• Title/Summary/Keyword: (D/C) ratio

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Polymerization of Sugar by Extrusion

  • Hwang, Jae-Kwan;Kim, Chul-Jin;Chong-Tai, Kim
    • Preventive Nutrition and Food Science
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    • v.2 no.4
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    • pp.296-300
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    • 1997
  • Glucose syrup and lactose, mixed with citric acid as a polymerizing catalyst, was processed using twin screw extruder, in which 40 of L/D(length/diameter) ratio was designed to provide sufficient retention in extruder for polymerization of sugars. The polymerization yields of glucose syrup were 36.90%, 55.44% and 77.10% at 160, 180 and 20$0^{\circ}C$, respectively, while those of lactose were 26.45%, 38.16% and 45.86% at the same temperatures. Gel permeation chromatography exhibited that the higher molecular weight fractions were increased with extrusion temperature, which also led to increasing hydrodynamic intrinsic viscosity. Both uco-oligosaccharides and lacto-oligosaccharides produced by extrusion of glucose syrup and lactose were stable for thermal treatments over a wide range of pH3.0~11.0. In addition, $\alpha$-amylase and amyloglucosidase treatment of gluco-oligosaccharides did not affect the solution viscosity, indicating the random linkage rather than $\alpha$-1, 4 linkages of glucose and thus the potential applications as a dietary fiber. In this research it was clearly observed that twin screw extrusion can be successfully utilized to produce gluco-oligosaccharides and lacto-oligosaccharides rapidly and continuously in conjunction with selective control of polymerized composition.

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Preparation and Characterization of Block Copolymer Containing Bisphenyl Propane Unit and Nanosilica Composite Membrane for Fuel Cell Electrolyte Application (비스페닐프로판 단위를 갖는 연료전지전해질용 블록공중합체/나노실리카 복합막 제조 및 특성)

  • KIM, AE RHAN
    • Journal of Hydrogen and New Energy
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    • v.28 no.2
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    • pp.144-149
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    • 2017
  • A proton-conducting bisphenylpropaned sulfonated fluorinated blockcopolymer (BPSFBC) was synthesized. Five kinds of polymer electrolyted composite membranes were preparated by incorporating silica ($SiO_2$) with various weight ratio. And their characteristics were investigated by FT-IR (fourier transform infrared), $^1H-NMR$ ($^1H$ nuclear magnetic resonance), TGA (thermogravimetric analysis), water uptake, FE-SEM (field emission scanning electron microscopes), and ion conductivity properties. The water uptake and ion conductivity were increased until 9 wt% $SiO_2$, and then decreased. The maximum proton conductivity equal to $52mScm^{-1}$ was measured for the BPSFBC/$SiO_2$-9 composite membrane at $90^{\circ}C$ and 100% relative humidity. From the measured results, it is distinct that the manufactured composite membrane BPSFBC/$SiO_2$-9 can be considered as a polymer membrane suitable for a fuel cell electrolyte.

Effects of Feed Moisture Content on Enzymatic Hydrolysis of Corn Starch in Twin-Screw Extruder and Saccharification of the Dried Extrudates

  • Solihin, Budiasih W.;Kim, Mi-Hwan;Im, Byung-Soon;Cha, Jae-Yoon;Ryu, Gi-Hyung
    • Food Science and Biotechnology
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    • v.16 no.3
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    • pp.381-385
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    • 2007
  • The objective of this experiment was to study the influence of feed moisture content on the degree of enzymatic hydrolysis of com starch in a twin screw extruder and the saccharification yield of the dried extrudate. The feed moisture content was set at 25, 30, and 35% and ${\alpha}$-amylase solution was directly injected into the feed section at a barrel temperature of $95^{\circ}C$ and screw speed of 250 rpm. Amyloglucosidase was used for the saccharification of the dried extrudate at a concentration of 0.055%(w/w). Expansion ratio and swelling factor of extrudates decreased with increasing the feed moisture content. Addition of ${\alpha}$-amylase during extrusion process raised reducing sugar content of extrudates which also increased with the feed moisture content. The saccharification yield of dried extrudate was higher for the extrudate with lower feed moisture content.

