• Title/Summary/Keyword: $WS_2$

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A Program of Water Quality Management for Agricultural Reservoirs by Trophic State (농업용 저수지의 부영양화와 수질관리방안)

  • Lee, Kwang-Sik;Yoon, Kyung-Sup;Kim, Ho-Il;Kim, Hyung-Joong
    • Korean Journal of Environmental Agriculture
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    • v.22 no.2
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    • pp.166-171
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    • 2003
  • A total of 498 agricultural reservoirs ranging from $164{\times}10^3\;m^3$ to $253{\times}10^6\;m^3$ in storage volume were investigated from 1990 to 2001 with respect to Chl-${\alpha}$, COD concentration and pollutant loading of BOD, TN, and TP. The lakes and reservoirs could be classified to 4 types using the relationships between the ratio of storage volume per water surface area(ST/WS) and Chl-${\alpha}$ concentration. It is recommended that the improvement of polluted lakes should be performed in the order of integrated consolidation type ${\rightarrow}$ watershed consolidation type ${\rightarrow}$ in-lake consolidation type ${\rightarrow}$ Management type and reservoir should be constructed to be over $5{\sim}6\;m$ in depth(ST/WS ratio) for preventing the eutrophication of agricultural reservoirs. We propose that water quality criteria for agricultural water is changed from less than 8 mg/L to less than 6 mg/L for safety value, $6{\sim}10\;mg/L$ for concern value, and more than 10 mg/L for countermeasure value in COD concentration, respectively.

Comparative Studies on Static Windrow and Aerated Static Pile Composting of the Mixtures of Cattle Manure and Rice Hulls -I. Variation of Physico-chemical Parameters (우분뇨와 왕겨 혼합물의 퇴비화에서 정치식과 통기퇴적식의 비교연구 -I. 퇴비재료의 이화학적 환경변화)

  • Sohn, Bo-Kyoon;Hong, Ji-Hyung;Park, Keum-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.4
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    • pp.403-410
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    • 1996
  • Variations of temperature and physicochemical environment during composting of a mixtures(2:1, v/v) of cattle manure and rice hulls(CMR) in two different composting methods, static windrow(SW) and aerated static pile system(ASPS), were monitored for evaluating the efficient composting system in greenhouse. The pH of composting materials increased to around 8.9 initially, then decreased and stabilized slowly to the neutral value. Composting materials in ASPS showed a rapid stabilization in pH value from the 4th week comparing to the speed in SW. Thermophilic stage for ASPS Lasted at 3 week whereas 6 weeks for WS. Required time to get thermophilic zone in compost was shorter in ASPS than in WS. Reduction rate in total carbon(T-C) was higher in ASPS than in WS. Organic matter was reduced more rapidly in ASPS than in SW showing 9 percent difference after the 6th week. Total nitrogen(T-N) increased while composting process, showing 9 percent after 6th week in WS and 1.8 percent after 7th week in ASPS. C/N ratio was stabilized after 6th week showing 17 and 21 level in WS and ASPS each. Quantity of ash and mineral content increased during composting in both system, showing higher content in ASPS. Composting process by intermittent, aerated static pile system in greenhouse had a significant effect on the reduction of required period for composting.

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The Concentration and Input/Output of Nitrogen and Phosphorus in Paddy Fields (논에서의 질소 및 인의 농도와 유출입)

  • Shin, Dong-Seok;Kwun, Soon-Kuk
    • Korean Journal of Environmental Agriculture
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    • v.9 no.2
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    • pp.133-141
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    • 1990
  • For the purpose of evaluating nutrient loadings into rivers and lakes from agricultural land, especially from paddy fields and also nutrient degradation in drainage channels, the Total Kjeldahl Nitrogen(TKN) and the Total Phosphorus(TP) were investigated in 29.5 ha. paddy fields in Hwa-Sung, Kyong-Ki, Korea, during the period from May 8, 1989 to Sep. 27, 1989. The results of the study can be su㎜arized as follows : 1. Annual inputs into paddy fields were 180 N-kg/ha 46 P-kg/ha. by fertilization, and 15.0 TKN-kg/ha. 10.0 TP-kg/ha. by irrigation, 8.0 TKN-kg/ha. 0.34 TP-kg/ha. by rainfall respectively. The amount of nutrient involved in surface runoff from paddies was 39.0 TKN-kg/ha. 9.2 TP-kg/ha. and in seepage 7.5 TKN-kg/ha. 2.1 TP-kg/ha. respectively 2. In WS1 stream(reach length equals 950m), nutrients decreased 0.31 TKN-mg/L/km, 0.01 TP-mg/L/km and in WS2 stream (reach length equals 750m) which are more meandering and undulating than WS1, the nutrients decreased 0.84 TKN-mg/L/km, 0.11 TP-mg/L/km. From these results, it was concluded that low stream velocity due to meandering and undulation promotes more degradation of nutrient concentrations. 3. For the purpose of decreasing nutrient loads from paddy fields, the amount of fertilizer used needs to be controlled, irrigation weirs need to be constructed in the drainage channels to delay the transportation of nutrients by decelerating the stream velocity and plants such as plantain-lily need to be cultivated in the channel to consume nutrients and therefore enlarge chances of self-purification.

