• Title/Summary/Keyword: 계면 공극

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Investigation of Electrical Resistance Properties in Surface-Coated Lightweight Aggregate (표면코팅 경량골재의 전기저항 특성)

  • Kim, Ho-Jin;Kim, Chang-Hyun;Choi, Jung-Wook;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.727-738
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    • 2023
  • In concrete, the interface between the aggregate and cement paste is often the most critical factor in determining strength, representing the weakest zone. Lightweight aggregate, produced through expansion and firing of raw materials, features numerous surface pores and benefits from low density; however, its overall aggregate strength is compromised. Within concrete, diminished aggregate strength can lead to aggregate fracture. When applying lightweight aggregate to concrete, the interface strength becomes critical due to the potential for aggregate fracture. This study involved coating the surface of the aggregate with blast furnace slag fine powder to enhance the interfacial strength of lightweight aggregate. The impedance of test specimens was measured to analyze interface changes resulting from this surface modification. Experimental results revealed a 4% increase in compressive strength following the coating of the lightweight aggregate surface, accompanied by an increase in resistance values within the impedance measurements corresponding with strength enhancement.

Study on the Defect Mechanism of Immersion Gold Layer (Immersion gold층의 결함 메카니즘 연구)

  • Lee, Dong-Jun;Choi, Jin-Won;Cho, Seung-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.3
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    • pp.35-40
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    • 2008
  • Investigation on immersion gold layers was carried out using TEM analysis for the purpose of understanding the defect of immersion gold layer. The immersion gold layers prepared with three different types of baths were observed. The results showed that the defect structure of immersion gold layer is strongly dependent on the types of gold baths. Spherical defects of average 10 nm size were located along the grain boundaries for the specimen formed at KAu$(CN)_2$ bath containing no reducing agent. In the case of the specimen processed at KAu$(CN)_2$ bath containing a reducing agent, the spherical defects of 5-10 nm size were distributed randomly in grains as well as at grain boundaries. However, such defects disappeared almost completely when $Na_{3}Au(SO_3)_2$ bath was used to fabricate an immersion gold.

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Effects of Orientation on Properties of Solid-State Extruded Polypropylene/Calcium Carbonate Composites (고상압출로 제조된 폴리프로필렌/탄산칼슘 복합재료의 물성에 미치는 배향의 영향)

  • Lee, Jaechoon;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.14 no.4
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    • pp.175-182
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    • 2013
  • In this work, we aim to investigate the specific gravity, thermal, and mechanical property changes of solid-state extruded polypropylene (PP)/calcium carbonate composites before and after orientation. For this work, we prepared $PP/CaCO_3$ composites having two different sizes (OM-1 and OM-10). On increasing the filler content, the specific gravity of the composites increases. The specific gravity of the oriented specimen containing filler in PP matrix is found to be much smaller than that of pre-specimen due to the formation of more microvoids. The presence of microvoids in case of oriented composite specimen significantly affected the tensile and flexural properties of the composites. It was observed that the effect of orientation on both flexural strength and modulus is much stronger than the effect of filler contents, regardless of the filler particle size.

Carbon Reduction Technology Applying the Surfactant and Carbon Dioxide Sequential Injection (계면활성제 및 이산화탄소 연속 주입을 활용한 탄소 저감 기술)

  • Seokgu Gang;Jongwon Jung
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.3
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    • pp.5-11
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    • 2024
  • Promising geological structures for carbon dioxide capture and subsurface storage include aquifers, depleted reservoirs, and gas fields. Among these, aquifers are gaining attention due to their potential for storing significant amounts of carbon dioxide compared to other geological structures. Therefore, there is a growing interest in enhancing carbon dioxide storage efficiency by understanding the characteristics of aquifers and developing technologies tailored to their properties. In this study, the storage efficiency of carbon dioxide injection following surfactant pre-injection into porous micro-models was evaluated. The results indicate that as the concentration of the surfactant solution injected prior to carbon dioxide injection increases, storage efficiency improves. Conversely, lower concentrations require more surfactant injection to enhance storage efficiency. Furthermore, under identical surfactant concentration conditions, the storage efficiency from surfactant pre-injection prior to supercritical carbon dioxide injection is approximately 30% lower compared to surfactant-co-solvent substitution as observed in previous studies. However, under the maximum concentration conditions investigated in this study, similar storage efficiencies to those of previous studies were achieved. These findings are expected to guide concentration determinations for surfactant application aimed at enhancing carbon dioxide storage efficiency in aquifers in future studies.

