• Bulletin of the Korean Chemical Society
• /
• v.30 no.10
• /
• pp.2208-2212
• /
• 2009

Oxidation of cycloalkenes with $O_2$ promoted by heterogeneous bis(acetylacetonato) cobalt (II) complex catalyst which can be recycled has been performed under mild conditions. It was found that $\beta$-ionone, cyclohexene, 1-methylcyclohexene, and $\alpha$-ionone were efficiently oxidized with $O_2$ in the presence of Co (II) complex and butyraldehyde at $55\;{^{\circ}C}$. A simple treatment of the resulting products led to epoxides as predominant products and a small amounts of allylic oxides, the chemoselectivity for the former being 82.1 - 90.8% with a 70.6 - 98.6% substrate conversion. On the other hand, oxidation of 1-phenylcyclohexene, 1-cyclohex-1-enylethan-1-one, $\alpha$-pinene, and $\beta$-pinene gave allylic oxides as major products.

• Journal of Korean Society for Atmospheric Environment
• /
• v.18 no.E3
• /
• pp.175-180
• /
• 2002

In order to study the distribution characteristics of natural volatile organic compounds (NVOCs), we investigated the seasonal variations of $\alpha$-and $\beta$-pinene levels in a pine forest in Florida for a you. The mean concentrations of $\alpha$- and $\beta$-pinene measured during the whole study period were computed to be 125: 86 (N = 65) and 86$\pm$52 pptv (N = 56), respectively. According to our data grouping scheme, the seasonal means for both pinones were observed to peak during fall with their max and min values in summer and winter, respectively. The overall results of our study suggest that terpenes are subject to highly strong temporal variability because of changes in their major source characteristics across seasons.

• Korean Journal of Pharmacognosy
• /
• v.24 no.3
• /
• pp.192-196
• /
• 1993

Essential oil of the root of Angelica decursiva(Miq.) Fr. et Sav. (Umbelliferae) was investigated. Essential oil was obtained from the dried roots by steam distillation and fractionated by column chromatography. Each isolate or fraction was identified by GC, GC-MS and spectral analysis. It was found to contain ten monoterpenes such as ${\alpha}-pinene$ (7.0%) etc. Three hydrocarbons, two aldehydes, three sesquiterpenes, two sesquiterpene alcohols, one aromatic compounds, one ketone, isobonyl acetate and two lactones were tentatively identified.

• Journal of Korean Society of Forest Science
• /
• v.103 no.3
• /
• pp.483-489
• /
• 2014

This study aimed at a scientific examination of the relationship between NVOCs concentration and the physical environment of red pine forest in spring season. Atmospheric NVOC samples in red pine forest was collected through five trials conducted from March to May 2013, using Tanax-Ta-charged disposable tubes and mini-pumps. At each trial, measurements were taken at three different points in daytime (sunrise, southing and sunset). For maximum accuracy, two tubes were used for each measurement at the same location, and the mean value was used for analysis. Compound analysis on the NVOC samples was done using the HS-SPME method and GC-MS. Analysis of the relationship between NVOC and the physical forest environment found higher concentrations of most substances, including ${\alpha}$-pinene and ${\beta}$-pinene, with higher temperature, dew point, and lower concentrations with higher wind velocity. The findings of this study offer scientific evidence which can inform the creation of 'healing forests' and 'recreational forests' as well as forest environment in general, helping to promote public health and recreational activities.

