• Title/Summary/Keyword: $Zn^{+2}/Fe^{+2}$ 이온

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Characterization of Cation Exchange and Cesium Selectivity of Synthetic Beta-Dicalcium Silicate Hydrate

  • El-Korashy, S.A.
    • Journal of the Korean Chemical Society
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    • v.46 no.6
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    • pp.515-522
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    • 2002
  • Solid beta-dicalcium silicate hydrate $(\beta-C_2SH)$ synthesized under hydrothermal conditions at $240^{\circ}C$ and Ca/Si=2 molar ratio shows cation exchange properties towards divalent metal cations such as Fe, Cu, Zn, Cd, or Pb. The ability of metal cation uptake by the solid was found to be in the order: $Fe^{2+}$$Cu^{2+}$$Zn^{2+}$$Cd^{2+}$ = $Pb^{2+}$. Cesium selectivity of the solid was demonstrated in the presence of univalent cation such as $Li^+$, $Na^+$ and $K^+$ and divalent cations such as $Ca^{2+}$, $Mg^{2+}$ and $Ba^{2+}$, which are one hundred times more concentrated than the $Cs^+$. The uptake of $Cs^+$ is maximum in the presence of $Mg^{2+}$ whereas it is minimum in the presence of $K^+$. The different affinities of ${\beta}-C_2SH$ towards divalent metal cations can be used for the separation of those ions. Due to its selectivity for cesium it can be used in partitioning of radioactive Cs+ from nuclear wastes containing numerous cations. The mechanism of the metal cation exchange and cesium selectivity reactions by the solid is studied.

Property of Mn-Zn Ferrite for Planar Core (평면코어용 Mn-Zn 페라이트의 물성)

  • Kim, Jong-Ryung;Oh, Young-Woo;Lee, Tae-Won;Kim, Hyun-Sik;Lee, Hae-Yon;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05a
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    • pp.96-100
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    • 2003
  • 평면형 자심재료용으로 응용하기 위한 Mn-Zn 페라이트에서 저손실 조성의 전자기적 특성과 분위기 조건에 따른 특성변화를 관찰하였다. $Fe_{2}O_{3}$ : MnO : ZnO 의 물비가 53 : 36 : 11 일 때, 가장 우수한 특성을 나타내었으며, $SiO_{2}$와 CaO는 입계 저항층 형성을 통한 손실은 감소시키고, 이로 인해 성능지수는 증가하여 100kHz ~ 200kHz 범위에서 최대값을 나타내어 전자기적 효율이 극대화되었다. 산소분압의 제어는 승온과정부터 산소분압을 제어시켜주어야만 Zn-loss 현상의 증가와 $Fe^{2+}$이온 농도의 감소 및 $Fe^{2+}-Fe^{3+}$ 이온간의 호핑(hoping)현상 등에 의한 손실을 최소화 할 수 있으며, 높은 투자율을 얻을 수 있었다. 그리고 소결 또는 냉각 중 평형 산소분압이 유지되지 못하면 다량의 결함이 출현하게 되고, 특히 $600^{\circ}C$이하에서 스피넬 상의 분해-산화반응이 일어나면서 미세구조 상에 결함으로 남게 되어 전자기적 특성이 저하되었다.

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The Treatment of Heavy Metal-cyanide Complexes Wastewater by Zn$^{+2}$/Fe$^{+2}$ Ion and Coprecipitation in Practical Plant (II) (아연백법 및 공침공정을 이용한 복합 중금속-시안착염 폐수의 현장처리(II))

