• E2M - 전기 전자와 첨단 소재
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• 제9권6호
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• pp.605-615
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• 1996

In this paper, the effect of alkaline oxide addition such as Li$_{2}$O and Na$_{2}$O on the microstructure and humidity sensitivity of V$_{2}$O$_{5}$(2 mol%)-doped TiO$_{2}$(98 mol%) was investigated as a function of amount (0, 1, 2, 5, 10 mol%) of Li$_{2}$O and Na$_{2}$O additives. The pores in the alkaline free sample were distributed mostly in the range between 0.16 and 1.0.mu.m in diameter and its porosity was 23.29%. Li$_{2}$O caused grain overgrowth and reduced the porosity with a narrow distribution of the pore size, leading to poor humidity sensitivity. Na$_{2}$O helped to enlarge the distribution of the pore size through the formation of small soluble phases. The pore sizes of the sample containing Na$_{2}$O 2mol% were distributed mostly in the range between 1.0 and 2.5.mu.m in diameter and its porosity and intrusion volume of mercury were 31.13 % and 0.1155 mL/g respectively, which consequently improved the humidity sensing characteristics such as the sensitivity and temperature-stability. Especially, the addition of 2mol% of Na$_{2}$O improved the humidity-sensing characteristics such as sensitivity and linearity in the whole range between 30 and 90 %RH (Percentage Relative Humidity)y)

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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• pp.898-901
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• 2004

[ $ZnCr_2O_4$ ]를 모물질로 하고 MgO, $TiO_2$를 몰비로 2:1, 4:1, 6:1, 및 8:1이 되게 정량적으로 조합한 후, 조사하였다. $ZnCr_2O_4$-MgO와 $ZnCr_2O_4-TiO_2$를 X-선 분석한 결과 Spinel 결정구조를 형성하였으며, 또한 SEM과 EDX 분석결과 각각 $Li_2CrO_4$와 $Li_3VO_4$의 형성으로 인하여 저항 특성이 나타나는 것을 알 수 있었다. $ZnCr_2O_4-MgO$, $ZnCr_2O_4-TiO_2$에서 MgO의 양이 증가할수록 저항값은 약간 감소하는 반면, $TiO_2$의 양이 증가할수록 저항값이 급격히 증가하는 특성을 나타내었고, 감습 특성에서도 M??보다 TiO2가 더 높게 나타내었다. 습에 따른 복원 특성의 경우 $700^{\circ}C$에서 소결한 ($ZnCr_2O_4:MgO=4:1$)과 ($ZnCr_2O_4:TiO_2=6:1$) 조성의 센서가 가장 양호하였다.

• 폴리머
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• 제33권1호
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• pp.19-25
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• 2009

내수성 감습막으로 사용하기 위하여 이온넨을 포함하는 광경화성 반응성 올리고머(PIDM)로부터 새로운 종류의 전해질 고분자를 제조하였다. PIDM, hexamethylene dimethacrylate(HDM), pentaerythritol triacrylate dimer(SP1013) 및 광개시제를 혼합하여 전극에 광개시 라디칼 중합과 동시에 도포하였다. 또한, 센서의 내수성 그리고 고온/고습에서의 안정성을 증진시키기 위하여 전극 기판에 비닐기를 가지는 실란 카플링제를 사용하여 전처리 하였다. 가교화된 이온넨으로 이루어진 습도센서의 상대습도에 대한 저항을 측정하였을 때, 저항은 20%$\sim$90%RH 상대습도 영역에서 $10^3$의 값이 변화하였으며 이것은 대기의 습도를 측정하는데 요구되는 특성을 만족시키고 있다. 그 밖에 온도의존성, 히스테리시스 응답 및 회복속도, 내수성 그리고 고온/고습에서 장기 안정성을 측정하여 습도센서로서 특성을 평가하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 C
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• pp.1066-1068
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• 1995

The formation properties and oxidation mechanism of electrochemically oxidized porous silicon(OPS) films have been studied. To examine the humidity-sensitive properties of OPS films, surface-type and bulk-type humidity sensors were fabricated. The oxidized thickness of porous silicon layer(PSL) increases with the charge supplied during electrochemical oxidation and current density. The humidity sensor shows high sensitivity at high relative humidity in low temperature. The sensitivity and linearity can be improved by increasing a porosity of PSL.

