• Title/Summary/Keyword: 가스용해량

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A Study on Livestock Odor Reduction Using Water Washing System (수세탈취시스템을 이용한 축산악취저감에 관한 연구)

  • Jeon, Kyoung-Ho;Choi, Dong-Yoon;Song, Jun-Ik;Park, Kyu-Hyun;Kim, Jae-Hwan;Kwag, Jung-Hoon;Kang, Hee-Sul;Jeong, Jong-Won
    • Journal of Animal Environmental Science
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    • v.16 no.1
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    • pp.21-28
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    • 2010
  • The odor problem in the livestock is increasing by 7% annually. Most importantly, the livestock odor problem in swinery accounts for the maximum ratio (54%). In this study, we reviewed the possibility of deodorizing swinery using an odor reduction device that can be used with the water washing system. First, the study confirmed that the solubility of odor gas, which was hydrogen sulfide, was very low regardless of the contact time with solvent, but the solubility of methyl mercaptan was found to increase along with the increase in time. The solubility of other odor gases, such as dimethyl sulfide, dimethyl disulfide and ammonia, was considerably high. Consequently, it is considered that if the odor reduction device for the water washing system deodorization is used in a swinery, the time during which the exhaust gas is in contact with usable water must be extended, or solvent quantity must be expanded. However, it is predicted that although hydrogen sulfide is easily generated in the anaerobic condition, it is difficult to expect high odor reduction efficiency because this gas has low solubility in water, especially in case it is used in the deodorization of the water washing system. The result of the solubility experiment using the bench-scale device practically manufactured represented the higher odor reduction ratio than expected. This result was possible because the removal efficiency of dust particles could be reached up to 93%. Therefore, it is judged that also the odor gas absorbed on dust particles could be removed by removal of dust. Consequently, it is expected that the higher order reduction ratio will be possible by structural improvement for increasing contact with water and odor gas.

Synthesis of Sulfonated Poly(phenylene sulfide) via Soluble Precursor and its Ammonia Gas Adsorption (용해성 전구체를 통한 Sulfonated Poly(phenylene sulfide)의 합성과 암모니아가스 흡착)

  • Son, Won Keun;Kim, Hyun Suk;Park, Soo Gil
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.666-671
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    • 1999
  • In this work, sulfonated poly(phenylene sulfide) (SPPS) was prepared by demethylation with aqueous NaOH solution after poly[methyl[4-(phenylthio)phenyl]sulfonium trifluoromethanesulfonate](PPST) was sulfonated with fumic sulfonic acid(10% $SO_{3}-H_{2}SO_{4}$). PPST soluble in organic solvents was synthesiszed by self-condensation polymerization of methyl-(phenylthio)phenyl sulfoxide(MPPSO). SPPS showed IR bands of asymmetric O=S=O stretching at $1200cm^{-1}$ and S-O stretching at $621cm^{-1}$ from $-SO_{3}H$ group. From the result, it could be known that sulfonic acid groups were introduced to poly(phenylene sulfide). when PPST was sulfonated for 12hr at $150^{\circ}C$, 1.48 sulfonic acid groups were introduced per repeat unit. The weight average molecular weight(Mw) of PPST and SPPS determined by high temperature GPC were 118323 and 131204, respectively. The SPPS exhibited adsorption capacity of ammonia gas $9.67mmol\;NH_{3}/g$ and it was much higher than that of active carbon or silica gel.

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Recyling and refining of molybdenum scraps by vacuum arc melting (진공(眞空) 아크 용해(溶解)에 의한 몰리브덴 스크랩의 재활용(再活用) 및 정련(精鍊))

  • Lee, Back-Kyu;Oh, Jung-Min;Lee, Seoung-Won;Kim, Sang-Bae;Lim, Jae-Won
    • Resources Recycling
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    • v.20 no.5
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    • pp.40-45
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    • 2011
  • We carried out to investigate the refining effect of molybdenum by Ar-H$_2$ vacuum arc melting(VAM) process for recycling Mo scrap. The purity of the Mo metals refined by VAM was evaluated using glow discharge mass spectromety(GDMS). From the result of GDMS, most impurities in the Mo metals except for W were removed by Ar-H$_2$ VAM down to a few mass ppm levels. The purity of the refined molybdenum scrap was improved up to 4N5(99.995%) from 3N(99.95%) of the initial Mo scrap. The amount of gaseous impurities such as C, N, and O in Mo scrap were decreased from 1290 ppm to 132 ppm. As a result, it is considered that a possibility of refining and cost-effective method for recycling Mo scrap by Ar-H$_2$ vacuum arc melting process was confirmed in this study.