  • Lee, Jong-Cheul;Lee, Young-Man;Kang, Ik-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.5
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    • pp.524-533
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    • 2008
  • Industrial wastewater generated in the electroplating and metal finishing industries typically contain toxic free and complex metal cyanide with various heavy metals. Alkaline chlorination, the normal treatment method destroys only free cyanide, not complex metal cyanide. A novel treatment method has been developed which destroys both free and complex metal cyanide as compared with Practical Plant(I). Prior to the removal of complex metal cyanide by Fe/Zn coprecipitation and removal of others(Cu, Ni), Chromium is reduced from the hexavalent to the trivalent form by Sodium bisulfite(NaHSO$_3$), followed by alkaline-chlorination for the cyanide destruction. The maximum removal efficiency of chromium by reduction was found to be 99.92% under pH 2.0, ORP 250 mV for 0.5 hours. The removal efficiency of complex metal cyanide was max. 98.24%(residual CN: 4.50 mg/L) in pH 9.5, 240 rpm with 3.0 $\times$ 10$^{-4}$ mol of FeSO$_4$/ZnCl$_2$ for 0.5 hours. The removal efficiency of Cu, Ni using both hydroxide and sulfide precipitation was found to be max. 99.9% as Cu in 3.0 mol of Na$_2$S and 93.86% as Ni in 4.0 mol of Na$_2$S under pH 9.0$\sim$10.0, 240 rpm for 0.5 hours. The concentration of residual CN by alkaline-chlorination was 0.21 mg/L(removal efficiencies: 95.33%) under the following conditions; 1st Oxidation : pH 10.0, ORP 350 mV, reaction time 0.5 hours, 2nd Oxidation : pH 8.0, ORP 650 mV, reaction time 0.5 hours. It is important to note that the removal of free and complex metal cyanide from the electroplating wastewater should be employed by chromium reduction, Fe/Zn coprecipitation and, sulfide precipitation, followed by alkaline-chlorination for the Korean permissible limit of wastewater discharge, where the better results could be found as compared to the preceding paper as indicated in practical treatment(I).

Problem Analysis and Improvement of an Experiment on Reactivityof Metals in ChemistryⅠ (화학Ⅰ 금속의 반응성 실험의 문제점 분석 및 개선방안)

  • Seong, Suk-kyoung;Choi, Chui-Im;Jeong, Dae-Hong
    • Journal of the Korean Chemical Society
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    • v.53 no.3
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    • pp.368-376
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    • 2009
  • In this study we investigated and tried to understand problems monitored in an experiment on reactivity of metals in chemistry I. Three problems were discussed. First, the reason that aluminium plate does not react with other metal ions such as zinc, iron and copper was studied and the way to overcome this problem was suggested. Second, the reason that the bubbles were generated when FeS$O_4$(aq) and Zn(s) react was discussed. Third, the precipitates which appeared in the reaction of FeS$O_4$(aq) and Zn(s) were identified. Through reference study and experimental investigation, we could reach the following results. First, aluminium could not react with other metal ions due to the surface oxide layer that is formed very fast and prevents aluminium from reacting with metal ions in solution. This problem could be overcome by allowing a competing reaction of acid and aluminium during the reaction of aluminium and metal ions. Second, the observed bubbles were identified to be hydrogen gas, produced by the reaction between metals and hydronium ion in the solution. Third, black precipitates that were produced on the surface of zinc plate and exhibited magnetic property were characterized to be $Fe_3O_4$(s), and brown precipitates that were produced in the solution phase were to be $Fe_2O_3$(s) by the analysis of X-ray photoelectron spectra.

A basic study on the recovery of Ni, Cu, Fe, Zn ions from wastewater with the spent catalyst (폐산화철촉매에 의한 폐수중 Ni, Cu, Fe, Zn이온 회수에 관한 기초연구)

  • Lee Hyo Sook;Oh Yeung Soon;Lee Woo Chul
    • Resources Recycling
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    • v.13 no.2
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    • pp.3-8
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    • 2004
  • A basic study on the recovery of heavy metals such as Zn, Ni, Cu and Fe ions from wastewater was carried out with the spent iron oxide catalyst, which was used in the Styrene Monomer(SM) production company. The heavy metals could be recovered more than 98% with the spent iron oxide catalyst. The alkaline components of the spent catalyst could be precipitated the metal ions of the wastewater as metal hydroxides at the higher pH 10.6 in Ni, pH 8.0 in Cu, pH 6.5 in Fe, pH 8.5 in Zn. But the metal ions are adsorbed physically on the surface of the spent catalyst in the range of the pH of the metal hydroxides and pH 3.0, which is the isoelectric point of the iron oxide catalyst.

