• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.207-210
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• 2005

In order to investigate the influence of the homo buffer layer on the microstructure of the ZnO thin film, undoped ZnO buffer layer were deposited on sapphire (0001) substrates by ultra high vaccum pulsed laser deposition (UHV-PLD) and molecular beam eiptaxy (MBE). After high temperature annealing at $600^{\circ}C$ for 30min, undoped ZnO buffer layer was deposited with various oxygen pressure (35~350mtorr). On the grown layer of undoped ZnO, Arsenic-doped(l, 3wt%) ZnO layers were deposited by UHV-PLD. The optical property of the ZnO was analyzed by the photoluminescence (PL) measurement. From $\Theta-2\Theta$ XRD analysis, all the films showed strong (0002) diffraction peak, and this indicates that the grains grew uniformly with the c-axis perpendicular to the substrate surface. Field emission scanning electron microscope (FE-SEM) revealed that microstructures of the ZnO were varied with oxygen pressure, arsenic doping level, and the deposition method of undoped ZnO buffer layers. The films became denser and smoother in the cases of introducing MBE-buffer layer and lower oxygen pressure during As-doped ZnO deposition. Higher As-doping concentration enhanced the columnar-character of the films.

• Journal of Korean Society of Steel Construction
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• v.18 no.2
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• pp.161-171
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• 2006

paper presents the results of a three-dimensional study of the natural vibration of laminated composite rectangular plates with various combinations of clamped and free boundaries. The Ritz method was used to obtain the stationary values of the associated Lagrangian, with displacements approximated using mathematicaly complete, characteristic orthogonal polynomials. The correctness of the three-dimensional model was established through a convergence study of the non-dimensional frequencies, followed by a comparison of the analytical findings in the existing literature. The wide scope of additional three-dimensional frequency results explains the influence of a number of geometrical and material parameters for angle-ply and cross-ply laminated plates, namely aspect ratio (${\mathcal{a/b}}$), thickness ratio (${\mathcal{a/h}}$), orthotropy of material, number of plies (${\mathcal{N}}$), fiber orientation angle (${\theta}$), and stacking sequence.

• Polymer(Korea)
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• v.24 no.3
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• pp.299-305
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• 2000

In order to increase the thermal stability at high temperatures, new hybrid ceramic percursors were synthesized by chemical modification of polycarbosilane (PCS). The structure of hybrid ceramic percursors were investigated by using FT-IR and $^1$H-NMR spectrometers. The syntheses of hybrid ceramic precursors were confirmed by monitoring the change of the adsorption peaks appearing at 0893, 1092, 609 $cm^{-1}$ / on the FT-IR spectra, and also by the presence of peaks at 3.8, 2.0, 0.6 ppm on the $^1$H-NMR spectra. The conversion of hybrid ceramic percursor was around 74 and 10 wt% higher than that of the pure PCS. After the heat-treatment at 150$0^{\circ}C$, the crystalline peaks for $\beta$-SiC were observed at 2$\theta$=35.7, 42.2, 61.0$^{\circ}$ on the X-ray powder diffractogram. It showed the conversion of hybrid ceramic percursor to crystalline $\beta$-SiC.

• Polymer(Korea)
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• v.32 no.6
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• pp.549-554
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• 2008

In order to synthesize polymer particle containing inorganic material, styrene and n-butylmethacrylate were copolymerized with alumina by dispersion polymerization. The weight ratio of styrene to n-butylmethacrylate was 3 : 1. A poly(N-vinyl pyrrolidon) was added as stabilizer. 2,2'-AzobisCisobutyronitrile) and 3-methacryloxypropyl trimethoxysilane were used as initiator and coupling agent, respectively. The weight ratio of 70 : 30 of isopropanol to distilled water was used as dispersion medium. According to the TEM measurement, we could confirm that alumina was dispersed into the polymer particle. The increase 'of concentration of alumina resulted in enhancement of particle size, but decreased its distribution. By the XRD method, it was found that the increase of alumina concentration showed the increase of intensity in peak and the increased 2$\theta$ value. From the TGA measurement, the increase of alumina concentration caused high heat resistance of the polymer. With respect to the type of initiator, the longer half life of initiator, the smaller particle size. We also found that the increase of particle stabilizer concentration made the decreased of particle size due to the accelerated generation of polymer particle in the early stage of reaction.