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Applications of Isotope Ratio Infrared Spectroscopy (IRIS) to Analysis of Stable Isotopic Compositions of Liquid Water (동위원소비 적외선 분광법(IRIS)을 이용한 물 안정동위원소 분석)

  • Jung, Youn-Young;Koh, Dong-Chan;Lee, Jeonghoon;Ko, Kyung-Seok
    • Economic and Environmental Geology
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    • v.46 no.6
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    • pp.495-508
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    • 2013
  • Recently, stable isotopes (${\delta}^{18}O$ and ${\delta}D$) of water are increasingly analyzed using laser-based technologies. These methods have advantages over Isotope Ratio Mass Spectrometry (IRMS) in that they can be used for in-situ measurements and require much less maintenance and preparation work. Two types of laser-based methods are currently available, which have different analytical principles; OA-ICOS (off-axis integrated cavity output spectroscopy) and WS-CRDS (wavelength-scanned cavity ring-down spectroscopy). In the WS-CRDS instrument, water is vaporized at controlled environment and transferred to an optical cavity by nitrogen carrier gas, and stable isotopic compositions of water vapor are measured using the degree of absorbance of specific wavelengths and the ratios of attenuation time of the laser intensity with the sensitivity of ppb to tens of ppt level. In this study, we introduce the principle of the WS-CRDS technology and the performance results including stability and comparisons with Isotope Ratio Mass Spectrometry (IRMS) and suggest possible applications of various topics in isotope hydrology.

Effects of Tillage and Cultivation Methods on Carbon Accumulation and Formation of Water-stable Aggregates at Different Soil Layer in Rice Paddy

  • Kim, Sukjin;Choi, Jong-Seo;Kang, Shingu;Park, Jeong-Hwa;Hong, Sunha;Kim, Tae-su;Yang, Woonho
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.634-643
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    • 2017
  • No-tillage is an effective practice to save labor input and reduce methane emission from the paddy. Effects of tillage and cultivation methods on carbon accumulation and soil properties were investigated in the treatments of tillage-transplanting (T-T), tillage-wet hill seeding (T-WS), minimum tillage-dry seeding (MT-S) and no-tillage dry seeding (NT-S) of rice. Soil carbon was higher in NT-S and MT-S, compared to T-T and T-WS. In NT-S and MT-S, soil carbon contents were the highest in the top soil (5 cm depth) and decreased with soil depth. In T-T and T-WS, however soil carbon contents showed no significant difference up to soil depth of 15 cm from the top. Carbon content was the highest in the soil particle size under $106{\mu}m$ and decreased as the soil particle size increased. Contents of water-stable aggregates in NT-S and MT-S were higher than those of T-T and T-WS. In NT-S and MT-S, contents of water-stable aggregates were the highest in the top soil and significantly decreased with soil depth while no significant difference up to the soil depth of 15 cm in T-T and T-WS. Available $SiO_2$ contents in the top soil were the highest in NT-S and MT-S while the lowest in T-T and T-WS. It is concluded that minimum or no disturbance of soil in rice cultivation can increase carbon accumulation in the soil, especially in the top layer, and subsequently contribute to the formation of the water-stable soil aggregates.

