• Journal of the Korean Wood Science and Technology
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• v.46 no.5
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• pp.449-470
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• 2018

A review of research trends on wood surface protection for exterior use obtained the following conclusions: It has been reported that inorganic compounds such as chrome and copper used as wood preservatives can protect wood from weathering. It has been shown that precoating with hydrophobic substances such as wax and oil, UV absorbers, and HALS (Hindered Amine Light Stabilizers) enhances weathering resistance on the surface of ACQ-treated wood. Opaque coatings of paint/stains and semitransparent stains on the surface of preservative treated wood can increase the synergistic effects on prevention of weathering deterioration. Also the need for repainting periodically for the protection of the preservative treated wood surface has also been suggested. ZnO or $TiO_2$ of fine particles, metal ions such as Co, Cr, Fe, Mn, Ni and Ti, and UV absorbers such as tris-resorcinol triazine derivatives, triazine and benzotriazole were introduced as additives for preventing UV in the transparent coating on wood. Several reports showed that chemical modification such as methylation, acetylation, or alkylations have made some increases the effects of preventing weathering with the increasing weight gain of chemical formulas. In heat-treated wood, there were various contradictory reports on the resistance of weathering, and there were some other reports emphasizing the necessity of painting with UV resistance, which leads to the necessity of more advanced studies.

• Journal of the Korean earth science society
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• v.25 no.6
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• pp.428-442
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• 2004

Dustfall samples were collected by the modified American dust jar (bulk type) at 5 sampling sites in the Nakdong river area from lune 2002 to May 2003. Nineteen chemical species (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, V, Zn, $Cl^-$, $NO_3^-$, $SO_4^{2-}$, and $NH_4^+$) were analyzed via the combination of ICP/AES, AAS, IC and UV. The purposes of this study were to qualitatively evaluate the chemical composition of dustfalls by examining their regional and seasonal distribution patterns. Computation of the enrichment factor showed that well-defined anthropogenic sources, particularly in Pb were found in the order Gamjeondong (industrial area), Wondong, Silla University, Samrangiin and Mulgum. The seasonal mean of soil contribution showed its highest value (16.3%) during the winter with an annual mean of 11.2%. The concentration ratio of [$SO_4^{2-}/NO_3^-$] was found to be highest (5.12) during the winter, while the lowest ratio value (3.30) was seen during the all. fall, Also regional equivalent ratios of [$SO_4^{2-}/NO_3^-$] were found in the order: Silla University (6.78), Gamjeondong (4.98), Mulgum (3.95), Wondong (3.85), and Samrangjin (2.87). Seasonal distribution of water soluble components for total dustfall were found in the order: spring (71.6%), summer (61.2%), fall (49.2%) and winter (48.6%) with a mean ratio of 57.6%. Regional contribution of sea salts of water soluble ions were found in the order: Silla university (34.5%), Gamjeondong (28.3%), Wondong (17.3%), Samrangiin (17.2%) and Mulgum (13.8%), the total mean contribution rate was 22.1%. As for the chemical composition of dustftll on the lower Nakdong river, there is a decreased influence of sea salt and artificial anthropogenic sources and increased influence of soil particle inland. Also, the total amount of deposition on the lower Nakdong river has decreased, with the river's surface serving as a confounding factor in resuspending dusts.

• Microbiology and Biotechnology Letters
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• v.17 no.6
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• pp.580-586
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• 1989

Penicillium sp. CB-20 was selected for strong polygalacturonase activity among various strains of molds found in soil. The optimum pH for the enzyme activity was 5.0 and optimum temperature was 4$0^{\circ}C$. The enzyme was relatively stable in acidic condition and unstable by heat treatment. The activation energy, Km and V$_{max}$ for the polygalacturonase were 2.499 Kcal/mol, 2.13$\times$10$^{-2}$mol/l, and 104.17 $\mu$mol/min. The activity of polygalacturonase was inhibited by Ag$^{+}$, Cu$^{++}$, Pb$^{++}$, Fe$^{+++}$, $Ca^{++}$, Na$^+$, Mn$^{++}$. The enzyme can be inactivated by the treatment ethylenediamintetra acetic acid, 2,4-dinitrophenol and $H_2O$$_2$. The results indicate the possible involvement of histidine, chelate and terminal amino group as active site. The enzyme was endo-type polygalacturonase.

