• Title/Summary/Keyword: 계면조건

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지지막의 특성에 의한 복합막의 성능 변화에 대한 연구

  • 곽상효;오종열;신세종;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.73-74
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    • 1996
  • 역삼투막은 높은 투과율과 배제율, 기계적 강도, 열적 안정성, 화학적 안정성, 성형성, 경제성 등의 여러 가지 조건을 동시에 만족시켜야 한다. 복합막을 통한 역삼투막의 제조는 위의 조건들을 만족시키는 역삼투막을 제조할 수 있는 훌륭한 제조 방법인데 지지막과 표면의 활성층을 여러 가지로 조합하여 다양한 성능의 막을 개발할 수 있기 때문이다. 지지막은 다공질의 고분자막으로 기계적 강도, 화학적.열적 안정성 등이 있어야 하는데 역삼투막이 가혹한 운전 조건에서 조작되기 때문이다. 그리고 지지막은 활성층과 안정된 결합을 할 수 있는 물리적 및 화학적 성질을 지녀야 한다. 활성층은 분리가 일어나는 곳으로 막의 배제율과 투과특성에 큰 영향을 미친다. 따라서 복합막의 제조에 있어서 고려되어야 할 사항은 지지막과 활성층의 재질의 선택, 지지막의 특성, 지지막 위에 얇고 안정된 활성층의 도포 방법, 성능향상과 활성층의 안정화를 위한 제조된 복합막의 후처리 방법 등이다. 지지막 위에 활성층을 도포시키는 방법은 계면중합법, 박층분산법, 침지코팅법, 기상증착법 등을 들 수 있는데 이 중에서 계면중합법을 이용한 복합막의 제조가 가장 실용적인 방법으로 인정되고 있고 현재 실용화되어 있다.

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The Change of Properties of reverse Osmosis Thin Film Composite Membrane according to Preparation Conditions (계면중합조건에 따른 복합막의 물성 변화)

  • Lee, Dong-Jin;Min, Byung-Ryul
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.276-285
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    • 1997
  • The theoretical and experimental analysis on polyamide used for reverse osmosis thin-film composite membrane had been conducted. The physicochemical properties of polyamide had been varied by preparation recipes which depends on kinds of monomer, solvents and polymerization time. These properties and performance as a reverse osmosis membrane had been calculated by group contribution method. The experimental results has the same trends with theoretical preview.

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Interfacial Adhesion between Screen-Printed Ag and Epoxy Resin-Coated Polyimide (에폭시수지가 도포된 폴리이미드와 스크린 프린팅 Ag 사이의 계면접착력 평가)

  • Park, Sung-Cheol;Kim, Jae-Won;Kim, Ki-Hyun;Park, Se-Ho;Lee, Young-Min;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.1
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    • pp.41-46
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    • 2010
  • The interfacial adhesion strengths between screen-printed Ag film and epoxy resin-coated polyimide were evaluated by $180^{\circ}$ peel test method. Measured peel strength value was initially around $164.0{\pm}24.4J/m^2$, while the heat treatment during 24h at $120^{\circ}C$ increase peel strength up to $220.8{\pm}19.2J/m^2$. $85^{\circ}C/85%$ RH temperature/humidity treatment decrease peel strength to $84.1{\pm}50.8J/m^2$, which seems to be attributed to hydrolysis bonding reaction mechanism between metal and adhesive epoxy resin coating layer.

Measurement of three-dimensional interfacial wave structures in nearly- horizontal countercurrent statified two-phase flow (근사수평 반류성층 2상유동에서의 3차원 계면파의 구조측정)

  • 이상천
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.3
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    • pp.599-606
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    • 1988
  • Structures of interfacial waves in nearly-horizontal countercurrent stratified air-water flow have been measured by means of a needle contact method. Based upon a statistical analysis for the liquid film distribution, statistical properties of the waves such as mean film thickness, mean wave amplitude and rms value of the wave fluctuation have been calculated. The results show that the film distribution can be described by a Gaussian probability density function for the three-dimensional wave regime. It is also indicated that the mean film thick ness and the rms value of the wave fluctuation increase as gas and liquid flow rates are increased in countercurrent two-phase flow. The dimensionless intensity of the wave fluctuation may be regarded as a function of the Froude number and the dimensionless mean film thickness.

