• 제목/요약/키워드: 개질연료

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DBD 플라즈마에 의한 연료개질 및 층류 화염 특성 변화 (The Effect of DBD Plasma on Fuel Reforming and on the Characteristics of Laminar Flames)

  • 김은강;박선호;송영훈;이원남
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.195-198
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    • 2014
  • $Fuel/N_2$ and fuel/air mixtures were treated with non-thermal DBD plasma and the changes in characteristics of laminar diffusion flame have been observed. Flame of $Fuel/N_2$ mixture generated more soot under plasma condition while less amount of soot was formed from fuel/air mixture flame. Luminescence spectrum and gas chromatography results confirmed that plasma energy converts a fraction of fuel molecules into radicals, which then form $C_2$, $C_3$, $C_4$ and higher hydrocarbon under no oxygen condition or turn into CO, $CO_2$ and $H_2O$ when oxygen is present.

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탄소지지체의 화학적 변형에 따른 연료전지용 백금-루테늄 촉매의 전기화학적 활성의 영향 (Effect of Chemical Modification of Carbon Supports on Electrochemical Activities for Pt-Ru Catalysts of Fuel Cells)

  • 김병주;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.94.1-94.1
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    • 2011
  • In this work, ordered mesoporous carbons (OMCs) were prepared by the conventional templating method using mesoporous silica (SBA-15) for Pt-Ru catalyst supports in fuel cells. The influence of surface modification on carbon supports on the electrochemical activities of Pt-Ru/OMCs was investigated with different pH. The neutral-treated OMCs (N-OMCs), base-treated OMCs (B-OMCs), and acid-treated OMCs (A-OMCs) were prepared by treating OMCs with 2 M $C_6H_6$, 2 M KOH, and 2 M $H_3PO_4$, respectively. The surface characteristic of the carbon supports were determined X-ray photoelectron spectroscopy (XPS). The electrochemical activities of the Pt-Ru catalysts had been enhanced when the OMCs supports were treated by basic or neutral agents, while the electrochemical activities had been decayed for the A-OMCs supported Pt-Ru.

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천연가스 개질기와 연계한 연료전지시스템의 운전특성 (Operating Characteristics on Coupling of Fuel-Cell System with Natural Gas Reformer)

  • 박세준;최용성;황종선;이경섭
    • 전기학회논문지P
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    • 제58권4호
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    • pp.639-643
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    • 2009
  • A reformer, which produces hydrogen from natural gas, plays a major role for producing quality hydrogen to fuel-cell system. In this paper, fuel processor is designed to deliver hydrogen(75%) from the reformer to 200W fuel-cell system, and the electrical output power of the fuel-cells is examined by being injected different hydrogen concentrations to the system. We verified that the output power characteristics of the fuel-cells with 75% reformed hydrogen was lower about 7% than the case of pure hydrogen supplied. The type of reformer in this experiment takes SMR(Steam methane reforming) process, and the temperature variation characteristics of reforming process by reactions are examined in operation.

초음파 개질 경유의 연료특성과 연소특성의 상관관계에 관한 연구 (II) -화학구조와 세탄가의 상관성- (A Study on Relationship between Fuel Characteristics and Combustion Characteristics of Reformed Diesel Fuels by Ultrasonic Energy Irradiation (II) - Relationship between Chemical Structure and Cetane Number -)

  • 이병오;류정인
    • 한국자동차공학회논문집
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    • 제11권1호
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    • pp.64-71
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    • 2003
  • In order to analyze the effect of the chemical structure and the cetane number of reformed diesel fuels by ultrasonic energy irradiation, proton nuclear magnetic resonance spectrometer$(^1H-NMR)$ was used. From the study, following conclusive remarks can be made. 1) Branch Index(BI), aromatics percentages, and alpha methyl radical$(H_{\alpha})$ of the reformed diesel fuels by ultrasonic energy irradiation decreased more than the conventional ones. 2) All the cetane numbers which were calculated from carbon type structure and hydrogen type distribution of the reformed diesel fuels increased more than the conventional ones. 3) It is more reasonable to predict cetane number equation from carbon type structure than from hydrogen type distribution. 4) BI, aromatics percentages, and $H_{\alpha}$ on both for conventional fuel and reformed diesel fuels by ultrasonic energy irradiation are inversely proportional to cetane number fur these fuels.