• Applied Biological Chemistry
• /
• v.47 no.1
• /
• pp.124-129
• /
• 2004

The composition of essential oils isolated from the aerial parts of Artemisia iwayomogi Kitamura and Artemisia capillaris Thunberg collected from two diffenent cultivation area, respectively, was analyzed by GC and GC-MS. Sixty components were identified in oils from A. iwayomogi. The major components of A. iwayomogi oil collected from one area (Sample A) were iso-pinocamphone (31.64%), 1,8-cineo1e (21.55%), ${\beta}-pinene$ (4.46%), pinocarvone (3.72%), myrtenal (3.42%) and trans-pinocarve1 (3.14%), and the major components of the oil from the other area (Sample B) were camphor (26.99%), 1,8-cineo1e (21.55%), ${\alpha}-terpineol$ (7.63%), borneol (4.10%), camphene (3.97%) and artemisia ketone (3.84%). Eighty components were identified in oils from A. capillaris. The major components were capillene $(26.01{\sim}30.31%)$, ${\beta}-pinene(8.55{\sim}18.38%)$, ${\beta}-caryophyllene(8.80{\sim}13.70%)$, ${\beta}-himachalene(1.67{\sim}5.57%)$, $cis,trans- {\alpha}-farnesene(2.10{\sim}7.38%)$ and germacrene D $(2.27{\sim}5.46%)$ and there was no difference in oil composition of A. capillaris between two cultivation area.

• Korean Journal of Weed Science
• /
• v.32 no.3
• /
• pp.195-203
• /
• 2012

The essential oil was extracted by steam distillation from the aerial part of erect bur-marigold (Bidens tripartita L.), one of the noxious weed in paddy field. The composition of the essential oil was analyzed by gas chromatography-mass spectrometry. The fragrance of the essential oil was green, herbal, oily, spicy. There were 42 constituents in the essential oil：17 hydrocarbons, 6 alcohols, 6 acetates, 5 N-containing compounds, 3 ethers, 3 ketones, 1 lactone and 1 S-containing compound. Major constituents were ${\alpha}$-phellandrene (22.50%), ${\alpha}$-pinene (22.21%), 2,4-dimethyl (2,5-dimethylphenyl) methyl ester benzoic acid (15.11%), limonene (10.66%), ${\beta}$-pinene (35.43%), and ${\beta}$-cubebene (5.27%). The $IC_{50}$ value in MTT assay using HaCaT keratinocyte cell line was 0.018%. However, attachment of patch with 0.1% of the erect bur-marigold essential oil for 24 hr did not show any skin toxicity. Overall results of this study suggest that the essential oil of erect bur-marigold could be used as a source for the development of perfumery industrial products.

• The Korean Journal of Pesticide Science
• /
• v.11 no.3
• /
• pp.179-185
• /
• 2007

Esterase isozymes were investigated from digestive juice of M. saltuarius adults after pesticide treatment. Twelve esterase isozymes were separated on 12% native-PAGE gel and stained with three different substrates(${\alpha}$-naphthyl acetate, ${\beta}$-naphthyl acetate, and ${\alpha}$-naphthyl butyrate). Interestingly, the isozyme of Est1(${\alpha}$-naphthyl acetate) was strongly inhibited by the carbofuran and methomyl. The Est1 activity was completely inhibited by the chlorpyrifos and partially inhibited by methidation about 70 %. In addition, eserine suppressed esterase isozyme activities of Est1 about 70% and isozyme activities of Est2, Est3, and Est4 were weakly inhibited. ${\alpha}$-pinene did not suppressed esterase isozyme activities but activities of esterases were very weakly inhibited in camphor and bornyl acetate.

• Journal of Korean Society for Atmospheric Environment
• /
• v.20 no.2
• /
• pp.175-183
• /
• 2004

In order to investigate the composition ratio and the emission rate of monoterpenes emitted from coniferous trees during summer, the enclosure chamber experiments were carried out for two tree species (Pinus densiflora and Pinus rigida). The major monoterpenes from the pine trees were $\alpha$-pinene, $\beta$-pinene, myrcene and $\beta$-phellandrene. There was no difference of the composition ratio between two sites for P. densiflora, but the difference was observed for P. rigida. Clearly, the ratio of $\beta$-pinene (26.1 %) for P. rigida was higher than that of $\beta$-phellandrene (12%) at the Gumsung mountain site, but the ratio of $\beta$-phellandrene (22.2%) was higher than that of $\beta$-pinene (9.9%) at the Chiri mountain site. Particularly, the composition ratio of $\beta$-phellandrene was higher than that of $\beta$-pinene for P. densiflora, and the opposite trend was found for P. rigida at the Gumsung mountain site. The characteristics of the composition ratio between two species were similar at the Chiri mountain site. As a result of the emission rate measurements, it was observed that both sites did not show any significant $\beta$ value (slope between emission rate and temperature) and ERs (Standard Emission rate at 3$0^{\circ}C$) difference. However, the $\beta$ value and ERs at the Chiri mountain site were slightly greater than those of Gumsung mountain site for both pine species. P. densiflora (1.703 and 1.971 $\mu\textrm{g}$C/gdw/hr) showed the higher monoterpene ERs than those of P. rigida (0.572 and 0.698 $\mu\textrm{g}$C/gdw/hr) at both sites.

