• Title/Summary/Keyword: 결정화유리

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A study on the thermochromism of $V_{1-x}M_xO_2$thin film ($V_{1-x}M_xO_2$박막의 thermochromism에 대한 연구)

  • Lee, Si-U;Lee, Mun-Hui
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.715-722
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    • 1994
  • Thermochromic $Vo_{2}$ thin films for "smart windows" were prepared by electron beam evaporationmethod on a glass substrate and spectral transmittances were examined by spectrophotometer. Substratetemperature of $300^{\circ}C$ and annealing temperature of $400^{\circ}C$ were found to be effective to give athermochromism on $Vo_{2}$ thin film due to the crystallization of the thin film. Furthermore, annealing of$Vo_{2}$ thin film affected the spectral transmittance and reduced the transmittance significantly at wavelengthbelow 500nm.$V_{0.95}W_{0.05}O_{2}$ thin film doped by 5 atomic percent of W showed semiconductor-metal transition around 0$0^{\circ}V_{0.995}W_{0.005}O_{2}$thin film which contains 0.5 atomic percent Sn showed therrnochrornisrn when it was depositedat substrate temperature of $300^{\circ}C$ and annealed at $450^{\circ}C$ for 5 hours in argon gas. The transitiontemperature of the $V_{0.995}W_{0.005}O_{2}$ thin film was found to be about $25^{\circ}C$ and showed some hysterisis. and showed some hysterisis.

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Characterization of Microbial Nitrate Uptake by Bacillus sp. PCE3 (Bacillus sp. PCE3 균주에 의한 질산이온 흡수 특성)

  • Yun, Yeong-Bae;Park, Soo-Jin;Han, Min-Woo;Kim, Young-Kee
    • Journal of Applied Biological Chemistry
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    • v.56 no.4
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    • pp.241-244
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    • 2013
  • Nitrate is one of the major nutrients in plants, and nitrate fertilizer often overused for the high yields of crops. Nitrate deposit in soil became one of the major reasons causing salt stress. Specially, salt stress is a serious problem in the soils of plastic film or glass houses. In this study, six microorganisms have been isolated from the wet soils near the disposals of livestock farms and their nitrate uptake activities were investigated. These bacteria were able to remove nitrate as high as 1,000-3,000 ppm (10-50 mM). The strain PCE3 showed the highest nitrate uptake activity and it removed more than 3,700 ppm. In order to identify these bacteria, genes of 16S rRNA were sequenced and analyzed. Phylogenetic trees were constructed with the neighbor-joining methods. Among these bacteria, strain PCE3 was identified as Bacillus species. When the growth and nitrate uptake activities were measured, both were maximal at $37^{\circ}C$ and optimal pH was pH 7-9. Bacillus sp. PCE3 removed nitrate up to 40-60 mM (2,500-3,700 ppm) depending on the nitrate concentration in media. Therefore, Bacillus sp. PCE3 can be a good candidate for the microbial remediation of nitrate-deposited soils in glass and plastic film houses.

Synthesizing Behavior of Calcium Chloroaluminate with using MSWI Fly Ash in the Different Sintering Conditions (생활폐기물(生活廢棄物) 소각(燒却) 비산(飛散)재의 소성(燒成) 조건(條件)에 따른 Calcium Chloroaluminate 합성(合成) 거동(擧動)에 관한 연구(硏究))

  • Yoo, Kwang-Suk;Lee, Seong-Ho;Hwang, Sun-Ho;Ahn, Ji-Whan
    • Resources Recycling
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    • v.19 no.5
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    • pp.68-74
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    • 2010
  • The aim of this study is to investigate the behaviors of synthesis of Calcium Chloroaluminte($11CaO{\cdot}7Al_2O_3{\cdot}CaCl_2$) under the melting temperature of municipal solid waste incineration fly ash(MSWI fly ash); $900^{\circ}C-1300^{\circ}C$ of sintering temperature. A sludge generated from a water purification plant (SW) was also used to fill up $Al_2O_3$ source, which might be deficient in MSWI fly ash. MF and SW were mixed at mixing ratio of 10 to 7, which is the mole ratio of CaO to $Al_2O_3$ of calcium Chloroaluminte. Mixed samples were sintered in the opened sintering reactor and the closed sintering reactor, respectively. The results showed that calcium chloroaluminte was formed at $1,000^{\circ}C$ in both reactors, but the temperature of decomposition of calcium chloroaluminte depended upon sintering reactor type; an opened sintering reactor and a closed sintering reactor, owing to the vaporization velocity of Cl.

