• Title/Summary/Keyword: 계면력

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Key Parameter of Peel-off Test for Reliability Assessment of Toner Film (토너 박막의 신뢰성 평가를 위한 Peel-off Test의 주요인자)

  • Kim, Kwang-Il;Kim, Dae-Eun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.11
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    • pp.1567-1573
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    • 2010
  • In printing systems, the reliability of printed material depends on the ability of the toner film to remain adhered to the paper surface. In order to measure the strength between the toner film and the paper surface, a peel-off test is often performed. After conducting the test, the amount of toner film remaining on the paper is measured in order to determine the interfacial strength. The results of this test can be affected by many factors such as the peeling rate, weight of the roller used, and dwell time of tape. Sensitivity analysis was performed with respect to peeling rate, weight of roller and dwell time of tape at different levels. It was found that the interfacial strength increased with an increase in these main parameters. On the other hand, the trend with respect to the percentage of toner loss was different. Further, the interfacial strength and percentage of toner loss were significantly affected by the peeling rate.

The Interface Adhesion of Diamond Thin Film Grown on Si by EACVD (EACVD로 Si 위에 성장한 다이아몬드 박막의 계면 접합강도)

  • 이철로;박재홍;임재영;김관식;천병선
    • Journal of the Korean Vacuum Society
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    • v.2 no.3
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    • pp.374-383
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    • 1993
  • 필라멘트와 Si 기판 사이의 기전력을 20, 80, 140, 200V로 증가시키면서 EACVD에 의하여 성장된 다이아몬드 박막에 대하여 다이아몬드/Si 계면분석 및 계면강도를 측정하였다. 주사형전자현미경(SEM), 고분해능투과형전자현미경(HRTEM), 오제이전자분석기(AES)에 의해 계면상태를 분석한 결과, 기전력 증가에 따라 활성탄화수소 이온(CmHn-)에너지가 증가되어져 CmHn-이 Siso로 침투(Impringement)가 증가되고 침투된 높은 에너지의 CmHn-이 Si과 화학결합하여 생성되는 SiC층 깊이 및 농도 분포도 증가된다. 풀 시험(Pull test)에 의한 계면강도 측정 결과, SiC층 깊이 및 농도분포가 증가할수록 계면강도가 증가하였다. 관찰된 파면과 파면의 X-선 메핑 결과 및 HRTEM과 AES에 의한 분석 결과, 기전력 증가에 따라 공극율이 적고 치밀한 다이아몬드 박막이 성장된다. 그리고 생성되는 SiC층 농도 및 깊이 분포가 증가함에 따라 다이아몬드/Si 계면이 강화되고, 상대적으로 파괴는 다이아몬드/Si 계면이 아닌 SiC층이나 Si 내부에서 발생된다. 결국, 기전력을 증가하여 활성탄화수소이온의 에너지를 증가함으로써 계면강도가 우수하며 공극율이 매우 적고 치밀한 다이아몬드 박막을 성장할 수 있다.

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Effect of SMA on the Interfacial Shear Strength for Single Glass Fiber and PC/SAN Blends (SMA가 PC/SAN 블렌드와 유리섬유간의 계면결합력에 미치는 영향)

  • Lee, Ui-Hwan;Nam, Gi-Jun;Lee, Jae-Uk
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.512-520
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    • 2001
  • One of the most important factors which affect the mechanical properties of fiber-reinforced composite materials is the interfacial shear strength (IFSS). The IFSS of glass fiber and polycarbonate (PC)/styrene-co-acrylonitrile (SAN) blend system has been measured by the single fiber fragmentation test (SFFT). SAN contents were varied up to 30 wt% and the IFSS increased with the SAN contents. Styrene-co-maleic anhydride (SMA) was used as the compatibilizer and the glass fiber was surface treated with organosilane coupling agents. Addition of small amount of SMA in PC/SAN blend improved the IFSS by chemical bonding between maleic anhydride and silanol. The optimum MA content was 0.4 wt% of total matrix contents. Also, IFSS was greatly affected by the miscibility condition of SAN/SMA blends, which depended on the copolymer composition of SAN and SMA. It was found out that, higher IFSS could be obtained when the SAN/SMA blend was in miscible pairs. In case of SAN/SMA miscible pairs, the IFSS depended on the MA content in total matrix, not on the MA content in SMA.

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Studies on Physical Behavior of Alkyl Polyglucosides (I) - Interfacial Activities and Detergency - (Alkyl Polyglucoside 계면활성제의 물리적 거동에 관한 연구 (I) - 계면활성과 세정력에 관하여 -)

  • Yoon, Yeo-Kyung;Choi, Kyu-Suk
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.451-456
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    • 1994
  • Alkyl polyglucosides (APG), so called natural nonionic surfactants, are prepared with glucose from corn starch and fatty alcohol from palm and/or coconut oil. When we studied on interfacial properties of APG, surface and interfacial tension, cmc, foaming and effectiveness, according to degree of polymerization of glucose unit (D.P.=1.2~1.8) and alkyl chain length, the former hardly affects but the latter greatly affects on them. The order of detergency for fatty acid soils decreased as followings ; APG 0814> APG 1214> APG 10> APG 0810> APG 08, and the samples with lowest interfacial tension and maximum adsorption had a better detergency.

