• Title/Summary/Keyword: $TiO_2-SnO_2$

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Manufacturing and Electrochemical Characteristics of SnO2/Li4Ti5O12 for Lithium Ion Battery (리튬이차전지용 SnO2/Li4Ti5O12의 합성 및 전기화학적 특성)

  • Yang, A-Reum;Na, Byung-Ki
    • Clean Technology
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    • v.21 no.4
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    • pp.265-270
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    • 2015
  • In order to increase the capacity of the lithium ion battery, the capacity of the anode should be increased. SnO2 and Li4Ti5O12 were studied to replace the graphite as the anode materials. In this study, SnO2/Li4Ti5O12 composite materials were synthesized by solid-state method. The study reported here attempts to enhance the electrochemical capacity of Li4Ti5O12 through the incorporation of SnO2. Sn-based Li ion storage materials are loaded on Li4Ti5O12 surface. The SnO2/Li4Ti5O12 composite material has higher capacity than Li4Ti5O12, but the cycling capacity was decreased due to SnO2.

Fabrication of SnO2-TiO2-based Thick Films for Hydrocarbon Gas Sensors (탄화수소계 가스센서를 위한 SnO2-TiO2계 후막의 제조)

  • 정완영;박정은;강봉휘;이덕동
    • Journal of the Korean Ceramic Society
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    • v.28 no.9
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    • pp.721-729
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    • 1991
  • SnO2-TiO2(Pt or Pd), as raw material for hydrocarbon gas sensors, was prepared by a coprecipitation method. The SnO2-TiO2-based thick film gas sensors were made by screen printing technique. The titanium dioxide synthesized was shown to be anatase structure from XRD peaks and was transformed to rutile structure between 700$^{\circ}C$ and 1000$^{\circ}C$. Titanium dioxide in SnO2-TiO2 thick films devices plays a very important role in the enhancement of the sensitivity to CH4 and C4H10. In the case of SnO2-TiO2(Pt) sensors, titanium dioxide that was rutile structure enhanced the sensitivity of the thick film to CH4. Platinum added to the raw powder at coprecipitation (as chloroplatinic acid VI hydrate) improved the gas sensitivity to hydrocarbon gases. Therefore, it is expected that the SnO2-TiO2(Pt) thick film sensors fabricated in this experiment could be put into practical use as LPG (primary component : C4H10 and C3H8) and LNG (primary component : CH4) sensors.

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A Comparison Study on Quantum Dots Light Emitting Diodes Using SnO2 and TiO2 Nanoparticles as Solution Processed Double Electron Transport Layers (용액공정 기반 SnO2와 TiO2를 이중 전자수송층으로 적용한 양자점 전계 발광소자의 특성비교 연구)

  • Shin, Seungchul;Kim, Suhyeon;Jang, Seunghun;Kim, Jiwan
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.3
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    • pp.69-72
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    • 2020
  • In this study, the inverted structured electroluminescence (EL) devices were fabricated with double electron transport layers (ETLs). The conduction band minimum (CBM) of TiO2 NPs is lower than SnO2 NPs. Therefore, it is expected that inserting TiO2 NPs between the SnO2 layer and the emission layer (EML) will reduce the energy barrier and transport electrons smoothly. The quantum dot light emitting diodes (QLEDs) with double ETLs showed the enhanced emission characteristics than those with only SnO2 layer.

