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Multi-residue Analysis of Pesticides using GC-TOF/MS, ECD, NPD with QuEChERS Sample Preparation (QuEChERS 전처리법과 GC-TOF/MS, ECD, NPD를 이용한 잔류농약 다성분분석)

  • Park, Jungwook;Kim, Aekyung;Kim, Jongpil;Lee, Hyanghee;Park, Duckwoong;Moon, Sujin;Ha, Dongryong;Kim, Eunsun;Seo, Kyewon
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.278-295
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    • 2014
  • Fast and accurate multi-residue pesticides inspecting method needs in Agro-Fishery Products Inspection Center. So, We tried to seek the optimum method using GC-TOF/MS, GC-ECD, GC-NPD after QuEChERS sample preparation. In GC-TOF/MS, 138 kinds of pesticide were spiked at 0.3 and $0.5{\mu}g/g$for the identification and quantification in lettuce sample. Recoveries of 77 pesticides were between 70 and 130% with RSD (relative standard deviation lower than 20% at $0.3{\mu}g/g$. In GC-ECD, NPD, 146 kinds of pesticide were spiked for the identification and quantification in lettuce. Recoveries of 61 species were between 70 and 130% with lower than 20%. These results indicated that GC-TOF/MS, GC-ECD, NPD analysis with the QuEChERS sample preparation can be partly applied to multi-residue pesticides in vegetables.

Measurement of Oxygen Saturation Concentration by Zeolite (제올라이트별 산소포화농도 측정 실험)

  • Park, Sung-Sik;Kim, Kwang-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.617-622
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    • 2018
  • Air is essential for human beings to survive, but urban air is polluted with soot and harmful gases, due to the increase in industrial development and the population. Thus, air pollution in large cities is of increasing interest in the research community. One of the plausible solutions to this problem is supplying sufficient oxygen to indoor spaces. The main principle of the oxygen generator is to separate oxygen from air using synthetic zeolite. Various synthetic zeolites have been applied to public indoor spaces with the focus being placed on the oxygen exchange quality. Among the characteristics of zeolites which can be applied to oxygen generators is their ability to adsorb nitrogen from the air and, in this way, generate only oxygen. Thus, we investigated the degree of nitrogen adsorption by five kinds of natural zeolite and LTA zeolite 3A, 4A, and 5A (two different sizes). Using the PSA method, the higher the degree of nitrogen adsorption, the higher the oxygen saturation concentration, it was found that the nitrogen adsorption degree of the 5A zeolite was the highest. 6% on average. It was also found that the size of the zeolite had a significant effect on the degree of nitrogen adsorption.

Human-Powered Generator designed for Sustainable Driving (고출력 지속이 가능한 인체 구동 방식의 자가 발전기 개발)

  • Lim, Yoon-Ho;Yang, Yoonseok
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.7
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    • pp.135-142
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    • 2015
  • Human-powered self-generating devices have been attractive with its operation characteristic independent from outer environment such as weather condition and wind speed. However, conventional self-generators have low electric power output due to their weakly-coupled electromagnetic structure. More importantly, rotary crank motion which is usually adopted by conventional self-generator to generate electricity requires specific skeletal muscles to maintain large torque circular motion and consequently, causes fatigue on those muscles before it can generate enough amount of electricity for any practical application. Without improvement in electric power output and usability, the human-powered self-generator could not be used in everyday life. This study aims to develop a human-powered self-generator which realized a strong electromagnetic coupling in a closed-loop tubular structure (hula-hoop shape) for easy and steady long-term driving as well as larger electric output. The performance and usability of the developed human-powered generator is verified through experimental comparison with a commercial one. Additionally, human workload which is a key element of a human-powered generator but not often considered elsewhere, is estimated based on metabolic energy expenditure measured respiratory gas analyzer. Further study will focus on output and portability enhancement, which can contribute to the continuous power supply of mobile equipments.

Application of Laser-Induced Breakdown Spectroscopy (LIBS) for In-situ Detection of Heavy Metals in Soil (토양내 중금속 실시간 탐지를 위한 레이저 유도붕괴 분광법의 활용에 대한 소개)

