• The Korean Journal of Rheology
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• v.6 no.2
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• pp.119-128
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• 1994

공압출되는 sheet die에서 뉴튼 유체의 수축흐름을 격자생성법을 이용한 유한차분법 을 사용하여 수치모사하였다. 계면조건의 처리방법을 개발하였고 점도 및 채널 모양이 압력 강하 및 신장속도에 미치는 영향을 알아보았다. 압력강하는 점도비의 영향을 크게 받았으며 신장속도는 점도비 및 채널 모양의 영향을 크게 받았다. 여러 가지채널모양에서 신장속도를 비교해 본 결과, 트럼펫 모양의 수축채널이 신장속도가 가장속도가 가장 작게 나타났다.

• The Microorganisms and Industry
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• v.14 no.3
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• pp.37-40
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• 1988

미생물에 의해서 생성되는 계면 활성제는 매우 다양하며, 그 특성은 사용되는 기질과 배양조건 등에 따라 다르게 된다. 일반적으로 소수성 부분은 대부분 지방산으로 이루어진 탄화수소 사슬이지만, 친수성 부분은 alcohol, ester등을 비롯하여 인산 또는 황산기와 같이 이온 그룹으로 구성되는 등 다양하다. 대부분의 biosurfactant는 생분해가 가능하며 독성이 없다. 따라서 오염문제를 야기하지 않으며 생물체에 적용가능한 장점을 갖고 있다. 따라서 앞으로 미생물을 이용한 biosurfactant의 개발및 응용가능성은 매우 높다고 볼 수 있다.

• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.606-614
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• 2019

A mixing ratio of the oil in water (O/W) emulsion of palm oil and the non-ionic surfactant (Tween-Span type) possessing different hydrophile-lipophilie balance (HLB) values was evaluated in this work. An optimum condition was determined through analysis of main and interaction effects of each quantitative factor using central composite design model-response surface methodology (CCD-RSM). Quantitative factors used by CCD-RSM were an emulsification time, emulsification speed, HLB value and amount of surfactant. On the other hand, the reaction parameters were the viscosity and mean droplet size of O/W emersion. Optimized conditions obtained from CCD-RSM were the emulsification time of 12.7 min, emulsification speed of 5,551 rpm, HLB value of 8.0 and amount of surfactant of 5.7 wt.%. Ideal experimental results under the optimized experimental condition were the viscosity of 1,551 cP and mean droplet size of 432 nm which satisfy the targeted values. The average error value from our actual experiment for verifying the conclusions was below to 2.5%. Therefore, a high favorable level could be obtained when the CCD-RSM was applied to the optimized palm oil to water emulsification.

• Journal of the Korean Society of Safety
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• v.7 no.2
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• pp.63-70
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• 1992

The aim of this research is to obtain a basic quantitative understanding of the effect of a noncondensable gas on the absorption of water vapor by a $H_2O$ / LiBr combination with n-octanol as the surfactant. Nonflowing aqueous solutions of LiBr (40,45,50 mass％) were exposed to saturated water vapor following the addition of an n-octanol sufactant (0.01 and 0.6 mass％). A small amount of a noncondensable gas (air) was allowed into the absorber (0.03 volume％) and its effect was analyzed by measuring the amount of water vapor absorbed. This study will aid to predict the performance of heat pump and safety operating condition when the noncondensable gas is not allowed in the absorber The results indicate that, in the presence of small amounts of a noncondensable gas, vapor absorption enhancement ratios are less than half o( those obtained under the same experimental conditions when a noncondensable gas is not present (1). The presence of a noncondensable gas causes the partial vapor pressure of air to increase at the vapor / liquid interface, which results in an instability of vapor absorption rate nd. hence, in an inhibition of interfacial disturbance.

• Journal of Soil and Groundwater Environment
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• v.14 no.6
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• pp.87-94
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• 2009

Surfactant-enhanced air sparging (SEAS) was developed to suppress the surface tension of groundwater prior to air sparging resulting in higher air saturation and larger contact area between NAPL and gas during air sparging. Larger contacting interface between NAPL and gas means faster mass transfer of contaminants from NAPL to gas phase. This new technique, however, is limited to relatively volatile contaminants because vaporization is its basic mechanism of mass transfer. In this study, SEAS was tested at an elevated temperature for a semi-volatile n-decane, which is expected not to be a good candidate of SEAS application due to its low vapor pressure at ambient temperature. Three sparging experiments were conducted using 1-dimensional column (5 cm id, 80 cm length) packed with sand; (1) ambient temperature ($23^{\circ}C$), column saturated with distilled water, (2) SEAS at ambient temperature ($23^{\circ}C$), for n-decane contaminated sand, (3) SEAS at elevated temperature ($73^{\circ}C$), for n-decane contaminated sand. Higher air saturation was achieved by SEAS compared to that by air sparging without surfactant application. The n-decane removal efficiency of SEAS at elevated temperature was significantly higher(> 10 times) than that of ambient SEAS. The n-decane concentrations in the gas effluent from column during SEAS at $73^{\circ}C$ are found to be 10 times of those measured at ambient temperature. Thus, SEAS technique can be applied for removal of semi-volatile contaminants provided that an appropriate technique for elevating aquifer temperature is available.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.217-217
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• 2003

