• Title/Summary/Keyword: (Sm/Y)-B-C-O

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c-axis Transport Properties of $SmFeAsO_{0.85}$ Single Crystals ($SmFeAsO_{0.85}$ 단결정의 c-축 전도 특성)

  • Park, Jae-Hyun;Doh, Yong-Joo;Lee, Hyun-Sook;Cho, B.K.;Lee, Hu-Jong
    • Progress in Superconductivity
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    • v.11 no.2
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    • pp.118-122
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    • 2010
  • Electrical transport properties were measured on $SmFeAsO_{0.85}$ single crystals along the c-axis for various temperatures and magnetic fields. For the measurements a mesa structure was fabricated on the surface of the single crystals. Samples showed a metallic temperature dependence of resistance and current-voltage curves without hysteretic multiple branch splitting that is usually observed in tunneling Josephson junctions. In addition, in ab-planar magnetic fields, samples did not show the Fraunhofer-type field modulation of the critical current. All these features indicate that the c-axis transport characteristics of $SmFeAsO_{0.85}$ single crystals are explained by the anisotropic bulk superconductivity rather than Josephson tunneling.

Measurement of Energy Dependent Differential Neutron Capture Cross-section of Natural Sm by Using a Continuous Neutron Flux below (연속에너지 중성자에 대한 천연 Sm의 중성자 포획단면적 측정)

  • Yoon, Jungran
    • Journal of the Korean Society of Radiology
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    • v.10 no.5
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    • pp.337-341
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    • 2016
  • We measured the neutron capture cross-section of natural Sm(n,${\gamma}$) reaction in the energy regions from 0.003 to 10 eV. The 46-MeV electron linear accelerator of Research Reactor Institute, Kyoto University was used for generating a continuous neutron source. The neutron time-of-flight method was adopted for energy measurement. An assembly of BGO($Bi_4Ge_3O_{12}$) scintillators composed of 12 pieces of BGO crystals measured prompt gamma rays from Sm(n,${\gamma}$) reaction. The BGO assembly was located at a distance of $12.7{\pm}0.02m$ from the neutron source. In order to determine the neutron flux impinging on the Sm, the $^{10}B(n,{\alpha}{\gamma})^7Li$ standard cross-section were used. Natural Sm(n,${\gamma}$) reaction measurement result of the neutron capture cross-section was compared with the results of evaluation of the BROND-2.2 and the previous experimental data of J. C. Chou and V. N. Kononov.

The Antimelanogenic Effects of Compounds Extracted from Bamboo Inner Film (죽황(竹黃)으로부터 분리한 미백활성 성분의 멜라닌생성 억제효과)

  • Lee, Ki-Moo;Lee, Eun-Chang;Cho, Soon-Chang;Moon, Surk-Sik
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.4
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    • pp.287-301
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    • 2008
  • In order to develop a new depigmenting agent, extracts were obtained from 60 native plants and their antimelanogenic activities were screened by evaluating the inhibitory effect on tyrosinase which is a major enzyme responsibles for the melanin synthesis. The extracts of Trichosanthes kirilowii fruits, Phyllostachys bambusoides inner films (BIF), Clerodendrum trichotomum leaves, and Acer okamotoanum leaves showed relatively high inhibitory effect on tyrosinase and their $IC_{50}$ values were $50{\sim}100{\mu}g/mL$. The extract of BIF inhibited melanin synthesis of B16F10 melanoma cells by 52%, which was the highest among those of various extracts. Furthermore, the effect of BIF extract is 10% higher than that of arbutin (42%), a popular depigmenting agent in Korea. Ten compounds having antimelanogenic activity were isolated from the BIF extract by solvent extraction and chromatography. These compounds were identified as phenolic derivatives: SM701, SM702, SM703, and BPR211 were hydroquinone derivatives; SM707 a gallic acid derivative; SM704, SM705, SM706, SM708 and SM709 ferulic acid derivatives. The free radical scavenging activities of these compounds were measured and compared to those of hydroquinone and vitamin C. The $SC_{50}$ values scavenging 50% DPPH of SM702 and SM709 were $60{\sim}70{\mu}M$ similar to that of hydroquinone and those of SM701 and SM708 were $30{\sim}40{\mu}M$ slightly lower than that of vitamin C. These results suggest the presence of components having high antioxidant activity in the BIF extract. The SM709, identified as 1,2-O-diferulylglycerol, inhibited the activities of tyrosine hydroxylase and dopa oxidase by 18 and 60%, respectively. The SM709 also inhibited the melanin synthesis of B16F10 melanoma cells by 62% and this was the highest antimelanogenic activity among those obtained from the various purified compounds. Therefore, antimelanogenic activity of the BIF extract was concluded to be due to both inhibition of DOPA oxidase and antioxidant activity.

