• Title/Summary/Keyword: $Y_2O_3$ additive

Search Result 532, Processing Time 0.028 seconds

Mechanical Properties of the Pressureless Sintered Al2O3-SiC Composites(2) : Dispersion Effects of SiC Whisker (상압소결한 Al2O3-SiC계 소결체의 기계적 성질(2) : SiC Whisker의 분산효과)

  • 김경수;이홍림
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.6
    • /
    • pp.704-712
    • /
    • 1988
  • In order to investigate the effect of the second phase on Al2O3 matrix, SiC whisker was dispersed in Al2O3 matrix as a second phase over the content range of 5vol% to 20vol%. To this mixture, Y2O3 or TiO2 powder was added as a sintering additive before isostatically pressing and pressureless sintering at 1800-190$0^{\circ}C$ for 90min in N2 atmosphere. With increasing SiC whisker content, relative densities of composites were decreased and the grain growth of Al2O3 was restricted. When Y2O3 was added as a sintering aid the sintering temperature was 180$0^{\circ}C$, the maximum values of flexural strength, hardness and fracture toughness were 537MPa, 12.1GPa, 3.7MPa.m1/2, respectively. However, when the sintering temperature was elevated to 190$0^{\circ}C$, maximum values of flexural strength, hardness and fracture toughness were 453MPa, 17.5GPa, 4.9MPa.m1/2, respectively. Improved mechanical properties are assumed to be attributed to the crack deflection by the second phase SiC whisker and whisker pullout mechanism.

  • PDF

A study on the Radiation Properties of Far-infrared and PTC Effect in the $BaTiO_3$ system by $MnO_2$ Amounts of Additives ($MnO_2$ 첨가량에 따른 $BaTiO_3$계의 PTC효과와 원적외선 방사특성에 관한 연구)

  • Song, Min-Joon;Park, Choon-Bae;Kang, Dou-Youl
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1993.05a
    • /
    • pp.3-5
    • /
    • 1993
  • It is very important that a spectrum of reflectance is in accord wi th a spectrum of absorbance for a effective heating. Therefore. the objective of this study was to achieve a technical composite for material plan which PTC thermistor increase a radiation property of far-infrared and keep a characteristic of R-T The Ceramic speciman studies had the composition $BaTiO_3$ with additive of 1.67 $Al_2O_3$, 3.75 $SiO_2$, 1.25 $TiO_2$, 0.15 $Sb_2O_3$ and 0.00-0.182 $MnO_2$. $MnO_2$ amounts of additives was both increase on the anomalous resistivity-temperature characteristics and high efficiency on the radiation properties bodies of far-infrared. This result shows that specimens produced high emissivity(average 0.8) of far-infrared at 4.5-15$[{\mu}m]$ by measuring a characteristic of IR and R-T.

  • PDF

Performance Evaluation of Cold Recycled Asphalt Mixtures with Asphalt Emulsion and Inorganic Additives (무시멘트 첨가제를 활용한 상온 재활용 아스팔트 혼합물의 성능 분석)

  • Park, Chang Kyu;Kim, kyungsu;Kim, Won Jae;Lee, Hyun Jong
    • International Journal of Highway Engineering
    • /
    • v.19 no.2
    • /
    • pp.137-142
    • /
    • 2017
  • PURPOSES :The objective of this study is to evaluate the performance of asphalt mixtures containing inorganic additive and a high content of reclaimed asphalt pavement (RAP). METHODS : The laboratory tests verified the superior laboratory performance of inorganic additive compared to cement, in cold recycled asphalt mixtures. To investigate the moisture susceptibility of the specimens, tensile strength ratio (TSR) tests were performed. In addition, dynamic modulus test was conducted to evaluate the performance of cold recycled asphalt mixture. RESULTS :It was determined that NaOH solution mixed with $Na_2SiO_3$ in the ratio 75:10 provides optimum performance. Compared to Type B and C counterparts, Type A mixtures consisting of an inorganic additive performed better in the Indirect tensile strength test, tensile strength ratio test, and dynamic modulus test. CONCLUSIONS : The use of inorganic additive enhances the indirect strength and dynamic modulus performance of the asphalt mixture. However, additional experiments are to be conducted to improve the reliability of the result with respect to the effect of inorganic additive.

