• Title/Summary/Keyword: 가압반응

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Reduction of Allergenicity of Domestic Pork Ham and Bacon by Autoclave Treatment (가압가열 처리에 의한 시판 돈육 햄과 베이컨의 알레르겐성 저감화 효과)

  • Kim, Seo-Jin;Kim, Koth-Bong-Woo-Ri;Song, Eu-Jin;Lee, So-Young;Yoon, So-Young;Lee, So-Jeong;Lee, Chung-Jo;Kim, Kyu-Earn;Ahn, Dong-Hyun
    • Food Science of Animal Resources
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    • v.30 no.1
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    • pp.133-140
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    • 2010
  • The pork hams and bacon comprising the most popular processed pork were treated with autoclave to investigate application of hypoallergenic pork. Among pork hams and bacon, two products with the highest binding ability were selected for experiments. The results of ci-ELISA on pork hams treated with autoclave showed that the binding ability of p-IgG and pigallergic patient's sera (P2) to PSA (porcine serum albumin) from pork ham samples by autoclave treatment at $121^{\circ}C$ for 30 min was slightly decreased. The binding ability to p-IgG of b and c bacon treated with autoclave was declined to below 16% and 11% as compared with control sample that showed 60% and 91% binding ability. The binding ability to P2 of b and c bacon treated with autoclave decreased to below 22% and 34% as compared with control sample that showed 95% and 126% binding ability. A result of immunoblotting on bacon showed that p-IgG as well as pig patient's sera did not recognize PSA well in autoclave treatment. The results obtained from this work indicated that autoclave treatment was effective for a reduction of allergenicity of pork hams and bacon. Therefore the autoclave treatment may be applied to development of hypoallergenic pork.

Application of Dissolved Air Flotation Technique to Improve Reservoir Water Quality (가압부상 공법을 이용한 호소수질개선 연구)

  • Kim, Tae-Hoon;Sei, Young-Ho;Ahn, Tae-Woong;Choi, I-Song;Oh, Jong-Min
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.491-493
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    • 2012
  • 우리나라는 농업용수, 생활용수 등의 목적으로 여러 개의 호소 등을 설치하여 운영 중에 있다. 하지만 몇몇 호소들은 인구증가 및 산업발달로 인하여 매년 오염도가 증가하는 것으로 알려져 있으며, 특히 부영양화 현상으로 인하여 남조류가 과다번식 할 경우 호소 수질 및 수생태계에 악영향은 미치는 것으로 알려져 있다. 따라서 호소의 부영양화 현상을 제어하기 위한 많은 연구가 이루어지고 있으며, 부영양화 현상을 발생시킬 수 있는 여러 제한인자 중 인(P)에 대한 관심이 많아지고 있는 실정이다. 부상분리의 일종인 DAF는 침전공정의 대안으로서 25년 전부터 유럽과 미국을 중심으로 정수 및 하수처리 공정에서 이용되어 왔다. 가압부상공법에서 발생되는 기포의 크기는 $50{\sim}100{\mu}m$ 정도로 부상물질인 스컴이 파괴될 가능성이 낮고 기포의 크기가 작아 공기의 용해효율이 높으며 대전작용, 물리적 흡착효과 등의 특징을 가진다고 알려져 있다. 또한 공기와 물 뿐만 아니라 Al 성분의 응집제인 PAC를 이용하여 버블을 발생시킬 경우 인의 제거 효율이 크다고 알려져 있다. 가압부상공법의 경우 응집 침전 공정과는 달리 발생되는 처리과정에서 발생되는 부산물을 외부로 유출 시킬 수 있기 때문에 호소 수질정화에 이용될 수 있다고 판단된다. 따라서 본 연구에서는 저수지의 형태와 유사한 반응조를 설계하여 DAF를 주입하는 실내실험을 진행하였으며, 이를 통해 호소수질 정화를 위한 DAF의 타당성에 대해 평가하기 위해 이루어졌다.

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Combustion Characteristics of Domestic Anthracite with High-Pressure TGA (가압열중량분석기를 이용한 국내무연탄의 연소특성 해석)

  • 류호정;한근희;진경태;이계봉;최정후
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.243-252
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    • 2001
  • Combustion characteristics of domestic anthracite coal were observed by high-pressure thermogravimetric analyzer with variation of pressure (1~16 atm) and heating rate (15, 20, $25^{\circ}C$/min) with non-iso-thermal method (temperature range : 25~100$0^{\circ}C$). Measured combustion reaction rate increased with increasing pressure. This result could be explained by the fact that the activation energy of coal combustion decreased with increasing pressure. Reaction order of coal combustion determined by Freeman and Carroll$^{[11]}$ method linearly increased from 1.04 to 1.30 and activation energy decreased from 47.37 to 14.42 Kcal/mol as pressure increased from 1 to 16 attn.

