• Title/Summary/Keyword: 고농도폐수

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A Study on the Removal of Nitrate Nitrogens by Redox Reaction of Zinc Ball (아연볼의 산화·환원 반응을 통한 연속식 질산성질소 처리에 관한 연구)

  • Kim, Joon Hwan;Kim, Jong Hwa;Song, Ju Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.487-494
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    • 2017
  • Since nitrate nitrogen is quite stable in aqueous solution, considerable skill is required to remove it. Low concentrations of nitrate nitrogen are easily removed, while high concentrations of nitrate nitrogen are difficult to remove. This study is to show that nitrate nitrogen in the form of gaseous nitrogen can be removed by using zinc ball with a diameter of about 3mm and to test the removal characteristics of nitrate nitrogen under various reaction conditions. As a result of this study, the treatment efficiency of nitrate nitrogen by continuous treatment with zinc ball was about 80%. However, there is a problem that the wastewater must be maintained in an acidic atmosphere of about pH 2, and the treated wastewater must be neutralized and discharged.

Integrated Wet Oxidation and Aerobic Biological Treatment of the Wastewater Containing High Concentration of Phenol (고농도 페놀 폐수의 습식산화와 호기성 생물학적 통합처리)

  • Choi, Ho-Jun;Lee, Seung-Ho;Yu, Yong-Ho;Yoon, Wang-Lai;Suh, II-Soon
    • KSBB Journal
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    • v.22 no.4
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    • pp.244-248
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    • 2007
  • The treatment of a model wastewater containing high concentration, 10 $g/{\ell}$, of phenol in an integrated wet oxidation-aerobic biological treatment was investigated. Partial wet oxidation under mild operating conditions was capable of converting the original phenol to biodegradable organic acids such as maleic acid, formic acid and acetic acid, the solution of which was subjected to the subsequent aerobic biological treatment. The wet oxidation was carried out at 150$^{\circ}C$ and 200$^{\circ}C$ and the initial pH of 1 to 12. The high temperature of 200$^{\circ}C$ and the acidic initial condition in the wet oxidation led to effluents of which biodegradability was higher in the subsequent biological oxidation process, as assessed by chemical oxygen demand (COD) removal. Homogeneous catalyst of $CuSO_4$ was also used for increasing the oxidation rate in the wet oxidation at 150$^{\circ}C$ and initial pH of 3.0. However, the pretreatment with the catalytic wet oxidation resulted in effluents which were less biodegradable in the aerobic biological process compared to those out of the non-catalytic wet oxidation at the same operating conditions.

Effects of Operating Parameters on the Removal Performance of Ammonia Nitrogen by Electrodialysis (전기투석에 의한 암모니아성질소의 제거 시 운전인자의 영향)

  • Yoon, Tae-Kyung;Lee, Gang-Choon;Jung, Byung-Gil;Han, Young-Rip;Sung, Nak-Chang
    • Clean Technology
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    • v.17 no.4
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    • pp.363-369
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    • 2011
  • To evaluate the feasibility of electrodialysis for ammonia nitrogen removal from wastewater, the effects of operating parameters such as diluate concentration, applied voltage and flow rate on the removal of ammonia nitrogen were experimentally estimated. The removal rate was evaluated by measuring the elapsed time for ammonia nitrogen concentration of diluate to reach 20 mg/L. Limiting current density (LCD) linearly increased with ammonia nitrogen concentration and flow rate. The elapsed time was linearly proportional to initial concentration of diluate. Due to relatively large equivalent ion conductivity and ion mobility of ammonia nitrogen, the removal rate increased consistently with flow rate. Increase in the applied voltage gave positive effect to removal rate. From the operation of the electrodialysis module used in this research, the flow rate of 3.2 L/min and 80~90% of applied voltage for LCD are recommended as the optimum operating condition for the removal from high concentrate ammonia nitrogen solution.

Effects of Operating Parameters on the Removal Performance of Nitrate-nitrogen by Electrodialysis (전기투석을 이용한 질산성 질소의 제거 시 운전인자의 영향)

  • Lee, Gwan-Ho;Lee, Gang-Choon
    • Clean Technology
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    • v.15 no.4
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    • pp.280-286
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    • 2009
  • To evaluate the feasibility of electrodialysis for nitrate-nitrogen removal from wastewater, the effect of operating parameters on the removal of nitrate-nitrogen was experimentally estimated. The limiting current density (LCD) linearly increased with the nitrate concentration and the flow rate. The time when the nitrate concentration of diluate reached at 20 mg/L was linearly proportional to concentration of diluate, and the concentration of concentrate did not affect the removal rate. Increase in the flow rate gave a positive effect on the removal rate and became insignificant at How rates greater than 1.6 L/min. The removal rate increased with the applied voltage, but the increment in the removal rate decreased as the applied voltage approached the LCD. From the operation of the electrodialysis module used in this research, the flow rate of 1.6 L/min and the voltage corresponding to the 80~90% of LCD were found be the optimum operating condition for the nitrate removal from highly concentrated nitrate-nitrogen solutions.

