• Korean Journal of Psychosomatic Medicine
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• v.25 no.2
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• pp.95-100
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• 2017

Objectives : This study was designed for the purpose of the relationship between psychopathology and suicide in North Korean Refugee Adolescents. Methods : The subjects were 104 North Korean Refugee Adolescents. We investigated the The Korean version of the Center for Epidemiologic Studies for Depression, Revised Children's Manifest Anxiety Scale and Rosenberg Self-Esteem Scale. We also investigated the suicide ideation, planning and attempt. The self-report was taken to the North Korean Refugee Adolescents. Results : The Center for Epidemiologic Studies for Depression Score(Z=-4.050, p<0.001), Revised Children's Manifest Anxiety Score(t=-2.757, p<0.01), Rosenberg Self-Seteem Score(Z=-2.328, p<0.05) were significantly associated with the suicide ideation in North Korean Refugee Adolescents. In logistic regression analysis, only The Center for Epidemiologic Studies for Depression Score(p<0.005) expected the suicidal ideation. Conclusions : The management of depression would be helpful to reduce the suicide in North Korean Refugee Adolescents.

• Journal of Environmental Health Sciences
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• v.32 no.2 s.89
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• pp.164-170
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• 2006

Ethylene oxide is a genotoxic carcinogen with widespread uses as industrial chemical intermediate and gaseous sterilant. 2-hydroxyethylated N-terminal valine in Hb is a good biomarker for biological monitoring of ethylene oxide exposure, because of its stability. For measuring the hemoglobin adduct formed by exposure of ethylene oxide, we studied the determination of (N-2-hydroxy-ethyl)valine(HEV) in hemoglobin adduct by using GC/MS. Firstly we synthesized HEV with 2-amino-ethanol and bromoisovaleric acid(BIVA) and confirmed it with GC/MS-FID. Its fragmentations were m/z 116(base ion, M+-45) and m/z 130(M+-31). For measuring HEV with higher sensitivity, we use derivatives which were PFPITH(pentafluorophenylisothiocianate) and TBDMS (tributyldimethylsilylation) by using Edman procedure. Its fragmentation were m/z 425(M+-57), m/z 383(M+-99) and m/z 172(M+-310) by using GC/MS. We did biological monitoring for mice inhalation exposure with 400 ppm ethylene oxide. The concentrations of hemoglobin adduct were $168{\pm}3.8\;and\;512{\pm}04$(nmol g-1 globin) at 0.5 hr/day 400 ppm ethylene oxide inhalation exposure group, and $631{\pm}17\;and\;2265{\pm}9.4$(nmol g-1 globin) at 1.0 hr/day 400 ppm ethylene oxide inhalation exposure for 1 and 4 weeks, respectively. We confirmed that (N-2-hydroxy-ethyl)valine(HEV) of hemoglobin was a good biomarker for biomonitoring of ethylene oxide exposure, and can measured with derivatives such as PFPITH(pentafluorophenylisothiocianate) and TBDMS(tributyldimethylsilylation) by using GC/MS.

• Journal of Magnetics
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• v.18 no.2
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• pp.150-154
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• 2013

$La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ and their hydrides were investigated to obtain large magnetocaloric effects (MCEs) in a wide temperature range, including room temperature, for applications in magnetic refrigents. Since the magnetization change due to the itinerant-electron metamagentic (IEM) transition for $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ becomes larger with increasing z, the isothermal magnetic entropy change ${\Delta}S_m$ and the relative cooling power (RCP) are enhanced. In addition, the Curie temperatrue $T_C$ of $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}$ is increased from 193 to 319 K by hydrogen absorption, with the IEM transition. The maximum value of $-{\Delta}S_m$, $-{\Delta}S{_m}^{max}$, in a magnetic field change of 2 T for $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}H_{1.1}$ is about 23 J/kg K at $T_C$ = 288 K, which is larger than that of 19 J/kg K at $T_C$ = 276 K for $La(Fe_{0.88}Si_{0.12})_{13}H_{1.0}$. The value of RCP = 179 J/kg of the former is also larger than 160 J/kg of the latter. It is concluded that the partial substitution of Nd improves MCEs in a wide temperautre range, including room temperature.