• MALSORI
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• no.4
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• pp.20-30
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• 1982

The aim of this paper is to analyse difficulties of the pronunciation in swedish vowels encountered by Koreans learners and to seek solutions in order to correct the possible errors. In the course of the analysis the swedish and Korean vowels in question are compared with the purpose of describing differences aha similarities between these two systems. This contrastive description is largely based on the students' articulatory speech level ana the writer's auditory , judgement . The following points are discussed : 1 ) Vowel length as a distinctive feature in Swedish compared with that of Korean. 2) A special attention is paid on the Swedish vowel [w:] that is characterized by its peculiar type of lip rounding. 3) The six pairs of Swedish vowels that are phonologically contrastive but difficult for Koreans to distinguish one from the other: [y:] ~ [w:], [i:] ~ [y:], [e:] ~ [${\phi}$:], [w;] ~ [u:] [w:] ~ [$\theta$], [$\theta$] ~ [u] 4) The r-colored vowel in the case of the postvocalic /r/ that is very common in American English is not allowed in English sound sequences. The r-colored vowel in the American English pattern has to be broken up and replaced hi-segmental vowel-consonant sequences . Korean accustomed to the American pronunciation are warned in this respect. For a more distinct articulation of the postvocalic /r/ trill [r] is preferred to fricative [z]. 5) The front vowels [e, $\varepsilon, {\;}{\phi}$) become opener variants (${\ae}, {\;}:{\ae}$] before / r / or supradentals. The results of the analysis show that difficulties of the pronunciation of the target language (Swedish) are mostly due to the interference from the Learner's source language (Korean). However, the Learner sometimes tends to get interference also from the other foreign language with which he or she is already familiar when he or she finds in that language more similarity to the target language than in his or her own mother tongue. Hence this foreign language (American English) in this case functions as a second language for Koreans in Learning Swedish.

• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.34-34
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• 2000

ZnO 박막은 대칭 육방정계(hexagonal) wurtzite-type crystal로써 결정구조에서의 이방성, 비화학양론 결합구조와 다양한 전기적, 광학적 그리고 타성파적 성질 때문에 현재 여러 응용분양에서 각광을 받고 있는 재료 중의 하나이다. 이러한 특성을 갖는 ZnO 박막은 결정학적으로 기판에 수직인 c-축 우선방위현상(preferred orientation)을 나타내며 압전 특성을 이용하여 응용을 할 경우 이 c-축 우선방위현상에 따라 압전 특성에 큰 차이가 있으며 ZnO 박막의 형성 조건에 의해 c-축 우성배향성은 큰 차이가 있다. 특히 스퍼터법을 이용하여 ZnO 박막을 형성하는 경우에는 투입전력, 기판온도, 분위기 가스압력, 타겟간 거리등의 증착조건에 의해 결정학적 및 전기적 특성이 크게 영향을 받게 된다. 따라서 결정학적으로 양호하며 고품위의 특성을 갖는 ZnO 박막을 제작하기 위해서는 최적의 증착조건을 확립하여 ZnO 박막을 제작할 필요가 있다. 본 연구에서 사용된 대향 타겟식 스퍼터장치는 두 개의 타겟이 서로 마주보게 배치되어 있고 양 타겟에 수직으로 분포하고 있는 자계가 ${\gamma}$-전자를 구속하게 되어 고밀도의 플라즈마를 형성할 수가 있다. 따라서 10-4Torr에서도 안정한 방전을 유지할 수가 있으며 기판의 위치가 플라즈마로부터 이격되어 (plasma-free)있는 위치에 있기 때문에 플라즈마내의 높은 에너지를 갖는 입자들의 기판충돌을 최대한 억제하여 고품위의ZnO 박막을 제작할 수가 있다. 이러한 특징을 갖는 대향타겟식스퍼터장치를 이용하여 본 연구에서는 비정질 slide glass를 기판으로 하여 ZnO 박막을 증착하였으며 XRD(X-ray Diffractometer)를 이용하여 증착된 ZnO 박막의 결정학적 특성을 측정하였다. ZnO 박막은 산소 가스압력과 기판온도, 인가 전류를 변화시켜가며 증착하였으며 이에 따른 박막의 결정성 변화를 알아보았다. 기판온도를 실온에서 점차 증가시켜나가면 $\Delta$$\theta$50은 급격히 감소하며 30$0^{\circ}C$에서는 결정성이 우수한 막을 얻을 수 있었다. 또한 산소 가스 압력이 0.5~1mTorr에서 $\Delta$$\theta$50은 양호한 값을 나타내었지만 그 이상에서는 c-축 배향성이 나빠짐을 확인하였다. 따라서 대향타겟식스퍼터 장치를 이용하여 ZnO 박막을 증착시 가스압력 0.5~1mTorr, 기판온도 20$0^{\circ}C$이상의 막 제작조건에서 결정성이 우수하게 나타나는 것을 확인할 수 있었다.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.5 s.170
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• pp.103-112
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• 2005