Large scale synthesis of the geometrically controlled carbon coils using $Al_2O_3$ ceramic boat for the supporting substrate (산화알루미늄 세라믹 보트 기판을 이용한 탄소마이크로 코일의 대량 합성)

  • Kim, Sung-Hoon
    • Journal of the Korean Applied Science and Technology
    • /
    • v.30 no.3
    • /
    • pp.423-430
    • /
    • 2013
  • Carbon coils could be synthesized using $C_2H_2/H_2$ as source gases and $SF_6$ as an incorporated additive gas under thermal chemical vapor deposition (CVD) system. Prior to the carbon coils deposition reaction, two kinds of samples having different combination of Ni catalyst and substrate were employed, namely, a commercially-made $Al_2O_3$ ceramic boat with Ni powders and a commercially-made $Al_2O_3$ substrate with Ni layer. By using a commercially-made $Al_2O_3$ ceramic boat, the synthesis of carbon coils could be enhanced as much as 10 times higher than that of $Al_2O_3$ substrate. Furthermore, the dominant formation of the microsized carbon coils could be obtained by using $Al_2O_3$ ceramic boat. The surface roughness of the supporting substrate of $Al_2O_3$ ceramic boat was understood to be associated with the large scale synthesis of carbon coils as well as the dominant formation of the larger-sized, namely the microsized carbon coils.

Humidity Sensitive Properties of $V_2O_5$-added $TiO_2$ Ceramics ($V_2O_5$ 첨가에 따른 $TiO_2$ 세라믹스의 감습특성)

  • Hyun, You-Do
    • Proceedings of the KIEE Conference
    • /
    • 2008.05a
    • /
    • pp.161-163
    • /
    • 2008
  • $TiO_2-V_2O_5$ sol was fabricated using sol-gel method and $TiO_2-V_2O_5$, thin films were fabricated using dip-coating method. $V_2O_5$ sol was added 0.01mole, 0.03mole, 0.05mole into $TiO_2$ sol. Capacitance of thin films decreased with increasing $V_2O_5$ additive and it increased largest at 0.01mole. Because adsorption time and desorption time of thin films was about 2 minutes 40 seconds and about 3 minutes 40 seconds respectively, adsorption time was faster about 1 minutes than desorption time.

  • PDF

Experimental Verification of the Decomposition of Y2O3 in Fe-Based ODS Alloys During Mechanical Alloying Process

  • Byun, Jong Min;Park, Chun Woong;Kim, Young Do
    • Metals and materials international
    • /
    • v.24 no.6
    • /
    • pp.1309-1314
    • /
    • 2018
  • In this study, we investigated the state of $Y_2O_3$, as a major additive element in Fe-based ODS alloys, during mechanical alloying (MA) processes by thermodynamic approaches and experimental verification. For this purpose, we introduced $Ti_2O_3$ that formed different reaction products depending on the state of $Y_2O_3$ into the Fe-based ODS alloys. In addition, the reaction products of $Ti_2O_3$, Y, and $Y_2O_3$ powders were predicted approximately based on their formation enthalpy. The experimental results relating to the formation of Y-based complex oxides revealed that $YTiO_3$ and $Y_2Ti_2O_7$ were formed when $Ti_2O_3$ reacted with Y; in contrast, only $Y_2Ti_2O_7$ was detected during the reaction between $Ti_2O_3$ and $Y_2O_3$. In the alloy of $Fe-Cr-Y_2O_3$ with $Ti_2O_3$, $YTiO_3$ (formed by the reaction of $Ti_2O_3$ with Y) was detected after the MA and heat treatment processes were complete, even though $Y_2O_3$ was present in the system. Using these results, it was proved that $Y_2O_3$ decomposed into monoatomic Y and O during the MA process.