  • Ko, Eun-Joung;Hamm, Se-Yeong;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.563-574
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    • 2007
  • Laser induced breakdown spectroscopy (LIBS) is a recently developed analytical technique that is based upon the measurement of emission lines generated by atomic species close to the surface of the sample, thus allowing their chemical detection, identification and quantification. With powerful advantages of LIBS compared to the conventional analytical methodology, this technique can be applied in the detection of heavy metals in the field. LIBS allows the rapid analysis by avoiding laborious chemical steps. LES have already been applied for the determination of element concentration in a wide range of materials in the solid, liquid and gaseous phase with simplicity of the instrument and diversity of the analytical application. These feasibility of rapid multi elemental analysis are appealing proprieties for the in-situ analytical technique in geochemical investigation, exploration and environmental analysis. There remain still some limitations to be solved for LIBS to be applied in soil environment as an in-situ analytical technology. We would like to provide the basic principle related to the plasma formation and laser-induced breakdown of sample materials. In addition, the matrix effect, laser properties and the various factors affecting on the analytical signal of LIBS was dealt with to enhance understanding of LIBS through literature review. Ultimately, it was investigated the feasibility of LIBS application in soil environment monitoring by considering the basic idea to enhance the data quality of LIBS including the calibration method for the various effects on the analytical signal of LIBS.

Partial Discharge Characteristics and Localization of Void Defects in XLPE Cable (XLPE 케이블에서 보이드 결함의 부분방전 특성과 위치추정)

  • Park, Seo-Jun;Hwang, Seong-Cheol;Wang, Guoming;Kil, Gyung-Suk
    • Journal of the Korean Society for Railway
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    • v.20 no.2
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    • pp.203-209
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    • 2017
  • Research on condition monitoring and diagnosis of power facilities has been conducted to improve the safety and reliability of electric power supply. Although insulation diagnostic techniques for unit equipment such as gas-insulated switchgears and transformers have been developed rapidly, studies on monitoring of cables have only included aspects such as whether defects exist and partial discharge (PD) detection; other characteristics and features have not been discussed. Therefore, this paper dealt with PD characteristics against void sizes and positions, and with defect localization in XLPE cable. Four types of defects with different sizes and positions were simulated and PD pulses were detected using a high frequency current transformer (HFCT) with a frequency range of 150kHz~30MHz. The results showed that the apparent charge increased when the defect was adjacent to the conductor; the pulse count in the negative half of the applied voltage was about 20% higher than that in the positive half. In addition, the defect location was calculated by time-domain reflectometry (TDR) method, it was revealed that the defect could be localized with an error of less than1m in a 50m cable.

Analysis on Importance of Information Security Factors for Smart Work using AHP -Based on the Mobile Office for Small Businesses- (AHP를 활용한 스마트워크 정보보호 요소의 중요도 분석 -중소기업의 모바일 오피스를 중심으로-)

  • Kang, Kyung-Hoon;Lim, Chae-Hong;Lim, Jong-In;Park, Tae-Hyoung
    • Journal of Digital Convergence
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    • v.11 no.3
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    • pp.415-426
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    • 2013
  • Smart work has recently introduced as a way to solve problems such as greenhouse gas emissions, low birth rate and aging as well as to improve productivity. Because of development of ICT infrastructure and the proliferation of smart devices, the mobile office has the most commonly used within types of smart work in Korea. But the adoption of the mobile office in small businesses is only half of that of large corporations. The security issue appears to be one of the biggest obstacles to the introduction of smart work in small businesses. Therefore, the purpose of this study is to analyze the information security factors that should be considered when the mobile office is introduced to small businesses. By analyzing the previous studies, the information security factors of the mobile office are classified 5 groups composed of 24 factors. 5 groups are terminals, applications and platforms, networks, servers and users. According to the survey result using AHP, 'User' was drawn to the most important group, and 'Data Encryption', 'Wireless LAN Control' and 'Terminal Recovery When Leaving' were drawn to the important information security factors of the mobile office among 24 factors.

Comparison of Flow Characteristics for the Development of a C-Type Strainer with Its Inlet and Outlet on a Straight Line (유입·유출구가 일직선상인 C형 스트레이너 개발을 위한 유동특성 비교)

  • Shin, Byung-kyun;Kwon, Chang-Hee
    • Journal of Digital Convergence
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    • v.14 no.11
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    • pp.257-265
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    • 2016
  • The purpose of this study was to develop a strainer that could protect a flow system by blocking the introduction of foreign substances into the pipe of industrial or architectural facilities. Strainers are installed at the front tip of valves, machines, or pumps in the piping line of clean water, oil, or gas. There are Y-type, U-type, and T-type strainers. The study identified problems with the Y-type strainers, develop a "C-type strainer with its inlet and outlet on a straight line" as a more improved new model, and compared them in functions in a full-scale strainer test. The study conducted a full-scale strainer test according to four situations at the flow laboratory of Korea Research Institute of Standards and Science by using the old Y-type strainer and C-type strainer 50A. The test results show that the C-type strainer had a higher capacity coefficient(Kv) than the Y-type one, recording 74.9% when there was no screen, 54.5% when there were no foreign substances in the screen, 54.2% when there was a 15% accumulation of foreign substances, and 52.4% when there was a 30% accumulation of foreign substances. The investigator conducted a test only with the 50A type due to the limitations of life-size strainers, but the results demonstrate that the C-type strainer had better flow characteristics than the Y-type one.

