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Water and oxygen permeation through transparent ethylene vinyl alcohol/(graphene oxide) membranes

  • Kim, Hye Min;Lee, Heon Sang
    • Carbon letters
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    • v.15 no.1
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    • pp.50-56
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    • 2014
  • We prepared ethylene vinyl alcohol (EVOH)/graphene oxide (GO) membranes by solution casting method. X-ray diffraction analysis showed that GOs were fully exfoliated in the EVOH/GO membrane. The glass transition temperatures of EVOH were increased by adding GOs into EVOH. The melting temperatures of EVOH/GO composites were decreased by adding GOs into EVOH, indicating that GOs may inhibit the crystallization of EVOH during non-isothermal crystallization. However, the equilibrium melting temperatures of EVOH were not changed by adding GOs into EVOH. The oxygen permeability of the EVOH/GO (0.3 wt%) film was reduced to 63% of that of pure EVOH film, with 84% light transmittance at 550 nm. The EVOH/GO membranes exhibited 100 times better (water vapor)/(oxygen) selectivity performance than pure EVOH membrane.

A Study on Graphene Oxide and Carboxylated Styrene-Butadiene Rubber(XSBR) Nanocomposites (그래핀 옥사이드/카르복실화한 스티렌-부타디엔 고무 나노 복합체에 관한 연구)

  • Jang, Sun Ho;Xu, Li Xiang;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.1
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    • pp.52-58
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    • 2017
  • Graphene oxide (GO)/carboxylated styrene-butadiene rubber (XSBR) nanocomposites with various contents of GO were prepared by a latex compounding method. It has been confirmed that the functional groups of GO and the hydrogen bonds between GO and XSBR are existed. It can be seen that the scorch time ($t_{s2}$), which is the measurement of incipient vulcanization of rubber, showed a delay after the addition of GO. Field emission scanning electron microscopy was employed to confirm the uniform dispersion of filler in the matrix. Indeed, with increasing fillers loading, the torque, tensile strength, thermal stability and crosslink density of obtained nanocomposites were improved. These results were correlated to the better dispersion of fillers through the rubber matrix.

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Influence of Ligand on Oxidation of Cyclohexane in the Biomimetic System (생체모방계에 의한 시클로헥산 산화반응에서 리간드의 영향)

  • Kim, Seong-Bo
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.202-205
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    • 2005
  • The effects of ligands on reactivity under GoAgg oxidation system have been studied. Picolinic acid containing carboxylic acid showed the most excellent activity among various ligands. Also, Picolinic acid of ortho position carboxylic group in pyridine ring largely increased reaction rates in the GoAgg oxidation systems. From these results, we proposed the new mechanism on the GoAgg oxidation using ligands having carboxylic group at ortho position.

Graphene oxide dispersed polyvinyl chloride/alkyd green nanocomposite film: Processing and physico-mechanical properties

  • Yadav, Mithilesh;Ahmad, Sharif;Chiu, Fang-Chyou
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.246-256
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    • 2018
  • Graphene oxide (GO) reinforced Polyvinyl chloride (PVC)-Waterborne Castor Alkyd (WCA) nanocomposites (PVC/WCA/GO) films were processed through solution blending technique. TGA showed that the thermal stability of PVC/WCA/GO-0.5 films was better than that of PVC/WCA blend film. With incorporation of 0.5 wt.% GO, the tensile strength and elastic modulus of the blend nanocomposite have significantly improved by about 260% and 185%, respectively, compared with neat polymer. The physicomechanical properties of these films suggest that the PVC/WCA/GO nanocomposite films may have a potential scope for their application in packaging industries. The results are supported by characterizations like FTIR, XRD, TEM and FESEM.

Study of Electrochemical Cs Uptake Into a Nickel Hexacyanoferrate/Graphene Oxide Composite Film

  • Choi, Dongchul;Cho, Youngjin;Bae, Sang-Eun;Park, Tae-Hong
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.123-130
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    • 2019
  • We investigated the electrochemical behavior of an electrode coated with a nickel hexacyanoferrate/graphene oxide (NiPB/GO) composite to evaluate its potential use for the electrochemical separation of radioactive Cs as a promising approach for reducing secondary Cs waste after decontamination. The NiPB/GO-modified electrode showed electrochemically switched ion exchange capability with excellent selectivity for Cs over other alkali metals. Furthermore, the repetitive ion insertion and desertion test for assessing the electrode stability showed that the electrochemical ion exchange capacity of the NiPB/GO-modified electrode increased further with potential cycling in 1 M of $NaNO_3$. In particular, this electrochemical treatment enhanced Cs uptake by nearly two times compared to that of NiPB/GO and still retained the ion selectivity of NiPB, suggesting that the electrochemically treated NiPB/GO composite shows promise for nuclear wastewater treatment.