A study on multi-media exposure and risk assessment of radon (자연 방사성 물질 중 라돈에 대한 다매체 노출 및 위해성 평가 연구)

  • 김예신;김진용;박화성;문지영;박성은;신동천
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.369-370
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    • 2003
  • 여러 가지 실내공기 오염물질중 라돈은 주로 자연 발생원으로부터 기인하는 물질로써 우리가 원하지 않는 비자발적 위험 요인(unwanted and involuntary risk factor)이며 전체 자연 방사성물질의 노출량에서도 많은 비율을 차지하는 것으로 알려져 있다(환경부, 2002). 라돈은 무색, 무취의 가스로 이를 흡입하는 경우 폐암을 유발하는 것으로 알려져 있다. 토양중 라돈은 지하수로 용해되어 지하수를 섭취하는 경우 노출될 수 있는데, 이로 인한 위해도보다는 실내공기로 인한 흡입 노출시의 위해도가 매우 크고, 이로 인해 실내 공기중 라돈의 위해도가 라돈으로 인한 전체 위해도의 90% 수준에 달하는 것으로 알려져 있다(NAS, 1999; 김순애 등, 2002). (중략)

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The Viscosity Change of ABS Resin According to Inert Gas Amount (가스의 용해량에 따른 ABS 수지의 점도 변화)

  • 정태형;하영욱;정대진
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.585-590
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    • 1997
  • Conventional foaming process has defects such as lower mechanical properties than ur~foaming material due to non-uniform cell distribution and environmental pollution problem caused by chemical blowing agency. So, a new foaming process such as Microcelluar plastics has been introduced to use inactive gases as a foaming agency. In order to apply Microcellular plastics for mass production process system such as extrusion, injection molding and blow molding, it needs to predict the change in material properties of polymer according to the amount of meltingas. In Polymer molding applying Microcelluar plastics, the change of viscosity among several material properties is the most important factor. Therefore, this paper is aimed to establish the method which not only finds out but also predicts the change of viscosity of ABS(Acrylonitri1e Butadiene Styrene) resin according to inert gas amount in extrusion molding.

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Study on $CaCO_3$ Preparation from MSWI Fly Ash (생활쓰레기 소각(燒却)비산재로부터 $CaCO_3$ 제조(製造)에 관한 연구(硏究))

  • Choi, Woo-Zin;Park, Eun-Kyu
    • Resources Recycling
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    • v.15 no.5 s.73
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    • pp.47-51
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    • 2006
  • The total amount of ash generated from the municipal solid waste incineration(MSWI) in Korea was approximately 420,000 tons in 2005 including 68,000 tons of fly ash. Fly ash from MSWI generally contains high amount of CaO (upto ${\sim}50%$) due to the treatment of flue gas by spraying CaO-base materials. Currently, most of fly ash generated is finally ended up with specially designed landfill sites and only less then 20% of fly ash is recycled. In the present work, preparation of $CaCO_3$ from the MSWI ny ash was studied to promote the fly ash recycling. Fly ash obtained from the dust collector in stoker-type MSWI is used to selectively dissolve CaO by using the sugar solution. Then, $CO_2$ gas was passed through the dissolved solution to pro- duce $CaCO_3$ powder. The optimum conditions for CaO dissolution were solid content 10%, reaction time 15 minutes, sugar concentration $10{\sim}15%\;and\;pH\;10.5{\sim}11.0$. The high grade $CaCO_3$ powder was obtained and the experimental conditions are also discussed.