• Journal of the Korean Chemical Society
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• v.50 no.4
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• pp.291-297
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• 2006

The equilibrium structures, relative energies and NBO analyses for the possible conformations and transition states which can exist on the internal rotation of CPDFB and CPCFB molecules have been investigated using DFT and ab initio methods with various basis sets. The interaction between bonding orbital ((C1-C3, C2-C3)) and antibonding orbital (n*(B9) and *(B9-Cl11)) was the main characteristic hyperconjugation in both molecules. In addition, the stabilization energy of CPDFB was 6.63kcal/mol and that of CPCFB was 6.97(E-form)/6.79(Z-form) kcal/mol for each conformation. The rotational barriers by internal rotation of BF2- and BFCl- functional groups were evaluated to be 5.3~6.7kcal/mol and 5.7~6.5kcal/mol respectively, which showed good agreement with the experimental values reported by previous dynamic NMR study. Finally, Z-form was more stable than E-form by 0.2 kcal/mol in CPCFB molecule and therefore Z-form was confirmed as global minimum.

• Bulletin of the Korean Chemical Society
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• v.17 no.9
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• pp.802-807
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• 1996

Second-order rate constants have been measured spectrophotometrically for the reactions of aryl benzoates (X-C6H4CO2C6H4-Y) with EtO-, Z-C6H4O- and Z-C6H4C(Me)=NO- in absolute ethanol at 25.0 ℃. All the reactions have been performed in the presence of excess 18-crown-6 ether in order to eliminate the catalytic effect shown by alkali metal ion. A good Hammett correlation has been obtained with a large ρ- value (-1.96) when σ- (Z) constant was used for the reaction of p-nitrophenyl benzoate (PNPB) with Z-C6H4O-. Surprisingly, the one for the reaction of PNPB with Z-C6H4C(Me)=NO- gives a small but definitely positive ρ- value (＋0.09). However, for reactions of C6H5CO2C6H4-Y with EtO-, correlation of log k with σ- (Y) constant gives very poor Hammett correlation. A significantly improved linearity has been obtained when σ0 (Y) constant was used, indicating that the leaving group departure is little advanced at the TS of the RDS. For reactions of X-C6H4CO2C6H4-4-NO2 with EtO-, C6H5O- and C6H5C(Me)=NO-, correlations of log k with σ (X) constants for all the three nucleophile systems give good linearity with large positive ρ values, e.g. 2.95, 2.81 and 3.06 for EtO-, C6H5O- and C6H5C(Me)=NO-, respectively. The large ρ values clearly suggest that the present reaction proceeds via a stepwise mechanism in which the formation of the addition intermediate is the RDS.

• Journal of Korea Water Resources Association
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• v.47 no.2
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• pp.119-133
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• 2014

The study adopted extended Kalman filter technique in an effort to predict Z-R relationship parameter as a stable value in real-time. Toward this end, a parameter estimation model was established based on extended Kalman filter in consideration of non-linearity of Z-R relationship. A state-space model was established based on a study that was conducted by Adamowski and Muir (1989). Two parameters of Z-R relationship were set as state variables of the state-space model. As a result, a stable model where a divergence of Kalman gain and state variables are not generated was established. It is noteworthy that overestimated or underestimated parameters based on a conventional method were filtered and removed. As application of inappropriate parameters might cause physically unrealistic rain rate estimation, it can be more effective in terms of quantitative precipitation estimation. As a result of estimation on radar rainfall based on parameters predicted with the extended Kalman filter, the mean field bias correction factor turned out to be around 1.0 indicating that there was a minor difference from the gauge rain rate without the mean field bias correction. In addition, it turned out that it was possible to conduct more accurate estimation on radar rainfall compared to the conventional method.