Hydrothermal Synthesis and Transition Metal Cations Exchange Characterization of Titanium and [Titanium+Alkali Metals] Substituted-11Å Tobermorites

  • El-Korashy, S.A.
    • Journal of the Korean Chemical Society
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    • v.48 no.2
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    • pp.129-136
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    • 2004
  • Titanium and [titanium+Na(K)] substituted 11${\AA}$ tobermorites solids synthesized under hydrothermal conditions at 180$^{\circ}C$ exhibit cation exchange properties toward heavy transition metal cations, such as Fe$^{2+},\;Zn^{2+},\;Cd^{2+}\;and/or\;Pb^{2+}$. The amount of heavy metal cations taken up by these solids was found in the order: Fe$^{2+}>Zn^{2+}>Cd^{2+}>Pb^{2+}$, and reached maximum at 10% [Ti+K]-substituted tobermorite. The total cation exchange capacity of the 10% Ti+Na (K) - substituted tobermorites synthesized here range from 71 to 89 meq/100 g, and 50-56 meq/100g for Ti-substituted only. Results indicated that 10% [Ti+K] substitution exhibit cation exchange capacity more 2.4 times than the unsubstituted-tobermorite. This is due to the increase of the number of active sites on the exchangers. The incorporation of Ti and/or [Ti+Na(K)] in the lattice structure of synthesized tobermorites is due to exchange of Ti$^{4+}{\Leftrightarrow}2Ca^{2+}\;and/or\;Ti^{4+}+2Na^+(K^+){\Leftrightarrow}3Ca^{2+}$, respectively. The mechanism of Ti and [Ti+Na(K)] incorporations in the crystal lattice of the solids during synthesis and the heavy metal cations uptaken by these solids is studied.

Behaviour of Magnetic Loss as a function of Process in Mn-Zn Ferrite (공정에 따른 Mn-Zn 페라이트의 자성손실 거동)

  • Kim, Jong-Ryung;Oh, Young-Woo;An, Yong-Woon;Kim, Hyun-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.541-545
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    • 2003
  • Mn-Zn 페라이트의 자심재료가 전자기 부품용 응용될 때, 소형화와 고효율화를 이루기 위한 공정변수에 따른 전자기적 특성변화를 고찰하였다. ZnO 의 몰비가 11 mole일 때, 가장 우수한 특성을 나타내었으며, $SiO_2$와 CaO는 입계 저항층 형성을 통한 손실을 감소시키고, 이로 인해 성능지수는 증가하여 $100\;kHz\;{\sim}\;200\;kHz$ 범위에서 최대값을 나타내어 전자기적 효율이 극대화되었다. 산소분압의 제어는 승온과정부터 산소분압을 제어시켜주어야만 Zn-loss 현상의 증가와 $Fe^{2+}$ 이온 농도의 감소 및 $Fe^{2+}-\;Fe^{3+}$ 이온간의 호핑(hoping)현상 등에 의한 손실을 최소화할 수 있으며, 높은 투자율을 얻을 수 있었다. 그리고 소결 또는 냉각 중 평형 산소분압이 유지되지 못하면 다량의 결함이 출현하게 되고, 특히 $600^{\circ}C$ 이하에서 스피넬 상의 분해-산화반응이 일어나면서 미세구조 상에 결함으로 남게 되어 전자기적 특성이 저하되었다.

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Biosorption of Metal Ions by Seaweed Alginate, Polyguluronate, and Polymannuronate (알긴산, 폴리글루론산 및 폴리만뉴론산에 의한 금속이온의 흡착)

