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90K 초전도체 Gd1Ba2Cu3O9-x의 구조에 관한 연구 (Structural Study of 90K Superconductor Gd1Ba2Cu3O9-x)

  • 이성익;권기정;이기봉;박병규;박병학;신현준
    • 한국세라믹학회지
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    • 제25권6호
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    • pp.577-584
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    • 1988
  • Gd1Ba2Cu3O9-x has been found to be a high Tc superconductor with a transitiion onset at 91K and zero resistance achieved at 87K. The structure as determined from x-ray diffraction is orthorhombic, with lattice constants b=3.842$\pm$0.002$\AA$, b=3.895$\pm$0.003$\AA$, and c=11.684$\pm$0.007$\AA$. The structural similarities between the Gd1Ba2Cu3O9-x compound and the well-studied single phase perovskite, Y1Ba2Cu3O9-x are discussed. A correlation between the observed x-ray spectrum and the effect of oxygen deficiencies in several of the unit cell planes is also discussed.

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SiO2 나노 입자로 코팅된 형광체 분말을 이용한 Gd2O3 : (Li, Eu) 필름 제조 (Synthesis of Gd2O3 : (Li, Eu) Films using Phosphor Powders Coated with SiO2 Nano Particles)

  • 박중철
    • 대한화학회지
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    • 제47권6호
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    • pp.619-624
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    • 2003
  • 졸겔법을 사용하여 $Gd_{1.9-x}Li_{0.1}Eu_xO_3$(x=0.02, 0.05, 0.08, 0.12) 형광체 분말을 합성하였다. 형광체 입자의 표면을 나노 크기의 $SiO_2$(입자크기${\thickapprox}30 nm$)로 코팅한 후 스핀-코팅법으로 유리 기판에 형광체 막을 제작하였다. 유리의 연화온도인 $700^{\circ}C$ 부근에서 융착 되는 $SiO_2$ 나노 입자들에 의해 $Gd_{1.9-x}Li_{0.1}Eu_xO_3$ 입자들은 유리 기판 표면 위에 강하게 융착 되었다(>9H, 연필 경도계). 본 연구에서 채택한, 형광체 막을 제조하는 간단하고 비용이 저렴한 이 방법은 디스플레이장치의 응용 분야에 적용될 수 있을 것으로 생각한다.

$Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ 초미세결정립합금의 자기특성 (Magnetic Propertes of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ Nanocrystalline Alloys)

  • 조용수;김만중;천정남;김택기;박우식;김윤배
    • 한국자기학회지
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    • 제5권5호
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    • pp.880-894
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    • 1995
  • B의 함유량을 6 at% 고정하고 Nd함유량을 3~5 at%로 변화시킨 $\alpha$-Fe기 Nd-Fe-B 합금의 자기특성이 조사 되었다. 급속응고법으로 제조된 $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ 비정질합금은 열처리에 의하여 초미세결정립으로 결정화하며, Nd의 함유량에 따라 잔류자화 및 보자력이 변한다. x=3의 경우 최적열처리조건에서 $\alpha$-Fe(Co) 부피분율의 증가로 잔류자 화는 증가하나, 보자력은 감소한다. 그러나 Nd 함유량의 증가는 $Nd_{2}{(Fe,\;Co)}_{14}B$ 부피분율의 증가로 인하여 잔류자화는 감소하나 보자력은 향상된다. $640^{\circ}C$, 10 min 열처리조건에서 $Nd_{5}{(Fe_{0.9}Co_{0.1})}_{85}B_{6}Nb_{3}Cu_{1}$의 결정립크기는 약 20 nm이며, 잔류자화, 보자력 및 최대에너지적 은 각각 1.35 T, 219 kA/m (2.75 kOe) 및 $129\;kJ/m^{3}$ (16.2 MGOe)으로 가장 우수하다.

