• Title/Summary/Keyword: 강재 부식

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Evaluation on electrochemical hybrid damage of arc thermal sprayed layer by cavitation experiment (캐비테이션 실험을 이용한 용사코팅 층의 전기화학적 복합손상 평가)

  • Park, Il-Cho;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.319-319
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    • 2015
  • 본 연구에서는 강재의 부식 방지를 목적으로 기존의 도장 방식법에 비해 내식성 및 내구성을 향상시키기 위해 아크 용사코팅법을 적용하였다. 실험은 실제 환경을 고려하여 캐비테이션 환경 하에서 다양한 전기화학적 실험을 동시에 병행하여 캐비테이션-부식 복합손상 거동을 분석하고자 하였다.

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An Experimental Investigation of the Effect of Corrosion on Dry Friction Noise (건성마찰 소음에 대한 부식 영향도 실험연구)

  • Baek, Jongsu;Kang, Jaeyoung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.12
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    • pp.1251-1256
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    • 2015
  • This study investigates the friction noise characteristic in relation to the corrosion of metal by using the frictional reciprocating and pin-on-disk system. From the experiments, it is found that the corrosion of metal advances the onset time and increases the magnitude of friction noise. Further, it is observed that the effect of corrosion on friction noise stems from the alteration of tribo-surface during repetitive frictional motion. The alteration of the corrosive contact surface induces a negative friction-velocity slope, by which the corrosion of metal can generate dynamic instability faster than non-corrosion of metal.

철강제의 황화물 응력부식

  • 권영각
    • Journal of the KSME
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    • v.30 no.2
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    • pp.155-162
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    • 1990
  • 원유나 각종 석유 제품을 취급하는 구조물 또는 설비들의 부식 균열현상은 이미 오래 전부터 보 고되어 왔으며, 이는 주로 석유나 LPG 등에 포함되어 있는 H/SUB 2/S에 의한 황화물 응력부식 (SSCC:sulfide stress corrosion cracking)으로 널리 알려져 있다(1,2). SSCC에 의한 균열 현상은 일반 저강도 철강재에서는 발생하지 않으며 주로 항복강도가 500MPa 이상의 강재에서 많이 나타 난다. 특히, 구조물이나 설비제작 과정에서 반드시 있게되는 용접부는 SSCC에 아주 민감한 부분 으로써, 대부분의 SSCC 균열이 용접 열영향부(HAZ:heat affected zone)에서 나타나고 있다. 이는 용접부의 미세조직이 모재와 달라 국부적으로 높은 경도를 갖는 부분이 있기도 하고, 또한 운전 조건으로는 만족되지 않는 응력부식 조건이 용접 잔류응력에 의해 만족될 수 있기 때문이기도 하다. 본 글에서는 이러한 SSCC에 의한 균열 특성을 SSCC기구 (SSCC mechanism)와 함께 석유화학 설비재료로 많이 사용되는 철강재를 대상으로 고찰해 보고자 한다.

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Development of Corrosion Detection Method for Closed U-ribs in Steel Bridges Using Ultrasonic Velocity Method (초음파 속도법을 활용한 강교 부식 손상탐지법 개발)

  • Kim, Woo-Seok;Mun, Seong-Mo;Kim, Cheol-Min;Lee, Kang-Moon;Im, Seok-Been
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.254-261
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    • 2021
  • This study was intended to develop an inspection method to detect defects in closed-cell steel members in steel girder bridges. The ultrasonic pulse velocity method was selected as a rapid and effective method to identify thickness changes of steel specimens caused by corrsion. This study developed an algorithm to expedite the process and improve the accuracy in the prediction of steel plate thickness. Also, both static and continuous scanning methods were compared to each other to identify the difference in accuracy, but the results revealed that both methods produce almost the same results. This study also provided the idea to calculate the height of water contained in the closed-cell steel member and results of laboratory experimental results. The water heights which is thicker than the steel plate thickness were detectable and predicted using the idea suggested by this study, but the water heights lower than the steel plate thickness were not possible. However, the results showed whether the steel member contains water or not.