Possibility about Application and Interpretation of Surface Nondestructive X-ray Diffraction Method for Cultural Heritage Samples by Material (유형별 문화재 시료의 비파괴 표면 X-선 회절분석법 적용과 해석 가능성)

  • Moon, Dong Hyeok;Lee, Myeong Seong
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.4
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    • pp.287-301
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    • 2019
  • Preservation of the original form is the principle for conservation, management and utilization of cultural heritages. Thus, non-destructive analysis of these samples are important field of the conservation science. In this study, examined the applicability of nondestructive surface X-ray diffraction analysis (ND-XRD) for cultural heritage by materials (rock specimen, jade stone, pigment painted specimen, earthen artifact, metal artifact). In result, all type of sample is recorded suitable X-ray diffraction patterns for identifying mineral composition in case of surface condition with adequate particle size and arrangement. And diffraction pattern is reflected surface information than matrix. Therefore, ND-XRD is thought to be applicable not only mineral identification but also interpretation of manufacturing technique and alteration trend about layered sample (in horizontally or vertically). Whereas some exceptional diffraction patterns were recorded due to overlapping information on specific crystal planes. It caused by skip the sample treatment (powdering and randomly orientation). It could be advantageously used for mineral identification, such as preferred orientation of clay minerals. In contrast, irregular diffraction pattern caused by single crystalline effect is required careful evaluation.

The Characterizations of Tape Casting for Low Temperature Sintered Microwave Ceramics Composite (저온소성 마이크로파 유전체 세라믹스 복합체의 Tape Casting특성)

  • Lee, Woo-Suk;Kim, Chang-Hwan;Ha, Mun-Su;Jeong, Soon-Jong;Song, Jae-Sung;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.132-139
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    • 2005
  • Sintering behavior of $BaO-Nd_{2}O_3-TiO_2$ with a Pb-based glassceramics frit were investigated in order to understand an effect of glassceramics as a low temperature sintering agent on dielectric ceramics. A green sheet form was fabricated through tape casting method with the glassceramic fut added $BaO-Nd_{2}O_3-TiO_2$. The dispersion properties, rheological properties and final density of dielectric composit slurry as a function of amount and composition of organic additives was examined. The dispersants' addition was effective in controlling dispersion of the ceramics in solution. The addition of excessive dispersant showed adverse effect on dispersion. The prepared slurries, containing ceramic : powders, glass-ceramics and various kinds of organic viechles, exhibited typical shear thinning behavior. The best properties of tape casting appeared powder to solvent ratio 65 : 35 and amount of the binder 6 wt$\%$ and plasticizer 3 wt$\%$. The viscosity of the slurry was 677 cps and green/sintered density in the tape was $3.3 g/cm^3,\;5.56 g/cm^3$ respectively.

Evaluation of field applicability for grouting method using self-healing grout material (자기치유 물질을 이용한 그라우팅공법의 현장적용성 평가)

  • Choi, Yong-Sung;Kim, Byoung-Il;Yoo, Wan-Kyu;Lee, Jae-Dug;Choi, Yong-Ki
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.5
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    • pp.485-500
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    • 2020
  • Due to various advantages such as small facilities, ease of construction and so on, the grouting technology which is widely used in construction field has developed remarkably compared with the past. However, the efforts to improve the homogeneity of quality, long-term durability and environmental problems have been continued. In recent years, new grouting method has been developed in order to solve problems such as low strength, durability and leaching phenomenon of liquid glass (sodium silicate) grouting material in Korea. A newly developed method integrates the injection material with the ground by the self-healing material of crystallization growth type. For this reason, it is known that improvement of the durability and water quality of the ground, prevention of leaching, and environment friendliness can be expected. The present study applied a newly developed method to test sites and verified its effect such as injection range, improvement effect, waterproofing performance and so on. Standard penetration test, field permeability test, borehole shear test, pressuremeter test and pH test were conducted, and the results were compared between before and after developed method application. As results of tests, the field applicability and improvement effect of developed method were proved to be excellent.