• Horticultural Science & Technology
• /
• v.34 no.2
• /
• pp.331-341
• /
• 2016

We analyzed the functional fragrant components of three species of Cymbidium oriental orchids using gas chromatography-mass spectrometry (GC/MS). For the comparative analysis, C. goeringii 'Minchunran', 'Jugeumhwa', C. forrestii 'Chwigae', 'Songmae', 'Yongja', and C. faberi 'Choemae', 'Namyangmae', 'Hwaja' were investigated. Major fragrant components detected by GC/MS were selected on the basis of more than 3% value according to the analysis of peak area (%). We found that ${\alpha}$-bergamotene, which has a cytotoxic effect on breast cancer, cervical cancer, and glioblastoma, and nerolidol, which induces apoptosis of human hepatoma cells (HepG2), inhibits the growth of Streptococcus mutans and babesiosis, and has antibacterial properties, are common substances produced by C. goeringii L. Nerolidol and ${\beta}$-bisabolene, which is cytotoxic and suppresses the growth of malignant melanoma cells (B16-F10), HepG2, and leukemia cells (HL-60, K562), are major substances in C. forrestii R. Furthermore, ${\alpha}$-pinene, which inhibits the growth of gliobastoma cells (SF-767) and inhibits the anti-inflammatory action of hepatoma cells (BEL-7402); 1,8-cineole, which is a potential therapeutic agent for the treatment of gastric ulcers; and 1,3,7-octatriene, which functions as a pheromone, are the most common substances in C. faveri R. Thus, substances identified as major fragrant components in oriental orchid species have multiple beneficial applications in human health. This research forms the basis for further studies of the roles of major fragrant components in oriental orchids.

• Journal of Environmental Science International
• /
• v.21 no.10
• /
• pp.1221-1234
• /
• 2012

There are many factors to influence the amount of terpene at the forest. However, it is poorly understood whether the amount is altered by meteorological factors. In order to study correlation analysis between terpene amount and meteorological(i.e., temperature, humidity, wind speed, solar radiation) and environmental factors(i.e., oxygen, carbonb dioxide) at the artificial coniferous forest of Chamaecyparis obtusa (site 1) and Cryptomeria japonica (site 2) nearby the $1^{st}$ reservoir at Mt. Moodeung, the research was executed during April to November in 2011. Forest density at site 1 was 1,692 trees/ha, being occupied with 87.2% of Chamaecyparis obtusa, higher than 925 trees/ha at site 2. Carbon dioxide at site 1 was in the range of 385~410 ppm in June, similar to at Anmyundo(395 ppm in 2010). Solar radiation has positive correlation with ambient temperature and inversely negative with relative humidity. Main species of terpene released were ${\alpha}$-pinene, camphene, ${\beta}$-pinene, cymene, ${\delta}$-limonene and camphor at two sites and terpene was more effluent at spring and summer than at fall. The large amount of terpene was emitted in the afternoon than in the morning under the influence of the wind speed and the topographical property. The terpene amount has positive correlation with relative humidity and oxygen, and negative with wind speed and soil temperature. Because correlations of ${\alpha}$-pinene and other terpene materials showed statistically significant within p=0.01. ${\alpha}$-pinene could be suggested as the basic material in explaining the amount of other terpene materials.