• Journal of the korean academy of Pediatric Dentistry
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• v.38 no.3
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• pp.229-236
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• 2011

ProRoot MTA(Dentsply Tulsa, U.S.A) which has similar component with Portland cement has setting expansion character and long setting time. Excessive expansion can cause fracture at the apical portion of the root and decreasing of volume stability. And the long setting time makes additional visits for crown restoration and slow setting process of this material can change physical properties itself. In this study, among requirements of root canal filling material(KS P ISO 6876) which is revised at 2008, we investigated the setting time and setting expansion. Objects are recently developed OrthoMTA(BioMTA, Korea), conventional ProRoot white MTA(Dentsply Tulsa, U.S.A) and White portland cement(Union, Korea). The results in setting expansion, OrthoMTA was $0.08{\pm}0.02%$, ProRoot white MTA and White portland cement were each $0.28{\pm}0.06$, $0.80{\pm}0.25%$(p<0.05). The results in setting time, OrthoMTA, ProRoot white MTA, White portland cement were each $307.78{\pm}3.83$ min, $150.44{\pm}2.35$ min, $235.33{\pm}9.07$ min(p<0.05).

• Journal of Adhesion and Interface
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• v.21 no.2
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• pp.65-70
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• 2020

Epoxy adhesive was mainly used to combine different composite materials. Epoxy adhesive was a typical thermosetting resin that can be bonded by changing from a linear structure to a three-dimensional network structure by curing reaction of epoxy and hardener. The curing conditions of epoxy adhesive were different with different types of hardener such as mixing ratio, curing time, and temperature. These curing conditions affected to the adhesive property of epoxy adhesive. In industry, it was difficult to proceed the applying epoxy adhesive and combining two parts immediately. The adhesive property decreased by humidity and pre-curing of epoxy adhesive in waiting time between two processes. In this paper, the glass fiber reinforced composite (GFRC) was combined with epoxy adhesive and adhesion property between epoxy adhesive and GFRCs was evaluated using single lap shear test. The different waiting times and humidity conditions were applied to epoxy adhesive in room temperature and adhesive property decreased as the waiting time increased. In small amount of humidity, the adhesive property increased because a small amount of moisture in the surroundings accelerated the curing reaction. In certain amount of humidity, however, the adhesion property decreased.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.233-233
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• 2009

기존 표면열처리기술에 단점인 대면적, 신속열처리를 위해 수중플라즈마 기술을 이용하여 표면경화와 경화 깊이층 제어를 실시였다. 수중플라즈마의 전원장치에 전압과 주기적인 전압과 시간을 달리하여 각각의 시편의 경도변화와 미세조직변화를 관찰하였다. 300V이상의 전압에서는 마르텐사이트가 관찰되었으며, 300V이하에서는 초석페라이트와 펄라이트가 혼합된상의 구조를 관찰할 수 있었다. 주기적인 전압과 시간을 달리하여 표면에서부터 $300{\mu}m$ 깊이만의 마르텐사이트로 형성시켜 경화 깊이층 제어가 가능하였다.

• Proceedings of the Korean Society of Disaster Information Conference
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• 2017.11a
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• pp.227-228
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• 2017

본 논문에 사용되는 칩들의 결합을 위해 다양한 접착제(바인더)가 나와 있으나, 환경 친화적인 제품이 많지 않고, 접착력이 떨어지고, 탄성이 작고, 경화시간이 길어서 제품 성능과 작업성에 문제가 많다. 본 Soft 포장재의 경우 하부층과 상부층의 2층 구조를 함으로써 보다 견고하고 내구성이 있는 구조를 가질 수 있으나, 하부층의 경화속도가 늦으면 시공이 길어지게 되기 때문에 경화시간을 단축할 접착제(바인더)의 개발이 절실히 요구된다. 또한 재료의 배합비율을 조절하여 Soft한 정도를 용도에 맞추어 그 배합비의 정도나 표준화된 단면을 적용하여야 한다.

• Journal of the Korean Geosynthetics Society
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• v.16 no.2
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• pp.131-138
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• 2017

In this study, the expansion and compressive strength tests of emergency restoration material were carried out to restore cavity causing ground subsidence. The expansion and compressive strength characteristics according to component ratio of main material - hardener and mix proportion of blowing agent - accelerator were analyzed based on the test results. As a result of the relationship of curing time - expansion ratio analyses, it confirmed that expansion ratio decreased with reduced curing time regardless of mix proportion of blowing agent - accelerator in main material, if component ratio of hardener increased. This means that component ratio of the main material - hardener had greatly affected the expansion ratio. The compressive strength characteristics of emergency restoration material confirmed that strength was affected by mix proportion of blowing agent - accelerator. Therefore, it is necessary to apply reasonable component ratio and mix proportion to consider the required injection time, expansion ratio and strength of restoration material, when emergency restoration in ground cavity is required.

