• Title/Summary/Keyword: 개회로

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Effect of Silicate and Lime Fertilizer on Growth of Zantedeschia aethiopica (규산질 및 석회질 비료가 칼라(Zantedeschia aethiopica) 생육에 미치는 영향)

  • Goo, Dae Hoe
    • FLOWER RESEARCH JOURNAL
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    • v.16 no.3
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    • pp.222-227
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    • 2008
  • Objective of this Research was to determine the influence of foliar application of $CaCl_2$ or $K_2SI_2O_5$ and soil application of $CaCO_3$ or $SiO_2$ on growth and cut flower quality of Zantedeschia aethiopica 'Wedding March'. To achieve this, $CaCl_2$ or $K_2SI_2O_5$ were applied at six leaf stage with the concentration of 0.05, 0.1 and 0.2% and $CaCO_3$ or $SiO_2$ were applied as basal fertilization with the amount of 100, 200, 400kg per 10a or 50, 100, 200, 400kg per 10a respectively. Plant material was used Zantedeschia aethiopica 'Wedding March'. Among calcium chloride($CaCl_2$) and calcium carbonate($CaCO_3$), calcium chloride foliar application was more effective than calcium carbonate with basal fertilization to growth of common calla 'Wedding March'. In the 0.1% solution foliar application of calcium chloride, plant height, leaf length and length of cut-flower was more longer than control. Length of leaf petiole was more longer and leaf fresh weight was more heavier than control. The degree of petiole hardness was more effective in the 0.1% solution calcium chloride foliar application than any other treatment. In the silicate fertilization treatment, plant height of 50kg per 10a treatment was most highest as 73.9cm. also its length of leaf petiole and leaf fresh weight was more effective than any other treatment. The hardness of petiole was better in the 50kg per 10a silicate fertilizer treatment. The cell shape of leaf petiole was round and tissue was regular in the treatment of 0.1% calcium chloride and 50kg per 10a silicate fertilizer but the cell of control was irregular round type. Macro element content of calcium was more amount in the treatment of silicate 50kg per 10a basal fertilization. The infected ratio of Erwinia was no relation with lime and silicate fertilizer treatment. Lime fertilizer treatment is effective for growth and flowering of Calla than silicate fertilizer and the suitable concentration was 0.1%.

Comparison of Membrane Degradation of PEMFC by Fenton Reaction and OCV Holding (Fenton 반응과 OCV Holding에 의한 PEMFC 고분자 전해질 막의 열화비교)

  • Oh, Sohyung;Kwag, Ahhyun;Lee, Daewoong;Lee, Mooseok;Lee, Donghoon;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.768-773
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    • 2019
  • The Fenton reaction, which evaluates the electrochemical durability of polymer membranes of polymer electrolyte fuel cells (PEMFC), and the degradation of polymer membranes by OCV holding method are compared. The Fenton reaction is a method that can evaluate the chemical durability of the polymer membrane at outside the cell in a shorter time than the OCV Holding method. The Fenton reaction was carried out at 30% hydrogen peroxide, 10 ppm iron, and $80^{\circ}C$ for 24 hours. OCV Holding was driven at $90^{\circ}C$, 30% relative humidity and OCV for 168 hours. The Fenton reaction caused a lot of degradation inside the polymer membrane. On the other hand, in OCV Holding, the membrane thickness was thinned by the entire surface and internal degradation. The fluorine emission rate was more than 10 times higher than that of OCV Holding due to the Fenton reaction. The hydrogen permeation rate increased about 30% at 24 hours of Fenton reaction. At OCV Holding, hydrogen permeability decreased after 24 hours and then increased. As a whole, there was a difference in a membranes deteriorated by Fenton reaction and OCV Holding.