Optical Properties of Infinite-Layer Superconductors $Sr_{0.9}$$Ln_{0.1}$Cu$O_2$ (LnLa, Gd, Sm) (무한층 초전도체 $Sr_{0.9}Ln_{0.1}CuO_2$(Ln=La, Gd, Sm)의 광학적 성질)

  • Mun, Mi-Ock;Park, Young-Sub;Kim, Kibum;Kim, Jae H.;A. B. Kuzmenko
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.13-16
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    • 2001
  • We have measured the reflectivity of superconducting infinite-layer compounds $Sr_{0.9}$ $Ln_{0.1}$ Cu $O_2$ (Ln=La, Gd, Sm) with $T_{c}$ : 39 K using a Fourier-transform infrared spectrometer. We have identified the optical phonon modes from their infrared reflectivity and conductivity spectra and have proposed possible displacement patterns. The La- and the Gd-doped compounds exhibited only four ($2A_{2u}$ $+2E_{u}$) out of the five ($2A_{2u}$ $3E_{u}$) infrared-active phonons predicted by a group theoretical analysis whereas the Sm-doped compound exhibited all five modes. For the La-doped sample, we investigated the temperature dependence of the optical response functions in a wide temperature range of 7 - 300 K. In FIR region, the reflectivity is apparently enhanced below ~120 $cm^{-1}$ as temperature decreases across $T_{c}$. The value of $2$\Delta$/k_{B}$ $T_{c}$ is about 4.5, which is consistent with maximum gap value of d-wave $high- T_{c}$ cuprates.> c/ cuprates.uprates.s.

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The Influence of $O_2$ Partial Pressure on Soft Magnetic Properties of As-deposited Fe-Sm-O Thin Films (산소분압에 따른 Fe-Sm-O계 박막의 연자기적 성질)

  • Yoon, T.S.;Cho, W.S.;Koo, E.S.;Li, Ying;Park, J.B.;Kim, C.O.
    • Korean Journal of Materials Research
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    • v.10 no.11
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    • pp.755-759
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    • 2000
  • The influence of $O_2$partial presure on saturation magnetization, coercivity and effective permeability(0.5~100MHz) of as-deposited Fe-Sm-O thin films, which were fabricated by RF magnetron reactive sputtering method, were investigated. The nanocrystalline Fe(sub)83.4Sm(sub)3.4O(sub)13.2 thin film fabricated at $O_2$partial pressure of 5% exhibits the best magnetic softness with saturation magnetization of 18kG, coercivity of 0.82 Oe and effective permeability about 2,600 at 0.5~100MHz. $\alpha$-Fe grain size is decreased with increasing $O_2$partial pressure. In case of $O_2$partial pressure of 10%, it is observed that FeO compound is formed and soft magnetic properties are decreased. The electrical resistivity of Fe-Sm-O thin films were increased with increasing $O_2$partial pressure, the electrical resistivity of Fe(sub)83.4Sm(sub)3.4O(sub)13.2 thin film with the best soft magnetic properties was 130 $\mu$$\Omega$cm. Therefore, It is assumed that the good soft magnetic properties of Fe(sub)83.4Sm(sub)3.4O(sub)13.2 thin film results from high electrical resistivity and decreasing $\alpha$-Fe grain size due to precipitation of Sm-Oxide phase.

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A Study on the Magnetic Properties of Amorphous Fe-Co-RE-B (RE=Nd, Sm, Gd, Tb) Alloys (비정질 Fe-Co-Re-B(RE=Nd, Sm, Gd, Tb) 합금의 자기적 성질)

  • 김경섭;유성초;김창식;김종오
    • Journal of the Korean Magnetics Society
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    • v.1 no.2
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    • pp.55-59
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    • 1991
  • The temperature-dependent magnetization curves of amorphous Fe-Co-(Nd, Sm, Gd, Tb)-B alloys were measured using a vibrating sample magnetometer from 77 K up to 900 K. The spin wave stiffness constants and the range of the exchange interaction were calculated from the saturation magnetization values at 0 K. Curie temperatures and the Bloch coefficients estimated from the saturation magnetization curves. The low temperature dependence of magnetization is in good agreement with Bloch relation, $M_{s}(T)=M_{s}(O)(1-BT^{3/2}-CT^{5/2})$. The spin wave stiffness constant and the range of exchange interaction are decreased by substitution of heavy rare earth (Tb, Gd).