Study on the Degradation Alleviation of Synthetic Polymer Solution Using Addition of Surfactant Additives at Low Temperature (저온에서 계면활성제를 첨가한 합성고분자 수용액의 퇴화원화에 대한 연구)

  • 김난진;이재용;윤석만;김종보
    • Journal of Energy Engineering
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    • v.9 no.2
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    • pp.102-108
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    • 2000
  • 난류상태로 유동중인 고분자 수용액은 순수 용매만의 경우에 비교할 때 동일유량에서 초기에 높은 마찰 저항감소효과를 보이며, 이러한 마찰저항감소효과는 펌프의 펌핑능력 증대로 큰 경제적 이익을 가져다준다. 그러나, 고분자 수용액은 그 극적인 마찰저항감소효과에도 불구하고 유동중에 가해지는 기계적 에너지, 열에너지 등에 의해서 초기의 높은 마찰저항감소효과를 점차적으로 상실하게 되기 때문에, 고분자 수용액의 퇴화를 완화시키기위한 연구가 필요하다. 따라서 본 연구에서는 기계적 퇴화특성이 비교적 강한 합성고분자와 계면활성제의 농도합계를 100wpm 으로 고정하고 비율을 11가지로 세분화하여 , 1$0^{\circ}C$의 온도에서 유속 1.5m/sec , 3.0m/sec 및 4.5m/sec 에 대한 퇴화경향을 알아보는 실험을 수행하였으며, 각 조건에서 합성고분자와 계면활성제의 적정비율을 관찰하였다. 실험 결과, 각 속도에서 시간에 따른 퇴화경향은 고속에서 기계적 에너지에 대한 퇴화를 볼 수 있었고, 계면활성제와 합성고분자를 혼합하여 첨가했을 경우 저온에서도 퇴화완화효과가 있음을 확인하였다.

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Study on the Effect of the Mg2+ Ion on the Behavior of Anionic Surfactants in Electrophoresis (전기 이동에서 Mg2+ 이온이 음이온 계면활성제의 거동에 미치는 영향)

  • Jeong, Hyuk
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.35-42
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    • 2005
  • This study reports the effect of $Mg^{2+}$ ions on the behavior of the anionic surfactant in electrophoresis. Intractions of $Mg^{2+}$ ions with carboxylates and sulfonates resulted large changes in their apparent mobilities. A comprehensive analysis of the electroosmotic and electrophoretic mobilities reveals that major cause for the variation of the apparent mobilities of anions arises from the electroosmotic mobilities.

Characteristics of Culture Conditions for the Production of Biosurfactant by Bacillus pumilus IJ-1 (Bacillus pumilus IJ-1의 생물계면활성제 생산을 위한 배양 특성)

  • Park, Eunjin;Kim, Jiyeon
    • Journal of Applied Biological Chemistry
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    • v.58 no.1
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    • pp.81-88
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    • 2015
  • To characterize the culture medium for the biosurfactant production by Bacillus pumilus IJ-1, the influences of various carbon, nitrogen and mineral sources were assessed. As a result, the highest biosurfactant production was observed after 96 h cultivation containing 0.5% (w/v) tryptone. The strain was able to grow and produce biosurfactant at 0-10% (w/v) NaCl, in the pH range of 5-10, and at $20-45^{\circ}C$. Optimal culture conditions for the biosurfactant production were at $20^{\circ}C$ and pH 9.0 after 72 h incubation and the surface tension of biosurfactant was 27.0 dyne/cm.

Phase behavior of CO2 + H2O + 2,2,3,3,3-pentafluoro-1-propanol mixture (이산화탄소+물+2,2,3,3,3-pentafluoro-1-propanol 혼합물의 상거동)

  • Shin, Hun Yong
    • Clean Technology
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    • v.24 no.4
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    • pp.275-279
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    • 2018
  • In this study, microemulsion formation of water and carbon dioxide was investigated by using surfactant as one of the methods for increasing the mutual solubility between water and carbon dioxide. The surfactant 2,2,3,3,3-Pentafluoro-1-propanol was added to form a microemulsion of water and carbon dioxide. The cloud point change and trend of micro emulsion were investigated by adding water and a certain amount of surfactant, 2,2,3,3,3-Pentafluoro-1-propanol to supercritical carbon dioxide. In the case of surfactant + carbon dioxide system, it was 8.35 ~ 12.69 MPa in temperature range of 313.2 ~ 353.2 K. In the case of water + surfactant + carbon dioxide system, the temperature ranged from 318.2 ~ 338.2 K to pressure range 7.83 ~ 17.28 MPa.