• Title/Summary/Keyword: 결합분석

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Synthesis of aluminum contained polycarbosilane and preparation of Si-Al-C-O nanocomposite fiber (Aluminum이 첨가된 polycarbosilane 합성 및 Si-Al-C-O 나노복합섬유 제조)

  • 신동근;류도형;김영희;김형래;정영근
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.240-240
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    • 2003
  • SiC 섬유의 고온강도를 향상시키기 위한 소결조제로 boron, aluminum 등을 사용할 수 있다. 본 연구에서는 폴리카보실란에 aluminum precursor를 첨가한 후 중합반응을 거쳐 Al-contained polycarbosilane을 합성하였다. 합성된 Al-contained polycarbosilane을 용융방사하여 섬유화 하고 열분해 공정을 통해 Si-Al-C-O 나노복합 섬유를 제조하였다. 먼저 aluminum butoxide와 polycarbosilane(commercial)을 200m1 xylene에 용해시켜 14$0^{\circ}C$에서 1시간 동안 reflux하였다. evaporator를 이용하여 xylene를 제거한 후 autoclave에서 25$0^{\circ}C$/30$0^{\circ}C$ 중합과정을 통해 가교결합 시켰다 이와 같이 합성된 시료는 ICP분석을 통해 aluminum 함량을 확인하였고 FT-IR(Fig.1) 및 GPC분석(Fig.2)으로부터 화학구조 및 분자량변화를 확인하였다. aluminum 첨가량이 증가함에 따라 Si-H/Si-$CH_3$의 결합크기의 비가 감소하였으며 이로부터 aluminum butoxide와 polycarbosilane의 가교결합이 이루어진 것으로 보이며 중합 후 분자량의 증가 또한 가교결합에 의한 결과로 사료된다 열무게감량(TGA) 측정 결과는 40$0^{\circ}C$부터 유기리간드의 분해가 일어나며 80$0^{\circ}C$이상에서 세라믹화 과정이 완료되었음을 알 수 있었다 또한 aluminum 첨가량이 증가함에 따라 세라믹 수율도 증가하였음을 확인하였다. 합성된 aluminum-contained polycarbosilane은 20$0^{\circ}C$에서 1시간 동안 불융화과정을 거쳐 환원 및 진공 분위기에서 고온 열처리하였으며 이로부터 얻어진 시료에 대해 XRD분석을 수행하였다. SEM과 TEM을 이용하여 미세구조를 관찰하였다.

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Analysis of Optimum Bias for Maximun Conversion Gain of Cascode Coupled Microwave Self-Oscillating-Mixer (Cascode 결합 마이크로파 자기발진 믹서의 최적변환이득을 위한 바이어스 조건 분석)

  • 이성주;이영철
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.3
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    • pp.492-498
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    • 2003
  • In this paper, We analyze the optimum bias conditions of cascode coupled microwave mixer for maximum conversion gain mixer. Microwave self-oscillating mixer by two GaAs MESFET cascode coupled, to upper GaAs MESFET operating as a oscillator with high Q dielectric resonator and the lower GaAs MESFET operated as a mixer with low noise and high conversion characteristics. As a result of experiments, cascode coupled microwave self oscillating mixer according to optimun bias shows an 5.92 dBm oscillating power, -132.0dBc/Hz @ 100KHz at 5.15GHz and 3dB conversion loss.

Implementation of Nano-Scale Grating-Assisted Coupler with Polarization-Insensitivity using Double-Sandwiched Guide (이중 샌드위치 도파로를 사용한 편광 무의존성 특성을 갖는 나노크기 격자 구조형 결합기의 구현)

  • Ho, Kwang-Chun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.2
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    • pp.221-227
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    • 2015
  • The polarization characteristics of nano-scale grating-assisted polarization-insensitive coupler (GA-PIC) consisted of double sandwiched rib-type layers are evaluated in detail by using modal transmission-line theory (MTLT) based on equivalent network. To obtain the polarization-insensitive condition of GA-PIC, the coupling lengths as a function of the refractive index and thickness of sandwiched rib-type layer as well as the grating thickness and period are analyzed for quasi-TE and quasi-TM modes. The numerical results show that the GA-PIC with hundreds of nanometer scale is realized by properly choosing structural and material parameters of double sandwiched layers and grating.