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Electrolytic Boronizing on Carbon Steels in Fused Slat of Borax and Sodium Chloride Mixture (붕사와 염화나트륨 혼합용융욕에서 탄현강의 전해붕화처리)

  • 이두환;김정기;김한삼;김수식
    • Journal of the Korean institute of surface engineering
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    • v.30 no.1
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    • pp.23-32
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    • 1997
  • The electrolytic boronizing on carbon steels in the mixture of $Na_2B_4O_7$ and NaCl was conducted at 750~$950^{\circ}C$ for 1~6 hours under 0.5A/$\textrm{cm}^2$ current density. The micorostructrure and microheredness of boronized layer was also studien. The effect of the additive such as $CaCl_2$ or NaOH on the formation of boronized layer was also investigated. The boronized layer were composed of two sublayers, i.e., FeB and $Fe_2B$ , which have tooth structure. the average layer thinknesses of the low carbon steel and SM45C boronized at $900^{\circ}C$ for 4hours were 153 and 138 $\mu\textrm{m}$, respectively. The thickness of the twosublayers was significantly increased with increasing boronizing temperature. To obtain a single $Fe_2B$ layer without FeB sublayer, the boronized materials ware homegenized at $950^{\circ}C$ for 4 hours. It was fount that the single layer with a microhardness Hv$\thickapprox$ 1120 -1250 was formed. The calculated activation energies for formation of boronized layer on the low carbon steel and SM45C were 18.7 and 12.6 Kcal/mol, respectively.

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Microwave dielectric properties of the 0.15(B $a_0.95$S $r_ 0.05$)O-0.15S $m_2$ $O_3$-0.7TiO $_2$ ceramics (0.15(B $a_0.95$S $r_ 0.05$)O-0.15S $m_2$ $O_3$-0.7TiO $_2$ 세라믹스의 마이크로파 유전특성)

  • 박인길;정장호;배선기;이영희
    • Electrical & Electronic Materials
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    • v.8 no.2
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    • pp.224-228
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    • 1995
  • 0.15(B $a_{0.95}$ S $r_{0.05}$)O-0.15S $m_{2}$ $O_{3}$-0.7Ti $O_{2}$ ceramics were fabricated by the mixed-oxide method. Microwave dielectric properties were investigated with sintering conditions. Increasing the sintering temperature from 1300 to 1375[.deg. C], the sintered density was increased from 5.44 to 5.63[g/c $m^{3$]. Increasing the sintering temperature, dielectric constant and quality factor were increased and temperature coefficient of resonant frequency was independent of sintering temperature. In the specimen sintered at 1375[.deg. C], dielectric constant, quality factor and temperature coefficient of resonant frequency were 80.79, 2784(at 3[GHz]), +11.07[ppm/.deg. C], respectively..

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High-Pressure Synthesis of $SmFeAsO_{1-x}F_x$(x=0.2) Single Crystals ($SmFeAsO_{1-x}F_x$(x=0.2)의 고압 단결정 합성)

  • Lee, Hyun-Sook;Park, Jae-Hyun;Lee, Jae-Yeap;Kim, Ju-Young;Cho, B.K.;Jung, Chang-Uk;Lee, Hu-Jong
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.87-91
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    • 2009
  • Fluorine-doped $SmFeAsO_{1-x}F_x$ single crystals with the nominal value of x=0.2 were grown at $1350-1450^{\circ}C$ under the pressure of 3.3 GPa by using the self-flux method. Plate-shaped single crystals in the range of a few-150 ${\mu}m$ in their lateral size were obtained. The detailed crystal structure was analyzed by using the x-ray diffractometry. Superconducting transition temperature, determined by the resistive transition, of a single crystal was about 49 K with a narrow resistive transition width of ${\sim}1$ K. A relatively sharp transition, a low residual resistivity, and a large residual resistivity ratio compared with those reported for $REFeAsO_{1-x}F_x$(RE=Sm, Nd) single crystals indicate the high quality of our single crystals.

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ANISOTROPY CONSTANTS OF $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ COMPOUNDS (RE=RARE EARTH)

  • Kim, H.T.;Kim, Y.B.;Park, W.S.;Kim, C.S.;Kim, T.K.;Jin, Han-Min
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.683-686
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    • 1995
  • Using by the x-ray diffractometry(XRD), the thermomagnetic analysis(TMA), a scanning electron microscopy (SEM-EDX), we knew that the $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ (RE=Ce,Pr,Nd,Sm,Gd,Tb) compounds were formed to tetragonal $ThMn_{12}$-type structure having a uniaxial magnetocrystalline anisotropy with easy magnetization c-axis. The intrinsic magnetic properties of those were determined by fitting the two magnetization curves of experimental and calculation magnetization. The anisotropy constant $K_{1}$ of this compounds was in the range of $1.75\;-\;9.2\;MJ/m^{3}$ and approximately one order higher than $K_{2}$. $SmFe_{11}Ti$ had the highest anisotropy of $K_{1}\;=\;9.2\;MJ/m^{3}$, $K_{2}\;=\;0.4\;MJ/m^{3}$ and ${\mu}_{o}H_{A}=\;19.8\;T$ among the compounds, substitution of any other rare earth elements for Sm decreased magnetocrystalline anisotropy.

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