• Applied Microscopy
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• 제24권3호
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• pp.78-86
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• 1994

A TEM study on proeutectoid ${\alpha}$ reaction at sub-eutectoid temperatures has been made in hypoeutectoid Ti-3.gw/o Co and Ti-5.2w/o Fe alloys. Widmanstatten ${\alpha}$ plates were formed in both alloys within the ${\beta}$ matrix with some modification of degenerate forms. These degenerate plates were formed by the sympathetic nucleation of ${\alpha}$ plates at ${\alpha}:{\beta}$ interphase boundaries. Three types of sympathetic nucleation, i.e., edge-to-edge, face-to-edge, face-to-face, were found in both alloys. The edge-to-edge sympathetically nucleated crystals formed a low-angle boundary between two crystals. The ${\alpha}:{\beta}$ interphase boundaries were found to be partially coherent interfaces which consist of regularly spaced misfit dislocations. The growth of these interphase boundaries were accomplished by the lateral movement of growth ledges. The intersection points of two ${\alpha}$ plates or the low angle boundaries which had formed by edge-to-edge sympathetic nucleation played a role as the potential sources of growth ledges during the growth of plate. The interfacial structures and the spatial morphologies of the degenerate proeutectoid ${\alpha}$ plates would be expected to influence the nucleation and growth of the succeeding eutectoid decomposition process.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.125-128
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• 2007

In these recent years, low cost and stable battery electrode materials have been studied for HV/HEV application. Spinel cathode material $LiMn_2O_4$ is widely studied as a promising cathode material of lithium ion secondary batteries because of it is low cost, easily to be prepared and capable to be operated in high voltage range. In this study, $LiMn_2O_4$ was undergoing surface modification with spinel lithium titanium oxide by sol-gel method in order to enhance its capacity retention. Properties of both unmodified and surface-modified $LiMn_2O_4$ were characterized by XRD, SEM, particle size analyzer while their cycling performance was tested with charge and discharge tester.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2018년도 춘계학술대회 논문집
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• pp.75-75
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• 2018

Commercially pure titanium (CP-Ti) and Ti-6Al-4V alloys have been widely used in implant materials such as dental and orthopedic implants due to their corrosion resistance, biocompatibility, and good mechanical properties. However, surface modification of titanium and titanium alloys is necessary to improve osseointegration between implant surface and bone. Especially, when titanium oxide nanotubes are formed on the surface of titanium alloy, cell adhesion is greatly improved. In addition, plasma electrolytic oxide (PEO) coatings have a good safety for osseointegration and can easily and quickly form coatings of uniform thickness with various pore sizes. Recently, the effects of bone element such as magnesium, zinc, strontium, silicon, and manganese for bone regeneration are researching in dental implant field. The purpose of this study was researched on the surface morphology of PEO-treated Ti-6Al-4V alloy after anodic titanium oxide treatmentusing various instruments. Ti-6Al-4V ELI disks were used as specimens for nanotube formation and PEO-treatment. The solution for the nanotube formation experiment was 1 M $H_3PO_4$ + 0.8 wt. % NaF electrolyte was used. The applied potential was 30V for 1 hours. The PEO treatment was performed after removing the nanotubes by ultrasonics for 10 minutes. The PEO treatment after removal of the nanotubes was carried out in the $Ca(CH_3)_2{\cdot}H_2O+(CH_3COO)_2Mg{\cdot}4H_2O+Mn(CH_3COO)_2{\cdot}4H_2O+Zn(CH_3CO_2)_2Zn{\cdot}2H_2O+Sr(CH_2COO)_2{\cdot}0.5H_2O+C_3H_7CaO_6P$ and $Na_2SiO_3{\cdot}9H_2O$ electrolytes. And the PEO-treatment time and potential were 3 minutes at 280V. The morphology changes of the coatings on Ti-6Al-4V alloy surface were observed using FE-SEM, EDS, XRD, AFM, and scratch tester. The morphology of PEO-treated surface in 5 ion coating solution after nanotube removal showed formation or nano-sized mesh and micro-sized pores.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 추계학술대회 논문집
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• pp.556-559
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• 1997

This paper describes the development process of mosquito trap with the effect of air cleaning by using the substance-field analysis and evolution pattern of systems in the theory of inventive problem solving (TRIZ). By the concept of standard solution about introducing S3 substance, modification of S1 (human) and S2 (mosquito) between first substance SI and second substance S2 with harmful effect, we got the concept of the mosquito trap with mosquito attractants instead of mosquito reluctants such as mosquito stick coil and skin medicine w~th bad and toxic smell. The number of mosquitos traped by one trap near cattle shed per one n~ght in summer, was over 10 thousands with some effects of air cleaning.

