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GC/MS-SIM for the Determination of Alkylphenols, Chlorophenols and Bisphenol A in Paper Materials

  • Kim, Hyub
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.05a
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    • pp.145-145
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    • 2003
  • A method for the determination of alkylphenols, chlorophenols and bisphenol A in paper materials using GC/MS-SIM has been developed. Eleven endocrine disrupting chemicals (EDCs) of phenols in paper samples were extracted with acetonitrile. Also, solid-phase extraction (SPE) with XAD-4 and subsequent conversion to isobutoxycarbonyl derivatives or tert.-butyldimethylsilyl derivatives for sensitive analysis with the selected ion-monitoring (SIM) mode. The recoveries were 82.4∼108.8 % by area ratio of pheranthrene-d$\sub$10/ vs bisphenol A d$\sub$l6/. (isoBOC derivatization and TBDMS derivatization) The SIM responses were linear with the correlation coefficient varying 0.9717∼0.9995 (isoBOC derivatization), and 0.9842∼0.9980 (TBDMS derivatization). The range of concentrations was respectively, 0.95∼l.44 ng/g in 2,4-dichlorophenol, 1.01∼1.17 ng/g in t-butylphenol, 2.17∼5.84 ng/g in pentachlorophenol, 12.68∼14.88 ng/g in nonylphenol and 30.84∼153.72 ng/g in bisphenol A.

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A Study on the Typological Classification of Exhibition Area in Museum Regarding Circulation area (동선공간과의 관계로 본 미술관 전시공간의 유형 분류에 관한 연구)

  • 이한기
    • Korean Institute of Interior Design Journal
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    • no.13
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    • pp.18-24
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    • 1997
  • Museums after '70's shows remarkable development in public area as well as exhibiiton area. One of the main changes in recent museums is to extend the concept of circulatin area, which regarded solely as a corridor connecting exhibition areas, as a multiple function area with various service facilities. This study aims to outline atypological classification of exhibition area considering with circulation area in museum. On the base of two principal types of exhibition area, that is room type vs open plant type, 30 representative worldwide museums are analyzed and four different types are identified as a result. 1) Loop type as a rotating structure of serial exhibition rooms 2) Cluster type which produce complicated circulation with rooms lied one upon another 3) Centrum type which is specially available to multistory exhibition area 4) Loft type with maximum flexibi쇼 and accessbility.

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Effect of Supplementation of Antioxidant Nutrient Against Oxidant Stress during Exercise

  • Kim, Hye-Yount
    • Journal of Nutrition and Health
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    • v.30 no.9
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    • pp.1061-1066
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    • 1997
  • This study was undertaken to evaluate the effect of 4 weeks of $\alpha$-tocopherol(800 I.U./d) supplementation on oxidant stress of eleven female aerobic -majoring students during rest and exercise. Changes in the activity of the antioxidant enzyme glutathione peroxidase were also studied. Serum $\alpha$-tocopherol concentration was significantly increased with vitamin E supplementation(710.1$\pm$113.8$\mu\textrm{g}$/dl vs. 1,485,8$\pm$105.2$\mu\textrm{g}$/dl). In addition, serum MDA concentration, an index of lipid peroxidation, significantly decreased after vitamin E supplementation. However, MDA values after exercise increased to pre-supplementation levels. Serum glutathione peroxidase activity significantly increased with vitamin E supplementation. The enzyme activity showed a trend toward decrease after exercise. Serum cholesterol values were not significantly affected by vitamin E supplementation. However, serum triglycerides significantly increased after supplementation against oxidative stress during resting periods. These supplements appraently work by decreasing lipid peroxidation and increasing glutathione peroxidase activity. However, vitamin E supplementation did not prevent exercise-induced increases in lipid peroxidation.

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Graphical Analysis of BMI, Broca and Rohrer Indices in Terms of Anthrophometric Levels (체형분류를 위한 BMI, Broca, Rohrer 방법의 도표 분석)

  • 이병순
    • Journal of Nutrition and Health
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    • v.30 no.2
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    • pp.195-200
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    • 1997
  • A graphical method to determine the anthropometric levels that's are lean, slightly lean, normal, slightly obese, obese by BMI, Broca and Rohrer indices was developed. On the graph of height vs. weight, regions corresponding to the anthropometric levels were separated by equations calculated with boundary conditions for BMI, Broca and Rohrer indices, respectivelyl. It was observed that the determinations of the anthropometric level was influenced by the weight to a larger extent than the hight, which magnitude was in the order of BMI>Broca>Rohrer. There appeared significant differences between the results of the anthropometric level for higher and weight by BMI, Broca and Rohrer indices, respectively. Conclusively, the graphical method was proved as a good means to analyze and compare the anthropometric levels from BMI, Broca and Rohrer indices.

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The Effect of Warning Labels on Cigarette Packages: Textual vs. Textual-Visual and Self-Efficacy

  • Halim, Rizal Edy;Muttaqin, Faisal
    • The Journal of Asian Finance, Economics and Business
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    • v.1 no.2
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    • pp.25-30
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    • 2014
  • The small number of fusion research that addresses fear-appeal and self-efficacy in the effectiveness of warning labels cause the label is not clear, then the purpose of the study is the first to examine the effect of the combination of the message. With the experimental method, a total of 240 participants were smokers consist of Indonesian university students in the age range 18-23 years. Data obtained then processed with ANOVA statistical methods and Test T. The results are consistent with previous studies that the visual warning labels more effective than the textual warning labels alone. Results also suggest that a warning label should be both visual and textual messages combined with self-efficacy. Limitations, this study does not differentiate among smokers and non-smokers, in addition to the images are used only one type of disease, so that the research needs to be done to distinguish these factors.