초전도체 선재를 제작하기위해 YBa$_2$Cu$_3$$O_{7-x}$ (YBCO) 와 Ni substrates사이의 계면 문제를 해결하기 위한 buffer layer로써 CaRuO$_3$ (CRO) thu film이 제안되었는데, 이런 buffer layer의 조건으로는Ni metal과 YBCO superconductor사이의 화학적 반응이 없어야 하고 metal component가 YBCO로 diffusion되는 것을 막아주어야 하며 substrates의 산화를 막아주어야 한다. 이런 조건을 만족시키는 것 중에서 CRO thin film이 가장 적절하였지만, CRO의 orthorhombic구조의 distortion에 의만 lattice mismatch 문제가 발생하였다. 이러한 문제를 해결하기 위해 이론적인 구조 분석을 통한 CRO의superconductor buffer layer로써의 가능성을 검토해 보는 것이 목적이다.

• Journal of the Microelectronics and Packaging Society
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• v.27 no.1
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• pp.37-43
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• 2020

The effects of O₂ plasma pre-treatment and post-annealing conditions on the interfacial adhesion of Ti thin film and WPR dielectric were investigated using 90° peel test for fan-out wafer level packaging (FOWLP) redistribution layer (RDL) applications. Peel strength between Ti film and WPR dielectric decreased from 8.9±1.3 g/mm to 2.7±0.9 g/mm for variation of O₂ plasma pre-treatment time from 30s to 300s, which is closely related to C-O-C or C=O bonds breakage at the WPR dielectric surface due to excessive plasma pre-treatment conditions. During post-annealing at 150℃, the peel strength abruptly decreased from 0 h to 24 h, and then maintained constant until 100 h, which is also mainly due to the damage of WPR dielectric which is weak to high temperature. Therefore, the optimum plasma pre-treatment conditions on the surface of dielectric is essential to interfacial reliability of FOWLP RDL.

• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.537-542
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• 1999

Removal of sulfur compounds in the petroleum products is essential for the prevention of sulfur oxides. However, conventional methods involving catalytic reactions are found to have some limitations in complete removal of harmful sulfur compounds and to require relatively high cost. Recently, desulfurization process using microorganisms is known to be promising in terms of excellent sulfur removal efficiency and reasonably low treatment cost. For the biodesulfurization process to be effective, the solubilization of sulfur compounds into aqueous solution is a prerequisite. In this study, polyoxyethylene nonionic surfactants were used in order to enhance the solubilization of sulfur spectrophotometer. The solubilization of sulfur compounds was found to increase with temperature and to bo abruptly increased at above 1 wt % surfactant solutions. It was also observed that the longer the hydrophobic chain of the surfactant molecule, the higher solubilizing power of a nonionic surfactant. It was found that the Tergitol series surfactants showed higher solubilizing capacity than Neodol series presumably due to the disruption of the regular packing in the hydrocarbon region of the surfactant aggregates.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.8
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• pp.449-455
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• 2016

This study is a part of research to develop a steel-concrete hybrid girder using ultra high-performance concrete with a compressive strength of 80 MPa. To this end, the Eurocode design formula for the shear resistance developed in a concrete-to-concrete interface was examined for the interface between concrete layers of different strengths. To examine the effect of the surface roughness on the shear resistance, a push-out test was conducted on specimens while considering the parameters of the Eurocode design equation. The actual behavior was evaluated with respect to the compressive strength of the concrete, the reinforcement ratio of the shear rebar, and the interfacial surface condition. The specimen with a rough interface shows 20-50% higher shear strength than that estimated by the design equation. In the case of failure mode, abrupt failure tends to occur at the interface of the concrete layer for the specimen with a low reinforcement ratio. It is expected that the shear strength of the concrete layer will increase according to the strength differential in the concrete layers.

• Proceedings of the Korean Nuclear Society Conference
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• 2003.05a
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• pp.147-147
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• 2003