• Title/Summary/Keyword: (D/C) ratio

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Preparation of V3.5+ Electrolyte for Vanadium Redox Flow Batteries using Carbon Supported Pt Dendrites Catalyst (카본 담지 백금 덴드라이트 촉매를 이용한 바나듐 레독스 흐름전지용 3.5가 바나듐 전해질의 제조)

  • Lee, Hojin;Kim, Hansung
    • Journal of the Korean Electrochemical Society
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    • v.24 no.4
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    • pp.113-119
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    • 2021
  • In this study, impurity free V3.5+ electrolytes were prepared using formic acid as a reducing agent and PtD/C as a catalyst and it was applied to VRFB. The well-oriented 3D dendrite structure of the PtD/C catalyst showed high catalytic activity in formic acid oxidation reaction and vanadium reduction reaction. As a result, the conversion ratio of electrolyte using the PtD/C was 2.73 mol g-1 h-1, which was higher than that of 1.67 mol g-1 h-1 of Pt/C prepared by the polyol method. In addition, in the VRFB charging and discharging experiment, the V3.5+ electrolyte produced by the catalytic reaction showed the same performance as the standard V3.5+ electrolyte prepared by the electrolytic method, thus proving that it can be used as an electrolyte for VRFB.

A Study on Fatigue Crack Propagation Behavior with Pure-Ti Plate (순수 티타늄 판재의 피로균열 전파거동에 관한 연구)

  • 오세욱;김태형;김득진;임만배
    • Journal of Ocean Engineering and Technology
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    • v.9 no.1
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    • pp.92-100
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    • 1995
  • The effect of different anisotropy and stress ratio on fatigue crack propagation behavior was investigated under various stress ratio(R=-0.4, -0.2, 0.2, 0.2, 0.4) using pure titanium sheet used in aerospace, chemical and food industry. The rack closure behavior under constant load amplitude fatigue crack propagation test was examined. Fatigue crack propagation rate da/dN was estimated in terms of effective stress intensity factor range, $\Delta$K$_{eff}$, regardless of various stress ratio but was influenced by anisotropy. Also, it was found that the effect of anisotropy was considerably decreased but still not negligible when he da/dN was evaluated by a conventional parameter, $\Delta$$K_{eff}$/E and when the modified da/dN.$\sqrt{\varepsilon}_f$ was evaluated by $\Delta$$K_{eff}$/E. On the other hand, da/dN could be evaluated uniquely by effective new parameter, $\Delta$K$_{eff}$/$sigma_{ys}$, regardless of anisotropy, as int he following equation da/dN=C''[\frac{{\Delta}K_{eff}}{{\sigma}_{ys}}]^{n''}. And effective stress intensity factor range ratio, U was estimated by the following equation with respect to the ratio of reversed plastic zone size, $\Delta r_{p}$ to monotonic plastic zone size, $r_p$ regardless of stress ratio and anisotropy. U=-4.45$(\Delta r_{p}/r_{p})^{2}$+4.1$(\Delta r_{p}/r_{p})$+0.245_{p})$+0.245

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Predictors of Meningitis in Febrile Infants Aged 3 Months or Younger (열이 있는 3개월 이하의 영아에서 수막염의 예측에 대한 연구)

  • Song, Hyang Soon;Kim, Eun Ok;Jang, Young Taek
    • Pediatric Infection and Vaccine
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    • v.16 no.1
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    • pp.40-46
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    • 2009
  • Purpose : The purpose of this study was to identify useful predictors for diagnosing bacterial meningitis and performing CSF studies in febrile infants three months or younger. Methods : Six hundred and fifty two febrile infants with a rectal temperature ${\geq}38.0^{\circ}C$ presented from January 2003 to April 2008 and were retrospectively studied. The total white blood cell count (WBC), band count, absolute neutrophil count (ANC), quantitative C-reactive protein (CRP) and blood cultures were performed on admission. The clinical variables associated with bacterial meningitis were analyzed. Results : In patients with bacterial meningitis, the clinical variables including CRP (P=0.036), band count (P=0.037), ANC (P=0.036) and age (P=0.001) were significantly different. The area under the receiver-operating characteristic curve was 0.969 for CRP, 0.946 for the band count, 0.765 for the ANC and 0.235 for age. A CRP cutoff point of 8 mg/dL was determined to maximize both the sensitivity and specificity (sensitivity 83%, specificity 95%, likelihood ratio 16.6). A CRP concentration of <7 mg/dL "ruled-out" bacterial meningitis, with a likelihood ratio of 0.17, a posttest probability of <0.1% and negative predictive value 91%. A CRP concentration greater than 9 mg/dL had a much higher likelihood ratio (20.1) than the band count (16.6) and ANC (2.2). Conclusion : The CRP concentration was a useful laboratory test for the differential diagnosis of bacterial meningitis among febrile infants three months of age or younger. A CRP concentration of <7 mg/dL effectively ruled out bacterial meningitis; a value ${\geq}9mg/dL$ increased the clinical suspicion of bacterial meningitis and the need for CSF evaluation.

