• Title/Summary/Keyword: 가황

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Evaluation of Quality Characteristics and Definition of Utilization Category in Korean Potato (Solanum tuberosum L.) Cultivars (국내산 감자(Solanum tuberosum L.)의 품종별 품질특성 평가 및 용도구분)

  • Lee, Yeh-Jin;Jeong, Jin-Cheol;Yoon, Young-Ho;Hong, Su-Young;Kim, Su-Jeong;Jin, Yong-Ik;Nam, Jeong-Hwan;Kwon, Oh-Keun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.3
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    • pp.271-279
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    • 2012
  • Total twenty cultivars of potato (Solanum tuberosum L.) were grown at Gangneung where is located in low land of Korea. Their tubers were harvested from 100 to 120 days after planting, and over 150 g of tubers were selected for quality evaluation. Dry matter, starch, amylose in starch, ascorbic acid, protein, individual sugars and mineral were analyzed and mealiness of cooked potatoes were also evaluated by panel test. Dry mater content was the highest in 'Haryeong', 'Jayoung' and 'Shepody', and the biggest starch granules were observed in 'Jayoung' and 'Sinnamjak'. In addition, the content of amylose was highest in 'Haryeong', 'Chudong' and 'Goun'. Mineral content showed the slight difference between cultivars, but it's tendency was not clear. Vitamin C content was highest in 'Jayoung' as 62.5 $mg{\cdot}100g^{-1}$ FW, and 'Chugang' exhibited the highest content of protein. Sugar content was lower in cultivars for single one than double cropping. The lowest sugar content was observed in 'Atlantic' and 'Namseo' among cultivars for single cropping, and in 'Goun' for double cropping. As a result of analysis for quality factors, we could select nine cultivars ('Atlantic', 'Gahwang', 'Gawon', 'Goun', 'Hareong', 'Irish Cobbler', 'Jasim', 'Jayoung' and 'Shepody') with high dry matter content and low reducing sugar as a cultivar group for processing. Additionally, seven cultivars ('Chugang', 'Gawon', 'Goun', 'Hareong', 'Irish Cobbler', 'Jasim' and 'Seohong') with high mealiness and amylose content and five cultivars ('Atlantic', 'Chudong', 'Gahwang', 'Jopung' and 'Jowon') with low mealiness and amylose content were classified as groups for boiled or steam cooking and for soup or pot dishes, respectively.

Design and Performance Evaluation of Two-Layered Microwave Absorbers(Dielectric/Magnetic) for Wide Oblique Incidence Angles Used for ITS (ITS용 2층형 전파 흡수체(유전체/자성체) 설계 및 경사 입사 흡수 특성 해석)

  • Kim, Jae-Woong;Kim, Sung-Soo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.11
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    • pp.1217-1223
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    • 2007
  • Advanced microwave absorbers for wide oblique incidence angles are required in many applications including wireless communication or vehicle identification in ITS(Intelligent Transport System) where 5.8 GHz DSRC(Dedicated Short Range Communication) system is applied. In this study, two-layered microwave absorber(with a laminate structure of dielectric/magnetic composites) has been designed for the achievement of low reflection coefficient over wide incidence angles at 5.8 GHz. Iron flake particles are used as the filler in the absorbing layer, and the magnetic composite sheet exhibits high magnetic loss due to ferromagnetic resonance in gigahertz frequencies. The surface layer of low dielectric constant containing small amount of carbon black is used as the impedance transformer. On the basis of transmission line theory, the reflection loss has been calculated for the two-layer structure with variation of incident angles for both TE(Transverse Electric) and TM(Transverse Magnetic) polarizations. At the optimum thickness of the composite layers, a low value of reflection loss(less than -10 dB) has been predicted for wide incidence angles up to $55^{\circ}$ which is in good agreement with the measured value determined by free-space measurement.