Performance Improvement of Pneumatic Artificial Muscle Manipulators using Magneto-Rheological Brake (MR Brake를 이용한 공압근육매니퓰레이터의 지능제어)

  • Ahn, Kyoung-Kwan;Thanh, T.D.C.;Ahn, Young-Kong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.572-575
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    • 2005
  • A novel pneumatic artificial muscle actuator (PAM actuator), which has achieved increased popularity to provide the advantages such as high strength and high power/weight ratio, low cost, compactness, ease of maintenance, cleanliness, readily available and cheap power source, inherent safety and mobility assistance to humans performing tasks, has been regarded during the recent decades as an interesting alternative to hydraulic and electric actuators. In order to realize satisfactory control performance, a variable damper Magneto Rheological Brake (MRB), Is equipped to the Joint of the manipulator. Superb mixture of conventional PID controller and a phase plane switching control method brings us a novel controller. This proposed controller is appropriate for a kind of plants with nonlinearity, uncertainties and disturbances. The experiments were carried out in practical PAM manipulator and the effectiveness of the proposed control algorithm was demonstrated through experiments, which had proved that the stability of the manipulator can be improved greatly in a high gain control by using MRB with phase plane switching control method and without regard for the changes of external inertia loads.

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A Design Criterion for the Vibration of a Marine Diesel Generator Set (선박용 디젤발전기의 진동 절연을 위한 설계 기준)

  • Lee, D.C.;Brennan, M.J.;Mace, B.R.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.648-655
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    • 2005
  • The resilient mounts of a diesel engine installed onboard a ship should be designed for both static and dynamic loads. If possible, the resonance frequencies of the six rigid body modes of the installation and the flexible modes of the engine support structure should not lie within the engine operation range. In this paper a design criterion is proposed to evaluate an isolation system which involves the summation of dynamic forces transmitted through the resilient mounts and elastic potential energy index stored in the mounts. A case study is also presented in which a diesel engine generator, which had an elastic foundation and was mounted in a 5500 TEU container vessel, was studied both theoretically and experimentally. The theoretical analysis of the test model was performed by using a single mass 6 degree of freedom system. Actual measurements of mechanical vibration of the Engine and its foundation onboard were carried out, which showed the importance of including the flexibility of the engine support structure in the mode

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A Study on the Behavior of Wrinkles in Cup Drawing with Al alloy by FEM (유한요소법에 의한 합금의 용기 성형시 Al 주름의 거동에 관한 연구)

  • Ko D.L.;Jeon C.Y.;Kim J.M.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1240-1243
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    • 2005
  • The wrinkling in the flange and wall of a part is a predominant failure mode in stamping of sheet metal parts. In many cases this wrinkling may be eliminated by appropriate control of the blank holding force(BHF), but BHF affects the draw depth. Gotoh had studied the wrinkles under $20{\mu}$ in height. In general, the height of wrinkles could be limited under $200{\mu}$ practically. Therefore small BHF can be allowed so that the depth of drawing could be increased. This paper represents the variation of the wrinkles of flange in the part of cup drawing by using aluminium alloy A1050 and A5052. This simulation is used by the explicit finite elements code $PAM-STAMP^{TM}$. The computed results are compared with the experimental results to show the validity of the analysis.

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Process Design for Multi-pass Profile Drawing using Round Materials (원형소재를 이용한 프로파일 다단 형상인발 공정설계)

  • Lee, I. K.;Choi, C. Y.;Lee, S. K.;Jeong, M. S.;Lee, J. W.;Kim, D. H.;Cho, Y. J.;Kim, B. M.
    • Transactions of Materials Processing
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    • v.24 no.4
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    • pp.234-240
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    • 2015
  • Multi-pass shape drawing is very important to produce steel profiles in round samples. In the current study, a process design system is developed for a multi-pass shape drawing. In general, the number of passes for a multi-pass shape drawing is 2 to 3 when the reduction ratio, drawing stress, and productivity are considered. Therefore, calculating the drawing stress and designing the intermediated die shapes are very important. In order to calculate the drawing stress, a shape drawing load prediction method is proposed using a general axisymmetric drawing load prediction model. An intermediate die shape design method is proposed using the initial and the final product shapes. Based on this analysis, a process design system is developed for multi-pass shape drawing for steel profiles. The system works with AutoCAD. The system was applied to design a shape drawing of a spline.