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900MWe 가압경수로에 대한 토륨핵연료 및 혼합핵연료 노선 핵특성 분석

  • 주형국;김영진;정형국;노재만;조진영
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.46-51
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    • 1998
  • 토륨핵연료를 이용한 플루토늄 소모에 대한 연구를 목적으로 조직된 IAEA CRP(Coordinated Research Program) 업무의 일환으로, 농축우라늄 및 플루토늄을 seed로한 토륨핵연료를 국내의 900MWe 가압경수로에 이용하였을 경우에 플루토늄을 비롯한 heavy isotope의 원소량 변화, 사용 후 핵연료로부터의 방사능 준위, 노심의 반응도 특성을 분석하여 혼합핵연료 노심과 비교하였다. (Th+Pu)O$_2$,는 혼합핵연료 보다 플루토늄의 소모량이 약 2.4배 많으며, fissile 플루토늄 원소의 존재비율은 10% 정도 더 감소하는 것으로 나타나 플루토늄 소모의 특성이 유리하고 핵비확산 성격이 강한 것으로 나타났다 사용후 핵연료의 방사능은, 핵연료가 노심에서 바로 인출된 시점에서 는 (Th+Pu)O$_2$,가 가장 낮으나, 그 이후로는 (Th+Pu)O$_2$와 혼합핵연료의 방사능은 비슷한 반면, (Th+U)O$_2$,의 방사능이 가장 낮은 것으로 나타나 장기적으로는 (Th+U)O$_2$가 가장 유리하다. 대략적인 전환비는 (Th+Pu)O$_2$노심이 약 0.56, (Th+U)O$_2$ 노심은 약 0.63, 혼합핵연료 노심은 약 0.61 정도로 추정되었다. 토륨핵연료의 연소도에 따른 반응도 변화, 가돌리니아봉의 중성자 횹수 성질 및 반응도 특성 등 노심특성은 seed 물질의 특성과 함량에 따라 좌우되는 것으로 나타났다.

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An Empirical Study on the Characteristics of Pore Water Pressure Reaction in Colluvium Model (붕적층내의 간극수압 반응에 관한 실험적 연구)

  • 정두영;최길렬
    • Geotechnical Engineering
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    • v.8 no.2
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    • pp.59-70
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    • 1992
  • This work is to study experimentally the measurment of pore air pressure according to rainfall in colluvium model and the characteristics of pore water pressure according to increasement of artesian ground water head. After modeling a geological feature of the Tertiary formation, the experiment was performed about sixty times on three kinds of soil. This experimental results showed the variation of pore water and pore air pressures with time, the change of void ratio and appling pressure head in the nonsaturated soil. It can be also expressed by the final pore water and the air reaction ratios and then formularizing the relationship between the permeability coefficient and the void ratio. In the results of this experiment, the patterns of the pore water pressure reaction are classified by the step-type and the wave-type, and the time-lag to reach final point of pore water pressure is in order sand, sandy silt and clayey sand.

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A Study of Alkali Metal Vapor Adsorption Behavior by Using Pressurized Reactor (가압반응기를 이용한 알칼리금속증기 흡착특성에 관한 연구)

  • 전수한;최병철;김형택
    • Journal of Energy Engineering
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    • v.11 no.2
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    • pp.114-121
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    • 2002
  • Alkali metal compounds existed in original coal or sorbents are exhausted as vapor or small particle at the outlet of combustor when operating PFBC power plant. These compounds can be removed with dust removal equipment, but total generation efficiency will be decreased because of lower operating temperature of dust removal equipment. Alkali metal contained in vapor phase is initially deposited onto turbine blade results in serious corrosion. The concentration of alkali vapor in the PFBC flue gas is 20∼40 ppm which is dependent on mineral characteristics and composition as well as operating condition of PFBC. However, the allowance limit of alkali metal vapor is assigned as less than 50 ppb for gas turbine when coal or oil is used as fuel. Therefore, alkali metal vapor in PFBC or IGCC process should be removed by solid sorbents to prevent corrosion of turbine blade and improve plant efficiency. In the present investigation, powder of Bauxite, Kaolinite and Limestone is used in the preparation of cylinder-type pellet which is inserted into the pressurized alkali removal reactor for the alkali absorption experiment. Experimental results showed that the alkali removal efficiency in the order of Bauxite, Kaolinite and Limestone. Alkali vapor removal efficiency is related with reaction temperature, porosity of pellet and alkali vapor concentration of flue gas.

