• Title/Summary/Keyword: {111} twin

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Relation Between the Growth Twin and the Morphology of a Czochralski Silicon Single Crystal (초크랄스키 실리콘 단결정에서 성장 쌍정과 결정 외형의 관계)

  • 박봉모
    • Korean Journal of Crystallography
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    • v.11 no.4
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    • pp.207-211
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    • 2000
  • In a Czochralski silicon single crystal, the relation between the growth twin and the crystal morphology was investigated. The growth twin is nucleated on the {111} facet planes near the growth ridges. When a {111} growth twin is formed in the <100> silicon crystal, the growth ridge where twin is nucleated will continuous through the twin plane. Other two ridges at the 90。 apart will be displaced about 33° and be deformed to facets. The ridge on the opposite side of twin nucleation will disappear by forming a slight hill. Because the growth ridges of silicon is due to the {111} planes, the variation in the growth ridge formation can be predicted clearly by considering the change of the {111} plane traces in the stereographic projection after twining.

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Orientation States of Ferroelectric Domains and {111} Twins in $BaTiO_3$ ($BaTiO_3$의 {111}쌍정계면과 강유전 분역의 배향성)

  • 박봉모;정수진
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.228-234
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    • 1996
  • It is very important to understand the domain structures of ferroelectric BaTiO3 in the poling process. Especially because {111} twinning is frequently observed in most BaTiO3 ceramics it is required to know the relations between the ferroelectric domains and the structural twin. In this study the domain structures of a {111} twinned crystal sample were observed under a polarizing microscope. and the relation between the {111} twin and the domain configurations could be classified into two types of 'V'-shape and linear shape penetrating perpendicular to the twin boundary. Domain formation obeys the symmetry of the {111} twining when a new domain structure is developed by heat treatment and surface deformation due to domain formation is also occured symmetrically between the both sides of the{111} twin boundary. This symmetrical behavior of the domains could be interpreted with the "head-to-tall" orientation of the domains across the {111} twin boundary.

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Coarsening Advantage of Twinned BaTiO3 Seed Particle

  • Jin, Hong-Ri;Jo, Wook;Hwang, Nong-Moon;Kim, Doh-Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.9 s.280
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    • pp.599-601
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    • 2005
  • The coarsening process of two different $BaTiO_3$ single crystal seeds, one with a (111) double twin and the other without it, was investigated. Due to the presence of Twin Plane Reentrant Edge (TPRE), the coarsening rate of the twinned seed crystal was significantly higher than that without a twin. For the coarsening by the 2-dimensional nucleation and lateral growth, the energy barrier for nucleation at the TPRE was analyzed to be about a half compared with that at the terrace planes.

Mechanism of Twin Columnar Growth in Aluminum Alloys (알루미늄 합금의 TCG 조직의 형성기구)

  • Kim, D.K.;Sanders Jr., T.H.
    • Journal of Korea Foundry Society
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    • v.7 no.3
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    • pp.192-198
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    • 1987
  • Commercial semicontinuous cast ingots of aluminum alloys often exhibit large grains composed of parallel arrays of continuous lamellae. Each lamella consists of a central {111} coherent twin boundary and wavy solidification boundary. This microstructure is referred to as a twin columnar growth(TCG) structure. The factors influencing the formation of a TCG structure include a unidirectional thermal gradient and the critical range of the alloying element content. The higher the thermal gradient is, the shorter the twin plane spacings are. The composition profile for an untwinned dendrite shows maximums at the positions of the interdendritic channels and the minimum appears at the center of the dendrite. While for twinned dendrite, it has wavy apperance. This profile has two local minimums instead of one shown in the untwinned.

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Shear-lag effect in twin-girder composite decks

  • Dezi, Luigino;Gara, Fabrizio;Leoni, Graziano
    • Steel and Composite Structures
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    • v.3 no.2
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    • pp.111-122
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    • 2003
  • The paper presents a model for analysing the shear-lag effect on the slab of twin-girder composite decks subjected to static actions, support settlements and concrete shrinkage, which are the main actions of interest in composite bridge design. The proposed model includes concrete creep behaviour and shear connection flexibility. The shear-lag in the slab is accounted for by means of a new warping function. The considered actions are then applied to a realistic bridge deck and their effects are discussed. The proposed method is utilised to determine the slab effective widths for three different width-length ratios of the deck. Finally, a comparison between the results obtained with the Eurocode EC4-2 and those obtained with the proposed model is performed.