Study on the Flame Retardation and Thermal Resistance for CPE Rubber Material Added Etching By-product of Aluminum (알루미늄 엣칭부산물을 첨가한 CPE 고무재료의 난연성 및 내열성 연구)

  • Kim, Kyung Hwan;Lee, Chang Seop
    • Journal of the Korean Chemical Society
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    • v.45 no.4
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    • pp.341-350
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    • 2001
  • Aluminum Hydroxide was employed as a thermal retardent and flame retardent for Chloropolyethylene (CPE) rubbery materials which is the construction material of automotive oil cooler hose. and then cure characteristics, physical properties, thermal resistance and flame retardation of compounded rubber were investigated, and optimum mixing conditions of rubber and flame retarding agent were deduced from the experimental results. CPE rubber material which has excellent properties of chemical corrosion resistance and cold resistance and inexpensive in price was used to prepare rubber specimen. The by-product of ething, produced from the process of surface treatment of aluminum was processed to aluminum hydroxide via crushing and purification, which is characterized by XRD, PSA, SEM and ICP-AES techniques in terms of phase, size, distribution, morphology and components of particles and then mixed to CPE rubber materials in the range of 0~80 phr. Hardness, tensile strength, elongation and thermal properties of compounded rubber specimens were tested. The optimum mixing ratio of rubber to additives to give maximum effect on thermal resistance and flame retardation, within the range of tolerable specification for rubber materials, was determined to be 40 phr. The flame retardation of CPE rubber materials was found to be increased by 5 times at this mixing ratio.

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Mechanical Properties of Acrylonitrile Functionalized Emulsion SBR/silica Compounds (아크릴로니트릴이 극성기로 도입된 유화중합 SBR/실리카 컴파운드의 기계적 물성)

  • Kim, Dong-Won;Seo, Byeong-Ho;Kim, Hee-Jeong;Paik, Hyun-Jong;Kang, Jong-Won;Kim, Won-Ho
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.54-64
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    • 2012
  • Acrylonitrile was introduced in the emulsion SBR to increase compatibility between silica and rubber. AN-SBR/silica compounds showed faster vulcanization time and higher delta torque values than SBR 1721/silica compounds because interaction between nitrile group of AN-SBR and silanol group on the silica surface could make hydrogen bond that prevented adsorption of the accelerator on the silica surface, which improved the vulcanization reaction efficiency and enhanced the degree of crosslinking. AN-SBR/silica compound showed higher values in minimum torque than SBR 1721/silica compound during the vulcanization because AN-SBR has higher molecular weight than SBR 1721 in the raw material. When PEG was added to the SBR 1721 and AN-SBR compounds, vulcanization time was faster than SBR 1721 and AN-SBR compounds without PEG because PEG has a large number of ether linkages which show high compatibility with silanol group on the silica surface that prevented the adsorption of the accelerator and the ingredients on the silica surface, which improved the vulcanization reaction efficiency. In the mechanical properties, AN-SBR compounds showed higher modulus values at 100%, 300% than SBR 1721 compounds because interaction between nitrile group of AN-SBR and silanol group on the silica surface enhanced the degree of crosslinking. In the dynamic properties, AN-SBR compounds showed lower tan ${\delta}$ values at $0^{\circ}C$ than SBR 1721 compounds in accordance with the $T_g$ values. AN-SBR compounds showed lower tan ${\delta}$ values at $60^{\circ}C$ than SBR 1721 compounds because interaction between acrylonitrile and silica caused strong filler-rubber interaction that induced low energy dissipation by the filler-filler interaction.