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External Space Characteristics of the Seowon -A case Study of Sangju Area- (서원의 외부공간 특성 -상주지방의 사례연구-)

  • 박영달;신영철
    • Journal of the Korean Institute of Landscape Architecture
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    • v.27 no.3
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    • pp.18-31
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    • 1999
  • The research deals with external space Seowon(lecture hall) dedicated to education and memorial rises in Sangju area of Choson Dynasty. Characteristics of Seowon as follow; 1. Seowon of Sangju area were built from the middle of 17C to the beginning of 18C. Ideological background of building functioning were grafted into the belief in the three God governing Childbirth, the theory of feng-shui(wind-and water-magic) which is in close connection with the principles of yin and yang, and confucianism and the philosophy of lao-tze and chung-tze. The formation of space were horizontally arrangement and vertical arrangement as the first-learning and then-ancestor shrine of Youngnam provinces. 2. Background and factors of site selection were applied geographical feature, tried to connect owner home town. 3. The shape of path of flow were simple of vertical and curved composition, were continued, were stabilized through composition of human scale's space by reasonable internal. A case of Sangju area, D/H ratio of the front area of buildings and courts was as follows. D/H=1>Hyangkyo> houses on the river>temples>lecture halls. D/H ratio ot the backside areas is as follows. D/H=1>Hyangkyo>houses on the river>lecture halls. 4. Inner garden were planted deciduous than evergreen trees with Lagerstroemia indica. Enclosed dominant trees were planted by Pinus densiflora, Querces seuata.construct GEM strain, and examined for the expression and functional stability in microcosms.

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Enzymatic Glycosylation of Fatty Acids by Methyl Glycosides (메틸글리코시드에 의한 지방산의 효소적 배당화)

  • SunWoo, Hwan;Kim, Chong-Tai;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.1
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    • pp.83-94
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    • 1999
  • Glycoside fatty acid esters were synthesized by lipase-catalyzed glycosylation of fatty acids with methyl glycoside in solvent and solvent free process. Optimum condition of solvent process using 2-methyl-2-propanol were : moral ratio of methyl glycoside to fatty acid 1:3: initial concentration of methyl glycoside 50g/l:enzyme(immodilized lipase Novozym 435 from Candidia antarctica) content 1%(w/v) : desiccant content 9%(w/v); reaction temperature $60^{\circ}C$: reaction time 10hrs. The yield of 99% was obtained. Solvent-free process was carried out in total absence of solvent at $70^{\circ}C$ under reduced pressure, 5-20mmHg. To give meximum yield of 99% at the optimum condition of molar ratio of methyl glycoside to fatty acid 1:3, enzyme content 10%(w/w), and reaction time 10hrs. The glycosylation reactivity of different glycosylation agents were sequent to $Methyl-{\beta}-D-fructofuranoside$. $Methyl-{\beta}-D-glucopyranoside$. $Methyl-{\beta}-D-fructofuranosi$ de, and $Methyl-{\alpha}-D-glucopyranoside$.

Production of D-Lactic Acid from DL-Lactonitrile by Pseudomonas sp. (Pseudomonas sp.에 의한 DL-Iactonitrile로부터 D-lactic acid의 생산)

  • 김현수;황인균;정남현;방원기
    • Microbiology and Biotechnology Letters
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    • v.30 no.4
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    • pp.373-379
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    • 2002
  • By using DL-acetonitrile as enzyme inducer, 90 bacteria were isolated from a field soil. Among the isolated strains, the strain WJ-003 showed the highest activity for production of D-lactic acid from DL-lactonitrile, and was partially identified as Pseudomonas sp. The production condition of D-lactic acid from DL-lactonitrile using resting cells as an enzyme source was optimized as follows: the reaction mixture contained 10 mM of DL-lactonitrile, 20 g of wet cells in 11 of 20 mM potassium phosphate buffer (pH 7.0) and the reaction was carried out at $30^{\circ}C$. After 18 h of reaction, 0.843 g/l of D-lactic acid was produced which corresponded to a conversion ratio of 93.7% and an optical purity of 99.8%. Additionally, when 10 mM of DL-lactonitrile was added once more to the reaction mixture at 14 h, 1.64 g/1 of D-lactic acid was produced after 28 h. In this experiment, the conversion ratio was 91.1% and optical purity 99.8%.