  • Jung, Dae-Young;Son, Chang-Woo;Kim, Sung-Koo;Kim, Yi-Joon;Chung, Chung-Han;Lee, Jin-Woo
    • Journal of Life Science
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    • v.19 no.5
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    • pp.553-560
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    • 2009
  • Based on $P_{1/2}$ values, relative affinities of alginate, polyguluronate, and polymannuronate for metal ions are, in order, as follows; 1) seaweed alginate: $Cu^{2+}$ > $Cd^{2+}$ > $Pb^{2+}$ > $Fe^{3+}$ >> $Zn^{2+}$ > $Sr^{2+}$ > $Ca^{2+}$ > $Co^{2+}$ >> $Cr^{6+}$ > $Mn^{2+}$ >> $Hg^{2+}$, $Mg^{2+}$, $Rb^+$, 2) polyguluronate: $Cd^{2+}$ > $Cu^{2+}$ > $Pb^{2+}$ > $Fe^{3+}$ >> $Ca^{2+}$ > $Sr^{2+}$, $Zn^{2+}$, $Co^{2+}$ >> $Mn^{2+}$ > $Cr^{6+}$ >> $Hg^{2+}$, $Mg^{2+}$, $Rb^+$, and 3) polymannuronate: $Cd^{2+}$, $Cu^{2+}$ > $Fe^{3+}$ > $Pb^{2+}$ > $Ca^{2+}$ > $Zn^{2+}$ > $Sr^{2+}$ > $Co^{2+}$ > $Cr^{6+}$ >> $Mn^{2+}$ >> $Hg^{2+}$, $Mg^{2+}$, $Rb^+$. Amounts of the metal ions, $Cd^{2+}$, $Cu^{2+}$, $Fe^{3+}$, $Pb^{2+}$, and $Zn^{2+}$, bound to 1 g of seaweed alginate, were measured as $363.5{\pm}45.0$, $226.3{\pm}9.2$, $1,299.4{\pm}$81.3, 500.7${\pm}$27.7, and 165.9${\pm}$11.4 mg, respectively. Amounts of the metal ions, $Cd^{2+}$, $Cu^{2+}$, $Fe^{3+}$, $Pb^{2+}$, and $Zn^{2+}$, bound to 1g of polyguluronate, were 354.5${\pm}$26.5, 177.6${\pm}$8.7, 1,288.6${\pm}$60.1, 424.0${\pm}$7.4, and 140.2${\pm}$28.5 mg, respectively, whereas those bound to 1 g of polymannuronate were 329.0${\pm}$10.3, 206.9${\pm}$1.9, 1,635.6${\pm}$11.1, 419.8${\pm}$12.6, and 251.0${\pm}$49.1 mg, respectively. Due to its higher solubility than alginate and higher affinity for metal ions than polyguluronate, polymannuronate can be used for bioremediation or biosorption of toxic and/or noble metal ions.

Reversed-Phase Liquid Chromatographic Separation of Metal Ions by Chelate Formation with 1-(2-Pyridylazo)-2-Naphthol (역상 액체크로마토그래피에 의한 1-(2-Pyridylazo)-2-Naphthol과 킬레이트를 형성하는 금속이온의 분리)

  • Kang, Sam Woo;Park, Sun Ja
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.197-202
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    • 1998
  • 1-(2-Pyridylazo)-2-Naphthol (PAN) has been widely used as a spectrophotometric reagent and metallochromic indicator for many metal ions. In this work, the chelate reagent of PAN was used as mobile phase additive for the separation of metal ions by reversed phase chromatography. Metal ions could be detected by monitoring the effluent at 570 nm with spectrophotometric detector. In order to investigate retention behaviors of the metal ions, the chromatograms and capacity factors were obtained as the variation of pH, ionic strength and composition of organic modifier in mobile phase. Under the obtained optimum conditions, the mixtures of Fe(III), Ni(II), Cu(II), Zn(II) and Co(II) could be separated successfully and the calibration curves under the recommended conditions showed an excellent linearity. The detection limits(S/N) were feasible at the nanogram level.

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A $M\"{o}ssbauer$ Spectroscopic Sthdy of Ion Distribution in $Ba_{2}{(Co,Zn)}_{2}Fe_{12}O_{22}$ ($M\"{o}ssbauer$ 분광 분석에 의한 $Ba_{2}{(Co,Zn)}_{2}Fe_{12}O_{22}$ 내의 이온 분포 연구)

  • 최상준;권순주
    • Journal of the Korean Magnetics Society
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    • v.6 no.2
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    • pp.73-79
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    • 1996
  • Y-type hexagonal ferrites$(Ba_{2}Me_{2}Fe_{12}O_{22}:Me=transition metal)$ have promising electromagnetic properties in GHz range. Co and Zn are good candidates for the transition metal. To understand their role on the properties, it is thus necessary to study the ion(s) distribution in that complex Y-type hexagonal ferrite structure. The authors report Mossbauer spectroscopic results from very reliable samples, which has been extensively characterized by chemical analysis, Rietveld analysis of X-ray diffraction patterns, and magnetic property measurements. Analyzing two samples, $Co_{2}Y$ and $Co_{1.6}Zn_{0.4}Y$, conclusions are made as follow: (1) Co ions prefer the tetrahedral interstitial sites in the S-block $(6c_{IV})$ and the octahedral sites $(18h_{VI})$ at the interface of S- and T-block. (2) Partial substitution of Co with Zn (within the experimental range) does not disturb the Fe distribution.

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