• Analytical Science and Technology
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• v.31 no.6
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• pp.240-246
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• 2018

The present study analyzed standard samples of three types of aluminum matrix certified reference materials (CRM) using GD-MS. Calibration curves were constructed for 13 elements (Mg, Si, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Sn, and Pb), with the slope representing the relative sensitivity factor (RSF). The x- and y-axes of the calibration curve represented ion beam ratio (IBR) and the authenticated value of the standard sample, respectively. In order to evaluate precision and linearity of the calibration curve, RSD and the coefficient of determination were calculated. Curve RSD for every element reflected high precision (within 10 %). For most elements, the coefficient of determination was ${\geq}0.99$, indicating excellent linearity. However, vanadium, nickel, and gallium curves exhibited relatively low linearity (0.90~0.95), likely due to their narrow concentration ranges. Standard RSF was calculated using the slope of the curve generated for three types of CRM. Despite vanadium, nickel, and gallium exhibiting low coefficients of determination, their standard RSF resembled that of the three types of CRM. Therefore, the RSF method may be used for element quantitation. Standard iron matrix samples were analyzed to verify the applicability of the aluminum matrix standard RSF, as well as to calculate the RSD-estimated error of the measured value relative to the actual standard value. Six elements (Al, Si, V, Cr, Mn, and Ni) exhibited an RSD of approximately 30 %, while the RSD of Cu was 77 %. In general, Cu isotopes are subject to interference: $^{63}Cu$ to $^{54}Fe^{2+}-^{36}Ar$ and $^{65}Cu$ to $^{56}Fe-Al^{3+}$ interference. Thus, the influence of these impurities may have contributed to the high RSD value observed for Cu. To reliably identify copper, the resolution should be set at ${\geq}8000$. However, high resolutions are inappropriate for analyzing trace elements, as it lowers ion permeability. In conclusion, quantitation of even relatively low amounts of six elements (Al, Si, V, Cr, Mn, and Ni) is possible using this method.

• Applied Biological Chemistry
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• v.20 no.1
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• pp.33-42
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• 1977

Asparagine biosynthesis by soybean sprouts grown under the dark conditions has been demonstrated. The amount of free asparagine synthesized in ten day-old soybean sprouts increases to 22.7% on the dry weight base. The effects of nitrogen compounds such as $NH_4Cl,\;(NH_4)_2SO_4$ and urea on asparagine synthesis during the sprouting were examined and the results showed that urea was more effective than other two compounds. Glutamine-dependent asparagine synthetase was partially purified (8.6 folds) through ammonium sulfate fractionation, followed by Sephadex G-150 gel filtration. The enzyme was very labile and required protection by thiol groups or high level of glycerol. The mixture of ATP and $Mg^{++}$ ion also stabilized the enzyme activity. The enzyme utilized glutamine more effectively than ${NH_4}^+$ as an amide donor for the formation of asparagine. The enzyme required L-aspartate (Km=3.1 mM), L-glutamine, ATP and $Mg^{++}$. It showed pH optimum of 7.5 and catalyzed the formation of ${\beta}-aspartyl$ hydroxamate in the presence of L-aspartate, ATP, $Mg^{++}$ and $NH_2OH$ in the reaction mixture.

• Journal of Life Science
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• v.14 no.3
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• pp.525-530
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• 2004

This study has been performed to examine physico-chemical properties and composition of venison in Deer breeds. According the results, moisture content in the venison ranged between 74% and 75%, and there were no significant differences among the breeds, or among the cutting parts. Fat content in the meats was estimated as less than 1% except in loin, protein contents was estimated as more than 22%, and ash content was estimated as more than 1.5%. For the contents of inorganic material in the loin, Fe$^{3+}$ content was higher in Elk than in other breeds, the contents of $Cu^{2+}$, $Mn^{2+}$, $K^{+}$, $Mg^{2+}$ and $Ca^{2+}$were higher in Red deer than in others, and the contents of $Fe^{3+}$, $K^{+}$, and $P^{+}$ were higher in Sika deer than in others. For the contents of inorganic material in the leg, the contents of $Cu^{2+}$, $Zn^{2+}$, $K^{+}$, $Ca^{2+}$ and $Mg^{2+}$ were higher in Elk than in other breeds, the contents of $Fe^{3+}$ and$P^{+}$ were higher in Red deer than in others, and the contents of $Cu^{2+}$ and $Fe^{3+}$were higher in Sika deer than in others. Amino acid contents in the venison alanine, proline, glycine, lycine and histidine were highly contained. and the contents of asparagine, cysteine, isoleucine and threonine were low. For the differences of amino acid contents among the breeds, the level was the higher in Sika deer than those of others. For the fatty acid in loin, the contents of myristic acid, oleic acid and linolenic acid in Sika deer were higher than those of others, the contents of myristic acid, palmitoleic acid, oleic acid and arachidonic acid in Red deer were higher than those of others and in Elk, the contents of palmitic acid and stearic acid were higher than those of others. For the contents of unsaturated fatty acid and polyunsaturated fatty acids, the level was higher in Red deer than those of others. For the fatty acid in leg, the contents of oleic acid, linolenic acid, linolenic acid and arachidonine acid in Sika deer were higher than those of others, the contents of myristic acid, palmitic acid, palmitoleic acid and oleic acid in Red deer were higher than those of others and in Elk, the contents of stearic acid and linolenic acid were higher than those of others. For the contents of saturated fatty acid, the level was lowest in Sika deer. For the contents of unsaturated fatty acid and polyunsaturated fatty acids were respectively highest in Sika deer. Comparing the contents inorganic materials between loin and leg, the concentrations in leg were generally higher than that of loin.n.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.2
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• pp.123-131
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• 1999