The Effect of Perceive Ease of Use, Perceive Usefulness and Perceive Risk towards Behavioral Intention of GO-FOOD Customer in Indonesia

  • SIDHARTA, Arvin Dillon;HONGDIYANTO, Charly
    • The Journal of Economics, Marketing and Management
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    • v.10 no.4
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    • pp.25-34
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    • 2022
  • Purpose: Technology and innovation drive new mobile application for ojek online. Using the theory of technology acceptance model and perceived risk theory, the researcher wants to find how these factors affect user's intention to use GO-FOOD that leads to technology adoption. Research design, data and methodology: The researcher uses GO-FOOD users that located in East Java, Indonesia for the object of study. Results: The findings of the research discovered that perceive usefulness and perceive ease of use do not significantly affect user's behavioral intention while perceive risk is significantly affecting the user's behavioral intention. Conclusions: The findings suggested that GO-FOOD or similar application should focus more on reducing or eliminating user's perception of risk towards the mobile application

Experimental investigation of mechanical and microstructural properties of concrete containing modified nano-Graphene Oxide

  • Maryam Ashouri;Ehsanollah Zeighami;Alireza Azarioon;Seyyed Mohammad Mirhosseini;Sattar Ebrahimi Yonesi
    • Advances in nano research
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    • v.16 no.5
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    • pp.435-444
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    • 2024
  • Microscopic defects within the microstructure of hardened cement paste are the main source of weakness in concrete. As a solution, nano-graphene oxide (GO) can be employed to improve the cement paste microstructure. However, there is a number of disadvantages, e.g., fluidity reduction and non-uniform dispersion. The present study sought to modify GO by fabricating a copolymer (PSGO) in a novel process to exploit the advantages of nano-GO while minimizing its disadvantages. Using 0.03wt% copolymerled to 38.8% higher tensile strength, 29.3% higher compressive strength and 25% higher workability. The SEM images revealed that GO and modified GO enhanced concrete by secondary hydration and bonding with C-S-H, creating a firm, integrated, and foil-like structure, and reducing the crack size and depth.

Synthesis, Characterization and Photocatalytic Activity of Reduced Graphene Oxide-Ce/ZnO Composites

  • Zhang, Wenjun;Zhao, Jinfeng;Zou, Xuefeng
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.127-134
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    • 2016
  • A series of Ce-doped ZnO (Ce/ZnO) nanostructures were fabricated using the co-precipitation method, then a simply nontoxic hydrothermal approach was proposed for preparation of reduced graphene oxide (rGO)-Ce/ZnO composites. The synthesized composites were investigated by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), photoluminescence spectroscopy (PL), electrochemical impedance spectroscopy (EIS), UV-vis diffuse reflectance spectroscopy (DRS) techniques and Raman pattern. The as-synthesized rGO-Ce/ZnO composites showed high photodecomposition efficiency in comparison with the rGO-ZnO, Ce/ZnO, pure ZnO under UV, visible-light and sunlight irradiation. The degradation of methylene blue (MB) (10 mg/L, 100ml) by 95.8% within 60 min by using rGO-2 (10 mg) under sunlight irradiation was observed. The repeated use of the rGO-2 was investigated, and the results showed almost no decay in the catalytic activity.

Direct Comparison of Optical Properties from Graphene Oxide Quantum Dots and Graphene Oxide

  • Jang, Min-Ho;Ha, Hyun Dong;Seo, Tae Seok;Cho, Yong-Hoon
    • Applied Science and Convergence Technology
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    • v.24 no.4
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    • pp.111-116
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    • 2015
  • The graphene oxide (GO) and graphene oxide quantum dots (GOQDs), which have gained research interest as new types of light-emitting materials, were synthesized by the modified Hummers method for oxidation of graphite flake and graphite nanoparticle. The optical properties of GO and GOQDs have been compared by mean of photoluminescence (PL), PL excitation (PLE), UV-vis absorbance, and time-resolved PL. The GO have an absorption peak at 229 nm and shoulder part at 310 nm, whereas the GOQDs show broad absorption with a gradual change up without any absorption peaks. The PL emission of GOQDs and GO showed the green color at 520 nm and the red color at 690 nm, respectively. The red emission of GO showed faster PL decay time than the green emission of GOQDs. In particular, the temporal PL profile of the GO showed redshift from 560 nm to 660 nm after the pump event.

Survey on 'Go Bag' Items in Internet Shopping Malls

  • PARK, Sang-Kyu;UHM, Tai-Hwan
    • Journal of Distribution Science
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    • v.17 no.7
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    • pp.39-44
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    • 2019
  • Purpose - This research was to help distribution of Go Bags (Survival Bag or Disaster Supplies Kit), which are useful for disaster preparedness, by surveying precomposed Go Bag items in internet shopping malls. Research design, data, and methodology - We checked 15 items including food, water, first aid kit, radio, flashlight or candles, battery, lighter or matches, whistle, blanket, towel, toilet paper, personal sanitations, raincoat, can opener, disaster manual in Go Bags based on the recommendations by the Ministry of the Interior and Safety. The number of items and price, domestic product, accreditation were compared using a Chi-square test. The Pearson's R was also used to summarize the strength of the linear relationship between the number of items and price, sub-items. Results - Mean of the sub-items was 21, and mean of the items was 8. There was a statistically significant difference between the number of items size and the price level (p=.014). There was also a statistically significant difference between the number of items and sub-items (p<.001), and correlation coefficient was a positive linear relationship of .467. Conclusions - Only eight were sold in the internet shopping malls as a precomposed Go Bag items. Even the approved Go Bags had no difference in the number of items. Higher prices had a relatively greater number of items, and it had a positive correlation between the size of sub-items and items.