The Effect of Temperature on the Process of Immiscible Displacement in Pore Network (공극 구조 내 비혼성 대체 과정에서 주입 온도가 유체 거동에 미치는 영향)

  • Park, Gyuryeong;Kim, Seon-ok;Lee, Minhee;Wang, Sookyun
    • Economic and Environmental Geology
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    • v.51 no.3
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    • pp.223-232
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    • 2018
  • The viscous force of fluids and the capillary force acting on the pore network of the porous media are important factors determining the immiscible displacement during geological $CO_2$ sequestration, these were directly affected by geological formation conditions and injection conditions. This study aimed to observe the migration and distribution of injected fluid and pore water, and quantitatively investigate displacement efficiency on various injection temperatures. This study aimed to perform micromodel experiments by applying n-hexane used as a proxy fluid for supercritical $CO_2$. In this study, immiscible displacement process from beginning of n-hexane injection to equilibrium of the distribution of the n-hexane and pore water was observed. The images from experiment were used to observe the displacement pattern and estimate the areal displacment efficiency of the n-hexane. For investigate the affects of the injection temperatures on the migration in macroscopic, migration of n-hexane in single pore was analyzed. The measurement revealed that the displacement efficiency at equilibrium state decreases as the temperature increases. The result from experiments indicate that the temperatures can affect the displacement pattern by changing the viscous forces and the capillary forces. The experimental results could provide important fundamental information on reservoir conditions and fluid injection conditions during geological $CO_2$ sequestration.

Effect of Added Pluronics on fabrication of Poly(L-lactic acid) Scaffold via Thermally-Induced Phase Separation (상 분리법을 이용한 Poly(L-lactic acid) Scaffold제조에 미치는 Pluronics의 영향)

  • 김고은;김현도;이두성
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.821-828
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    • 2002
  • Regular and highly interconnected macroporous poly(L-lactic acid) (PLLA) scaffolds with pore size of 10∼300 ㎛ were fabricated through thermally induced phase separation of a PLLA-dioxane-water ternary system in the presence of a small amount of Pluronics. Addition of Pluronics to the ternary system raised the cloud-point temperature curve in the order of P-123< F-68< F-127. The Pluronics act as nuclei for the phase separation. This assistance is enhanced with increasing length of the hydrophilic PEO blocks in the Pluronics molecules. Liquid-liquid spinodal phase separation was induced at higher temperatures in the systems containing Pluronics because the spinodal region is raised to higher temperature. The absorption of Pluronics onto the interface stabilizes a macro scale structure and increases the interconnection of pores.

The Effect of Electrochemical Treatment in Lowering Alkali Leaching from Cement Paste to an Aquatic Environment: Part 2- Microscopic Observation (전기화학적 기법을 통한 시멘트페이스트의 수중노출에 따른 알칼리이온 침출저감 효과: Part 2- 미세구조 분석)

  • Bum-Hee Youn;Ki-Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.145-152
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    • 2023
  • In this study, microscopic observation was made on the surface of cement paste immersed in an aquatic environment for 100 days at electrochemical treatment to mitigate the leaching of alkali ions. To quantitatively rank the hydration products, unhydrated grains and porosity in the interfacial region, the backscattered electron(BSE) images were obtained by scanninng electron microscopy. As a result, it was found that the porosity on the surface was significantly reduced by the electrochemical treatment, while unhydrated grains were more or less increased presumably limited hydration reaction under electric charge. At electrochemical treatment, Ca2+ ions present in C-S-H gel could be precipitated with OH- to form Ca(OH)2 then to lower C-S-H gel and simultaneously to enhance Ca(OH)2. Substantially, the risk of alkali leaching could be lowered by the limited ionized matrix under electrochemical treatment.