• Journal of the Korean GEO-environmental Society
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• v.11 no.11
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• pp.77-85
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• 2010

Unconfined compressive strength tests were performed to evaluate curing characteristics of controlled low strength material(CLSM) made with coal ashes. It is found that unconfined compressive strength normalized by curing times, increases as decreasing the water contents of CLSM particularly during first three days. Dynamic cone penetrometer tests were also carried out to evaluate cost-effective CLSM lump strength characteristics with time. It takes around 10 days to reach target strength, 500kPa (penetration rate, 20mm/blow). Curing rate significantly decreases after 10 days elapsed regardless of CLSM formulation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.5D
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• pp.483-492
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• 2012

The early setting time of concrete is an important factor determining the slip up velocity of the slip-form system. Accordingly, need is for a technique evaluating the early setting time in order to secure the safety of the slip-form system and the construction quality of concrete. This paper intends to estimate the early setting time by evaluating the setting degree of concrete using surface wave velocity so as to determine the slip up time of the slip-form system. Penetration resistance test and compressive strength test are performed first to clarify the relationship between the early setting time of concrete and the compressive strength. Then, compressive strength test and ultrasonic wave test are conducted to examine the relation between the compressive strength and the surface wave velocity. Continuous wavelet transform is adopted to measure the surface wave velocity. Numerical analysis is carried out to demonstrate the appropriateness of the application of continuous wavelet transform. Based on these results, the propagation velocity of the surface wave required for the slip up of slip-form system is suggested. Finally, a reduced model test of the slip-form system is conducted to verify the feasibility of the proposed surface wave velocity for the determination of th slip up velocity.

• 대한치과보철학회:학술대회논문집
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• 1996.11a
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• pp.83-84
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• 1996

• The Korean Journal of Rheology
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• v.10 no.4
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• pp.227-233
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• 1998

The effects of 1 mol% N-benzylpyrazinium hexafluoroantimonate(BPH) as a thermal latent initiator and blend compositions composed of cycloaliphatic and DGEBA epoxies were investigated in the rheological properties and cure kinetics. Latent properties were performed by measurement of the conversion as a function of reaction time using isothermal DSC at $150^{\circ}C$ and $50^{\circ}C$ Rheological properties of the blend systems were investigated in terms of isothermal experiments using a rheometer. The gelation time was obtained from the evaluation of storage modulus (G'), loss modulus (G") and damping factor (tan$\delta$)). Cross-linking activation energy ($E_c$) was also determined from the Arrhenius equation based on gel time and curing temperature. As a result, the gel time and cross-linking activation energy increased with increasing DGEBA composition. The cure activation energies ($E_a$) were obtained by Kissinger method using dynamic DSC thermograms. In this work, the cure activation energy decreased with increasing CAE concentration, which might be resulted from the short repeat units, simple side-groups and viscosity of reaction media.edia.

• Composites Research
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• v.17 no.4
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• pp.40-46
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• 2004

A single lap shear test was used to investigate the effects of the ratio of a catalyst to a self-healing agent and curing temperature on the bond performance of autonomic polymer composites. DCPD (dicyclopentadiene), ENB (5-ethylidene-2-norbornene), and their mixture were used as self-healing agents and bis(triclohexylphosphine) benzyllidine ruthenium (IV) dichloride Grubbs' catalyst was used as a catalyst. During the experiments, the catalyst ratios of 1.0wt% and 0.5wt% were applied to DCPD, the catalyst ratio of 0.lwt% was applied to ENB, and the catalyst ratio of 0.5wt% was applied to the mixtutes of DPCD and ENB. In addition, the curing temperatures of $25^{\circ}C$, $60{\circ}C$, and $80^{\circ}C$ were considered. According to the results, the higher catalyst ratio and the longer curing time were required to obtain more stabilized bond shear strength of DCPD. ENB with a lower catalyst ratio was cured faster than DCPD. Unlike DCPD, ENB stabilized after a steady fall from its peak as the curing time increased. Moreover, the mixtures of DCPD and ENB revealed similar curing behavior to ENB, but the increase in mixture ratio of ENB to DCPD caused curing process to be faster. Also the increase in curing temperature caused the bond shear strength to be higher and the curing time to be quicker.