3초, 고도는 800 m 이다.

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A LIST OF HEPATICAE COLLECTED IN THE CRATER OF MT. HANLA, WITH 6 NEW ADDITIONS TO THE KOREAN FLORA (말기녹종을 포함한 한나산화구벽의 태류)

  • Hong, Won-Shic;Kim, Byong-Tak
    • Journal of Plant Biology
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    • v.4 no.1
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    • pp.13-15
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    • 1961
  • 1. This study was made on the flora of Hepaticae in the crater of Mt. Hanla ($33^{\circ}$20' N. Lat. $126^{\circ}$4' E. Long), Isl. Quelpart. 2. the total fo the occurring species of the crater are twelve, out of which the following 6 species are new to the Korean flora. (1) Bazzania tricrenata (Wahlenb.) Trev. (2) Plagiochila satoi Hatt. (3) Scapania ampliata St. (4) Radula boryana (Web.) Nees. (5) Cololejeunea kodamae Kamimura. (6) C. macounii (Spruce) Evans. 3. The hepaticae flora of the crater consists of the following elements: Holarctic element. 4 species (33%), East Asiatic element. 2. species (16%), Korean-Japan element. 5. species (41%), North-Pacific element. 1 species (8%).

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Determination of Efficient Operating Condition of UV/H2O2 Process Using the OH Radical Scavenging Factor (수산화라디칼 소모인자를 이용한 자외선/과산화수소공정의 효율적인 운전 조건도출)

  • Kim, Seonbaek;Kwon, Minhwan;Yoon, Yeojoon;Jung, Youmi;Hwang, Tae-Mun;Kang, Joon-Wun
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.534-541
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    • 2014
  • This study investigated a method to determine an efficient operating condition for the $UV/H_2O_2$ process. The OH radical scavenging factor is the most important factor to predict the removal efficiency of the target compound and determine the operating condition of the $UV/H_2O_2$ process. To rapidly and simply measure the scavenging factor, Rhodamine B (RhB) was selected as a probe compound. Its reliability was verified by comparing it with a typical probe compound (para-chlorobenzoic acid, pCBA); the difference between RhB and pCBA was only 1.1%. In a prediction test for the removal of Ibuprofen, the RhB method also shows a high reliability with an error rate of about 5% between the experimental result and the model prediction using the measured scavenging factor. In the monitoring result, the scavenging factor in the influent water of the $UV/H_2O_2$ pilot plant was changed up to 200% for about 8 months, suggesting that the required UV dose could be increased about 1.7 times to achieve 90% caffeine removal. These results show the importance of the scavenging factor measurement in the $UV/H_2O_2$ process, and the operating condition could simply be determined from the scavenging factor, absorbance, and information pertaining to the target compound.

A Study on Dissolve and Remove Analysis of Organic Chemicals Using a Mixed Method of Advanced Oxidation and Micro Filtering - Water Drinking Point - (고도산화와 정밀여과의 혼성공법을 이용한 유기화학물질의 분해 및 제거분석에 관한 연구 - 먹는 물을 중심으로 -)

  • An, Tai-Young;Jun, Sang-Ho;Ahn, Tae-Seok;Han, Mi-Ae;Hur, Jang-Hyun;Pak, Mi-Young
    • Membrane Journal
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    • v.17 no.2
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    • pp.99-111
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    • 2007
  • It is impossible to remove toxic organic substances that are recognized as a cancer caused suspicious element in drinking water using the conventional water purification method. This study introduces groundwater into a reaction chamber as an effective amount of water to process this water using a mixed method of AOP oxidation and M/F membrane and purifies it as a desirable level by artificially mixing such toxic substances in order to effectively process the water. Based on this fact, this study configures an optimal operation condition. The VOCs existed in toxic substances was investigated as a term of phenol and toluene, and agricultural chemicals were also investigated as a term of parathion, diazinon and carbaryl. The experiment applied in this study was performed using a single and composite soolution. In the operation condition applied to fully dissolve and remove such substances, the amount of $H_2O_2$ injected in the process was 150 mL of a fixed quantity, the value of pH was configured as $5.5{\sim}6.0$, the temperature was controlled as a range of $12{\sim}16^{\circ}C$, the dissolved amount of ozone was applied more than 5.0 mg/L, the reaction time was determined as an optimal condition, such as $30{\sim}40$ minutes, and the segregation membrane in the same reactor was determined for acquire water drinking of large quantity using a pore size of $0.45{\mu}m$ M/F membrane.

Effects of Advanced Oxidation of Penicillin on Biotoxicity, Biodegradability and Subsequent Biological Treatment (고도산화공정 처리가 페니실린의 생독성, 생분해도 및 생물학적 분해에 미치는 영향)

  • Luu, Huyen Trang;Minh, Dang Nhat;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.690-695
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    • 2018
  • Advanced oxidation processes (AOPs) composed of O3 and UV were applied to degrade penicillin (PEN). The degradation efficiency was evaluated in terms of changes in the absorbance (ABS) and total organic carbon (TOC). The combination of $O_3/H_2O_2/UV$ and $O_3/UV$ showed the best performance for the reduction of ABS (100% for 9 min) and TOC (70% for 60 min) values, although the mineralization was uncompleted under the experimental condition in this study. The change in biotoxicy was monitored with Escherichia coli susceptibility and Vibrio fischeri biofluorescence. The E. coli susceptibility was eliminated completely for 9 min by $O_3/UV$, and the toxicity to V. fischeri biofluorescence was 57% reduced by $O_3/H_2O_2/UV$. For the ultimate treatment of PEN, it is suggested that an AOP using $O_3/UV$ is followed by biological treatment, utilizing the enhanced biodegradability by the AOP. During 30 min of $O_3/UV$ treatment, the $BOD_5/COD$ ratio as an indication of biodegradability showed about 4-fold increment, compared to that of using a non-treated sample. TOC removal rate for AOP-pretreated PEN wastewater increased 55% compared to that of using the non-pretreated one through an aerobic biological treatment by Pseudomonas putida for artificial wastewater containing 20 mg/L of PEN. In conclusion, $O_3/UV$ process is recommended as a pretreatment step prior to an aerobic biological process to improve the ultimate degradation of penicillin.

Determination of Optimal Livestock Wastewater Treatment Process for Linked Treatment in Sewage Treatment Plant (하수처리장 연계처리를 위한 가축분뇨 최적 처리공정 선정에 관한 연구)

  • Kim, Choong Gon;Shin, Hyun Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.3
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    • pp.52-59
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    • 2012
  • As the result of reviewing the linked treatment of water quality for treating process at public livestock wastewater treatment facilities for fair selection of the proper linked process in case of linking sewage treatment plant for livestock wastewater, in case of wastewater processed by bio-reactor that is only biologically-treated, the load factor showed relatively high as 1.67%(base on design quality), 2.59%(base on operation quality) regarding COD and 3.69%(base on design quality), 7.67%(base on operation quality) regarding $COD_{Mn}$ but it is judged that there is nearly no influence on the operation of sewage treatment plan. And, in case of oxidized flotation-treated water & biofiltlation-treated water that are the advanced wastewater treatment, the load factor is approximately 1% and there is concern about the installation of excessive facilities in case of installing the advanced wastewater treatment. So, in case of considering the economic efficiency & stable operation of sewage treatment plant S, it is judged to be desirable to link with wastewater processed by bio-reactor that is biologically-treated.