• Title/Summary/Keyword: 결정성 분석

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The Characteristics of Diisopropyl Methylphosphonate Adsorption on Zirconium-based Metal Organic Frameworks Manufactured by using Different Acids as Modulators (서로 다른 산을 조절인자로 활용하여 제조한 지르코늄 기반 금속유기골격체의 Diisopropyl Methylphosphonate 흡착 특성)

  • Jang, Wonhyeong;Kim, Honghyun;Jeong, Sangjo
    • Applied Chemistry for Engineering
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    • v.32 no.5
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    • pp.524-531
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    • 2021
  • Depending on the type and amount of acid used as a modulator in the manufacturing process, the structural properties of UiO-66 can be modified and the adsorbability of chemical warfare agents can be enhanced. In this study, several acids as a modulator were used to synthesize UiO-66. Their properties were analyzed with FT-IR, XRD, titrator, and adsorption isotherms using chemical warfare agent simulant, DIMP. The UiO-66, structurally damaged by hydrochloric acid as a modulator, showed lower crystallinity and DIMP adsorption capacity and also smaller specific surface area and volume of voids compared to those of UiO-66, which was manufactured using acetic acid, and formic acid as a modulator. Additionally, UiO-66 which was synthesized by adding formic acid and hydrochloric acid as a modulator, showed the highest DIMP adsorption capacity and is likely to be used as an adsorbent for chemical warfare agent in the future.

Kinetic Study on the Oxidation Reaction of Alcohols by Cr(VI)-Quinoline Compound (크롬(VI)-퀴놀린 화합물에 의한 알코올류의 산화반응에 대한 반응속도론적 연구)

  • Park, Young-Cho;Kim, Soo-Jong
    • Journal of Convergence for Information Technology
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    • v.11 no.9
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    • pp.109-114
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    • 2021
  • Cr(VI)-quinoline compound[(C9H7NH)2Cr2O7] was synthesized by the reaction between of quinoline and chromium(VI) trioxide, and structure was FT-IR, elemental analysis. The oxidation ability of benzyl alcohol greatly depends upon the dielectric constant of the used organic solvent, where carbon tetrachloride was worst and N,N'-dimethylformamide was best solvent. Noticeably, in N,N'-dimethylformamide solvent, Cr(VI)-quinoline compound oxidized substituted benzyl alcohols. The Hammett reaction constant(ρ)=-0.69(303K). As a resuit, Cr(VI)-quinoline compound was found as efficicent oxidizing agent that converted benzyl alcohol, allyl alcohol, primary alcohol and secondary alcohols to the corresponding aldehydes or ketones. Cr(VI)-quinoline compound was selective oxidizing agent of benzyl alcohol, allyl alcohol and primary alcohol in the presence of secondary alcohol ones.

In Vitro Tissue Culture Frequency and Transformation of Various Cultivars of Soybean (Glycine max (L.) Merr.) (다양한 콩 자원들의 기내 조직배양 효율 및 형질전환)

  • Seo, Mi-Suk;Cho, Chuloh;Jeong, Namhee;Sung, Soon-Kee;Choi, Man-Soo;Jin, Mina;Kim, Dool-Yi
    • Korean Journal of Plant Resources
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    • v.34 no.4
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    • pp.278-286
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    • 2021
  • Efficient in vitro regeneration system is essential for the successful crop breeding of soybean (Glycine max (L.) Merr.) using the new biotechnology. The genotype of donor plants strongly influences the establishment of tissue culture system. Therefore, the screening of genotypes with excellent tissue culture ability is very important for soybean genetic improvement. In this study, we report the tissue culture efficiency of 21 soybean cultivars belong to Korean soybean core-collection and two foreign cultivars (Jack and Maverick). The Kwangan, Anpyeong and Seonam are share close genetic relationship in 21 cultivars and these three cultivars were observed the high frequency of germination and regeneration. Furthermore, the high tissue culture abilities were also observed in the Williams 82 used in reference genome sequencing and the two foreign cultivars. The transformation of pBAtc:tRNA with bar gene was performed by Agrobacterium tumefaciens in the cultivars with high tissue culture ability. Transformation of the bar gene was identified by PCR analysis in Kwangan, Pungwon, Seonam, and Maverick. Our results provide useful information for the breeding of various soybean cultivars by plant biotechnology such as, genome editing.

