• Journal of the Korean Ceramic Society
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• v.24 no.2
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• pp.117-122
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• 1987

Glass forming ranges in the AlF3-(Mg＋Sr＋Ba)F2-P2O5 system are studied and ultraviolet transmission, infrared transmission, coefficient of refractive index, thermal expansion coefficient, density and chemical durability of the glasses are determined. Glass forming range is restricted MgF2 0-10wt%, SrF2 10-50wt%, BaF2 10-40wt% in this system. While BaF2 is substituted by SrF2, density and refractive index are decreased, micro hardness and thermal expansion coefficient are increased according to the increasing of SrF2 at fixed MgF2 contents. These samples represent high transmittance(93%) from 400nm to 3800nm and chemical durability of these samples show less than 0.3mg/$\textrm{cm}^2$$.$hy by weightloss.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.4
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• pp.133-140
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• 2006

The growth characteristics and properties of large size $SrAlF_5$ single crystals are described and compared with those of $BaMgF_4$. Transmission spectra in the vacuum ultraviolet wavelength region indicate a high transparency of $SrAlF_5$ (about 90% without considering surface reflection loses) down to 150 nm, on contrast to the optical loses observed for $BaMgF_4$. The ferroelectric character of $SrAlF_5$ is evidenced by the reversal of the spontaneous polarization in a hysteresis loop. The higher potential of $SrAlF_5$ in comparison with $BaMgF_4$ for the realization of all-solid-state lasers in the ultraviolet wavelength region by the quasi-phase matching (QPM) technique is pointed out. $SrAlF_5$, besides a higher grade of transparency, shows a nonlinear effective coefficient similar to that of quartz and uniaxial nature, on contrast to the one order smaller nonlinear coefficient and biaxial character of $BaMgF_4$. The refractive index of $SrAlF_5$ from the ultraviolet to the near-infrared wavelength region is measured by the minimum deviation method. The Sellmeier and Cauchy coefficients are obtained from the fits to the curves of the ordinary and extraordinary refractive indices, and the grating period for the first order QPM is estimated as a function of the wavelength. The poling periodicity for 193 nm SHG from 386 nm is $4{\mu}m$.

• Journal of the Korean Ceramic Society
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• v.24 no.3
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• pp.277-281
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• 1987

The various contents of MgF2 from 0 to 12.5wt% are studied in the AlF3-(Mg＋Sr＋Ba)F2-P2O5 system for the effects of various properties in glasses and the atmosphere of melting was controlled by N2 and Ar gas respectively. Density, refractive index, infrared transmission, thermal conductivity and thermal expansion coefficient of glasses are determined. Density, refractive index and thermal conductivity are decreased, micro-hardness and thermal expansion coefficient are increased according to the increasing of MgF2 contents. Infrared transmittance decreases with increasing the MgF2 contents and it slightly dropped by air than N2 and Ar atmosphere. Other properties are not influenced by atmosphere control.

• Journal of the Korean Ceramic Society
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• v.24 no.4
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• pp.321-328
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• 1987

The chemical durability of six alumino fluorophosphate glass samples studied. The composition of glass varied with MgF2 content from 0 to 12.5wt% in 30AlF3-2MgF2-(50-x)MF2-10P2O5(M; Sr, Ba). Samples were maintained in distilled water at 95$^{\circ}C$ from 1 to 100hrs. Weight loss, pH change and leached elements of the solution, and IR transmittance of samples were measured and also their surfaces were observed by SEM. Chemical durabilities of these samples were increased with increasing MgF2 contents. The following various properties were increased rapidly up to 10 hours after that changed slowly. The sample after leached at 95$^{\circ}C$ during 100 hrs showed 0.5mg/$\textrm{cm}^2$ in weight loss. The pH of leached solution is 6.2 and concentration of Mg, Sr, and Ba element of that leached solution were 24,115 and 125 ppm, respectively. The infrared transmittance of leached sample decreased 7% compare to unleached one. And also SEM photomicrograph and EDS analysis showed that the corrosion of samples were decreased with respect to increasing MgF2 content.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.9
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• pp.825-828
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• 2008

$Sr_xBa_{(1-x)}TiO_3$ red phosphors doped with Pr(0.13 mol%) and Al(O.23 mol%) were synthesized by solid state reaction method. Orthorhombic perovskite structure with increasing value of x in $Sr_xBa_{(1-x)}TiO_3$:Pr,Al phosphors changed to cubic perovskite structure. Emission bands at 615 nm and 492 nm in $Sr_{0.25}Ba_{0.75}TiO_3$:Pr,Al and $BaTiO_3$:Pr,Al phosphors were observed at room temperature. The main cause of green luminescence at 492 nm was explained by the change of the 4f5d band.

• Korean Journal of Crystallography
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• v.13 no.1
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• pp.25-30
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• 2002

The M/sub 1-x/Na/sub 2x/Al₂(BO₃)₂O (M = Ca and Sr) solid solution systems have been shown interstitial solid solutions and continuous substitutional solid solutions. The symmetry around the Eu site of yEu/sup 3+/ : M/sub 1-x/Na/sub 2x/Al/sub 2-y/Mg/sub /(BO₃)₂O (M = Ca and Sr) changes the intensities and the chromaticities of transitions. The Eu/sup 3+/ion can be very bright and efficient and have the desired emission wave-length depending on the site symmetry of the Eu/sup 3+/ion site. As the amount of Na in the Eu/sup 3+/ion doped Ca/sub 1-x/Na/sub 2x/Al₂(BO₃)₂O system increases, the Eu site symmetry is going to be a noncentrosymmetric site. With increasing x, the decreased intensity in the /sup 5/D/sub 0/→/sup 7/F₁(590 nm) transition relates to the low symmetry of the Eus/up 3+/-doped Ca/sub 1-x/Na/sub 2x/Al₂(BO₃)₂O system, because of the Ca-centered octahedron in the CaAl₂(BO₃)₂O compound. The SrAl₂(BO₃)₂O compound also provides an improved chromaticity due to the lower site symmetry of Eu/sup 3+/ion.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.1148-1151
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• 2002