Self-Aggregated Nanoparticles of Lipoic Acid Conjugated Hyaluronic Acid (히알루론산에 결합된 리포산 자기조립체의 제조 및 특성)

  • Hong, In-Rim;Kim, Young-Jin
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.561-565
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    • 2008
  • Hyaluronic acid (HA) is a natural glycosaminoglycan and is used widely in the pharmaceutical field. Lipoic acid (LA) helps the regeneration of exogenous and endogenous antioxidants such as Vitamin C and Vitamin E as well as glutathione. It also acts as antioxidant indirectly. Hydrophilic HA as a biodegradable and biocompatible polymer was conjugated with hydrophobic LA as an antioxidant to form the graft copolymer. The carboxyl group of HA was modified by adipic acid dihydrazide (ADH). The synthesis of HA-g-LA graft copolymers was characterized by FT-IR, $^1H$-NMR spectroscopy. The conjugates could form the self-assembled nanoparticles in aqueous solution. The particle size and critical aggregation concentration were verified to use the nanoparticle as a carrier fur the hydrophobic material.

Optical Characteristics of Blazed Grating-Assisted Directional Coupler (Blazed 격자 구조형 방향성 결합기의 광학 특성)

  • Ho, Kwang-Chun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.19 no.5
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    • pp.175-180
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    • 2019
  • The optical characteristics and power transfers between guiding channels of blazed grating-assisted directional coupler (B-GADC) are evaluated in detail by using novel and rigorous modal transmission-line theory (MTLT) based on eigenvalue problem. To evaluate the coupling efficiency of B-GADC, the dispersion curves as a function of the grating period and wavelength are analyzed numerically for quasi-TE and quasi-TM modes. Furthermore, symmetric, sawtooth and asymmetric grating profiles are considered to know the effect of blazing characteristics on power transfer of GADC. The numerical results show that the grating period for minimum-gap condition to obtain maximum power transfer decreases gradually as the blazed structure changes from symmetric to asymmetric profile. On the other hand, the coupling length increases reversely.

Plasma Surface Modification of Graphene and Combination with Bacteria Cellulose (Graphene의 플라즈마 표면 개질과 박테리아 셀룰로오스와의 결합성 검토)

  • Yim, Eun-Chae;Kim, Seong-Jun;Oh, Il-Kwon;Kee, Chang-Doo
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.388-393
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    • 2013
  • The study was focused to evaluate the possibility for combination membrane of bacterial cellulose (BC) and graphene with high electrical properties. BC with natural polymer matrix was known to have strong physical strength. For the combination of graphene with BC, the surface of graphene was modified with oxygen plasma by changing strength and time of radio waves in room temperature. Water contact angle of modified graphene grew smaller from $130^{\circ}$ to $12^{\circ}$. XPS analysis showed that oxygen content after treatment increased from 2.99 to 10.98%. Damage degree of graphene was examined from $I_D/I_G$ ratio of Raman analysis. $I_D/I_G$ ratio of non-treated graphene (NTG) was 0.11, and 0.36 to 0.43 in plasma treated graphene (PTG), increasing structural defects of PTG. XRD analysis of PTG membrane with BC was $2{\theta}$ same to BC only, indicating chemically combined membrane. In FT-IR analysis, 1,000 to 1,300 $cm^{-1}$ (C=O) peak indicating oxygen radicals in PTG membrane had formed was larger than NTG membrane. The results suggest that BC as an alternation of plastic material for graphene combination has a possibility in some degree on the part like transparent conductive films.