• Journal of the Korean Applied Science and Technology
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• v.40 no.1
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• pp.59-70
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• 2023

This study is a meta-analysis study to comprehensively investigate the effects of flipped learning teaching applied to nursing students in Korea through systematic review. Data collection was conducted by a team of two researchers from November 20 to December 20, 2022. A total of 129 papers were searched through the domestic database, and duplicate papers were removed and the final 9 studies were selected. Flipped learning improved critical thinking disposition of nursing students 0.91(Z=8.36, p<.001), learning self-efficacy 0.35 (Z=2.62, p=.009), self-directed learning ability 0.81(Z=6.53, p<.001), academic achievement 0.60(Z=5.18, p<.001), and self-efficacy 0.66(Z=4.79, p<.001). Based on the results of this study, it was confirmed that flipped learning is an effective teaching method applicable to the domestic nursing education field, and an objective basis was presented for the direction of flipped learning class design. In the future, we suggest repeated studies that comprehensively analyze the effects of various outcome variables that have a positive effect on flipped learning.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2008.05a
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• pp.193-196
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• 2008

Z. Cao had proposed NFRM(new fuzzy reasoning method) which infers in detail using relation matrix. In spite of the small inference rules, it shows good performance than mamdani's fuzzy inference method. In this paper, we propose 2. Cao's fuzzy inference method using learning ability witch is used a gradient descent method in order to improve the performances. Because it is difficult to determine the relation matrix elements by trial and error method which is needed many hours and effort. Simulation results are applied linear and nonlinear system show that the proposed inference method has good performances.

• Journal of the Korean Institute of Navigation
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• v.7 no.1
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• pp.33-62
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• 1983

A navigator on bridge needs to know every kinds of motion characteristics of his vessel at sea. Generally when a vessel is completely built, the shipyard makes turning circle diagrams from the results of turing circle tests made during the sea trials for the reference of the vessel's owner. But referring only the data of a turning circle diagram, an officer on bridge can not figure out his vessel's maneuvering characteristics sufficiently, So nowadays the shipyard often adds Z test to turning circle test for more detail references. In this paper the author made Z and turning circle tests at the rudder angles of 15 and and 35 degress separately and in each of the case made a turrning circle diagram from the results of the turning circle test and the esults numerically calculated from mathematical formula made on the base of the maneuvering indices got from the Z test and compared them each other for the purpose of finding the correlations between them. Followings are concluded from the results. An actual turning circle diagram and a calculated one from the results of the Z test at same rudder angle coincides each other well when the center of the calculated circle is transferred by 1.7B toward the direction of the initial turning perpendicularly to the original course and 0.5L toward the direction in parallel with original course in case of the rudder angle of 35 degrees and 1.2B and 0.3L toward each of the above mentioned directions in case of rudder angle of 15 degrees.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.1
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• pp.72.4-73
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• 2015

Over the last decade, more than 50 quasars have been discovered at redshift about 6 when reionization of the universe occurred. However, most of them are luminous quasars (zAB < 21 mag), implying that such a biased quasar sample, which cannot represent the entire population of quasars at z~6, is not enough to understand the properties of quasars in the early universe. Recently, we have been performing the Infrared Medium-deep Survey (IMS), a moderately wide (120 deg2) and deep (JAB ~ 22.5 - 23 mag) near-infrared imaging survey. Combining this with the optical (ugriz) imaging data from the CFHT Legacy Survey (CFHTLS), we have identified more than 10 faint quasar candidates at z~6 in the IMS field by using multiple color selection criteria. From now on, we will perform spectroscopic confirmations of these faint quasar candidates with IMACS on the Magellan Baade Telescope at Las Campanas Observatory and GMOS on the Gemini South Telescope at Gemini Observatory. The confirmed quasars will be used to constrain the faint-end slope of the quasar luminosity function at z~6 and calculate the ratio of quasar ionizing flux to required flux for reionization of the universe. Moreover, these confirmed quasars will be followed up with near-infrared spectroscopy to determine their black hole masses and Eddington ratios to check the rapidness of their growth.