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Effects of Diols on the foaming and emulsion properties in surfactant solutions

  • Lee, Giam;Oh, Seong-Geun
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.4
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    • pp.488-498
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    • 2022
  • The effects of 1,3-Butanediol, 1,2-Pentanediol, and 1,2-Hexanediol in surfactant solutions on cmc, surface tension, foaming and emulsifying properties were determined. The addition of diols in aqueous surfactant solution decreased cmc and surface tension, and enhanced the foaming and emulsifying power. This trend is more significant by the longer hydrocarbon chain length of the diols. This property was confirmed because the diol's alkyl chain and the hydrophobic interaction with the surfactant reduce the cohesive force of water and increase the interaction between the head groups of the surfactant at interface. In addition, MIC test was conducted to determine the preservative power of each diol, and as a result, the antibacterial activity was effective in the order of 1,2-HDO > 1,2-PDO > 1,3-BDO. The results of this study show that diol can be applied to cosmetics as an auxiliary surfactant and antibacterial agent.

Limonene 유화공정에 의한 환경친화성 수성세정제 개발

  • Kim, Min-Hui;Ryu, Hwa-Yeol;Ju, Chang-Sik;Kim, Si-Yeong
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2006.11a
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    • pp.519-520
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    • 2006
  • 계면활성제의 종류로 OA-n계열에서 분자량이 낮은 OA 300이 가장 우수한 세척력을 보였고 계면활성제의 함량은 3 wt.%일 때 가장 좋았다. 이는 평균입경이 작고 접촉각이 낮은 것으로 분석되어지며 세척력은 우수하지만 저장안정성은 떨어졌다. 그러나 OA 600의 경우 세척력은 떨어지나 저장안정성이 우수하여 이를 혼합한 계면활성제를 사용하여 저장안정성을 높였다.

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Measurement of Isoelectric Point of Betaine Zwitterionic Surfactant by QCM(Quartz Crystal Microbalance) (QCM(Quartz Crystal Microbalance)을 이용한 Betaine 양쪽성 계면활성제의 등전점 측정)

  • Kim, Ji Sung;Park, Jun Seok;Lim, Jong Choo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.31-37
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    • 2009
  • A zwitterionic surfactant shows not only detergency but also mildness effect since it shows characteristics of a nonionic or an anionic surfactant above an isoelectric point, while showing characteristics of a cationic surfactant below an isoelectric point. Therefore, a zwitterionic surfactant can serve as a dual function surfactant by a single molecule through the interconversion of cleaning and softening effects depending on pH variations of the aqueous solution. In this study, physical properties of betaine surfactant such as CMC, surface tension, interfacial tension, contact angle and viscosity were measured and phase behavior study was performed. Also dual function characteristics of betaine zwitterionic surfactant were investigated by measuring an isoelectric point using QCM(quartz crystal microbalance) and zeta potential measurement. The CMC of betaine surfactant was near $10^{-4}mol/L$ and the surface tension at CMC was about 32 mN/m. The interfacial tension between 1 wt% aqueous solution and n-decane measured by spinning drop tensiometer at pH 2~10 resulted in an increase in interfacial tension until pH 5 and a decrease with pH after 5 and equilibration time showed the similar trend with an increase in pH. The isoelectric point of betaine surfactant measured by QCM experiment was found to exist between 3.0 and 3.3, which is the same as the result determined by zeta potential measurement.

Adhesion Behaviors of Semiconductive-Insulation Interfaced Liquid Silicone Rubber for EHV Cable Accessory (초고압 접속재용 반도전-절연체 액상실리콘 계면의 접착거동)

  • Yoon, Seung-Hoon;Kim, Hyun-Seok;Kim, Ji-Hwan;Lee, Jung-Hee
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.123-127
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    • 2003
  • 액상실리콘으로 이루어진 초고압전력케이블용 프리몰드 접속재의 반도전-절연체 계면접합체를 다양한 제조조건과 조합별로 제조하여 계면접착력에 대한 영향을 검토하였다. 후가교적용 시 계면접착력이 강화되며 grade조합에 따른 특성차이가 존재하였다. 하지만 고온 장시간의 후가교 조건에서는 계면간의 화학적 결합력의 저하로 인해 오히려 접착력이 낮아지기도 하였다. 절연 RTV와의 계면접착성은 S-1재료가, 절연 LSR의 경우에는 S-3 재료가 가장 우수하였으며 도전안정성 측면에서도 S-3 재료가 상대적으로 유리하였다. 매입형 전극체를 제조하여 절연파괴거동을 연구한 결과 계면접착성과의 직접적인 상관관계는 크지 않음을 알 수 있었다.

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Studies on the N-Acyl Amino Acid Type Surfactants(4) Surface Active Properties of N-Acyl-N-Methyl-β-Alanine Salts (N-아실 아미노산계 계면활성제에 관한 연구 (제 4 보) N-아실-N-메틸-β-알라닌 염류의 계면활성)

  • No, Seung-Ho;Lee, Sun-Ju;Kim, Tae-Young;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.216-221
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    • 1991
  • Surface activities of four potassium N-acyl-N-methyl-${\beta}$-alaninate including surface tension, foaming power, foam stability, emulsifying power and dispersion power were measured respectively, and critical micelle concentration(cmc) was evaluated. Consequently these anionic surfactants with long chain acyl amide showed good emusifying power of O/W type, foaming, foam stability and dispersion effect.

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