Reinforcement of Rubber Properties by Carbon Black and Silica Fillers: A Review

  • Seo, Gon;Kim, Do-Il;Kim, Sun Jung;Ryu, Changseok;Yang, Jae-Kyoung;Kang, Yong-Gu
    • Elastomers and Composites
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    • v.52 no.2
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    • pp.114-130
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    • 2017
  • Enhancing the properties of rubber, such as the tensile strength, modulus, and wear abrasion, by the addition of carbon black and silica as fillers is very important for improving the performance of rubber products. In this review, we summarize the general features of 'the reinforcement of rubber by fillers' and the equations for representing the reinforcement phenomena. The rubber reinforcement was attributed to enhancement of the following: the rubber, bound rubber, formation of networks, and combination between rubber chains and silica followed by entanglement. The reinforcement capability of silica species with different surface and networked states demonstrated the importance of the connection between the silica particles and the rubber chains in achieving high reinforcement. The model involving combination followed by entanglement can provide a plausible explanation of the reinforcement of rubber by carbon black and silica because the combination facilitates the concentration of rubber chains near the filler particles, and entanglement of the rubber chains around the filler particles enforces the resistance against deformation and breakage of rubber compounds, resulting in high reinforcement.

Changes of asparagine content in potato (Solanum tuberosum L.) tuber during storage (저장 중 감자 아스파라진 함량의 변화)

  • Jin, Yong Ik;Cho, Ji Hong;Chang, Dong Chil;Im, Ju Sung;Park, Young Eun;Yu, Hong Sub;Jeong, Jin Cheol;Park, Kyeong Hun;Chung, Il Min
    • Journal of Plant Biotechnology
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    • v.39 no.4
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    • pp.300-304
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    • 2012
  • In order to research changes of asparagine content according to stage after harvest to storage, it was analysed asparagine content of potato tuber and potato sprout. The results of the asparagine content in potato cultivars after harvest ranked in cv. Superior, cv. Gahwang, cv. Atlantic and cv. Goun in descending order. The content of asparagine in potato was approximately 1300 mg/100g (D.W.) The changes the asparagine content according to storage condition and the difference of asparagine between tuber and sprout can be summarized as follows. In the asparagine content of potato cultivars, Little variation in the content was observed while potato tubers were stored at $4^{\circ}C$. However, after 3 months of storage at $10^{\circ}C$, the content increased by 9.7%, indicating that the content increases as the storage temperature and period increases. The content of asparagine also increased during sprouting of potato tubers. In the sprout, the proximal region contained 21% higher content of asparagines than the distal region, which suggests that the sprout develops with the increasing of the content of asparagines.

Experimental Study on the Characteristics of Asphalt Seal Waterproofing Material for Underground External Walls According to Temperature (온조도건에 따른 외벽방수용 아스팔트 씰계 재료의 흘러내림 특성에 관한 실험)

  • Um, Tae-Ho;Kim, Young-Sam;Shin, Hong-Chul;Cho, Jae-Woo;Kim, Young-Geun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.1
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    • pp.1-5
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    • 2018
  • The present study investigated the characteristics of vertical sagging down of high temperature in chamber and characteristics of vertical sagging down in the outdoor asphalt sheet and asphalt seal under korea ltimate condition using asphalt seal products of solvent based type, solventless type, water dispersion type, and heat melting type, which are currently applied in Korea. Prior to the investigation of outdoor vertical sagging down characteristics, the assessment of sagging down performance of single use of sealing products at $20^{\circ}C$, $40^{\circ}C$, $60^{\circ}C$ was conducted and the result showed that sagging down did not occur at $20^{\circ}C$ but some solventless type, water dispersion type specimens at $40^{\circ}C$ had sagging down up to 10 mm. In addition, some solventless type, water dispersion type specimens had sagging down up to 55 mm at $60^{\circ}C$. For specimens to which asphalt seal and renovated asphalt sheet were layered over the outdoor concrete vertical surface, sheet sagging and sagging down occurred up to 50 mm in water dispersion specimens after three month later since the construction in summer.