• 전기학회논문지P
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• 제62권2호
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• pp.95-97
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• 2013

$CaTiO_3$ thin films using silk screen printing technology were fabricated and their humidity sensitive characteristics have been investigated. The specimens were sintered at $1000^{\circ}C$, $1050^{\circ}C$, $1100^{\circ}C$ for 1 hour and the best humidity sensitivity was shown in the specimens sintered at $1000^{\circ}C$. The humidity sensitivity decreased with increasing measuring frequencies and was stable at different abient temperatures. Hysteresis of impedance variation with increasing and decreasing relative humidity were negligible.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1992년도 하계학술대회 논문집 B
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• pp.737-739
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• 1992

The microstructure and humidity sensitive characteristics of $V_2O_5$ doped $CaTiO_3$ were studied. Sensing elements were prepared in bulk form. This element exhibits a porous structure. The grain grows and electrical conductivity increases as doping amount of $V_2O_5$ increases. The change of impedance and capacitance under different r.h is remarkable, and the conduction carriers of this element were ions.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 Techno-Fair 및 합동춘계학술대회 논문집 전기물성,응용부문
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• pp.161-163
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• 2008

$TiO_2-V_2O_5$ sol was fabricated using sol-gel method and $TiO_2-V_2O_5$, thin films were fabricated using dip-coating method. $V_2O_5$ sol was added 0.01mole, 0.03mole, 0.05mole into $TiO_2$ sol. Capacitance of thin films decreased with increasing $V_2O_5$ additive and it increased largest at 0.01mole. Because adsorption time and desorption time of thin films was about 2 minutes 40 seconds and about 3 minutes 40 seconds respectively, adsorption time was faster about 1 minutes than desorption time.

• 대한한의학원전학회지
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• 제19권3호
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• pp.1-12
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• 2006

통과분석(通過分析) ${\ulcorner}$금궤요약심전${\lrcorner}$ 습병조문중우재경적주석(濕病條文中尤在涇的注釋), 득출여하결론(得出如下結論). 습사감인(濕邪感人), 시우태양이류인관절(始于太陽而流人關節), 평일사덕불급지인(平日士德不及之人), 역감습사(易感濕邪), 습병(濕病), 무한부작(無寒不作), 여경병비풍불성(如涇病非風不成), 습병지표증시신번동(濕病之表證是身煩疼), 관절동번(關節疼煩); 이증시소변불리(裏證是小便不利), 대변반쾌(大便反快), 습황유우습사외성이기양내울발생(濕黃由于濕邪外盛而其陽內鬱發生). 표증오하발생적홰, 포만(胞滿), 소변불리등증원인시양기내울(小便不利等證原因是陽氣內鬱). 발열(發熱), 일포소극(日哺所劇), 불시여폐양명유관(不是與肺陽明有關), 이시여풍유휴작유관련(而是與風有休作有關聯). 치료외습증적발한법시징징발한(治療外習證的發汗法是徵徵發汗), 불시과도발한(不是過度發汗), 여과발한과도(如果發汗過度), 근거풍사이습사상존(僅去風邪而濕邪尙存). 약풍습재표(若風濕在表), 가이용마황가출탕(可以用痲黃加朮湯), 마황행인의이감초탕이발한(痲黃杏仁薏苡甘草湯以發汗), 약이한출이표허(若已汗出而表虛), 가이용방기황기탕이실표행습, 약표허무열(若表虛無熱), 불가발탕(不可發湯), 소이용계지부자탕이온경산습(所以用桂枝附子湯以溫經散濕), 혹용백출부자탕이보탕행습(或用白朮附子湯以補湯行濕), 약표이지탕구허(若表裏之湯俱虛), 가이용감초부자탕이포중겸발산(可以用甘草附子湯以補中兼發散).

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.328-331
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• 1995

TiO$_2$thin films for humidity sensors have been deposited by RF magnetron sputter and hygroscopic characteristics were investigated. Grain diameter of thin films were increased and hygroscopic characteristics were good as discharge power. Hygroscopic characteristics of thin films heated for 15 min at 500$^{\circ}C$ were better and more linear than that at 400$^{\circ}C$ and were unchanged as Ar flow rate.

• 한국세라믹학회지
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• 제37권6호
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• pp.537-544
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• 2000

Thin-film humidity sensor which TiO2, ZrO2, or CeO2 was added to MgCr2O4-based materials, respectively, were fabricated on the alumina substrate by using a resistant-heating evaporator. Thin films were approximately 2${\mu}{\textrm}{m}$ in grain size and shwoed porous microstructures. The resistance of the sensor decreased with increasing the relative humidity and the MgCr2O4-TiO2 sensor had the best humidity-sensing characteristics (linearity in relative humidity versus resistance).