Utilization and Application of Microorganisms in Treating Food Processing Wastes -Recovery of Mycelial Proteins- (식품가공공장 폐수의 미생물학적 처리 및 응용 -미생물 균체단백질 회수-)

  • Cho, Sung-Hwan;Choi, Jong-Duck;Lee, Sang-Yeol;Ki, Woo-Kyung;Kim, Ze-Uook
    • Applied Biological Chemistry
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    • v.32 no.4
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    • pp.424-434
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    • 1989
  • The rationale for the use of fungi in treating waste streams from food processing plants I~as been that of incorporating the dissolved and suspending nutrients into a macroscopic organism which can be filtered out readily. In order for a process using fungi to meet these objectives we examined a strain of fungi, Aspergillus fumigatus, which grew well on a variety of polysaccharide-containing materials and showed both efficient BOD removal and high quality protein recovery. In this experiment the fungal choice was based on the laboratory screening studies where the criteria used was BOD and COD reduction, growth response, mycelial yield, and the ability to compete with the natural flora. In the fermentation system used far the continuous culture of Aspergillus fumigatus the best combination of operating variables, inoculum ratio, temperature, initial pH, fermentation time and agitation rate was 5%(v/v), $35{\sim}40^{circ}C,\;pH\;4.5{\sim}5.0$, 2days and 150rpm, respectively. The fungus reduced BOD and COD to 94.0 and 90.4%, respectively and 3.15g of dry mycelium per liter of alcohol waste was harvested during 48hr of incubation time. The protein efficiency ratios for the control diet and the experimental diet containing the fungal protein were $3.42{\pm}0.15$ and $3.40{\pm}0.43$, respectively.

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Study on application of membrane for wastewater in biogas plants (BGP(Biogas Plant) 발생폐수의 분리막 적용 연구)

  • Kim, Shin-Young;Chang, In-Soung;Kim, Jang-Kyu;Yu, Myeong-Jung
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.503-503
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    • 2010
  • 국제협약에 따라 2012년부터 유기성폐기물의 해양배출이 금지됨에 따라 환경문제를 유발하는 축산분뇨, 음식물쓰레기, 농축산 폐기물 등의 처리가 곤란한 실정이다. 그러나 최근 저탄소 녹색성장으로 정부가 폐자원 에너지화에 관심을 기울이면서 위의 폐기물을 바이오가스로 전환하는 바이오가스 플랜트(Biogas Plant, BGP)의 이용이 보다 활성화 될 전망이다[1]. 이 바이오가스 처리방법에서 유기물은 메탄가스로 배출되고[2], 나머지 영양성분들(질소, 인산, 칼륨 등)은 모두 소화액에 남아있으므로[3] 이들은 친환경농업에서 필요한 액비로도 활용이 가능하며, 혐기소화 처리방법은 일반적인 가축분뇨 처리과정에서 발생되는 악취문제도 해결할 수 있는 장점 또한 가지고 있다. BGP는 유기성 폐기물에서 혐기성소화를 통해 바이오가스를 만드는 장점이 있는 반면, 가스를 만들고 남은 소화액은 액비로 활용이 가능하지만, 액비로 활용이 불가능할 경우 악성 폐수로 그 처리가 매우 까다로운 단점이 있다. 일반적인 생물학적인 폐수처리방법으로는 처리가 곤란하며, 환경기준을 맞추도록 처리하는데 많은 비용이 소요된다. 이러한 폐액처리를 위해 공정의 단순화와 높은 처리 효율[4]을 가지면서, 액비 또는 정화처리공정이 가능한 방법으로서 분리막공정이 바람직하나, BGP 발생폐액의 성상이 고농도의 오염물질을 함유하고 있어 적용이 쉽지 않다. 따라서 본 연구에서는 이를 보안할 수 있는 와류발생형 막모듈을 이용하여 Biogas Plant의 발생폐수에 대하여 분리막을 이용한 효과적인 처리공정을 개발하고 그에 따른 최적의 조건을 찾는 연구를 하고자 한다. 와류발생형 막모듈을 막과 막 사이에 와류를 발생시킴으로써 막에 전단력을 가하여 막의 가장 큰 단점인 막오염을 줄이는 방법으로 기존의 막모듈과 큰 차이가 있을 것으로 예상된다. 본 연구에서는 기존의 분리막 모듈[5]과 와류발생형 막모듈의 차이를 실험을 통해 확인하며, 막에 가해지는 압력, 막을 통과하는 유량 등의 차이를 두어 최적조건을 탐색하였다.