A Study on the Mechanical Properties of Surface Activated Waste EPDM and The Analysis of Odor Materials (표면 활성화된 폐 EPDM 분말의 물성과 냄새 성분 분석 연구)

  • Choi, J.;Kim, S.;Chung, K.;Chung, J.;Yoo, T.;Yang, J.
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.249-258
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    • 2007
  • In this study, the EPDM powder which was surface activated by high temperature and shear pulverization process was prepared and the mechanical properties and odor material analysis were investigated. Analysis for particle size and size distribution of waste of the EPDM powder has been performed. The waste EPDMs used in this study were 4 types of solid, sponge, solid+sponge, and solid+metal. According to the results, the solid type showed the smallest particle size among the 4 types of EPDM powder. Effective surface devulcanization of EPDM powder could be obtained by the addition of the reclaiming agent. The dicumyl peroxide was considered as the best crosslink agent for dynamic vulcanization when the surface activated EPDM powder was blended with polyolefin in order to make TPE. Also, the optimum amounts of DCP was 6 phr in terms of surface crosslink reaction and mechanical properties of EPDM powder. The processes of water adsorption and rose oil addition were employed to remove the odor of EPDM powder caused by reclaiming agent. The GC/MS was used to analyze the odor compounds.

Physical Properties of the Silica-Reinforced Tire Tread Compounds by the Increased Amount of Vulcanization Agents (가교제 증량이 트레드용 실리카 컴파운드의 물성에 미치는 영향)

  • Seo, Byeongho;Kim, Ki-Hyun;Kim, Wonho
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.201-208
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    • 2013
  • In this study, effect of different amounts of sulfur and vulcanization accelerators in the acrylonitrile styrene-butadiene rubber (AN-SBR)/silica compounds on the properties of tire tread compound were studied. As a result, cure rate and degree of cross-linking of the compounds were increased due to enhanced cross-linking reactivity by the increased amounts of sulfur and vulcanization accelerators. Also, abrasion resistance and the mechanical properties such as hardness and modulus of the compounds were improved by enhanced degree of cross-linking of the compounds. For the dynamic properties, tan ${\delta}$ value at $0^{\circ}C$ was increased due to the increase of glass transition temperature ($T_g$) by enhanced degree of cross-linking of the compound, and tan ${\delta}$ value at $60^{\circ}C$ was decreased. Initial cure time ($t_1$) showed the linear relationship with tan ${\delta}$ value at $60^{\circ}C$. This result is attributed that reduced initial cure time ($t_1$) of compounds by applying increased amount of curatives can form cross-linking in early stage of vulcanization that may suppress development of filler network. This result is verified by observation on the surface of annealed compounds using AFM (atomic force microscopy). Consequently, decreased initial cure time is considered a very important parameter to reduce tan ${\delta}$ at $60^{\circ}C$ through reduced re-agglomeration of silica particles.

Analysis of Nitrosamines Concentration in Condom by using LC-MS/MS (LC-MS/MS를 이용한 콘돔에 함유된 니트로사민류 농도 분석)

  • Park, Na-Youn;Kim, Sungmin;Jung, Woong;Kho, Younglim
    • Journal of the Korean Chemical Society
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    • v.62 no.3
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    • pp.181-186
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    • 2018
  • Nitrosamines are the nitrosocompounds which are produced by nitrosation reactions of the secondary amine and nitrite, and has been found to be produced through the vulcanization process during the production of rubber products Recently, nitrosamines have been detected in rubber products and become a major topic. Condoms are disposable medical devices, so safety is important because they come into direct contact with the skin and mucous membranes. In this study, we developed an analytical method for nitrosamines in condoms by applying ISO 29941 method. The samples were eluted by distilled water, and target compounds were extracted by liquid-liquid extraction with dichloromethane. And then after concentrated, and quantitatively analyzed by LC-MS/MS. The accuracies of the analytical method were ranged from 85.8 to 108.7%, precisions were lower than 11.5%, and the detection limits were from 0.11 (NDPA and NDBA) to 0.48 (NPYR) ng/mL. Among the 31 condom samples, NDBA was detected from 2 cases by extraction of distilled water, and NDMA were detected from 1 case, NDEA from 4 cases and NDBA from 26 cases by extraction of artificial saliva (pH 4.5). The total amount of nitrosamines in all samples were less than $500{\mu}g/kg$.