Impacts of Urban-Rural Residence on Later Life (도시-농촌 거주에 따른 노후 생활특성의 차이)

  • 이인수
    • Journal of the Korean housing association
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    • v.10 no.4
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    • pp.23-30
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    • 1999
  • This study has been performed to analyze impacts of urban vs rural residence on later life. In this study, 329 Koreans aged 60 or more were interviewed for their current sociodemographic status and daily life styles. The results are drawn as follows: 1. There is no regional impact on birth order; rate of those born as the first child was not significantly different over regions. 2. For the household composition, the rate of three generations was significantly higher in rural areas than in urban areas. 3. More than 85% of the subjects lived in owned homes in rural areas, while 77% did in urban areas. 4. More than 89% of the subjects lived in single-structured homes in rural areas, while only 45% did in urban areas. The results indicate that in planning public housing for the aged, more social spaces accommodating grandchildren and ownership units need to be allocated for rural facilities. In addition, it is recommended that daily activity schedules need to be differentiated so that rural residents have meals and houseworks earlier than urban residents.

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Kinetics of Thermal Dehydration of Ha-dong Kaolin (하동카오린의 열분해속도에 관한 연구)

  • 박희찬;손명모
    • Journal of the Korean Ceramic Society
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    • v.18 no.1
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    • pp.35-40
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    • 1981
  • The kinetics of the dehydration of Ha-dong kaolin was studied isothermally at various temperatures. Dehydration rate was measured by thermogravimetry method in the temperature range of 440~50$0^{\circ}C$ and the particle size range of 170~325mesh. The general equation f($\alpha$)=kt, where $\alpha$ is the fraction reacted in the time and the function f($\alpha$) depends on the reaction mechanism, was applied to this reaction. The function, f($\alpha$) was obtained by application of reduced-time plot and plot of lnln (1-$\alpha$) vs. ln (time), and expressed as (1-$\alpha$) ln (1-$\alpha$)+$\alpha$=kt. The dehydration followed the diffusion-controlled reaction model and gave activation energy of 30Kcal/mole.

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Fabrication of excimer laser annealed poly-Si thin film transistor using polymer substrates

  • Kang, Soo-Hee;Kim, Yong-Hoon;Han, Jin-Woo;Seo, Dae-Shik;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1162-1165
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    • 2006
  • In this paper, the characteristics of polycrystalline silicon thin-film transistors (poly- Si TFTs) fabricated on polymer substrates are investigated. The a-Si films was laser annealed by using a XeCl excimer laser and a four-mask-processed poly-Si TFT was fabricated with fully self-aligned top gate structure. The fabricated nMOS TFT showed field-effect mobility of ${\sim}30\;cm^2/Vs$, on/off ratio of $10^5$ and threshold voltage of 5 V.

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A study on the optimal condition of the fabrication glass-cloth/epoxy composite material (Glass-cloth/epoxy 복합재료의 최적제작조건에 관한 연구)

  • Kwak, Young-Soon;Cho, Jung-Soo;Choi, Se-Won;Lee, Kyu-Chul;Lee, Jong-Ho
    • Proceedings of the KIEE Conference
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    • 1989.11a
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    • pp.68-71
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    • 1989
  • This paper is to investigate the optimal condition of fabrication for glass-cloth/epoxy composite material. According to the result in this paper, in fabrication of composite materials, the optimal condition of treatment for epoxy silane coupling agent is 1.5% water solution of silane coupling agent by weight. Then, % weight ratio of silane coupling agent VS, glass cloth is about 0.3%. And the optimal post cured condition of glass cloth/epoxy composite material is about 30 hours at 100$^{\circ}C$.

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Improved Fluorometric Assay Method for Ribonuclease Activity

  • Lee, Jong-Soo;Choi, Jong-Soo
    • BMB Reports
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    • v.30 no.4
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    • pp.258-261
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    • 1997
  • A simple quantitative assay method for ribonuclease activity has been developed. This method is based on the decrease of fluorescence intensity emitted by the ethidium bromide bound to RNA due to the degradation of RNA by ribonuclease. The substrate RNA was reacted with ribonuclease A and the fluorescence intensity was measured after the addition of ethidium bromide. The intensity difference was calculated using a blank reaction mixture containing no RNase. Whole cellular RNA substrate produced a significant error and was not suitable for this assay method possibly because of local microheterogeniety caused by high molecular weight rRNA. but satisfying results were obtained with tRNA substrate. The intensity difference increased linearly by raising enzyme concentration up to $2{\times}10^{-4}$ Kunitz Units of ribonuclease A. More refined and reliable results were obtained by use of initial reaction velocities which were calculated from the plots of intensity difference vs time. A linear relationship between initial velocities and enzyme concentrations was observed up to 0.01 Kunitz Units of enzyme.

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