Study on Mineralogical Characteristics and Firing Condition of the 4-6th Century Earthenware Excavated from the Seonggok-ri, Cheongdo-gun, Gyeongsangbuk-do (경상북도 청도군 성곡리에서 출토된 4-6세기 토기의 광물학적 특성 연구 및 소성환경 추정)

  • Woo, Hyeon Dong;Kim, Ok Soon;Jang, Yun Deuk
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.3
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    • pp.123-129
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    • 2016
  • This study is conducted to estimate the firing temperature and condition of the 4-6th Century earthenwares excavated from the ancient tombs in the Seonggok-ri, Cheongdo through mineralogical approaches, and to contrast to the characteristics of the earthenware from the Changnyeong the adjacent area to the Cheongdo. The Cheongdo earthenware was mainly composed of quartz, pores and vitric matrix with minor parts of feldspars, felsic volcanic fragments and opaque minerals, of which quartz crystals frequently show embayed texture and pores was partly filled with amorphous quartz. Mullite, hematite and cristobalite were found by XRD spectrometer additionally, and in the SEM image the Mullite contents are evenly distributed from the central part to the marginal part. As a result, the firing temperature of the Cheongdo earthenware could be 1,100 to $1,200^{\circ}C$, which is higher than that of the Changnyeong. Distribution characteristics of mullite in the Cheongdo and the Changnyeong earthenware indicate that the Cheongdo earthenware was under the longer firing time or more homogeneous thermal condition in the kiln than the Changnyeong.

A load Balancing System for improving the Performance of Semantic Web based Visual Media Retrieval Framework (분산시각 미디어 검색 프레임워크의 성능향상을 위한 부하분산 시스템)

  • Shim, Jun-Yong;Won, Jae-Hoon;Kim, Seh-Chang;Kim, Jung-Sun
    • Proceedings of the Korean Information Science Society Conference
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    • 2006.10b
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    • pp.213-217
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    • 2006
  • 기존의 Ontology를 이용한 이미지 검색 시스템이나 간단한 구조를 가진 메타데이터 기반의 분산 이미지 검색 시스템들의 단점들을 극복하기 위해 다양한 이미지 제공자들의 자율성을 보장하면서, Semantic 기반의 이미지 검색을 지원하는 분산 시각미디어 검색 프레임워크인 HERMES(The Retrieval Framework for Visual Media Service)가 제안되었다. 분산 환경에서는 시스템의 규모가 커지면서 사용자들의 상호작용 성능을 떨어뜨리지 않으면서 다수의 동시 사용자들을 처리할 수 있는 확장성(Scalability)이 중요한 이슈가 된다. 제안된 프레임워크에서는 서비스를 사용하는 다수의 사용자들이 Broker 서버에 동시에 접속했을 경우 발생하는 Overhead에 대한 문제를 해결 할 수 없었기 때문에 성능의 저하와 확장성을 고려할 수 없는 문제를 안고 있다. 이런 문제를 해결하기 위해서 Broker 서버의 내부 컴포넌트의 수행시간을 측정하고 이를 주기적으로 수집하여 저장하는 Monitoring System이 추가로 연구되었지만, 수집한 정보를 가공하여 다수의 Broker 서버에 대한 부하를 분산하는 알고리즘은 제공되지 않았다. 본 논문에서는 다수의 동시 사용자들이 접속했을 경우에도 성능의 저하 없이 비슷한 수준의 서비스를 제공하기 위해서 Broker 서버를 증설하여 Monitoring System으로부터 각각의 Broker 내부 컴포넌트의 수행시간을 측정하여 저장하고, 저장된 데이터에 대하여 각 Broker들에 대한 우선순위를 결정하는 테이블을 작성한다. 사용자로부터 Query를 입력받는 User Interface는 Broker의 Ranking Table을 참조하여 다수의 Query 수행을 여러 서버로 분산처리하게 함으로써 성능에 대한 신뢰성을 향상 시킬 수 있는 Load Balancing System을 제안한다.할 때 가장 효과적인 라우팅 프로토콜이라고 할 수 있다.iRNA 상의 의존관계를 분석할 수 있었다.수안보 등 지역에서 나타난다 이러한 이상대 주변에는 대개 온천이 발달되어 있었거나 새로 개발되어 있는 곳이다. 온천에 이용하고 있는 시추공의 자료는 배제하였으나 온천이응으로 직접적으로 영향을 받지 않은 시추공의 자료는 사용하였다 이러한 온천 주변 지역이라 하더라도 실제는 온천의 pumping 으로 인한 대류현상으로 주변 일대의 온도를 올려놓았기 때문에 비교적 높은 지열류량 값을 보인다. 한편 한반도 남동부 일대는 이번 추가된 자료에 의해 새로운 지열류량 분포 변화가 나타났다 강원 북부 오색온천지역 부근에서 높은 지열류량 분포를 보이며 또한 우리나라 대단층 중의 하나인 양산단층과 같은 방향으로 발달한 밀양단층, 모량단층, 동래단층 등 주변부로 NNE-SSW 방향의 지열류량 이상대가 발달한다. 이것으로 볼 때 지열류량은 지질구조와 무관하지 않음을 파악할 수 있다. 특히 이러한 단층대 주변은 지열수의 순환이 깊은 심도까지 가능하므로 이러한 대류현상으로 지표부근까지 높은 지온 전달이 되어 나타나는 것으로 판단된다.의 안정된 방사성표지효율을 보였다. $^{99m}Tc$-transferrin을 이용한 감염영상을 성공적으로 얻을 수 있었으며, $^{67}Ga$-citrate 영상과 비교하여 더 빠른 시간 안에 우수한 영상을 얻을 수 있었다. 그러므로 $^{99m}Tc$-transierrin이 감염 병소의 영상진단에 사용될 수 있을 것으로 기대된다.리를 정량화 하였다. 특히 선조체에서의 도파민 유리에 의한 수용체 결합능의 감소는 흡연에 의한 혈중 니코틴의 축적 농도와 양의 상관관계를 보였다(rho=0.9, p=0.04). 결론: $[^{11}C]raclopride$ PET을 이용하여 비흡연 정