Durability Test of PEMFC Membrane by the Combination of Chemical/Mechanical Degradation (화학적/기계적 열화 병행방법에 의한 PEMFC 고분자막 내구성 평가)

  • Lim, Daehyeon;Oh, Sohyeong;Jung, Sunggi;Jeong, Jihong;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.339-344
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    • 2021
  • In order to improve the PEMFC (Proton Exchange Membrane Fuel Cell) durability, it is important to accurately evaluate the durability of the membrane in a short time. Recently, DOE (Department of Energy) reported a protocol that combines the chemical and mechanical durability of membranes to evaluate them effectively. This protocol applies chemical/mechanical deterioration to the membrane by repeating wet/dry while OCV (Open Circuit Voltage) holding. The problem of this protocol is that it is highly affected by electrode degradation due to change cycles in OCV and that the evaluation time is long. By using oxygen instead of air as the cathode gas while leaving the other conditions of the DOE protocol as it is, the durability evaluation time could be reduced from 408 hours to 144 hours. By reducing the number of voltage change cycles to 1/3, the electrode degradation due to the voltage change cycle was reduced to 1/12 when oxygen was used compared to air at the end, thereby enabling more accurate evaluation of polymer membrane durability.

Effect of Pt-Co/C Cathode Catalyst on Electrochemical Durability of Membrane in PEMFC (PEMFC에서 Pt-Co/C Cathode 촉매가 고분자막의 전기화학적 내구성에 미치는 영향)

  • Sohyeong Oh;Dong Geun Yoo;Myoung Hwan Kim;Ji Young Park;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.189-195
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    • 2023
  • As a PEMFC (Polymer Exchange Membrane Fuel Cell) cathode catalyst, Pt-Co/C has recently been widely used because of its improved durability. In a fuel cell, electrodes and electrolytes have a close influence on each other in terms of performance and durability. The effect on the electrochemical durability of the electrolyte membrane when Pt-Co/C was replaced in the Pt/C electrode catalyst was studied. The durability of Pt-Co/C MEA (Membrane Electrode Assembly) was higher than that of Pt/C MEA in the electrochemical accelerated degradation process of PEMFC membrane. As a result of analyzing the FER (Fluorine Emission Rate) and hydrogen permeability, it was shown that the degradation rate of the membrane of Pt-Co/C MEA was lower than that of Pt/C MEA. In the OCV (Open Circuit Voltage) holding process, the rate of decrease of the active area of the Pt-Co/C electrode was lower than that of the Pt/C electrode, and the amount of Pt deposited on the membrane was smaller in Pt-Co/C MEA than in Pt/C MEA. Pt inside the polymer membrane deteriorates the membrane by generating radicals, so the degradation rate of the membrane of Pt/C MEA with a high Pt deposition rate was higher than Pt-Co/C MEA. When the Pt-Co/C catalyst was used, the electrode durability was improved, and the amount of Pt deposited on the membrane was also reduced, thereby improving the electrochemical durability of the membrane.

An Institutionalization and Legislation Productivity of Korean Metropolitan Councils: Panel Data Analysis (광역의회제도화와 입법생산성: 패널데이터 분석)

  • Jung, SungEun
    • Korean Journal of Legislative Studies
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    • v.26 no.1
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    • pp.105-145
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    • 2020
  • This study analyzes the effect of institutionalization of Korean metropolitan councils on legislation productivity. Based on the theory of institutionalization of legislatures, three independent variables (stability, complexity and adaptability) were selected to measure the level of institutionalization of a metropolitan council and nine sub-analysis indicators. The main results of the analysis of the effect of the institutionalization of the metropolitan council on legislation productivity are as follows: First, the factors that determine the number of reported bills were the ratio of first-term lawmakers, average number of elected of the chairmen, number of special committees, number of legislative experts, actual age of metropolitan councils, and number of voters per lawmaker. Second, the factors that determine the rate of reported bills were the average number of elected of the chairmen, the number of special committees, the number of legislative experts, the actual age of metropolitan councils, and the number of voters per lawmaker. Third, the factors that determine the number of reported bills per lawmaker is the average number of elected of the chairmen, the actual age of metropolitan councils, and the number of voters per lawmaker. The above result points out that legislation productivity differences of past metropolitan councils can be understood as differences arising from legislative institutionalization levels and several policy considerations can be made to enhance legislation productivity of metropolitan councils.