Design and Application of Career Education Program Related to the Subject Manual Training and Home Economics of Middle School (중학교 기술·가정교과와 연계한 진로교육 프로그램의 구안과 적용)

  • Lee, Hee Soon;Kim, Hee Jin;Yun, Song Hea;Cheon, Seong Moon
    • Journal of vocational education research
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    • v.29 no.3
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    • pp.247-263
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    • 2010
  • The purpose of this study is making the career education program related to the subject, Manual Training and Home Economics, to present the effective guidance and to improve career maturity of students about the unit, "Making a choice of career and Job ethics" of middle school senior's course. In order to estimate this program, 60 students of 2 classes were chosen as research subjects among middle school seniors and each of classes was divided into two groups, an experimental group and a control group. After the experimental group was trained the career education program related to Manual Training and Home Economics for 15 sessions, the effect was verified by comparing tests before and after program execution. In order to prove effects of the program. Each grade of both the experimental group and the control group was taken analysis of covariance (ANCOVA). Result of the program experiment is following. First, after executing the career education program related to Manual Training and Home Economics to the experimental group, participants showed that both attitude and ability for career maturity were improved in each sub-factor field of the career maturity as a result of tests before and after program execution. Second, in program satisfaction estimation, most of students had a positive attitude and in every time satisfaction, they made high estimation on the program, especially including the proper level of students and interesting activities. Finally, the final program was completed based on the result of effect analysis of the program.

A Study on the Structural Behavior of FPSO Topside Module by Support Condition (지지조건에 따른 FPSO 상부 모듈의 구조적 거동에 관한 연구)

  • Jang, Beom-Seon;Ko, Dae-Eun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.18-23
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    • 2018
  • FPSO consists of topside modularized plants for production of crude oil, and hullside structures that serve as support for the topside and storage of produced crude oil. The structural behavior of the FPSO topside module and its supporting hull depends on the interface structure that connects them, and the interface structure consists of a combination of individual unit support structures called Module Support Seat (MSS). Types of interface structures are various and, accordingly, the basic design of the FPSO topside module structure is greatly influenced, so various design methods should be considered from the initial design phase. Structural design of FPSO topside module requires consideration of the number of MSSs, connection type, and structural analysis options such as the range of finite element models, load conditions, and boundary conditions for verification of structural strength. In this study, the comparison combination cases for the above considerations were derived and the strength evaluation was performed, and the structural behavior characteristics of the topside module were compared and analyzed through a detailed review of the analysis results. The results of this study are considered to be a good reference for designing a more reliable topside module structure.

A Study on the Direction of Core Technology Development for a Smart Earthwork System (스마트 토공시스템을 위한 요소기술 개발 방향에 관한 연구)

  • Kim, Sung-Keun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.6
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    • pp.967-977
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    • 2018
  • The problems of lack of skilled worker and poor productivity at the construction site continue to be raised, and the introduction of construction automation as one of the solutions to this has been considered. The development of various types of equipment and systems has been carried out, especially for earthwork operations with multiple construction equipment. However, the level of commercialization of developed equipment or systems is very limited. Although the single-product type of earthwork equipment has been applied to the site, the integrated type of earthwork system is still in the field testing stage. Considering these constraints, the limited budget and research period, a strategy is needed to identify which technology areas and core technologies should be developed first. In this study, the technology areas and detailed core technologies that are essential for the development of earthwork systems at the level of commercialization are set and the priority of development is determined. In addition, the earthwork system that has been developed so far is analyzed and the detailed development direction is presented based on it. The findings can be used for a decision making to set the priority for core technologies that should be developed first in the limited budget and period.

Application of Geospatial Information Utilization System using Unmanned Aerial Image (무인항공 영상을 이용한 공간정보 응용 시스템 활용 방안)

  • Lee, Keun-Wang;Park, Joon-Kyu
    • Journal of Digital Convergence
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    • v.17 no.2
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    • pp.201-206
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    • 2019
  • Korea is constructing geospatial information application system for geospatial information utilization, but it is trying to establish a system for joint use of geospatial information system centering on Ministry of Land Transport and Transport due to the problem of sharing. The purpose of this study is to investigate and analyze the geospatial information application system operated by local governments, and to suggest the application of geospatial information application system using unmanned aerial images. As a result of the research, it was found that the functions of existing spatial information application system are concentrated on the public services and it is difficult to share and utilize data between administrative departments. In addition, the utilization of the system using unmanned aerial image has been suggested, and additional functions such as vector display, area calculation, and report generation have been derived to improve the usability of geospatial information application system. If additional functions of spatial information application system are added through further studies in the future, it will be possible to use it as a basic data of field survey and policy decision in related fields. And non-experts will be able to improve the efficiency of work by utilizing highly accurate geospatial information in various fields.