A Protein Structure Comparison System based on PSAML (PSAML을 이용한 단백질 구조 비고 시스템)

  • Kim Jin-Hong;Ahn Geon-Tae;Byun Sang-Hee;Lee Su-Hyun;Lee Myung-Joon
    • Journal of KIISE:Computing Practices and Letters
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    • v.11 no.2
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    • pp.133-148
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    • 2005
  • Since understanding of similarities and differences among protein structures is very important for the study of the relationship between structure and function, many protein structure comparison systems have been developed. Hut, unfortunately, these systems introduce their own protein data derived from the PDB(Protein Data Bank), which are needed in their algorithms for comparing protein structures. In addition, according to the rapid increase in the size of PDB, these systems require much more computation to search for common substructures in their databases. In this paper, we introduce a protein structure comparison system named WS4E(A Web-Based Searching Substructures of Secondary Structure Elements) based on a PSAML database which stores PSAML documents using the eXist open XML DBMS. PSAML(Protein Structure Abstraction Markup Language) is an XML representation of protein data, describing a protein structure as the secondary structures of the protein and their relationships. Using the PSAML database, the WS4E provides web services searching for common substructures among proteins represented in PSAML. In addition, to reduce the number of candidate protein structures to be compared in the PSAML database, we used topology strings which contain the spatial information of secondary structures in a protein.

Studies on the Productivity and the Productive Structure of the Forests III. Comparison between the Productivity of Pinus rigida and of Pinus rigitaeda Plantation (삼림의 생산구조와 생산력에 대한 연구 III. 리기다소나무와 리기테다소나무의 비교)

  • 김준호
    • Journal of Plant Biology
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    • v.19 no.3
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    • pp.85-91
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    • 1976
  • A comparison betwen the productivity of Pinus rigida which is native in the Eastern United States, and P. rigitaeda which is F1 hybrid between P. rigida and P. taeda, has been established. For each tree the diameter at breast height (D) and the height of tree (H) were measured in three years. The standard sample trees were down and then weighed each organ. From obtained data the allometric relation between $D_2H$ and dry weight of the trunk (Ws), the branches (Wb) and the leaves (Wl) of P. rigida were approxmated by $$Ws=0.0592 (D^2H)^{0.837}$$ $$Wb=0.0065 (D^2H)^{0.989}$$ $$Wl=0.0447(D^2H)^{0.690}$$ and those of P. rigitaeda were approximated by $$Ws=0.0522 (D^2H)^{0.843}$$ $$Wb=0.0037 (D^2H)^{1.117}$$ $$Wl=0.0207 (D^2H)^{0.856}$$ From the above, the standing crops of above ground of P. rigida were estimated to be as much as 16.93-34.35 ton dry matter per ha, and those of P. rigitaeda were 20.45-45.55 ton per ha. Annual net production was appraised at 8.07-9.35 ton/ha.yr in P. rigida and at 11.59-13.41 ton/ha.yr in P. rigitaeda (1.0:1.4). It is assumed that high productivity of P. rigitaeda stand compared with P. rigida resulted from an increase of the leaf amount with age. Photosynthetic ability under the saturated light of the current and theold leaves of P. rigida were respectively 2.62 and 0.66mg CO2/g. d. wt..hr and those of P. rigitaeda were 1.17 and 0.96mg CO2/g.d. wt.hr. Respiration of the current and the old leaves at $25^{\circ}C$ were 1.00 and 0.90 mg CO2/g. d. wt..hr. in P. rigida and 0.90 and 0.45mg CO2/g.d.wt.hr in P. rigitaeda. It is assumed that photosynthetic longevity of P. rigitaeda leaves was vigorously maintained longer than that of P. rigida.

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Transition Metal Dichalcogenide Nanocatalyst for Solar-Driven Photoelectrochemical Water Splitting (전이금속 디칼코제나이드 나노촉매를 이용한 태양광 흡수 광화학적 물분해 연구)