A study on the manufacture of dielectric glass-ceramics (유전성 glass-ceramics 제조에 관한 연구)

  • 이종근;박용완;이병하;현동석;이준영
    • Journal of the Korean Ceramic Society
    • /
    • v.19 no.4
    • /
    • pp.281-286
    • /
    • 1982
  • The composition of glasses to be suitable for crystallisation of $BaTiO_3$ by heat-treatment and the dielectric properties of the glass-ceramics were investigated. The composition of the family of glasses was defined by the formula $\chi$ $BaTiO_3 + (100-$\chi$)Al_2O_3$.$2SiO_2$ and excess BaO. Data were presented on dielectric constant and loss tangent at various frequencies. The effects of excess BaO on dielectric properties were investigated. The additions of $Na_2O$ and $Nb_2O_5$ shifted the Curite temperature of these glass-ceramics. The glass composition which was able to be melted at 145$0^{\circ}C$ and moulded as homogeneous glass phase without devitrification should contain $Al_2O_3$.$2SiO_2$ more than 30 mole %. The more the amount of additive BaO increased, the more dielectric constant increased. When the maximum heat-treatment temperature was 105$0^{\circ}C$, we obtained higher dielectric constant than that of 95$0^{\circ}C$. The dielectric constant and the dielectric loss were stable at frequencies between 5$\times$104 and 107 cycle per second. When $Na_2O$ and $Nb_2O_5$ were added, the Curie temperature, presented at 14$0^{\circ}C$ to 15$0^{\circ}C$, shifted to lower temperature. Therefore, the glass-ceramics having high dielectric constant at room temperature were obtained.

  • PDF

Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
    • /
    • v.15 no.3
    • /
    • pp.190-197
    • /
    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

Influence of post-annealing on DC degradation characteristics in $ZnO-Bi_2O_3$ Varistor ($ZnO-Bi_2O_3$ 계 바리스터에서 후열처리가 DC 열화 특성에 미치는 영향)

  • 소순진;김영진;소병문;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1999.05a
    • /
    • pp.333-336
    • /
    • 1999
  • The relationship between the DC degradation characteristics of the $ZnO-Bi_2O_3$ varistor and post-annealing is investigated in this study. $ZnO-Bi_2O_3$ varistors containing $SiO_2$ range 0.3 mol% were fabricated by standard ceramic techniques. The post- annealing is performed at $550^{\circ}C$ for 0, 1.5 and 5h. A little phase transition is found according to the analysis of X-ray diffraction. DC degradation tests were conducted at $115\pm3^{\circ}C$ for periods up to 22h. Current-voltage analysis was used to determine nonlinear coefficients($\alpha$). Capacitance-voltage analysis enable the donor density($N_d$) and the barrier height($E_B$) to be determined. From above analysis, it is found that the past-annealing for 5h improved degradation characteristics in $ZnO-Bi_2O_3$ with Si additive.

  • PDF

Densification Behavior of Reaction-Bonded Silicon Nitride Prepared by Using Coarse Si Powders (조대 Si입자분말을 사용한 질화반응 Si3N4의 치밀화 거동)

  • 이주신;문지훈;한병동;박동수;김해두
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.1
    • /
    • pp.45-50
    • /
    • 2002
  • Effect of sintering additives on the densification behavior of reaction-bonded silicon nitride prepared by using coarse Si powders is discussed. Sintering additives such as 6 wt% $Y_2O_3$+1wt% $A1_2O_3$ (6YlA) did not give rise to full densification, while full densification was obtained by using the sintering additives such as 6wt% $Y_2O_3$+3 wt% $A1_2O_3$+ 2wt% $SiO_2$ (6Y3A2S) and 9wt% $Y_2O_3$+ 1.5wt% $A1_2O_3$+ 3wt% $SiO_2$ (9Yl.5A3S). In the case of 6Y3A2S addition, high fracture strength of 960 MPa and the fracture toughness of $6.5 MPa.m^{1/2}$ were obtained.