An Optimization Model Based on Combining Possibility of Boundaries for Districting Problems (경계 결합 가능성 기반 구역설정 최적화 모델)

  • Kim, Kamyoung
    • Journal of the Korean Geographical Society
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    • v.49 no.3
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    • pp.423-437
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    • 2014
  • Districting is a spatial decision making process to make a new regional framework for affecting human activities. Natural barriers such as rivers and mountains located within a reorganized district may reduce the efficiency of reorganized human activities. This implies that it is necessary to consider boundary characteristics in a districting process. The purpose of this research is to develop a new spatial optimization model based on boundary characteristics for districting problems. The boundary characteristics are evaluated as continuous value expressing the possibility of combining adjacent two basic spatial units rather than a dichotomous value with 1 or 0 and are defined as an objective function in the model. In addition, the model has explicitly formulated contiguity constraints as well as constraints enforcing demand balance among districts such as population and area. The boundary attributes are categorized into physical and relational characteristics. Suitability analysis is used to combine various variables related to each boundary characteristic and to evaluate the coupling possibility between two neighboring basic units. The model is applied to an administrative redistricting problem. The analytical results demonstrate that various boundary characteristics could be modeled in terms of mixed integer programming (MIP).

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Performance analysis of underwater acoustic communication based on beam diversity in deep water (심해에서의 빔 다이버시티를 이용한 수중음향통신 성능 분석)

  • Kim, Donghyeon;Park, Heejin;Kim, J. S.;Park, Joung-Soo;Hahn, Joo Young
    • The Journal of the Acoustical Society of Korea
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    • v.38 no.6
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    • pp.678-686
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    • 2019
  • Underwater communication performance is degraded by the influence of Inter-Symbol Interference (ISI) due to multipath. Passive time reversal processing is the most effective technique for mitigating multipath, and the diversity combining method can be used to improve its performance. This paper analyzed communication performance using the beam diversity combining method, which combines signals obtained through the beam steering to various angles. Directions of arrival were estimated through the beam-time migration, which, in turn, was estimated from probe signals received by a vertical line array. The performance was analyzed based on the number and type of combinations among the estimated angles. In this paper, the data obtained from the Biomimetic Long range Acoustic Communications 2018 (BLAC18) experiment, which was conducted in the East sea, ~50 km east of Pohang, in October 2018, were used for the analysis. The output Signal to Noise Ratio (SNR) was used as communication indicators.

A Discourse-based Compositional Approach to Overcome Drawbacks of Sequence-based Composition in Text Modeling via Neural Networks (신경망 기반 텍스트 모델링에 있어 순차적 결합 방법의 한계점과 이를 극복하기 위한 담화 기반의 결합 방법)

  • Lee, Kangwook;Han, Sanggyu;Myaeng, Sung-Hyon
    • KIISE Transactions on Computing Practices
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    • v.23 no.12
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    • pp.698-702
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    • 2017
  • Since the introduction of Deep Neural Networks to the Natural Language Processing field, two major approaches have been considered for modeling text. One method involved learning embeddings, i.e. the distributed representations containing abstract semantics of words or sentences, with the textual context. The other strategy consisted of composing the embeddings trained by the above to get embeddings of longer texts. However, most studies of the composition methods just adopt word embeddings without consideration of the optimal embedding unit and the optimal method of composition. In this paper, we conducted experiments to analyze the optimal embedding unit and the optimal composition method for modeling longer texts, such as documents. In addition, we suggest a new discourse-based composition to overcome the limitation of the sequential composition method on composing sentence embeddings.

Outage Probability Analysis of Macro Diversity Combining Based on Stochastic Geometry (매크로 다이버시티 결합의 확률 기하 이론 기반 Outage 확률 분석)

  • Zihan, Ewaldo;Choi, Kae-Won
    • The Journal of the Korea institute of electronic communication sciences
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    • v.9 no.2
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    • pp.187-194
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    • 2014
  • In this paper, we analyze the outage probability of macro diversity combining in cellular networks in consideration of aggregate interference from other mobile stations (MSs). Different from existing works analyzing the outage probability of macro diversity combining, we focus on a diversity gain attained by selecting a base station (BS) subject to relatively low aggregate interference. In our model, MSs are randomly located according to a Poisson point process. The outage probability is analyzed by approximating the multivariate distribution of aggregate interferences on multiple BSs by a multivariate lognormal distribution.