디젤기관의 매연저감에 미치는 초음파 영향 (Effects of the Smoke Reduction of Diesel Engine Operated with Ultrasonically Reformed Fuel)

  • 이병오;김용국
    • 한국자동차공학회논문집
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    • 제18권3호
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    • pp.88-94
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    • 2010
  • In this paper, the effect of the ultrasonic energy on the diesel engine's smoke reduction has been investigated for indirect injection diesel engine. The smoke concentration of the ultrasonically reformed diesel fuel was reduced remarkably in comparison with conventional diesel fuel. And in-cylinder pressure, heat release rate and mass fraction burned was improved but combustion duration was decreased. However, The combustion durations and the smoke concentrations of both diesel fuels were proportional to the increases of engine loads. Also, When the combustion duration has been increasing, the smoke emission has been augmenting in the shape of the exponential functions.

팔라듐 촉매의 메탄 부분산화에 관한 연구 - 반응온도에 따른 효과 - (A Study of Partial Oxidation of Methane by Pd Catalyst - Effects of Reaction Temperature -)

  • 이택홍;문영환
    • 한국수소및신에너지학회논문집
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    • 제15권3호
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    • pp.244-249
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    • 2004
  • Pd catalyst have been used in hydrogenation, oxidation, and low temperature combustion reaction. Recently, it has been candidated as a possible reagents in the partial oxidation of methanol reformers of the fuel cell. Pd catalysts, even though it is very precious and expensive, catalytic functioning is good, but it still need to be improved in the matter of durability and low catalytic activity after calcination. In this study, we synthesize the improved Pd catalyst and study their chemical functioning.

일산화탄소 저감을 위한 개질가스의 전이반응 연구 (Investigation of the Water Gas Shift from Reforming Gas for CO Removal)

  • 김성천;윤문중;전영남
    • 대한기계학회논문집B
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    • 제31권10호
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    • pp.855-859
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    • 2007
  • Hydrogen as an energy carrier in fuel cell offers perhaps the largest potential benefits of reduced emissions of pollutants and greenhouse gases. The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. Reduction of carbon monoxide to an acceptable level of 10ppm involves high temperature and low temperature water gas shift (WGS), followed by selective oxidation of residual carbon monoxide. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 5000 ppm. In the water gas shift operation, gas emerges from the reformer is taken through a high temperature shift (HTS) catalyst to reduce the CO concentration to about $2{\sim}4%$ followed to about 5000 ppm via a low temperature shift (LTS) catalyst.

수소스테이션용 $20Nm^3$/hr급 컴팩트형 고효율 수소제조장치 기술개발 (Development of $20Nm^3$/hr Scale High Efficiency Steam Reformer for Hydrogen Fueling Station)

  • 오영삼;박달영;조영아
    • 신재생에너지
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    • 제1권4호
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    • pp.12-18
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    • 2005
  • 세계적으로 수소에너지를 미래 에너지의 대안으로 여겨지고 있기 때문에 수소에너지 관련기술은 미래 국가 경쟁력을 좌우할 것으로 예상되고 있으며 수소에너지시대의 핵심인 수소스테이션 관련기술을 개발은 국가 연료전지 시장을 비롯한 수소 자동차 산업 전반에 큰 영향을 미칠 것으로 예상되고 있다. 이에 따라 전 세계적으로 수소에너지를 차세대 에너지원으로 개발하기 위하여 전력을 다하고 있으며 수소제조기술개발 및 수소스테이션 실증연구가 진행되고 있다. 본 연구에서는 수소스테이션용 $20Nm^3$/hr급 컴팩트형 고효율 수소제조장치 기술개발내용에 대하여 소개하고자 한다.

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CRDI 방식 디젤기관의 초음파 조사 Bio-diesel 혼합연료 적용 특성에 관한 실험 연구 (Experimental Study on the Application Characteristics of Bio-diesel blended Fuel by Ultrasonic Irradiation in CRDI type Diesel Engine)

  • 정영철;임석연;박성영;최두석;류정인
    • 한국분무공학회지
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    • 제12권3호
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    • pp.131-137
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    • 2007
  • This is an experimental study on characteristics of engine performance and discharged materials in common-rail type diesel engine. The bio-diesel fuel is mixed with the diesel fuel in common use at the ratio of 20% or 100%. The diesel fuel and blended fuel is irradiated by ultrasonic wave energy. The diese1 fuel, blended fuel, reformed diesel fuel and reformed blended fuel by ultrasonic wave energy are applied to the experimental engine individually. The results are compared with one of the diesel fuel in common use and analyzed.

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