Reducing the Test Time for Chemical/Mechanical Durability of Polymer Electrolyte Membrane Fuel Cells (고분자연료전지의 화학적/기계적 내구성 평가 시간 단축)

  • Sohyeong Oh;Donggeun Yoo;Kim Myeonghwan;Park Jiyong;Choi Yeongjin;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.517-522
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    • 2023
  • A chemical/mechanical durability test of polymer membrane evaluation method is used in which air and hydrogen are supplied to the proton exchange membrane fuel cell (PEMFC) and wet/dry is repeated in the open circuit voltage (OCV) state. In this protocol, when wet/dry is repeated, voltage increase/decrease is repeated, resulting in electrode degradation. When the membrane durability is excellent, the number of voltage changes increases and the evaluation is terminated due to electrode degradation, which may cause a problem that the original purpose of membrane durability evaluation cannot be performed. In this study, the same protocol as the department of energy (DOE) was used, but oxygen was used instead of air as the cathode gas, and the wet/dry time and flow rate were also increased to increase the chemical/mechanical degradation rate of the membrane, thereby shortening the durability evaluation time of the membrane to improve these problems. The durability test of the Nafion 211 membrane electrode assembly (MEA) was completed after 2,300 cycles by increasing the acceleration by 2.6 times using oxygen instead of air. This protocol also accelerated degradation of the membrane and accelerated degradation of the electrode catalyst, which also had the advantage of simultaneously evaluating the durability of the membrane and the electrode.

Effect of Compensation for Thickness Reduction by Chemical Degradation of PEMFC Membrane on Performance and Durability (PEMFC 고분자막의 화학적인 열화에 의한 두께 감소 보정이 성능 및 내구성에 미치는 영향)

  • Sohyeong Oh;Yoojin Kim;Seungtae Lee;Donggeun Yoo;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.1-6
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    • 2024
  • As the demand for hydrogen electric vehicles for commercial vehicles increases, the durability of PEMFCs must increase more than five times that of passenger cars, so research and development to improve durability is urgent. When the PEMFC membrane electrode assembly (MEA) undergoes chemical degradation, the MEA thickness decreases and pinholes occur. In this study, changes in the performance and durability of the MEA were measured while increasing the clamping pressure of the unit cell after open circuit voltage (OCV) holding, an accelerated chemical degradation experiment. As the clamping pressure increased, the resistance of the polymer membrane and the membrane/electrode contact resistance decreased, improving the I-V performance and reducing the hydrogen permeability. As the hydrogen permeability decreased, the OCV increased. When the pinhole area was removed and the MEA clamping pressure was increased, the hydrogen permeability decreased sharply, confirming that the local degradation has a large effect on the performance and durability of the entire cell. When the pinhole was removed and re-clamping and OCV holding was evaluated, it was confirmed that the durability improved according to the decrease in membrane resistance and hydrogen permeability.

Fundamental research to investigate methods of vocational competency enforcement in field of home economics education - revision of the current NCS based vocational highschool education curriculum and investigation in change of direction in vocational home economics education - (가정과교육에서의 직업역량 강화 방안 탐색을 위한 기초 연구 - NCS 기반 고교 직업교육과정 개정과 가사실업계 직업교육의 변화 방향 탐색 -)

  • Jang, Myung Hee
    • Journal of Korean Home Economics Education Association
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    • v.26 no.4
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    • pp.129-146
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    • 2014
  • This study is a fundamental research in the field of home economics education to enforce vocational competencies. It was carried out in the purpose of examining the recent economical and social environmental changes and its management system related to the vocational training in the field of home economics education. It seeks change in direction in relation to the National Competency Standard(NCS) based on revisions in the educational system. The method of study was mostly through reference and data analysis, professional advisory and public hearing. The main research results are as follows. First, the main environmental change factors in relation to vocational training have been integrated to the changes in; population structure, gender related economic activities, generation composition, communications technology, and innovation of living technique. These change factors are forecasting innovations in related industries, lifestyle changes, demand for manpower and changes in capabilities required for each specific profession. Second, according to the analysis of current home economics education training, vocational home educations high school accounts for 9.4% of the total number of specialized high schools, where 8 standard departments are specialized in and characterized into 137 different department names. Despite differences among departments, overall employment rate of graduates were measured 44.7%, which rates above the entrance rate of 41.9%. These numbers show great change since 2010(overall employment rate 16.9%, entrance rate 75.2%), a meaningful outcome resulting from changes in policy from the previous employment-centered education system. Third, NCS based on high school vocational home economics education system revision and investigations in change of direction in vocational home economics, this study attempts to provide background for revision from the development of NCS. It also provides proposals for restructuring division of current classification and departments of home economics education, and propositions for further future research.