Structural properties of GeSi/Si heterojunction compound semiconductor films by using SPE (SPE법을 통해 형성된 $Ge_xSi_{1-x}/Si$이종접합 화합물 반도체의 결정분석)

  • 안병열;서정훈
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.4 no.3
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    • pp.713-719
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    • 2000
  • In order to Prepare the$Ge_xSi_{1-x}/Si$(111) heterosructure by solid phase epitaxy (SPE), about 1000A of Au and about 1000A Ge were sequentially deposited on the Si(111) substrate. The resulting Ge/Au/Si(111) samples were isochronically annealed in the high vacuum condition. The behaviors of Au and Ge during thermal annealing and the structural Properties of $Ge_xSi_{1-x}$ films were characterized by Auger electron spectroscopy (AES), X-ray diffraction (XRD) and high resolution transmission electron microscopy (TEM). The a-Ge/Au/Si(111) structure was converted to the Au/GeSi/Si(111) structure. Defects such as stacking faults, point defects and dislocations were found at the GeXSil-X(111) interface, but the film was grown epitaxially with the matching face relationship of $Ge_xSi_{1-x}/$(111)/Si(111). Twin crystals were also found in the $Ge_xSi_{1-x}/$(111) matrix.

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Generation of Longitudinal Twin of GaAs Single Crystal by LEC Method (LEC법 GaAs 단결정의 종단쌍정 발생)

  • Gang, Jin-Gi;Yu, Hak-Do;Park, Jong-Mok
    • Korean Journal of Crystallography
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    • v.2 no.1
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    • pp.1-11
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    • 1991
  • When GaAs single crystals are grown by LEC method, a serious problem is that longitudinal twins are often generated. the growth axis is changed from (100) to (221) direction by logitudinal twin. In this experiment, 3 inch GaAs single crystals, slaving (100) uonh axis, were von by LEC method. Striations and edge facets generated during crystal growth, were observed by SPW photo-etching. Relationship between striations and edge facets was studied. Instability of their generation was the cause of goneration of longitudinal twins. The shape of striations was changed with the growth conditions such as crystal diameter and melt volume. In the region of crystal edge: there was the microscopic fluctuation by the instability of melt convection. Edge facets consisting of {111} plane developed well in the region which striation were convex to the melt. Because the angle between striation and {111} edge facet decreased in that region. Longitudinal twins were generated on the crystal surface at the <111> direction which is perpendicular to the growth axis. These were generated by unstable melt convection and propagated in the crystal as crystal grew. Longitudinal twins were generated when regrowth rate was very fast after {111} edge facets were remelted. So, in order to supress the generation of longitudinal twin, abrupt change of melt convection must be prohibited.

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Diamond Synthesis by Acetylen Flame (아세틸렌 불꽃에 의한 다이아몬드 합성)

  • 이윤석;박윤휘;이태근;정수진
    • Journal of the Korean Ceramic Society
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    • v.29 no.12
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    • pp.926-934
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    • 1992
  • Uniform diamond films in a few $\textrm{mm}^2$ size and locally isolated diamond single crystals in size of 60 $\mu\textrm{m}$ were synthesized on Si-wafer and Al2O3 substrate by the method of acetylene flame. The effects of substrate temperature and flow ratio of oxygen to acetylene on the morphology of deposited diamond were investigated. According to the observations of growth behavior of diamond on Si substrate with respect to substrate surface pretreatment and flow ratio, it was shown that well faceted diamonds could grow uniformly when flow ratio was above 0.9 and substrates were densely scratched. With increasing substrates temperature, the crystal morphology changes from octahedron bounded by only {111} plane below 850$^{\circ}C$ to cubo-octahedron with almost equal development of {111} and {100} plane in the temperature range of 850∼950$^{\circ}C$. Between 950∼1050$^{\circ}C$, the {111} faces become rough and concave. Above 1050$^{\circ}C$, new crystallites begin to grow on concave {111} surface and overall morphology looks like cubo-octahedron with degenerated {111} faces. These changes of morphology can be understood in terms of the different growth mode of each crystallographic plane with respect to the substrate temperature and supersaturation. And the observed phenomena on {111} planes can be related to the face instability and twin generation.

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Atomic structure and crystallography of joints in SnO2 nanowire networks

  • Hrkac, Viktor;Wolff, Niklas;Duppel, Viola;Paulowicz, Ingo;Adelung, Rainer;Mishra, Yogendra Kumar;Kienle, Lorenz
    • Applied Microscopy
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    • v.49
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    • pp.1.1-1.10
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    • 2019
  • Joints of three-dimensional (3D) rutile-type (r) tin dioxide ($SnO_2$) nanowire networks, produced by the flame transport synthesis (FTS), are formed by coherent twin boundaries at $(101)^r$ serving for the interpenetration of the nanowires. Transmission electron microscopy (TEM) methods, i.e. high resolution and (precession) electron diffraction (PED), were utilized to collect information of the atomic interface structure along the edge-on zone axes $[010]^r$, $[111]^r$ and superposition directions $[001]^r$, $[101]^r$. A model of the twin boundary is generated by a supercell approach, serving as base for simulations of all given real and reciprocal space data as for the elaboration of three-dimensional, i.e. relrod and higher order Laue zones (HOLZ), contributions to the intensity distribution of PED patterns. Confirmed by the comparison of simulated and experimental findings, details of the structural distortion at the twin boundary can be demonstrated.