Effect of V$_2$O$_5$ Addition on Microwave Dielectric Properties of (Zr$_{0.8}$,Sn$_{0.2}$)TiO$_4$ (V$_2$O$_5$의 첨가가 (Zr$_{0.8}$,Sn$_{0.2}$)TiO$_4$의 마이크로파 유전특성에 미치는 영향)

  • 이경호
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.1
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    • pp.27-32
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    • 2001
  • The effect of $V_2O_5$, a donor-type dopant on the degradation of quality factor of ($Zr_{0.8}, Sn_{0.2})TiO_4$was compared with Ta$_2$O$_{5}$ doped ($Zr_{0.8}, Sn_{0.2})TiO_4$ in terms of microstructure, electrical conductivity, and oxidation state of the dopant. It is well known that the addition of the donor type species such as $Ta_2O_5,Nb_2O_5, Sb_2O_5, WO_{3}$, increases the quality factor of ($Zr_{0.8}, Sn_{0.2})TiO_4$due to decrease the oxygen vacancy concentration. Unlike other dopants, however, the addition of $V_2O_5$ decreased the quality factor. The degradation of quality factor of ($Zr_{0.8}, Sn_{0.2})TiO_4$was resulted from the formation of grain boundary phase and $V_2O_5$rich fiber shaped secondary phase, and the increasing the oxygen vacancy concentration due to unstability of oxidation state of vanadium ions in ($Zr_{0.8}, Sn_{0.2})TiO_4$ceramic.c.

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Characteristics of $TiO_2-$SnO_2$ Thin Films Fabricated Using Sol-Gel Method (솔-젤법에 의해 제작된 $TiO_2-$SnO_2$ 박막의 특성)

  • You, Do-Hyun;Yuk, Jae-Ho;Lim, Kyung-Bum
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.11
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    • pp.511-516
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    • 2002
  • $TiO_2-SnO_2$ thin films are fabricated using sol-gel method. In case the amount of water required hydrolysis smaller than that for stoichiometry, Ti sol forms clear sol which has normal chain structure. On the contrary, in case the amount of water required hydrolysis larger than that for stoichiometry, Ti sol forms suspended sol which has cluster structure. The thickness of thin films increase about $0.03{\sim}0.04{\mu}m$ every a dipping. The permittivity and dissipation factor of $TiO_2-SnO_2$ thin films decrease with increasing frequency. Thin films show semiconductive characteristics above $400^{\cric}C$.

Dielectric, Electrical Properties of $TiO_2-SnO_2$ Thin Films Fabricated using Sol-Gel Method (솔젤법에 의해 제작된 $TiO_2-SnO_2$ 박막의 유전적, 전기적 특성)

  • You, Do-Hyun;Lim, Kyung-Bum
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.79-81
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    • 2004
  • $TiO_2-SnO_2$ thin films are fabricated using sol-gel method. The thickness of thin films increase about $0.03{\sim}0.04{\mu}m$ every a dipping. The permittivity and dissipation factor of $TiO_2-SnO_2$ thin films decrease with increasing frequency. Thin films show semiconductive characteristics above $400^{\circ}C$.

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Synthesis of SnO2-TiO2-V2O5 System Yellow Pigment (SnO2-TiO2-V2O5계의 노랑안료 합성)

  • Joo, In-Don;Hwang, Dong-Ha;Lee, Hyun-Soo;Park, Joo-Seok;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.639-642
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    • 2009
  • The research was performed to find out the optimum firing condition for the $SnO_2-TiO_2-V_2O_5$ system yellow pigment. The pigment based on $SnO_2-V_2O_5$ system showed very intense yellow color and it was used widely in ceramics industry. Synthesized pigment, with partial substitutions of $SnO_2\;by\;TiO_2$, was fired at $1300{^{\circ}C}$ soaking 1h and it showed bright yellow color. $SnO_2-TiO_2-V_2O_5$ system was very more intensive changes in yellow color by colorimetric value $b^*$ than $SnO_2-V_2O_5$ system. Synthesized yellow pigments were characterized by X-ray diffraction (XRD), FT-IR, and UV-vis spectroscopy. The best composition for yellow pigment was 93:7:0.5(mole%) for $SnO_2-V_2O_5-TiO_2$. The measurement of CIE $L^*a^*b^*$ of pigment was $L^*(78.82),\;a^*(-4.88)\;and\;b^*$(59.25).