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Fundamental Studies on the Calcium Precipitation for the Reuse of Wastewater Containing Phosphate (칼슘 침전처리에 의한 인산폐수 재사용에 관한 연구)

  • Kim Yaung-Im;Kim Dong-Su
    • Resources Recycling
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    • v.12 no.4
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    • pp.38-43
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    • 2003
  • Phosphate is an essential material for the growth of organisms. However. since relatively small amount is required. a large amount of phosphate is abandoned in wastes and wastewater. which contaminate the ecological environment including aquatic system. Purpose of this study is to treat especially high concentrated phosphate wastewater by use of calcium precipitation method. The pH range considered was from 6 to 12 and the maximum removal of phosphate was attained at pH 12. The con-centration of phosphate was observed to decrease rapidly until a half amount of calcium ion to its equivalent for the formation of calcium phosphate precipitate was added. which resulted in the decrease of the remaining concentration of phosphate down to 0.0027 mM. The effect of fluoride ion was examined and the concentration ratio between the phosphate and fluoride ion did not have any significant influence on the removal efficiency of phosphate. The effect of pH was also investigated. With the increasing of the pH in solution, the removal rate of phosphate was increased. Also it was investigated that the effect of fluoride on the phosphate removal was not significant.

Isolation and Characterization of $\alpha$-Amylase Producing Bacillus sp. AIV 1940 and Properties of Starch Synthetic Wastewater Degradation ($\alpha$-Amylase 생성균주 Bacillus sp. AIV 1940의 분리, 특성 및 합성폐수분해능)

  • 박형수;김무훈;양선영;조미영;고범준;박용근
    • Korean Journal of Microbiology
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    • v.38 no.1
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    • pp.1-6
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    • 2002
  • $\alpha$-Amylase producing bacteria were isolated from activated sludge of corn processing wastewater plant and paddy field soil samples and selected by the direct iodine reaction. The isolate was identified as Bacillus sp. after morphology, API system and fatty acid analyses. To enchance $\alpha$-amylase productivity, a successive mutation of Bacillus sp. AIV 19 was performed using the treatment of nitrosoguanidine(NTG).The mutant, Bacillus sp. AIV 1940, showed about 1.8-fold level of amylase activity compared with parental strain. The isolate was Gram-positive and rod (2.8-3.0 $\mu$m long, 0.5-0.6 $\mu$m wide) type. The strain increased the bacterial mass at 3000 mg/l starch concentration. Organic substance removal rate was 40.2, 72.3% respectively after 1 and 3 day reaction using starch synthetic wastewater (intial CODcr was 4,455 mg/l).

Removal Characteristics of Heavy Metals by Continuous Neutralization of Plating Wastewater with Waste-Oyster Shells (폐굴껍질에 의한 산성도금폐수의 연속 중화시 중금속제거 특성)

  • 김형석;송동근;성낙창
    • Resources Recycling
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    • v.7 no.3
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    • pp.36-41
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    • 1998
  • Objective of the research is to deteonine the praeLic따 running parameters for neutralization and removal of heavy metals from plating wastewater with waste-oyster shells by the Bohart$.$Adams equation. Waste-oyster shells discharged from the d domestic oyster cultnring fields cause a serious ocean environmental pollution. However, it is expected that those are able to b be recycled for removal of heavy metals through neutralization of plating wastewater because the shells contain approximate 93% $CaCO_3$, and have multi-pore voids. By applying the results of the continuous experiments to Bohart-Adams equation, s service time decreases in the order of Cr>Fe>Cu while removal efficiencies of metals become less in the order of Fe>Cr>Cu.

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Optimization of Operating Conditions for Each Linked Treatment Scenario using Sewage Treatment Modeling (하수처리 모델링을 이용한 연계처리 시나리오별 운전조건 최적화)

  • Kim, Sungji;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.23 no.1
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    • pp.7-13
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    • 2021
  • Due to rapid industrial development, population growth, and improvement of living standards, the amount of sewage and wastewater, including nutrients, is increasing every year. In addition to the increasing amount of sewage and wastewater generation, untreated linked treated water (manure, livestock manure, industrial wastewater, leachate, food waste) is also increasing, and many of the linked treated water flows directly into nearby sewage treatment plants. The associated treated water causes many problems because of its own characteristics, low flow rate with high concentration compared to existing inflow sewage. In order to solve this problem, it is necessary to investigate the quantity and quality of the connected treated water whichh is flowed into the sewage treatment plant, and a study the effect on sewage treatment. Therefore, in this paper, we would like to examine the effect of the linked treated water. Seasonal effect associated with water pollution conditions was considered. In addition, a scenario was created through the distribution and inflow of connected treated water along with the water temperature conditions. Through scenario analysis, we intend to optimize the operating conditions of linked processing.