This paper presents one-axis high precision scanning system and illustrates the design of modified $X-Y-{\theta}$ stage as a tracker using VCM and commercialized air bearings for it. The scanning system for 100nm resolution is composed of the 3-axis stage and one axis long stroke linear motor stage as a follower. In this study a previous proposed and presented structure of VCM for the fine stage is modified. The tracker has 3 DOF($X-Y-{\theta}$ motions by four VCM actuators which are located on the same plane. So 4 actuating forces are suggested and designed to create least pitch and roll motions. This article will show about the design especially about optimal design. The design focus of this fine stage is to have high acceleration to accomplish high throughput. The optimal design of maximizing acceleration is performed in restrained size. The most sensitive constraint of this optimal design is heat dissipation of coil. There are 5 design variables. Because the relationship between design variables and system parameters are quite complicated, it is very difficult to set design variables manually. Due to it, computer based optimal design procedure using MATLAB is used. Then, this paper also describes the procedures of selecting design variables for the optimal design and a mathematical formulation of the optimization problem. Based on the solution of the optimization problem, the final design of the stage is also presented. The results can be verified by MAXWELL. The designed stage has the acceleration of about 5 $m/s^{2}$ with 40kg total mass including wafer chuck and interferometer mirror. And the temperature of coil is increased $50^{\circ}C$. In addition, the tracker is controlled by high precision controller system with HP interferometer for it and linear scaler for the follower. At that time, the scanning system has high precision resolution about 5nm and scanning resolution about 40nm in 25mm/s constant speed

• Applied Chemistry for Engineering
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• v.25 no.3
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• pp.312-317
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• 2014

Catalytic combustion of benzene over CuO-$CeO_2$ mixed oxides prepared by co-precipitation method were investigated. The CuO-$CeO_2$ mixed oxides were also prepared using different precipitant and CuO precursor. They were characterized by XRD, BET, XPS and $H_2-TPR$. In the CuO-$CeO_2$ catalysts, characteristic copper oxide peaks were shown at $2{\Theta}=35.5^{\circ}$ and $38.5^{\circ}$ regardless of the precipitant. The Cu0.35 catalyst prepared using $NH_4OH$ as a precipitant revealed the highest activity on the combustion of benzene. In addition, the pretreatment with hydrogen enhanced the catalytic activity and the catalyst reduced at $400^{\circ}C$ showed the highest activity on the combustion of benzene.

• Korean journal of food and cookery science
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• v.21 no.6 s.90
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• pp.942-949
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• 2005

To improve the textural properties and stabilize the structure and gel matrix of non-waxy rice starch gels, non-waxy rice starch/gum mixture gels were prepared from various food gums, gum arabic, guar, algin, deacyl gellan, xanthan and gellan gums. The morphological and textural properties and freeze-thaw stability of their gels were compared. Rice starch/gum mixture gels with various gums formed a more homogeneous gel matrix with smaller particle size than rice starch gel without Em, but the trends differed depending on the gum types. The textural properties of rice starch/gum mixture gels were changed with the gum types. The shape of the rice starch/gum mixture gel matrix was desirable when mixed with gellan and algin. The textural properties of gels hardened in the rice starch/algin mixture gel and softened in the rice starch/algin mixture gel. The rice starch gels showed V-type crystallinity by x-ray diffractometer, but the peak at $2\theta$ = $20^{o}$ was decreased with increasing gum addition. The freeze-thaw stability increased with increasing gum addition. Gellan and algin were especially effective.

• Journal of the Korean Society of Food Science and Nutrition
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• v.29 no.5
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• pp.766-769
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• 2000

This study was attempted to investigate granular properties of acorn flours which were prepared by soaked nut and sediment. X-ray diffraction pattern of acorn flour was B type and was not affected by soaking treatment. The principal indices of the pattern were at diffraction angles ($2{\theta}$) of $14.5^{\circ},\;17.2^{\circ},\;19.7^{\circ},\;22.2^{\circ}\;and\;24.5^{\circ}$. The shape of acorn flour was elliptical and some rounded triangular by scanning electron microscope (SEM). The granule size of acorn flours varies from $4\;{\mu}{\textrm}{m}$ to approximately $20\;{\mu}{\textrm}{m}$. although morphology of the acorn flour was not affected, the non-starchy substances of surface was slightly changed by soaking.