To get the basic information for the improvement of the optimum levels of upland soil fertility and fertilizer application, the soil samples in two hundred fifteen site were collected from the major condiment vegetable cultivation areas such as red pepper, garlic and onion fields. Physico-chemical properties of the soil samples were investigated. Soil texture distribution of soil samples in red pepper, garlic and onion cultivation areas was in order of loam (L), sandy loam (SL), silt loam (SiL) and clay loam (CL) (35.4, 31.6, 14.9 and 7.0%, respectively). The average pH of soil in garlic and onion cultivation areas were over pH 6.0, whereas in red pepper was under pH 5.5. The frequency distribution of soil pH in total sampling sites were 58.7% in under pH 6.0 and 21.4% in below pH 5.0, in contrast to 10.3% in over pH 7.0. The organic matter contents were in the range of $20{\sim}30g\;kg^{-1}$, and the onion field soils was a little higher than those in red pepper or garlic. The available phosphate contents were in the range of $719{\sim}746mg\;kg^{-1}$ and were not different among in red pepper, garlic and onion. The frequency distribution of available phosphate in total sampling sites were found 62.8% of above $600mg\;kg^{-1}$, which was over the standard level for upland soil improvement, and then 22.3% was exceeded $1,000mg\;kg^{-1}$, especially. In the exchangeable cations, the K and Ca contents in garlic (1.27 and $9.11cmol\;kg^{-1}$) and onion (1.20 and $8.39cmol\;kg^{-1}$) were higher than in red pepper (0.96 and $5.87cmol\;kg^{-1}$), respectively. The Mg contents in garlic field soils ($2.17cmol\;kg^{-1}$) were higher than those in red pepper and onion (1.51 and $1.80cmol\;kg^{-1}$). This exchangeable K, Ca and Mg contents were higher than the standard level for upland soil improvement. The contents of microelement were ranged in $54.3{\sim}60.1mg\;kg^{-1}$ for Fe, $31.3{\sim}42.3mg\;kg^{-1}$ for Mn, $1.7{\sim}2.3mg\;kg^{-1}$ for Cu and $4.8{\sim}5.5mg\;kg^{-1}$ for Zn, respectively.

• Microbiology and Biotechnology Letters
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• v.17 no.3
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• pp.207-212
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• 1989

Cultural conditions for $\alpha$-D-Glucosidase Inhibitor production from Streptomyces sp. YS-221-B isolated from soil arid identified as Streptomyces flauovirens or a subspecies of it were investigated. When the strain was cultured in a flask containing 2% glucose, 0.3% asparagine, 0.0002% riboflavin, 0.05% $K_2$HPO$_4$, 0.1% MgSO$_4$.7$H_2O$, 0.05% NaCl, pH 8.0 at 3$0^{\circ}C$, maximum production of the inhibitor was obtained after 8-9 days of cultivation. Sugar alcohols such as mannitol, i-inositol, erythritol as carbon sources, asparagine and beef extract as nitrogen sources were favorable for inhibitor production. Among vitamins, riboflavin, p-aminobenzoic acid, pyridoxamine and folic acid promoted the production of inhibitor, but depressed by the addition of hesperidine, and also depressed by cobalt, lithium and ferrous salts.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.133.2-133.2
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• 2010