Noncondensable gas's influence in waster vapor absorption accompanying interfacial disturbance into aqueous solution of LiBr

  • Dong-Ho RIE;Keun-Oh Lee
    • Journal of the Korean Society of Safety
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    • v.7 no.2
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    • pp.63-70
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    • 1992
  • The aim of this research is to obtain a basic quantitative understanding of the effect of a noncondensable gas on the absorption of water vapor by a $H_2O$ / LiBr combination with n-octanol as the surfactant. Nonflowing aqueous solutions of LiBr (40,45,50 mass%) were exposed to saturated water vapor following the addition of an n-octanol sufactant (0.01 and 0.6 mass%). A small amount of a noncondensable gas (air) was allowed into the absorber (0.03 volume%) and its effect was analyzed by measuring the amount of water vapor absorbed. This study will aid to predict the performance of heat pump and safety operating condition when the noncondensable gas is not allowed in the absorber The results indicate that, in the presence of small amounts of a noncondensable gas, vapor absorption enhancement ratios are less than half o( those obtained under the same experimental conditions when a noncondensable gas is not present (1). The presence of a noncondensable gas causes the partial vapor pressure of air to increase at the vapor / liquid interface, which results in an instability of vapor absorption rate nd. hence, in an inhibition of interfacial disturbance.

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Calculation of non-condensable gases released in a seawater evaporating process (해수 증발과정에서의 기체방출량 계산)

  • Jeong, Kwang-Woon;Chung, Hanshik;Jeong, Hyomin;Choi, Soon-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.182-190
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    • 2017
  • All liquids contain a small amount of gaseous components and the amount of gases dissolved in a liquid is in accordance with Henry's Law. In a multi-stage thermal-type seawater desalination plant, as the supplied seawater undergoes variations in temperature and pressure in each evaporator, the gases dissolved in the seawater are discharged from the liquid. The discharged gases are carbon dioxide, nitrogen, oxygen, and argon, and these emitted gases are non-condensable. From the viewpoint of convective heat transfer, the evaluation of non-condensable gas released during a vacuum evaporation process is a very important design factor because the non-condensable gases degrade the performance of the cooler. Furthermore, in a thermal-type seawater desalination plant, most evaporators operate under vacuum, which maintained through vacuum system such as a steam ejector or a vacuum pump. Therefore, for the proper design of a vacuum system, estimating the non-condensable gases released from seawater is highly crucial. In the study, non-condensable gases released in a thermal-type seawater desalination plant were calculated quantitatively. The calculation results showed that the NCG releasing rate decreased as the stage comes getting a downstream and it was proportional to the freshwater production rate.

Improvement of Solubilization and Anaerobic Biodegradability for Sewage Sludge Using Ultrasonic Pre-treatment (하수슬러지의 초음파 전처리를 통한 가용화 및 혐기성 생분해도 향상)

  • Lee, Chae-Young;Park, Seung-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.3
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    • pp.83-90
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    • 2008
  • The ultrasonic pre-treatment of sewage sludge (SS) was investigated to increase soluble organic material and to improve anaerobic biodegradability. Ultrasonic disintegration of SS increased the amount of soluble chemical oxygen demand (SCOD), protein and carbohydrate concentrations whereas particle size decreased due to the break-up of cell walls. In terms of anaerobic biodegradability, ultrasonic pre-treatment enhanced the anaerobic biodegradation of SS, leading to the methane gas production improvement. Biochemical methane potential (BMP) of SS was 211.3 ml $CH_4/gVS$ whereas BMP after ultrasonic pre-treatment was 294.3 ml $CH_4/gVS$. The improvement in BMP for SS treated with ultrasonic disintegration was as high as 40 %. This result indicated that disintegration of SS was efficient for enhancing anaerobic biodegradability.

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A Study on Lithium Leaching from the Fly Ash of Taean Electric Power Plant (태안화력발전소 비산재로부터 리튬용출연구)

  • Kim, Kang-Joo;Lee, Eun-Gyu;Lee, Jae-Cheol;Hwang, Soo-Yeon;Kim, Chang-Hyeon
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.117-122
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    • 2012
  • The leaching of Li from fly ashes was studied. The fly ash produced from the Taean electric power plant of the Korea Western Power Co., Ltd. was used for this study. The Li leaching was observed according to the changes in solid:solution ratio, solution types (seawater or deionized water), and the $CO_2$ condition in the atmosphere. The results showed that the Li concentrations in the solution increased continuously as the solid:solution ratio increased. The Li leaching per unit mass of fly ash was greater when the deionized water was used for the experiment and when the $CO_2$ dissolution is limited during the reaction because the precipitation of $CaCO_3$ is suppressed under those conditions. At high solid:solution ratio, $Mg^{2+}$, the ion preventing the Li extraction from seawater by adsorption, was effectively removed from the seawater.