• 한국표면공학회지
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• 제49권2호
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• pp.191-195
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• 2016

Among the lithium metal oxides for hybrid-capacity, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. However, LTO has a limitation of low ionic and electronic conductivity. To enhance the ionic and electronic properties of $Li_4Ti_5O_{12}(LTO)$, we synthesized the spherical LTO/CNT composite by sol-gel process for hybrid capacitors. CNT interconnection networks between CNT-LTO particles enhanced electronic conductivity and electrochemical charging/discharging properties. All of the LTO samples was observed to show the spinel structure and spherical morphology with the diameter of $5{\sim}10{\mu}m$. Especially, spherical LTO/CNT composite of the CNT-3 wt% showed the enhanced capacity from 110 mAh/g to 140 mAh/g at 10 C.

• 대한화장품학회지
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• 제30권2호
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• pp.197-200
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• 2004

감촉 및 광학적 요소는 파우다 파운데이션에 있어서 매우 중요한 요소이다. 이러한 감촉과 광학적인 요소를 동시에 만족하는 분체에 관심을 가지고 다양한 소재 및 제조방법을 연구 중에 바륨설페이트를 기본 입자로 하는 복합화 된 분체를 개발하게 되었다. 바륨설페이트는 입자의 모양이 매우 넓고 표면의 굴곡이 없는 판상으로 감촉면에서 부드러운 사용성과 균일한 부착 특성을 나타내며 굴절율도 피부보다 약간 높은 수준으로 인위적이지 않고 자연스러운 광학적 특성을 나타내고 있다. 그러나 파운데이션에서 요구되는 광학적 특성인 자외선 차단능력이나 커버력, 블루밍 효과에 있어서는 기대수준에 못 미치는 것을 알 수 있었다. 이러한 특징은 파우다 파운데이션에서 사용되는 대부분의 분체에 있어서 공통적으로 나타나는 특성으로 감촉적인 측면(소프트, 밀착력 등)과 광학적 측면(커버력, 자외선 차단력 등)을 동시에 만족하는 분체가 극히 드문 것을 알 수 있다. 본 연구에서는 이러한 점을 극복하고자 감촉적인 측면에서 우수한 바륨설페이트를 모입자로 하고 자외선 차단능력과 블루밍에서 우수하나 자체의 응집력이 강하고 사용감이 거친 특징을 나타내고 있는 티타늄디옥사이드를 자입자로 하여 복합화하려 하였다. 이때 중요 요소로 복합화 되는 티타늄디옥사이드의 함량에 따라 복합안료의 감촉적인 측면과 분산력 등이 민감하게 달라지는 것을 알 수 있었다. 이에 패널을 이용하여 복합안료의 사용성에 영향을 미치지 않는 수준의 함량을 결정하여 복합화 처리했으며, 사용자가 피부에 도포시 발생되는 피지나 땀에 대한 변색과 사용감을 고려하여 피지나 땀에 강한 발수, 발유 능력을 나타내며 부드러운 감촉의 디메치콘으로 복합안료를 코팅 처리하여 복합분체를 만들게 되었다. 이렇게 만든 복합분체(barium sulfate/TiO$_2$/dimethicone)를 패널을 이용한 테스트와 기기를 이용한 테스트를 실시하여 효과를 검증하게 되었다.

• 한국자기학회지
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• 제17권6호
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• pp.221-225
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• 2007

[ $Co_{73}Pt_{27}-TiO_2$ ] 수직자기 기록매체에 대해 집속이온빔(FIB)을 이용한 $Ga^+$ 이온 조사에 따른 자기적 특성의 변화를 조사하였다. $Ga^+$ 이온 도즈량을 $1\times10^{15}ions/cm^2$에서 $30\times10^{15}ions/cm^2$까지 증가시켰을 때 도즈량 $20\times10^{15}ions/cm^2$ 이상에서 수직자기이방성 및 강자성 특성이 사라지는 것이 관찰되었으며, 이는 스퍼터링 효과에 따른 수직자기 기록층의 두께 감소보다는 $Ga^+$ 이온 주입에 따른 수직자기 기록매체내의 조성 분포의 변화에 따른 것으로 보인다. $Ga^+$ 이온 조사법을 이용하며 $70\times70nm^2,\;100\times100nm^2$ 크기의 자기구조체 패턴을 형성하였다.