Numerical Study of Combustion Characteristics by Pressure and Oxygen Concentration in Counter-Flow Diffusion Flame Model (대향류 확산 화염 모델에서의 압력 및 산소분율에 따른 연소 특성 변화에 관한 수치해석 연구)

  • Park, Jinje;Lee, Youngjae
    • Clean Technology
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    • v.27 no.1
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    • pp.93-103
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    • 2021
  • As the seriousness and necessity of responding to climate change and reducing carbon emissions increases, countries around the world are continuing their efforts to reduce greenhouse gases. Among various efforts, research on CCUS, capturing and utilizing carbon dioxide generated when using carbon-based fuels, is actively being conducted. Studies on pressurized oxy-fuel combustion (POFC) that can be used with CCUS are also being conducted by many researchers. The purpose of this study is to analyze basic information related to the flame structure and pollutant emissions of pressurized oxy-fuel combustion. For this, a counter-flow diffusion flame model was used to analyze the combustion characteristics according to pressure and oxygen concentration. As the pressure increased, the flame temperature increased and the flame thickness decreased due to a reaction rate improvement caused by the activation of the chemical reaction. As oxygen concentration increased, both the flame temperature and the flame thickness increased due to an improvement to the reaction rate and diffusion because of a change in oxidizer momentum. Analyzing the related heat release reaction by dividing it into three sections as the oxygen concentration increased showed that the chemical reaction from the oxidizer side was subdivided into two regions according to the mixture fraction. In addition, the emission index of NO classified according to the NO formation mechanism was analyzed. The formation trend of NO according to each analysis condition was presented.

Solid $CO_2$ sorbents and WGS catalyst for pre-combustion $CO_2$ capture (연소전 $CO_2$ 회수를 위한 고체 흡수제 및 WGS 촉매 특성 평가)

  • Eom, Tae Hyoung;Lee, Joong Beom;Park, Keun Woo;Choi, Dong Hyuk;Baek, Jeom-In;Ryu, Chong Kul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.111.1-111.1
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    • 2010
  • 석탄가스화복합발전(IGCC: Integrated Gasification Combined Cycle)의 고온 고압 합성가스로부터 $CO_2$를 저비용으로 포집하기 위한 연소전 포집 기술 중 유동층 촉진수성가스전환(SEWGS) 공정이 제안되어 연구개발 중에 있다. 연소전 $CO_2$ 포집을 위한 SEWGS 공정은 동일한 2탑 순환 유동층 반응기에서 고온 고압의 합성가스($H_2$, CO)를 유동층 WGS 촉매를 사용하여 CO를 $CO_2$로 전환하는 동시에 전환반응으로 생성된 $CO_2$를 흡수제를 이용하여 포집하는 기술이다. 본 연구는 $CO_2$ 회수와 WGS 반응이 동시에 이루어지는 공정에 적용 가능한 건식 재생 흡수제 및 유동층 WGS 촉매 개발을 목표로 $CO_2$ 흡수제(P Series) 및 WGS 촉매(PC Series) 조성을 제안하고 분무건조기를 이용하여 6~8kg/batch로 성형 제조하였다. 제조된 $CO_2$ 흡수제 및 촉매의 특성 평가 결과 내마모도(Attrition resistance)를 포함한 물리적 특성이 유동층 공정의 요구조건을 만족하는 결과를 얻을 수 있었다. 또한, 모사 석탄 합성가스를 이용하여 20bar, $200^{\circ}C$ 흡수/$400^{\circ}C$ 재생 조건에서 열중량 분석기(TGA) 및 가압 유동층(Fluidized-bed) 반응기를 통한 흡수제의 $CO_2$ 흡수능 평가를 수행하였다. 그 결과 내마모도(AI) 3% 이하로 기계적 강도가 우수하며, $CO_2$ 흡수능 17.6 wt%(TGA) 및 11wt%(가압 유동층)를 나타냈다. 유동층 WGS 특성 평가 결과 내마모도가 7~35%로 우수하였고, CO 전환율은 $200^{\circ}C$에서 80% 이상으로, 유동층 SEWGS 공정에 적용 가능한 특성을 확인하였다.

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Preparation of Calcium Sulfate α-Hemihydrate from FGD Gypum in the Autoclave (가압반응기를 이용한 배연탈황석고로부터 α형 반수석고의 생성)

  • Park, Seung-Soo;Kim, Ki-Hyoung;An, Hi-Soo;Park, Kwang-Kyu
    • Applied Chemistry for Engineering
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    • v.17 no.6
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    • pp.619-624
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    • 2006
  • This study was performed to investigate the formation process of calcium sulfate ${\alpha}$-hemihydrate from FGD gypsum produced at thermal power plant burning bituminous coal. The experimental results showed that calcium sulfate $\alpha$-hemihydrate with a large aspect ratio was produced in the temperature range of $120^{\circ}C$ and $140^{\circ}C$ in the absence of additives through dissolution-recrystallization mechanism. It was also observed that addition of Na-succinate as a catalyst changed crystal shape from acicular to prismatic, resulting in decreased water/powder ratio down to 33%. Optimum concentration of Na-succinate was 20mM. It was confirmed that the optimum moulding pressure and moisture content of moulded body from FGD gypsum were $30kg_f/cm^2$ and between 10% and 15% respectively, which prevent moulded body from collapsing and maximize the capillary effect by given pore volume while autoclaving.