Development of Epoxy/Boron Nitride Composites for High Heat Dissipation of Metal Copper Clad Laminate (MCCL) (Metal Copper Clad Laminate (MCCL)의 고방열 특성을 위한 Epoxy/BN 복합체 개발)

  • Choi, Ho-Kyoung;Choi, Jae-Hyun;Choi, Bong-Goo;Yoon, Do-Young;Choi, Joong-So
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.64-68
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    • 2020
  • In this study, metal copper clad laminate can be prepared using epoxy composite filled with thermally conductive fillers. In order to improve the thermal conductivity of epoxy composites, it is important factor to form conductive networks through appropriate packing of conductive fillers in epoxy composite matrix and to decrease the amount of thermally resistant junctions involving a epoxy composite matrix layer between adjacent filler units. This is because epoxy has a thermal conductivity of only 0.2-0.3W, so in order to maintain high thermal conductivity, thermally conductive fillers are connected to each other, so that the gap between particles can be reduced to reduce thermal resistance. The purpose of this study is to find way to achieve highly thermally conductive in the epoxy composite matrix filled with Al2O3 and Boron Nitride(BN) filler by filler loading and uniform dispersion. As a results, the use of Al2O3/BN hybrid filler in epoxy matrix was found to be effective in increasing thermal conductivity of epoxy composite matrix due to the enhanced connectivity offered by more continuous thermally conductive pathways and uniform dispersion without interfacial voids in epoxy composite matrix. In addition, surface treatmented s-BN improves the filler dispersion and adhesion between the filler and the epoxy matrix, which can significantly decrease the interfacial thermal resistance and increase the thermal conductivity of epoxy composite matrix.

Effects of Fine Aggregate Size on Penetration Performances of SSPM (잔골재의 입도분포가 SSPM의 침투성능에 미치는 영향)

  • Yoon, Hyun-Kwang;Youn, Da-Ae;Lee, Chan-Woo;Park, Wan-Shin;Yun, Hyun-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.25-31
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    • 2019
  • This study was conducted to evaluate the penetration performance of the Silane Surface Protection Material (SSPM) penetrating the micro pore of concrete surface. The results was indicated microstructure, porosity and penetration depth of applied SSPM. Silica sand and conventional sand were used as fine aggregate in mortar. And liquid and cream types SSPM were used. The amounts of SPM were applied the 127, 255, 382, 510 g/m2 on the surface of mortar. The penetration depth specimens were made with $100{\times}30mm$ in according with KS F 4930. Penetration depth was evaluated according to KS F 4930, divide specimen and then spraying with water in cross section of specimens, and measure the depth of the non-wetted area. The microstructure result of mortar applied SSPM, it was obtained liquid and cream SSPM in mortar. The porosity results of SSPM application specimens were improved with than that of plain specimens. Test results indicated that the penetration depth of SPM were improved with increasing in amounts of SSPM. As a result of test, application of SSPM to concrete surface, it will improve durability.

The Effect on Partial Melting on Superplastic Flow of ${Si_3}{N_{4p}}$/2124 Al Composites (II) (국부적 용융이 ${Si_3}{N_{4p}}$/2124 Al 복합재의 초소성 거동에 미치는 영향 (II))

  • Jeong, Ha-Guk;Kim, Hye-Seong
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.585-589
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    • 2001
  • Many experimental results have revealed that the development of cavitaition during tensile deformation is limited by the Presence of liquid phases. However, the presence of liquid phases does not always lead to high-strain-rate superplasticity, because too much liquid causes intergranular decohesion at grain boundaries/interfaces in metal-matrix composites. Thus, it is important to examine the nature of interfaces of superplastic composites in order to understand the origin of superplastic flow related to liquid grain boundaries during high-strain-rate superplastic deformation. This study shows that a large elongation is obtained at the temperature, that is close to the onset temperature for partial melting in the superplastic composites, but the elongation significantly decreases at slightly higher temperatures, which are close to the end temperature fur partial melting. This indicates that there is an optimum amount of the liquid phase for obtaining high-strain-rate superplasticity in these materials.

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