• Title/Summary/Keyword: 경북대학교

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Ruthenium Complex-Catalyzed Synthesis of Indoles from N-Substituted Anilines and Alkanolamines

  • 이동엽;조찬식;김주의;윤영주;심상철;송한철
    • Bulletin of the Korean Chemical Society
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    • v.17 no.12
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    • pp.1132-1135
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    • 1996
  • N-Substituted anilines react with triethanolamine at 180℃ in the presence of a catalytic amount of tris(triphenylphosphine)ruthenium(Ⅱ) chloride to give the corresponding 1-substituted indoles in good to high yields. Similar treatment of the anilines with N-benzyldiethanolamine or triisopropanolamine in place of triethanolamine also affords the indoles in good yields. An intermolecular alkyl group transfer between anilines and alkanolamines is assumed to be the key step of these reactions.

Retraction: Changes in the volatile aromatic compounds and amino acid contents of distilled soju using co-fermentation by Saccharomyces cerevisiae and Hanseniaspora uvarum yeasts (Retraction: Saccharomyces cerevisiae 와 Hanseniaspora uvarum 효모 혼합발효를 이용한 증류식 소주의 휘발성 향기성분 및 아미노산 함량 변화)