현재 융융탄산염 연료전지의 공기극으로 다공성의 lithiated NiO를 사용하고 있는데 이 재료의 경우 크게 두 가지의 문제점을 안고 있다. 첫 번째는 Ni이 전해질 내로 용해하는 것이고, 두 번째는 낮은 활성으로 인한 높은 공기극의 분극이다. Ni이 전해질로 용해되는 문제는 Co나 Fe를 코팅하여 공기극 표면에 $Li_x(Ni_yCo_{1-y})1-xO_2$나 $Li_x(Ni_yFe_{1-y})_{1-x}O_2$를 형성시켜 NiO의 전해질 내로 용해되는 것을 억제하는 방법이나 ZnO, MgO, $La_2O_3$ 등의 산화물을 NiO 표면에 코팅하여 전해질과 접촉을 막는 방식으로 해결하는 등 많은 연구가 이루어져 왔다. 하지만 연료극의 비해 상당히 높은 공기극의 분극으로 인해 큰 전압손실이 일어나 용융탄산염 연료전지 성능이 낮아지는 문제의 경우 이를 해결하고자 하는 연구는 상대적으로 많이 진행되지 못한 상태이다. 특히 현재 용융탄산염 연료전지의 장기수명화를 위해 기존의 작동온도인 $650^{\circ}C$ 보다 다소 낮은 온도인 $600{\sim}620^{\circ}C$에서 작동하려는 움직임이 있다. 작동 온도가 내려가면 전해질이 휘발되는 속도가 낮아져 전해질 부족에 따른 운전시간이 줄어드는 문제를 해결할 수 있어 장기 수명화를 위해서는 작동온도를 낮추는 것이 매우 유리하다. 하지만 작동 온도가 내려가면서 양 전극에서 일어나는 전기화학 반응 속도가 느려지기 때문에 각 전극에서의 활성화 분극으로 인한 전압손실은 더욱 커질 수밖에 없다. 특히 연료극의 수소산화반응 속도는 공기극의 산소환원반응에 비해 매우 빠르기 때문에 작동 온도가 내려감에 따라 연료극의 분극이 커지는 것에 비해 공기극의 분극이 급격히 커지게 된다. 따라서 운전온도가 낮아지는 상황에서는 낮은 작동온도에서도 성능감소가 적게 일어나 0.8V 이상 운전(150mA/$cm^2$, 단위전지 기준)이 가능한 공기극의 개발이 매우 필요한 실정이다. 이를 해결하고자 본 연구에서는 고체 산화물 연료전지의 공기극의 재료로 많이 연구되고 있는 혼합전도성 물질의 페로브스카이트 구조의 물질을 기존 NiO 전극에 코팅하여 새로운 공기극을 개발하였다. 페로브스카이트 구조의 물질로 대표적인 LSCF 물질을 사용하였으며 LSCF를 코팅한 공기극을 이용한 단위전지에서 150mA/$cm^2$의 전류를 흘려주었을 때 0.84V의 성능을 1000hr 유지하였다. 이는 기존의 NiO 전극을 사용했을 때보다 15~20mV 높은 값이다. 낮은 작동온도에서도 좋은 성능을 보였는데, 기존의 NiO 전극의 경우 $630^{\circ}C$에서 0.79V의 성능을 보인 반면 LSCF가 코팅된 공기극의 경우 $620^{\circ}C$에서 0.811V의 매우 좋은 성능을 보였다. 이는 LSCF의 산소이온전도성 및 전기전도성이 공기극에서의 분극을 낮추어 성능을 증가시키는 것으로 보인다.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.51 no.3
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• pp.199-203
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• 2006

In the late growth stage of rice plant, the growth declines even though they grow well in early growth stage. This phenomenon is called autumn declining and it often accompanies the infection of Helminthosporium leaf spot disease. This study was carried out to identify the related environmental factors and to establish the integrated control system of Helminthosporium Leaf Spot Disease in rice. The total area of infected paddy field by Helminthosporium leaf spot was 470 ha in 2000 and 1,004 ha in 2001, which occupied about 1% of the total paddy area in Gyeongbuk province, Korea. The ill-drained sandy paddy occupied 50% of the total area of infected paddy fields and followed by sandy paddy (28%). Comparing the content of soil elements between infected and normal paddy, it was clarified that the organic matter content of normal was higher than that of infected paddy and the contents of inorganic elements such as Mn, Fe, Zn and available $SiO_2$ were also higher in normal paddy. The results of comparing the inorganic elements between infected and normal rice plants also showed the same results. The contents of inorganic elements such as MgO, $SiO_2$, Fe, Mn were higher in normal rice plants. Especially highly significant difference of $SiO_2$ content on both soil and rice plants was noticeable.