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A Study on Photoreceptor by Using the Effect of Additives

  • 유진;김영순;유국현
    • Bulletin of the Korean Chemical Society
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    • 제22권7호
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    • pp.709-715
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    • 2001
  • We have been studied photosensitization mechanism's additive effect, of perylene 3,4,9,10-tetracarboxyl-diimide and X-phthalocyanine (charge generation materials), using the photochemical and photoelectrochemical approach. It was found that the photoreceptor on the excited state reacts with metal oxide, which creates the charge transfer on the interface of SnO2/electrolyte. In the electrode (X5P1) made of five X-phthalocyanine and single perylene 3,4,9,10-tetracarboxyldiimide layers, the cathodic photocurrent of X-phthalocyanine in the 400-600 nm region was increased by the addition of perylene 3,4,9,10-tetracarboxyldiimide. The maximum wavelength of fluorescence of perylene 3,4,9,10-tetracarboxyldiimide showed no dependence on the temperature. The addition of 4-dibenzylamino-2-methylbenzaldehyde diphenylhydrazone known as charge transport material was represented as decreasing photocurrent for X-phthalocyanine and perylene 3,4,9,10-tetracarboxyldiimide, respectively. In the electrode (X1P1) made of single X-phthalocyanine and single perylene 3,4,9,10-tetracarboxyldiimide layers, an anodic photocurrent of about 10.5 nA was generated by addition of hydroquinone at 550 nm. And the characteristic of photoinduced discharge was shown to decrease by a factor of 5 and the speed of dark decay was increased by a factor of 1.2.

한국산 민물 새우류에 관한 생물학적 연구 2. Palaemon modestua의 생태 (BIOLOGICAL STUDIES ON THE FRESH-WATER SHRIMPS IN KOREA 2. The Ecology of Palaemon modestua)

  • 정경석
    • 한국수산과학회지
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    • 제3권2호
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    • pp.110-116
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    • 1970
  • 낙동강산 민물 새우, Palaemon modestua의 성장, 산란 및 성비등의 생태에 관해 조사한 결과는 아래와 같다. 1. 산란기간은 $4\~9$월 사이이며, 주 산란기는 7월이다. 2. 만 1년만에 생식 행위를 하며, 산란 후 10월 말경까지는 대부분 사멸하는 것 같다. 3. 성비 (수컷/암컷$\times$100)는 일평균 $78.5\%(44.2\~95.5\%)$이며, 4월과 9월에는 $44.2\%,\;44.9\%$로 하락하였다. 4. 포란 개체의 최소의 크기는 체장 29mm, 체중 0.5gr, 갑장 7mm 내외였다. 5. 포란 미수의 출현이 가장 많은 체장은 $31\~41mm$ 내외이었다. 6. 체장(X)과 난수(Y)의 회귀 관계식은 $$Y=0.0000203937X^{3.5668}$$이었다. 7. 체장(X)과 체중(Y)의 회귀 관계식은 $$female\;:\;Y=0.099801X^{2.85407}$$, $$male\;:\;Y=0.004198X^{3.40614}$$이었다. 8. 두흉 갑장(X)과 체중(Y)의 회귀 관계식은 $$female\;:\;Y=5.56008X^{2.25503}$$, $$male\;:\;Y=5.09541X^{2.28875}$$이었다. 9. 두흉 갑장(X)과 체장(Y)의 회귀 관계식은 female : Y=5.07540+3.36057X, male : Y=4.90514+3.47791X이었다.

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Perovskite-Like Strontium Titanium Zirconium Oxide Solid Solutions Prepared at Atmospheric Pressure

  • Choy, Jin-Ho;Kim, Ha-Suck;Kwon, Young-Uk;Kim Chong Hee
    • Bulletin of the Korean Chemical Society
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    • 제6권6호
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    • pp.344-347
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    • 1985
  • Perovskite type oxides of $SrTiO_3,SrZrO_3,and\;SrTi_{1-x}Zr_xO_3$ have been systematically synthesized at $1250^{\circ}C$and $1550^{\circ}C$ with specimens containing additions of up to x=0.9 of zirconium by solid state reactions and characterized by X-ray diffraction. X-ray diffraction studies showed that the compound $SrTi_{1-x}Zr_xO_3$ has cubic structure. The lattice paramters of $SrTi_{1-x}Zr_xO_3$ solid solutions obey the Vegard's law and fairly large increase in volume can acompany the formation of this solution with increasing Zr content(X). Assuming the lattice constants of perovskite type compounds $A(B_{1-x}B'_x)O_3$where $B_{1-x}B'_x$ is $Ti_{1-x}Zr_x$, to be a linear function of the ionic radii of B and B' ions, the disordered ion pair of $Ti^{4+}$and $Zr^{4+}$ was verified from the lattice constants of a series compounds varying x=0,0.05, 0.25, 0.5, 0.75, 0.9, and 1.0 with known isovalent pairs.