Dielectric ceramics with nominal composition of $(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$ was prepared using the conventional mixed oxide process-derived powder. Effect of $SiO_2$, $MnO_2$ and $Al_2O_3$ impurity addition on the microwave properties was examined in some detail. Measured relative permittivity $(\varepsilon_r)$ values were in the range of 53 to 59 and showed little dependence on impurity addition. In contrast, quality factor $(Q{\cdot}f)$ and temperature coefficient of resonant frequency $(\tau_f)$ values were greatly influenced by the type and the amount of impurities. It was found that 0.1~0.2wt% addition of $Al_2O_3$ was most effective for improving the properties, where ${\varepsilon}_r$, $Q{\cdot}f$ and $\tau_f$ values were 57.7, 10000, and +7ppm/$^{\circ}C$, respectively.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.620-626
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• 2015

$Ho^{3+}$ doped $SrAl_2O_4$ upconversion phosphor powders were synthesized by spray pyrolysis, and the crystallographic properties and luminescence characteristics were examined by varying activator concentrations and heattreatment temperatures. The effect of organic additives on the crystal structure and luminescent properties was also investigated. $SrAl_2O_4:Ho^{3+}$ powders showed intensive green emission due to the $^5F_4/^5S_2{\rightarrow}^5I_8$ transition of $Ho^{3+}$. The optimal $Ho^{3+}$ concentration in order to achieve the highest luminescence was 0.1%. Over this concentration, emission intensities were largely diminished via a concentration quenching due to dipole-dipole interaction between activator ions. According to the dependence of emission intensity on the pumping power of a laser diode, it was clear that the upconversion of $SrAl_2O_4:Ho^{3+}$ occurred via the ground state absorption-excited state absorption processes involving two near-IR photons. Synthesized powders were monoclinic as a major phase, having some hexagonal phase. The increase of heat-treatment temperatures from $1000^{\circ}C$ to $1350^{\circ}C$ led to crystallinity enhancement of monoclinic phase, reducing hexagonal phase. The hexagonal phase, however, did not disappear even at $1350^{\circ}C$. When both citric acid (CA) and ethylene glycol (EG) were added to the spray solution, the resulting powders had pure monoclinic phase without forming hexagonal phase, and led to largely enhancement of crystallinity. Also, N,N-Dimethylformamide (DMF) addition to the spray solution containing both CA and EG made it possible to effectively reduce the surface area of $SrAl_2O_4:Ho^{3+}$ powders. Consequently, the $SrAl_2O_4:Ho^{3+}$ powders prepared by using the spray solution containing CA/EG/DMF mixture as the organic additives showed about 168% improved luminescence compared to the phosphor prepared without organic additives. It was concluded that both the increased crystallinity of high-purity monoclinic phase and the decrease of surface area were attributed to the large enhancement of upconversion luminescence.

• Journal of the Korean institute of surface engineering
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• v.39 no.1
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• pp.35-42
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• 2006

In this study, the fatigue properties on the cavitation damage of the flame quenched 8.8Al-bronze (8.8Al-4.5Ni-4.5Fe-Cu) as well as the current nuclear pump impeller materials (8.8Al-bronze, STS316 and SR50A) has been investigated using an ultrasonic vibratory cavitation test. For this the impact loads of cavitation bubbles generated by ultrasonic vibratory device quantitatively evaluated and simultaneously the cavitation erosion experiments have been carried out. The fatigue analysis on the cavitation damage of the materials has been made from the determined impact load distribution (e.g. impact load, bubble count) and erosion parameters (e.g. incubation period, MDPR). According to Miner's law, the determined exponents b of the F-N relation ($F^b$ N = Constant) at the incubation stage (N: the number of fracture cycle) were 5.62, 4.16, 6.25 and 8.1 for the 8.8Al-bronze, flame quenched one, STS316 and SR50A alloys. respectively. At the steady state period, the exponents b of the F-N' curve (N': the number of cycle required for $1{\mu}m$ increment of MDP) were determined as 6.32, 5, 7.14 and 7.76 for the 8.8Al-bronze, flame quenched one, STS316, and SR50A alloys, respectively.

• Journal of the Microelectronics and Packaging Society
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• v.19 no.2
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• pp.41-45
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• 2012

Oxynitride green phosphors for white light emitting diodes (LEDs) were synthesized and their optical properties were evaluated. The N/O ratio ($\delta$) of $SrSi_2O_{2-{\delta}}N_{2+2/3{\delta}}:Eu^{2+}$ closely depended on the synthesizing conditions. The most excellent green emission (545 nm), which was assigned to the $5d{\rightarrow}4f$ transition of $Eu^{2+}$ ions, was achieved at the conditions of $1700^{\circ}C$, 5 mol% $Eu^{2+}$, and $H_2$ atmosphere. The well-developed $Ca-{\alpha}-SiAlON:Yb^{2+}$ particles with homogeneous size were obtained at m = 3 (n = 0.15) for the compound of $Ca_{0.5m-0.005}Yb_{0.005}Si_{12-(m+n)}Al_{m+n}O_nN_{16-n}$, resulting in the strong green emission at around 550 nm.