Characteristics of Leachate from Blast Furnace Slag and Its Impacts on Environment (고로(高爐) 슬래그 침출수(浸出水)의 특성(特性)과 환경(環境)에 미치는 영향(影響))

  • Choi, Eui So;Kwon, Soo Youl;Lee, E.C.;Park, W.M.
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.55-60
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    • 1987
  • Impacts on ground water quality, growth of crops, and degree of corrosion due to the leachate produced from the contact of rain water with blast furnace slag as an aggragate used for roadway pavement were evaluated. Results from slag and soil leaching tests indicated pH, $SO_4$, $Ca^{{+}{+}}$ and $Mg^{{+}{+}}$ concentrations of ground water could be increased due to the use of slag, and pot test suggested slag would not adversely affect growth of Raphanus Satius L niger. Accelerated corrosion test revealed that slag leachate had a tendency to increase corrosion on cast iron at the beginning, however the degree of corrosion became similar to that experienced in soil after about 50 days at 50 degrees in centigrade.

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Investigation on optimum corrosion protection potential by electrochemical method of S355ML steel for marine structure in seawater (해양구조물용 S355ML 강의 해수환경 하에서 전기화학적 방법에 의한 최적 방식전위 규명)

  • Jeong, Gwang-Hu;Park, Il-Cho;Han, Min-Su;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.145-145
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    • 2016
  • 해양환경용 구조물은 극심한 부식 환경에 노출되어 있고 부식손상으로 인한 직간접적 경제적 손실이 발생하고 있는 상황이다. 이에 대한 방식대책으로써 음극방식법이 선박, 교량, 각종 화학장비에 널리 이용되고 있으며, 이러한 산업분야에 가장 흔히 적용되고 있는 음극방식 중 하나가 피방식체에 일정 전류 또는 음극 전위를 인가하는 외부전원법이다. 이는 전도성 부식환경인 해수환경 하에서 철강 및 해양환경용 구조 재료의 내식성을 월등히 향상시킬 수 있기 때문에 설계에 있어서 고급 내식재료 대신 경제적인 상용 재료를 적용할 수 있어 비용 절감효과를 가질 수 있다. 한편 적정 방식전위에서는 부식손상으로부터 강재를 보호하지만, 과방식 전위에서는 취성이 발생함으로써 내구성 감소의 역효과가 나타날 수도 있기 때문에 최적 방식전위의 규명은 반드시 필요하다. 따라서, 본 연구에서는 S355ML강에 대하여 천연해수 용액에서 다양한 정전위를 조건으로 전기화학실험을 실시하여 최적 방식전위를 규명하고자 하였다. 시험편은 에머리 페이퍼로 2000번까지 연마하였고, 아세톤과 증류수로 세척하여 실험하였다. 전기화학(정전위) 실험은 천연해수 속에서 $1.28cm^2$의 면적만을 노출시켜 진행하였으며, OCP로부터 -2.0V까지의 음극분극 곡선을 분석하여 정전위 조건들을 선정하였다. 그리고 외부 직류전원장치를 이용하여 1,200초 동안 다양한 정전위를 인가하였으며, 기준전극은 Ag/AgCl 전극을 이용하였다. 실험 후에는 주사전자현미경과 3D 현미경을 통해 시험편 표면을 관찰하였으며, 그 결과 일부 음극분극 구간에서 강재 표면에 전착물에 의한 뷸균일한 피막이 형성되었다. 또한, 일정 전위구간에서 용해 및 과전압에 대하여 표면손상 정도를 관찰하여, 해수환경 하에서 S355ML강의 최적 방식전위를 규명하였다.