Electrochemical Performance and Cr Tolerance in a La1-xBaxCo0.9Fe0.1O3-δ (x = 0.3, 0.4 and 0.5) Cathode for Solid Oxide Fuel Cells

  • Choe, Yeong-Ju;Hwang, Hae-Jin
    • 한국세라믹학회지
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    • 제52권5호
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    • pp.308-314
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    • 2015
  • The electrochemical performance and Cr poisoning behavior of $La_{1-x}Ba_xCo_{0.9}Fe_{0.1}O_{3-{\delta}}$ (LBCF, x = 0.3, 0.4, 0.5) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathodes were investigated for solid oxide fuel cells (SOFCs). The polarization resistance of the LBCF/GDC/LBCF symmetrical cell was found to decrease with increasing Ba content (x value). This phenomenon might be associated with the high oxygen vacancy concentration in the LBCF sample, with x = 0.5. In addition, there was no chromium poisoning in the LBCF cathode. On the other hand, the polarization resistance of the LSCF cathode was found to significantly increase after exposure to gaseous chromium species; it appears that this result stemmed from the formation of $SrCrO_4$ phase. Therefore, it can be expected that LBCF can be a durable potential cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFC).

NONLINEAR VARIATIONAL INEQUALITIES AND FIXED POINT THEOREMS

  • Park, Sehie;Kim, Ilhyung
    • 대한수학회보
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    • 제26권2호
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    • pp.139-149
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    • 1989
  • pp.Hartman and G. Stampacchia [6] proved the following theorem in 1966: If f:X.rarw. $R^{n}$ is a continuous map on a compact convex subset X of $R^{n}$ , then there exists $x_{0}$ ..mem.X such that $x_{0}$ , $x_{0}$ -x>.geq.0 for all x.mem.X. This remarkable result has been investigated and generalized by F.E. Browder [1], [2], W. Takahashi [9], S. Park [8] and others. For example, Browder extended this theorem to a map f defined on a compact convex subser X of a topological vector space E into the dual space $E^{*}$; see [2, Theorem 2]. And Takahashi extended Browder's theorem to closed convex sets in topological vector space; see [9, Theorem 3]. In Section 2, we obtain some variational inequalities, especially, generalizations of Browder's and Takahashi's theorems. The generalization of Browder's is an earlier result of the first author [8]. In Section 3, using Theorem 1, we improve and extend some known fixed pint theorems. Theorems 4 and 8 improve Takahashi's results [9, Theorems 5 and 9], respectively. Theorem 4 extends the first author's fixed point theorem [8, Theorem 8] (Theorem 5 in this paper) which is a generalization of Browder [1, Theroem 1]. Theorem 8 extends Theorem 9 which is a generalization of Browder [2, Theorem 3]. Finally, in Section 4, we obtain variational inequalities for multivalued maps by using Theorem 1. We improve Takahashi's results [9, Theorems 21 and 22] which are generalization of Browder [2, Theorem 6] and the Kakutani fixed point theorem [7], respectively.ani fixed point theorem [7], respectively.

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소결온도에 따른 (l-x)$TiTe_3O_{8}$-x$MgTiO_3$ 세라믹스의 마이크로파 유전 특성 (Microwave Dielectric Properties of the (l-x)$TiTe_3O_{8}$-x$MgTiO_3$ Ceramics with Sintering Temperature)

  • 최의선;김재식;이문기;류기원;이영희
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권9호
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    • pp.459-463
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    • 2004
  • In this study, the (l-x)$TiTe_3O_{8}$-x$MgTiO_3$ ceramics were investigated to obtain the improved dielectric properties of a high temperature stability and a sintering temperature of less than $900^{\circ}C$ which was necessary for the LTCC. According to the X-ray diffraction patterns of the (l-x)$TiTe_3O_{8}$-x$MgTiO_3$(x=0∼1) ceramics, the columbite structure of $TiTe_3O_{8}$ and ilmenite structure of $MgTiO_3$ were coexisted. Increasing the $MgTiO_3$ mole ratio(x), the density and dielectric constant were decreased and temperature coefficient of resonant frequency was moved to the negative direction and the quality factor was increased. In the case of the 0.6$TiTe_3O_{8}$-0.4$MgTiO_3$ ceramics sintered at $830^{\circ}C$ for 3hr., the microwave dielectric properties were $\varepsilon_{\gamma}$=29.3, Q${\times}$$f_{\gamma}$=39.600GHz and $\tau$$_{f}$=+9.3ppm/$^{\circ}C$.