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Investigation of Vascular Plants in the Eco-Arboretum Site, Mt. Gumwon (금원산 생태수목원 조성 부지의 관속식물상 연구)

  • Oh, Hyun-Kyung;Shin, Hyun-Tak;Beon, Mu-Sup
    • Korean Journal of Plant Resources
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    • v.21 no.2
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    • pp.117-127
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    • 2008
  • The vascular plants in the Eco-Arboretum site, Mt. Gumwon appeared to be 369 taxa; 84 families, 217 genera, 319 species, 43 varieties and 7 forms. Based on the list of the rare plants, 2 taxa existed in the studied areas; Abies koreana (Preservation priority order; No. 73), Paeonia obovata (No. 97) and based on the list of Korean endemic plants, 12 families, 14 genera, 11 species, 3 varieties, 1 hybrid, 15 taxa existed; Cephalotaxus koreana, Abies koreana (Planted species), Carex okamotoi, Salix hallaisanensis, Salix purpurea var. japonica, Clematis trichotoma, Thalictrum actaefolium, Lespedeza ${\times}$ tomentella, Vicia nipponica, Stewartia koreana, Hypericum attenuatum var. confertissimum, Paulownia coreana (Planted species), Weigela subsessilis, Aster koraiensis (Planted species). Specific plant species by floral region were total 38 taxa; Paeonia obovata in class V , 13 taxa (Lilium leichtlinii var. tigrinum, Betula costata, Betula davurica, Ulmus davidiana, Spiraea frutschiana, Prunus maackii, Syringa reticulata var. mandshurica, Cynanchum inamoenum, Lonicera subhispida, Cacalia firma, etc.) in class III , 5 taxa (Heloniopsis orientalis, Chrysosplenium pilosum, Acer triflorm, Viola tokubuchiana var. takedana, Teucrium veronicoides, etc.) in Class II . 19 taxa (Dryopteris erythrosora, Arisaema ringens, Veratrum versicolor, Polygonatum inflatum, Salix glandulosa, Betula schmidtii, Alnus hirsuta, Quercus variabilis, Aconitum japuense, Dicentra spectabilis, Chrysosplenium flagelliferum, Impatiens noli-tangere, Ilex macropoda, Tilia amurensis, Fraxinus mandshurica, Trigonotis icumae, etc.)in class I . The naturalized plants in this site were 5 families, 13 genera, 15 taxa (Rumex acetocella, Rumex obtusifolius, Trifolium repens, Oenothera odorata, Erigeron annuus, Erigeron philadelphicus, Bidens frondosa, Taraxacum officinale, etc.) and naturalization rate was 4.1% of all 369 taxa vascular plants.

A study on the compatibility of implant drivers (임플란트 드라이버의 호환성에 대한 연구)

  • Kim, Min-Soo;Lee, Jong-Hyuk
    • The Journal of Korean Academy of Prosthodontics
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    • v.52 no.1
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    • pp.34-41
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    • 2014
  • Purpose: In this study, the diameter of each implant driver was measured and compared to find out the compatibility of implant drivers. Materials and methods: Drivers from 12 implant systems being used in Dankook University Dental Hospital were included in this study. The shapes of the implant drivers were segregated, and the effective length and the diameter of upper, middle, lower part of driver tips were measured (n=10). The measured data were mathematically analyzed for its compatibility. Results: A driver with the smallest diameter (1.17 mm) had the highest compatibility at the upper part of driver tip. This driver could be used for a bigger driver up to 1.35 mm in diameter. There were several driver groups which had the same diameter so as to be interchangeable each other. In the middle part, the smallest diameter measured was 1.2 mm and this was able to replace a driver up to 1.40 mm diameter. Since the diameter generally became thicker from upper part (the tip of driver) to the lower part (the shank of driver), some drivers with bigger diameter at the upper part so which was failed to show any compatibility became compatible with a driver which had smaller diameter at the upper part but wider in the middle part. The compatibility of torx shape drivers were affected by the inner diameter of the drivers not only by the outer diameter. Furthermore, the inner diameter of torx drivers decided the compatibility between torx and hex drivers. Conclusion: From the study it was found that compatibility in drivers existed among certain implant systems and to check its compatibility the diameter at a certain effective length should be measured. However, there has been not enough studies about long-term use of compatible drivers, so effects of using compatible drivers on drivers and implants are unknown. Therefore, usage in inevitable cases only is recommended and further study is needed.