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The Study on the Corrosion Behavior of STS 304 for Gas Boiler in the Condensed Water (응축수 중에서 가스보일러용 STS 304의 부식거동에 관한 연구)

  • Du Yun Byoung;Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.9 no.1 s.26
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    • pp.21-25
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    • 2005
  • This paper was studied on the corrosion behavior of STS 304 for gas boiler in the condensed water, the electrochemical polarization test of STS 304 for gas boiler in the condensed water was carried out. And the corrosion behavior of STS 304 was considered. The main results are as following: 1) As corrosion environment is acidified from neutrality, the polarization resistance of STS 304 decreases and the corrosion potential is less noble. 2) The corrosion reaction mechanism of STS 304 is cathodic control. 3) As corrosion environment is acidified, the passive potential range of STS 304 decreases. Also, the passive current density of STS 304 increases.

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Evaluation of Steel Corrosion and Flexural Strength Coated with Cementitious Repair Material (시멘트계 보수재료로 코팅된 강재의 부식 및 휨강성 평가)

  • Yoon, Yong-Sik;Kim, Tae-Sang;Kim, Ho-Ryong;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.243-249
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    • 2016
  • The present work is for an evaluation of resistance to corrosion in steel coated with cementitious repair material, so that 3 cases of steel plate(Normal, Welding, Welding & coating case) are subjected to ICM(Impressed Current Method) for acceleration of corrosion for 7days. Tested and estimated corrosion ratio through Faraday's Law are compared, and the related flexural strength are evaluated. In Normal and Welding cases, similar level of corrosion ratio(70%) is evaluated, however only 17% level of corrosion ratio is evaluated in the Welding & coating case, which indicates that cementitious repair material is effective to anti-corrosion due to a block of chloride penetration. The flexural test results are consistent with those in accelerated corrosion test, which shows a significant flexural strength in Welding & coating case by 3.4times greater than the others. The cementitious material repair coating is evaluated to be effective to anti-corrosion in welding of steel plate.

Evaluation of Fatigue Strength Share Effect of the Rust Due to Corrosion at Ship Structural Plate (선체구조 판부재에서 해수부식현상에 기인하는 부식층의 피로강도분담효과에 관한 연구)

  • Kim, Won Beom
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.5
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    • pp.2063-2068
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    • 2013
  • Ship and offshore structures, those are to be used under the seawater conditions are prone to corrosion. In this research, the effect of rust existence on the fatigue strength at structural member of ship and offshore structure was investigated. For this purpose, fatigue tests for the rust removed specimen were conducted. In addition, the comparison of fatigue strength between rust removed specimen and rusted specimen was conducted. With these test results, fatigue strength share effect was investigated. Finally, at this research, it was found that there is fatigue strength share effect on the rust. In comparison of fatigue strength reduction factor, fatigue strength of the rust removed specimen is 18.1% lower than that of the rusted specimen. From the above, it was known that as far as there are not any harmful ingredients in it, rust on the steel plate is beneficial in an aspect of fatigue strength.

Prediction of Concrete Corrosion using Electrodchemical Technique (전기화학적인 콘크리트 부식의 예측)

  • 이종권;박지환
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.2
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    • pp.80-83
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    • 2002
  • The effect of chloride content on the corrosion of reinforced bar in concrete was studied. The mixing ratio of the concrete was 1 : 1.78 : 5.35 : 4.73 (water : content : ballast : sand). The studied chloride content was in the range of 0∼3.5 wt%. The corrosion potentials were measured in every week for two years. The copper-copper sulfate electrode (CSE) was employed as a reference electrode. After two years, the corroded structure was examined and compared to measured corrosion potential. Any visible difference was founded in the specimen located indoor and outdoor. The chloride concentration enhanced rusting and reinforced bar, shifting the potential to active range. The results showed good argument with Van daveer criteria. In 3.5 wt% chloride, the potential shifted belong -350 mV after 58week. Specimen in 1.75 wt% chloride, showed the potential between -200 mV∼-350 mV. However those in free chloride solution maintained above -200 mV for the studied period. It can the concluded that the chloride enhanced corrosion of rebar in concrete and the electrochemical potential can be a promising corrosion monitoring technique.

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