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A Study on the Annealing Effect of SnO Nanostructures with High Surface Area (높은 표면적을 갖는 SnO 나노구조물의 열처리 효과에 관한 연구)

  • Kim, Jong-Il;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.536-542
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    • 2018
  • Tin dioxide, $SnO_2$, is a well-known n-type semiconductor that shows change in resistance in the presence of gas molecules, such as $H_2$, CO, and $CO_2$. Considerable research has been done on $SnO_2$ semiconductors for gas sensor applications due to their noble property. The nanomaterials exhibit a high surface to volume ratio, which means it has an advantage in the sensing of gas molecules. In this study, SnO nanoplatelets were grown densely on Si substrates using a thermal CVD process. The SnO nanostructures grown by the vapor transport method were post annealed to a $SnO_2$ phase by thermal CVD in an oxygen atmosphere at $830^{\circ}C$ and $1030^{\circ}C$. The pressure of the furnace chamber was maintained at 4.2 Torr. The crystallographic properties of the post-annealed SnO nanostructures were investigated by Raman spectroscopy and XRD. The change in morphology was confirmed by scanning electron microscopy. As a result, the SnO nanostructures were transformed to a $SnO_2$ phase by a post-annealing process.

Effect of Acid Treatment of Graphitized Carbon on Carbon Corrosion in Polymer Electrolyte Membrane Fuel Cells (결정성 탄소의 산처리가 고분자연료전지의 성능과 내구성에 미치는 영향 평가)

  • Oh, Hyung-Suk;Han, Hak-Soo;Kim, Han-Sung
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.181-188
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    • 2009
  • Pt catalyst was adsorbed on Carbon nanofiber (CNF) by modified polyol method after acid treatment of the carbon support with $HNO_3$ and $H_{2}SO_{4}$. As the time for acid treatment increases, more oxygen functional groups on carbon surface were produced which improve the loading amount and dispersion of Pt catalyst on carbon supports. In order to inspect the effect of CNF acid treatment time on electrochemical corrosion, constant potential of 1.4 V was applied to a single cell for 30 min and the amount of $CO_2$ emitted was monitored with on-line mass spectrometry. According to the results of our experiment, more $CO_2$ was produced with Pt/ oxidized-CNF catalyst in compared to that with unoxidized-CNF. Increasing acid treatment time also induces the more $CO_2$ emission. Besides, performance degradation after corrosion test expanded with severer carbon corrosion. From the observed results, it can be concluded that the acid treatment of CNF is beneficial to catalyst loading, but it also is a significant factor declining the fuel cell durability by accelerating electrochemical oxidation of carbon support.