Formation and Color of the Spinel Solid Solution in NiO-ZnO-$Fe_2O_3$-$TiO_2$-$SnO_2$ System (NiO-ZnO-$Fe_2O_3$-$TiO_2$-$SnO_2$ 계 Spinel 고용체의 생성과 발색에 관한 연구)

  • 이응상;이진성
    • Journal of the Korean Ceramic Society
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    • v.28 no.4
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    • pp.305-314
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    • 1991
  • This study was conducted to research the formation and the color development of NiO-ZnO-Fe2O3-TiO2-SnO2 system for the purpose of synthesizing the spinel pigments which are stable at high temperature. After preparing ZnO-Fe2O3 as a basic composition, {{{{ chi }}NiO.(l-{{{{ chi }})ZnO.Fe2O3 system, {{{{ chi }}NiO.(l-{{{{ chi }})ZnO.TiO2 system, and {{{{ chi }}NiO.(l-{{{{ chi }})ZnO.SnO2 system were prepared with {{{{ chi }}=0, 0.2, 0.5, 0.7, 1 mole ratio respectively. The manufacturing was carried out at 128$0^{\circ}C$ for 30 minutes. The reflectance measurement and the X-ray analysis of these specimens were carried out and the results were summarized as follows. 1. In the specimens which included NiO, it was difficult for the spinel structure to be formed. 2. As increasing the contents of NiO and Fe2O3, all the groups which were yellow or green colored changed to brown. 3. NiO-ZnO-Fe2O3 system and NiO-ZnO-TiO2 system formed the spinel structure and the illmenite structure appeared in NiO-TiO2 system.

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Formation and Color of the Spinel Solid Solution in CoO-ZnO-$Fe_2O_3$-$TiO_2$-$SnO_2$ System (CoO-ZnO-$Fe_2O_3$-$TiO_2$-$SnO_2$계 Spinel 고용체의 생성과 발색에 관한 연구)

  • 이응상;이진성
    • Journal of the Korean Ceramic Society
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    • v.28 no.11
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    • pp.897-907
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    • 1991
  • This study was conducted to research the formation and the color development of CoO-ZnO-Fe2O3-TiO2-SnO2 system for the purpose of synthesizing the spinel pigments which are stable at high temperature. After preparing CoO-ZnO-Fe2O3, in which CoO causes the color, as a basic composition, $\chi$CoO.(1-$\chi$)ZnO.Fe2O3 system, $\chi$CoO.(1-$\chi$)ZnO.TiO2 system and $\chi$CoO.(1-$\chi$)ZnO.SnO2 system were prepared with $\chi$=0, 0.2, 0.5, 0.7, 1.0 mole ratio respectively. The manufacturing was carried out at 128$0^{\circ}C$ for 90 minutes. These specimens were analyzed by the reflectance measurement and the X-ray diffraction analysis and the results were summarized as follows: 1. All of the specimens formed the spinel structure and were colored with stable yellow or blue. 2. As the content of CoO and Fe2O3 in the specimens being increased, the reflectance of each specimen was measured becoming lower and the colors were changed from yellow to greyish blue and from blue to dark blue. 3. As the substituting amount of Co2+ ion for Zn2+ ion in $\chi$CoO-ZnO-TiO2-SnO2 system being increased, the colors were changed from blue to greyish blue. The colors were changed from yellow to grayish green owing to the tetrahedral Co2+ ions being increased, the octahedral Co2+ ions being decreased with increasing the amount of Sn4+ ions. 4. CoO-ZnO-Fe2O3-TiO2-SnO2 system, in which Zn2+ was substituted with Co2+ and Fe3+ was substituted with Ti4+ and Sn4+, easily formed the spinel structure without regard to the amount of substitution or the ion owing to the selectivity of the coordination number: 4 of Zn2+, 4 of Co2+, 6 of Fe3+ or 6 of Ti4+ and Sn4+.

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