A Study of the characteristics of NOx measurement and analysis methods of the SCR system for ships (선박용 SCR 시스템 NOx 측정 및 분석 방식의 특성 연구)

  • Kim, Sung-Yoon;Lee, Young-Ho;Kim, Min;Park, Sam-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.387-392
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    • 2015
  • A method for measuring and analyzing the $NO_x$ in ships is described in $NO_x$ Technical Code 2008. The analysis device, as required by the Code, has been to use a Chemi-luminescence detection method or Heated Chemi-luminescence detection. on the other hand, selective catalytic reduction using $NH_3$ as a reducing agent has an interference effect on the analyzer, and causes measurement error. In this study, the Chemi-luminescence detection method was examined according to how it affects the concentration of $O_2$, CO, $SO_2$, $NH_3$. Fourier transform infrared spectrometry analysis equipment and measurement methods were compared. In order to confirm the effect of the physical interference of the measuring device, it was confirmed by decomposing a measuring device. Consequently, white precipitate and moisture were generated inside the chemiluminescence detection system and I found that affecting interference. The influence of interference highlights the need to consider the minimized $NO_x$ measurement method.

The Study of Plate Powder Coated Nano Sized ZnO Synthesis and Effect of Sensory Texture Improvement (나노 ZnO 입자가 코팅된 판상 분체의 합성과 사용감 증진 효과에 대한 연구)

  • Jin-Hwa , Lee;Ju-Yeol, Han;Sang-Gil, Lee;Hyeong-Bae, Pyo;Dong-Kyu, Lee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.173-180
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    • 2004
  • Nano sized ZnO particle as 20-30nm applies for material, pigments, rubber additives, gas sensors, varistors, fluorescent substance as well as new material such as photo-catalyst, sensitizer, fluorescent material. ZnO with a particle size in the range 20-30nm has provided to be an excellent UV blocking material in the cosmetics industry, which can be used in sunscreen product to enhance the sun protection factor and natural makeup effect. But pure ZnO particles application limits for getting worse wearing feeling. We make high-functional inorganic-composite that coated with nano-ZnO on the plate-type particle such as sericite, boron nitride and bismuthoxychloride. In this experiment, we synthesized composite powder using hydrothermal precipitation method. The starting material was ZnCl$_2$ Precipitation materials were used hexamethylenetetramine(HMT) and urea. We make an experiment with changing as synthesis factors that are concentrations of starting material, precipitation materials, nuclear formation material, reaction time, and reaction temperature. We analyzed composite powder's shape, crystallization and UV-blocking ability with FE-SEM, XRD, FT-IR, TGA-DTA, In vitro SPF test. The user test was conducted by product's formulator. In the results of this study, nanometer sized ZnD was coated regardless of the type of plate-powder at fixed condition range. When the coated plate-powders were applied in pressed powder product, the glaze of powder itself decreased, but natural make-up effect, spreadability, and adhesionability were increased.

Optimal Design of a Coil for Improved Heating Efficiency of Electric Induction Boiler (전기유도보일러의 발열효율개선을 위한 권선최적설계)

  • Kim, Youn-Hyun;Kim, Sol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.476-482
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    • 2019
  • Regulatory protocols such as the Convention on Climate Change and the regulation of greenhouse gas emissions act as catalysts for the development of high-efficiency energy equipment and the efficient use of energy. Among the fields where energy consumption is high, the electric heating equipment is not efficient. The electric boiler mainly uses a method of circulating water by contacting the heater. When the existing electric boiler is used, the water minerals are contacted with the high-temperature heater to be carbonized and adsorbed, thereby promoting the corrosion of the heater and lowering the efficiency of the heater. For this reason, an electric induction boiler, which has high energy efficiency and is applied to an induction heating system that can uniformly heat the object to be heated rather than conduction or convection heating, is in the limelight. This method induces a boiler pipe And it is recognized as an alternative that can solve the problem that occurs when heating is performed by direct heating. Despite the fact that research on induction heating has been conducted for a relatively long period of time, there have been few studies on the electrothermal technology using induction heating. Therefore, in this paper, to improve the heat efficiency of electric induction boiler, the influence of the cross sectional area, number of windings and winding layers is analyzed by finite element method through parametric study method. The method of finding the design point which maximizes the total loss is proposed by the alternating winding design method which can maximize the heat generation by analyzing copper and iron losses.