  • Yoo, Jisun;Cha, Eunhee;Park, Jeunghee;Lim, Soo A
    • Journal of the Korean Electrochemical Society
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    • v.23 no.2
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    • pp.25-38
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    • 2020
  • Photoelectrochemical water splitting has been considered as the most promising technology for generating hydrogen energy. Transition metal dichalcogenide (TMD) compounds have currently attracted tremendous attention due to their outstanding ability towards the catalytic water-splitting hydrogen evolution reaction (HER). Herein, we report the synthesis method of various transition metal dichalcogenide including MoS2, MoSe2, WS2, and WSe2 nanosheets as excellent catalysts for solar-driven photoelectrochemical (PEC) hydrogen evolution. Photocathodes were fabricated by growing the nanosheets directly onto Si nanowire (NW) arrays, with a thickness of 20 nm. The metal ion layers were formed by soaking the metal chloride ethanol solution and subsequent sulfurization or selenization produced the transition metal chalcogenide. They all exhibit excellent PEC performance in 0.5 M H2SO4; the photocurrent reaches to 20 mA cm-2 (at 0 V vs. RHE) and the onset potential is 0.2 V under AM1.5 condition. The quantum efficiency of hydrogen generation is avg. 90%. The stability of MoS2 and MoSe2 is 90% for 3h, which is higher than that (80%) of WS2 and WSe2. Detailed structure analysis using X-ray photoelectron spectroscopy for before/after HER reveals that the Si-WS2 and Si-WSe2 experience more oxidation of Si NWs than Si-MoS2 and Si-MoSe2. This can be explained by the less protection of Si NW surface by their flake shape morphology. The high catalytic activity of TMDs should be the main cause of this enhanced PEC performance, promising efficient water-splitting Si-based PEC cells.

Synthesis of $WS_2$ Solid Lubricant and Its Application to Ball Bearing ($WS_2$고체윤활제의 합성 및 구름베어링 적용)

  • 신동우;윤대현;최인혁;김경도;정진수;정용선
    • Tribology and Lubricants
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    • v.15 no.1
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    • pp.77-82
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    • 1999
  • The processing conditions fur the synthesis of platelet W $S_2$ lubricant powder through a solid-gas reaction were optimized. The mixture of tungsten and sulfur powders were sealed in a vacuum of 10$^{-6}$ torr, prior to heat-treating at 85$0^{\circ}C$ fur 8 days. The reaction product showed a well-developed platelet W $S_2$ powder with an average size of 3.8 ${\mu}{\textrm}{m}$. The TGA/DTA analysis of the synthesized W $S_2$ powder was performed up to 120$0^{\circ}C$ at a rate of 1$0^{\circ}C$/min in flowing air (100 ${\mu}{\textrm}{m}$/min) atmosphere. The weight loss was about 6% up to 120$0^{\circ}C$ compared to the original weight. A rapid weight loss of about 5% occurred in the temperature range of 44$0^{\circ}C$ to 66$0^{\circ}C$ and an exothermic peak observed due to the transition of W $S_2$ to W $O_3$. The synthesized W $S_2$powder was coated on the commercial deep grooved ball bearing (No. 6203) to examine the effect of W $S_2$, coating layer on the noise and endurance of the ball bearing. The level of noise obtained from W $S_2$, coated-ball bearing (56 ㏈) was higher. than the value (32 ㏈) occurred in the case of greece lubrication. The endurance of the ball-bearing assembled after the coating of W $S_2$ powder onto each part increased 50 times compared to the non-coated ball-bearing..

NUTRITIONAL QUALITY OF WILTED NAPIER GRASS (Pennisetum purpureum Schum.) ENSILED WITH OR WITHOUT MOLASSES

  • Yokota, H.;Kim, J.H.;Okajima, T.;Ohshima, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.5 no.4
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    • pp.673-679
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    • 1992
  • To investigate the effects of molasses addition at ensiling on nutritional quality of wilted napier grass, chemical quality and nutrient composition of the silages, digestibility and nitrogen retention at feeding trials were analysed using 4 goats in a cross over design. The results are as follows : 1. Molasses addition at ensiling decreased pH value (3.99) and ammonia nitrogen, and increased lactic acid content by 285% compared to non-additive silage (83.5 g/kg dry matter). 2. There were no differences in digestibilities of dry matter, crude protein, neutral detergent fiber, acid detergent fiber, hemicellulose and cellulose between the silage ensiled with molasses (MS silage) and the silage ensiled without molasses (WS silage). Urinary nitrogen excretion, however, significantly (p<0.05) decreased in goats fed the MS silage, and nitrogen retention was positive in goats fed the MS silages, but negative in goats fed the WS silage. 3. Acetic acid concentration in remained fluids in goats fed the MS silage was lower and propionic and butyric acid concentrations were higher than those in goats fed the WS silage. As water soluble carbohydrate content was higher in the MS silage than in the WS silage, a part of added molasses was still remained in the silage at the feeding trials and could be utilized for energy sources by the goats. Nitrogen may be also effectively utilized in goats fed the MS silage, because the silage were inhibited in proteolysis during ensiling.