• 한국전기전자재료학회논문지
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• 제29권6호
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• pp.342-347
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• 2016

We investigated the effect of $Bi_{1/2}(Na_{0.82}K_{0.18})_{1/2}TiO_3$ (BNKT) modification on the ferroelectric and electric-field-induced strain (EFIS) properties of lead-free $0.97Bi_{1/2}(Na_{0.82}K_{0.18})_{1/2}TiO_3-0.03LaFeO_3$ (BNKTLF) ceramics as a function of BNKT content (x= 0, 0.1, 0.2, 0.3, 0.5, and 1). BNKT-modified BNKTLF powders were synthesized using a conventional solid-state reaction method. As the BNKT content x increased from 0 to 1 the normalized electric-field-induced strain ($S_{max}/E_{max}$) was observed to increase at relatively low fields, i.e., below the poling field. Moreover, BNKTLF-30BNKT showed about 460 pm/V as low as at 3 kV/mm, which is a considerably high value among the lead-free systems reported so far. Consequently, it was confirmed that ceramic-ceramic composite, a mixture of an ergodic relaxor matrix and embedded ferroelectric seeds, is a salient way to make lead-free piezoelectrics practical with enhanced EFIS at low field as well as less hysterical.

• 한국세라믹학회지
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• 제39권3호
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• pp.252-258
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• 2002

Titanium(IV) isopropoxide에 킬레이팅 리간드로 Acetylacetone(Acac), Ethyl-acetoacetate(Etac) 그리고, Ethanolamine을 첨가시켜 변형된 티타늄 알콕사이드를 합성한 후 졸-겔 방법으로 투과성 티타늄 산화물 박막을 제조하였다. 박막 제조 조건이 최적의 상태일 때는 티타니아 졸 용액의 농도가 3wt% 이하이고, 리간드로는 Acetyl acetone(Acac)를 선택하고, pH가 2.5로 조절하였을 때였다. 순수한 티타늄 산화물 박막보다는 리간드가 치환된 박막들의 굴절률이 더 높았고 가시광선 영역에서 80% 이상의 투과율을 나타냄을 알 수 있었다. 티타니아 졸 상태에서는 입자 크기가 나노 크기를 나타냈으며 분말로 소성 후 마이크론 크기로 증가함을 알 수 있었다. 티타늄 박막들은 400$^{\circ}$C에서 무정형에서 anatase로 상전이가 일어나고 700$^{\circ}C$에서는 rutile로 변화됨을 XRD로 관찰하였다. 박막의 결정형태와 모양 및 크기도 SEM과 XRD로 측정하였다. 또한 분말의 물성 및 구조를 SEM, XRD, TGA 그리고 DSC로 알아보았고, 박막의 광학적 특성에 대해서는 ellipsometer로 굴절률과 막두께를 측정하여 비교하여 보았다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.222-222
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• 2011

Titanium dioxide (TiO2) has a number of applications in optics and electronics due to its superior properties, such as physical and chemical stability, high refractive index, good transmission in vis and NIR regions, and high dielectric constant. Atomic layer deposition (ALD), also called atomic layer epitaxy, can be regarded as a special modification of the chemical vapor deposition method. ALD is a pulsed method in which the reactant vapors are alternately supplied onto the substrate. During each pulse, the precursors chemisorb or react with the surface groups. When the process conditions are suitably chosen, the film growth proceeds by alternate saturative surface reactions and is thus self-limiting. This makes it possible to cover even complex shaped objects with a uniform film. It is also possible to control the film thickness accurately simply by controlling the number of pulsing cycles repeated. We have investigated the ALD of TiO2 at 100$^{\circ}C$ using precursors titanium tetra-isopropoxide (TTIP) and H2O on -O, -OH terminated Si surface by in situ X-ray photoemission spectroscopy. ALD reactions with TTIP were performed on the H2O-dosed Si substrate at 100$^{\circ}C$, where one cycle was completed. The number of ALD cycles was increased by repeated deposition of H2O and TTIP at 100$^{\circ}C$. After precursor exposure, the samples were transferred under vacuum from the reaction chamber to the UHV chamber at room temperature for in situ XPS analysis. The XPS instrument included a hemispherical analyzer (ALPHA 110) and a monochromatic X-ray source generated by exciting Al K${\alpha}$ radiation (h${\nu}$=1486.6 eV).