Characteristics of Undrained Static Shear Behavior for Sand Due to Aging Effect (Aging 효과에 따른 모래의 비배수 정적전단거동 특성)

  • 김영수;김대만
    • Journal of the Korean Geotechnical Society
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    • v.20 no.6
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    • pp.137-150
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    • 2004
  • Aging effect of sands showed insignificant result in comparison with that of clay, so that it has not been studied so far. But, as penetration resistance increase has been observed with the lapse of time after deposition and disturbance, aging effect of sands has been actively investigated by field tests, and recently many researchers are performing not oかy field tests but also laboratory tests on sands, so aging effects of sands have been also examined by laboratory tests. In this study, to observe the aging effect of undrained static shear behavior for Nak-Dong River sand, undrained static triaxial tests were performed with changing relative density$(D_r)$, consolidation stress ratio$(K_c)$, and consolidation time. These tests showed that modulus within elastic section increased as consolidation time increased, and in addition, phase transformation point strength$(S_{PT})$ and critical stress ratio point strength $(S_{CSR})$ also increased. But pore water pressure ratio$(u/{p_c}')$ decreased as consolidation time increased, so with this various result, aging effect of static shear for sands can be observed as well.

A Model Study on Development of Animal Wastes Treatment System for a Full-time Farm Household Raising Livestock (전업양축농가의 축분뇨처리시스템 개발을 위한 모형실험)

  • 최홍림;김현태;정영륜
    • Journal of Bio-Environment Control
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    • v.2 no.1
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    • pp.16-26
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    • 1993
  • A sundry system is one of popular systems for composting livestock manure, of which main honest is to utilize unlimited, clean, and free solar radiation. A sundry system with a composter of two horizontal screw-type concrete ducts at different height, was constructed and operated for three days for each test in May, 1993, to evaluate its composting performance. Four treatments of the mixture ratio of swine manure and saw dust (manure : sawdust= 1 : 1.25, 1 : 1, 1 : 0.7, 1 : 0.5) were implemented to evaluate the effect of the mixture ratio on degradation of the composting materials of a sundry system with a screw-type composter. Maximum temperature of the composting materials was over 5$0^{\circ}C$ at D1 or D2 (one or two days after operation starts) for each test. Mean C/N ratio and water contents of the materials were reduced by more than 15 and 20%, respectively. Microbial density of each test showed a typical variation with the lapse of the composting time. Mesophilic microorganism seemed to play more important role on degradation of the materials than thermophilic. A sundry system with a screw-type composter can be considered as a feasible system on basis of maturity data. The conclusion was completely reverse from that of Choi et at., although both adopted a sundry system. A further study is recommended to pursue the cause of better performance of the screw-type composter, whether it was due to affirmative weather or more efficient composter.

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Fabrication of Perforated Strings for Transparent Silicon Shingled Photovoltaic Modules (투광형 실리콘 슁글드 태양광 모듈을 위한 타공형 스트링 제작)

  • Kim, Han Jun;Park, Min-Joon;Song, Jinho;Jeong, Taewung;Moon, Daehan;Jeong, Chaehwan
    • Current Photovoltaic Research
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    • v.8 no.4
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    • pp.120-123
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    • 2020
  • Transparent photovoltaics (PV) are used in various applications such as building-integrated photovoltaics (BIPV). However, crystalline silicon (c-Si) is not used for developing transparent PV due to its opaque nature. Here. we fabficate the three holes in 6-inch c-Si solar cells using laser scribing process with an opening area ratio of about 6.8% for transparent c-Si solar modules. Moreover, we make the shingled strings using the perforated cells. Our 7 interconnected shingled string PV cells with 21 holes show a solar to power conversion of 5.721 W. In next work, we will fabricate a transparent c-Si PV module with perforated strings.

The Point Load Index of the Daegu Shale and its Relation to the Uniaxial Compressive Strength (대구지역 셰일의 점재하지수 특성 및 일축압축강도와의 상관성)

  • Lee, Younghuy;Youn, Chanho
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.3
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    • pp.37-45
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    • 2009
  • The experimental study was carried out to evaluate the characteristics of the point load index and the uniaxial compressive strength of inherently anisotropic shale in the laboratory. In the testing program the effects of size and the shape on the point load index were investigated both in the axial and diametral direction. In general, the point load index of the shale was constant when the length/diameter (L/D) ratio of the specimen is greater than 1.0 in the diametral direction. The point load index in axial direction shows slight decrease as the L/D ratio is increased and the corner breakage was observed when L/D ratio is greater than unity. The minimum point load index was observed in the bedding angle of $\beta=15^{\circ}{\sim}30^{\circ}$ in the axial point load tests and of $\beta=30^{\circ}$ in the uniaxial compression tests. The relationship between the point load index and the uniaxial compressive strength was linear to ${\sigma}_c=25.0 I_{s(50)}$ for the specimen with the bedding plane angle, $\beta$ at the range of $0^{\circ}{\sim}90^{\circ}$. On the other hand, this relationship was appeared linear to ${\sigma}_c=14.4 I_{s(50)}$ when the bedding angle, $\beta$ is fixed to 90${^{\circ}}$ and this correlation is much different from ${\sigma}c=22 I_{s(50)}, which is generally applied to the rock specimen with no bedding plane in ISRM (1985). The anisotropic strength with different $\beta$ angle shows the shoulder type and this can be suitably modelled by the corrected Ramamurthy'(1993)s equation with the index value of 'n' equal to 3.0.

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