Deep Learning Based Prediction Method of Long-term Photovoltaic Power Generation Using Meteorological and Seasonal Information (기후 및 계절정보를 이용한 딥러닝 기반의 장기간 태양광 발전량 예측 기법)

  • Lee, Donghun;Kim, Kwanho
    • The Journal of Society for e-Business Studies
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    • v.24 no.1
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    • pp.1-16
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    • 2019
  • Recently, since responding to meteorological changes depending on increasing greenhouse gas and electricity demand, the importance prediction of photovoltaic power (PV) is rapidly increasing. In particular, the prediction of PV power generation may help to determine a reasonable price of electricity, and solve the problem addressed such as a system stability and electricity production balance. However, since the dynamic changes of meteorological values such as solar radiation, cloudiness, and temperature, and seasonal changes, the accurate long-term PV power prediction is significantly challenging. Therefore, in this paper, we propose PV power prediction model based on deep learning that can be improved the PV power prediction performance by learning to use meteorological and seasonal information. We evaluate the performances using the proposed model compared to seasonal ARIMA (S-ARIMA) model, which is one of the typical time series methods, and ANN model, which is one hidden layer. As the experiment results using real-world dataset, the proposed model shows the best performance. It means that the proposed model shows positive impact on improving the PV power forecast performance.

Design of Miniaturization Terminal Antenna for 2.4 GHz WiFi Band with MZR (MZR을 이용한 2.4 GHz WiFi 대역 소형 단말기 안테나 설계)

  • Lee, Young-Hun
    • Journal of IKEEE
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    • v.23 no.1
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    • pp.14-21
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    • 2019
  • In this paper, we implemented an on-board miniaturization antenna operating 2.4 GHz using MZR(Mu Zero Resonator). It is must be operating under the constraint that the size of the small terminal PCB should be $78{\times}38{\times}0.8mm^3$ and the size of the system should be $63{\times}38{\times}0.8mm^3$ and the size of the radiating part should be $15{\times}38{\times}0.8mm^3$. The feeding structure uses a CPW structure for stable feeding and a feeding point at the upper left of the system board. A magnetic field coupling structure is used for coupling the feeding part and the antenna. The resonance frequency of the MZR is determined by the series inductance and capacitance of the cell, so the gap between the cells, the length of the cell, the length of the interdigital capacitor, and the spacing between the radiation part and the ground plane are analyzed. The antenna was designed and fabricated using the results. The total size of the antenna including the feed structure is $20.8{\times}9.0{\times}0.8mm^3$, and the electrical length is $0.1664{\lambda}_0{\times}0.072{\lambda}_0{\times}0.0064{\lambda}_0$. The measurement result for 10 dB bandwidth, gain and directivity are 440 MHz(18.3%), 0.4405 dB, and 2.722 dB respectively. It is confirmed that the radiation pattern has omnidirectional characteristics and it can be applied to ultra small terminal antenna.

Threshold Condition for Exclusion of Riprap into Bypass Pipe (저층수 배출관에 유입된 사석의 배제 한계조건)

  • Jeong, Seokil;Lee, Seung Oh
    • Journal of Korean Society of Disaster and Security
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    • v.12 no.1
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    • pp.57-66
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    • 2019
  • One of the most serious problems with concrete small dams or barriers installed in small/median rivers is the deposit of sediments, especially, in Korea. An effective way to discharge such sediments to downstream is to construct a bypass pipe under the river bed. However, efficiency may become lowered if ripraps are entered into the bypass pipe. Therefore, in this study, we derived the threshold condition for the exclusion of ripraps from the bypass pipe using 3D numerical analysis. Upstream flow of the small dam was assumed to be stationary, and the energy concept was applied to the control volume containing the bypass pipe and its periphery. As a result, when the ratio of the water level difference between upstream and downstream to the diameter of the riprap was approximately equal to 1.2, the threshold condition for exclusion of the stones or riprap from the bypass pipe was affirmatively determined. If the characteristics of the adsorptive sediment adversely affecting the river environment in the future would be taken into account, results from this study are expected to put to practical use in the management of concrete small dam with bypass pipe system.