Effect of Loading Rate on Acidogenic Fermentation of Domestic Waste Sludge (산발효에 있어서 하수슬러지의 유입부하율의 영향)

  • Eom, Tae-Kyu;Han, Dong-Yueb
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.1
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    • pp.15-21
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    • 2004
  • The purpose of this research was to investigate loading rate of influent for acidogenic fermentation. Laboratory batch experiments were conducted, at $35^{\circ}C$, HRT 18hr, pH 6 and used 3.5L reactor. Loading rate of influent was varied 2.0 to 4.0g VSS/L, TOA concentration is decreased according to increasing loading rate Over 2.5g VSS/L. When loading rate is 2.0g VSS/L, hydrolysis percentage show the maximum value of 87%. Most of SCFA is consist of HAc, HPr, I-HBu and MBu. HAc concentration is 5,233mg/L in the 2.0g VSS/L condition. So, for this study, we think that limiting loading rate is 2.5g VSS/L. SCFA species was investigated to HAc, HPr, I-HBu and n-HBu during our studying. HAc/SCFA ratio is about 89.3%, SCFA production rate is highest to $1,104mg\;COD/L/d{\cdot}gPCOD$ for 2.0g VSS/L loading rate.

Synthesis of Lithium Titanate Whisker Using Ion-Exchange of Acid Treatment

  • Um Myeong-Heon;Lee Jin-Sik
    • Korean Journal of Materials Research
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    • v.14 no.9
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    • pp.627-633
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    • 2004
  • Lithium titanate whiske($Li_{x}Ti_{4}O_9$) was prepared by an ion-exchange reaction. To this end, the initial material, potassium tetratitanate ($K_{2}Ti_{4}O_9{\cdot}nH_{2}O$) was prepared by calcination of a mixture of $K_{2}CO_3\;and\;TiO_2$ with a molar ratio of 2.8 at $1050^{\circ}C$ for 3 h, followed by boiling water treatment of the calcined products for 10 h. Fibrous potassium tetratitanate could be transformed into layered hydrous titanium dioxide ($H_{2}Ti_{4}O_9{\cdot}nH_{2}O$) through an exchange of $K^{+}\;with\;H^{+}$ using 0.075 M HCl. Also, lithium titanate whisker was finally prepared as $Li^{+}\;and\;H^{+}$ ions were exchanged by adding 20 mL of a mixture solution of LiOH and $LiNO_3$ to 1g whisker and stirring for $5\~15$ days. The average length and diameter of the $Li_{x}Ti_{4}O_9$ whiskers were $10\~20{\mu}m\;and\;1\~3{\mu}m$, respectively.

Preparation and Characterization of Water-Soluble Phosphate Glasses Containing Cu by Sol-Gel Method (졸-겔법에 의한 Cugkadb 인산염계 수용성 유리의 제조 및 특성)

  • 오승환;최세영;김경남
    • Journal of the Korean Ceramic Society
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    • v.35 no.4
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    • pp.319-324
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    • 1998
  • Sol-gel derived phosphate water-sioluble glasses containing Cu were prepared. Powder-shape of glasses were added in D.I water used polyethylene bottle. After solution contained glass powder were submerged in water bath on 25$^{\circ}C$ their dissolution behavior/characteristics bactericidal effect and cytotoxicity test were evaluated. The maximum amount of Cu(35 mol%) via sol-gel method was more 5 mol% increased than that with melting process. The stage of total dissolution was more dominant than that of selective leaching dur-ing dissolution due to dissolved amount of glasses increased linearly with time. The ratio of Cu+ to {{{{ {Cu }^{2+ } }} was 3:7 so that the structure of glasses is more predominant 2-dimension chain structure than 3-dimenshion po-lymeric structue. The stage of total dissolution was more dominant than that of selective leaching during dissolution. Bactericidal effect against all bacteria showed that solutions which contained 40 ppm and 100 ppm of Cu killed 80 percentages of bacteria within 2 hours and 100 percentages of those within 12 hours. The results of cytotoxicity test for L929 cells showed no cytotoxicity were observed within 96 hours for dis-solved solution that contains 40 ppm and 100 ppm of Cu.

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