• Title/Summary/Keyword: $Sol_0{^4}$

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Differences in Treatment Outcomes According to the Insertion Method Used in Extracorporeal Cardiopulmonary Resuscitation: A Single-Center Experience

  • Han Sol Lee;Chul Ho Lee;Jae Seok Jang;Jun Woo Cho;Yun-Ho Jeon
    • Journal of Chest Surgery
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    • v.57 no.3
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    • pp.281-288
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    • 2024
  • Background: Venoarterial extracorporeal membrane oxygenation (ECMO) is a key treatment method used with patients in cardiac arrest who do not respond to medical treatment. A critical step in initiating therapy is the insertion of ECMO cannulas. Peripheral ECMO cannulation methods have been preferred for extracorporeal cardiopulmonary resuscitation (ECPR). Methods: Patients who underwent ECPR at Daegu Catholic University Medical Center between January 2017 and May 2023 were included in this study. We analyzed the impact of 2 different peripheral cannulation strategies (surgical cutdown vs. percutaneous cannulation) on various factors, including survival rate. Results: Among the 99 patients included in this study, 66 underwent surgical cutdown, and 33 underwent percutaneous insertion. The survival to discharge rates were 36.4% for the surgical cutdown group and 30.3% for the percutaneous group (p=0.708). The ECMO insertion times were 21.3 minutes for the surgical cutdown group and 10.3 minutes for the percutaneous group (p<0.001). The factors associated with overall mortality included a shorter low-flow time (hazard ratio [HR], 1.045; 95% confidence interval [CI], 1.019-1.071; p=0.001) and whether return of spontaneous circulation was achieved (HR, 0.317; 95% CI, 0.127-0.787; p=0.013). Low-flow time was defined as the time from the start of cardiopulmonary resuscitation to the completion of ECMO cannula insertion. Conclusion: No statistically significant difference in in-hospital mortality was observed between the surgical and percutaneous groups. However, regardless of the chosen cannulation strategy, reducing ECMO cannulation time was beneficial, as a shorter low-flow time was associated with significant benefits in terms of survival.

Novel Sulfonated Poly(arylene ether sulfone) Composite Membranes Containing Tetraethyl Orthosilicate (TEOS) for PEMFC Applications (고분자 전해질형 연료전지를 위한 TEOS가 함유된 술폰화 폴리아릴렌에테르술폰 복합막의 제조 및 특성)

  • Lee, Keun-Kyu;Kim, Tae-Ho;Hwang, Taek-Sung;Hong, Young-Taik
    • Membrane Journal
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    • v.20 no.4
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    • pp.278-289
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    • 2010
  • A series of composite membranes based on sulfonated poly(arylene ether sulfone) (SPAES) were prepared via addition of tetraethyl orthosilicate (TEOS) and solution casting method. The morphological structure, water uptake, proton conductivity of the resulting composite membranes were extensively investigated as function of the content of TEOS. By the sol-gel reaction, TEOS molecules were not completely converted to $SiO_2$ particles, but formed only oligomer-type. Also, EDS confirms that the resulting silicon dioxide was homogeneously distributed in the composite membranes. As the content of TEOS increased, the prepared membranes increased water uptake and proton conductivity at high temperature and low relative humidity condition. In particular, considerably high proton conductivity (0.015 S/cm) at $120^{\circ}C$ and 48%RH was demonstrated in the composite membrane containing 200% TEOS, which is 10 times greater than that of unmodified SPAES membrane. Also, the composite membranes were found to have enhanced thermal stability compared to the unmodified membrane.

The Change of the Near Eye Position according to the Spectacle and Contact Lens Wearing (안경과 콘택트렌즈 착용에 따른 근거리안위의 변화)

  • Han, Sun-Hee;Kim, Bong-Hwan;Kim, Hak-Jun;Park, Jun-Sung;Park, Hae-Been;Kim, Mi-Jeong;Park, Ju-Hyeong;Kim, Jin-Sol;Lee, Kyeong-Hoon;Kim, Jong-Hwan;Ha, Na-Ri
    • Journal of Korean Clinical Health Science
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    • v.3 no.4
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    • pp.435-443
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    • 2015
  • Purpose. This study was to investigate comparison of the near eye position according to the spectacle and contact lens wearing. Methods. We measured the AC/A ratio and near horizontal phoria using modified Thorington method in each case spectacle and contact lens wearing of equivalent spherical power after measuring the full corrected diopter for 20 subjects (men 5, woman 15, $21.15{\pm}1.35$ years) without specific ocular diseases, ocular surgery experience and vision anomalies. Results. It was shown high correlation between spectacle and contact lens wearing as AC/A ratio is a correlation coefficient 0.99 (p=0.00), near horizontal phoria is a correlation coefficient 0.95 (p=0.00). And contact lens wearing increased as AC/A ratio by $0.32{\pm}1.35$ ${\Delta}/D$ (p=0.31) and near horizontal phoria by $-0.17{\pm}2.18$ ${\Delta}$ (p=0.73) than spectacle wearing but there was no statistically significant difference. As the higher myopic grade AC/A ratio increased and then was shown decreased tendency in -6.00 D < $SED{\leq}-4.00$ D group (p>0.05) and as the higher myopic grade near exophoria increased but there was no statistically significant difference (p>0.05). Conclusions. We should consider that the subjects who had the lower AC/A ratio or higher near exophoria in -6.00 D < $SED{\leq}-4.00$ D group were necessary to measure AC/A ratio and near horizontal phoria when they were wearing contact lens because contact lens wearing tended to increase the near exophoria than spectacle wearing.

Degradation of TCE by Persulfate Oxidation with Various Activation Methods (heat, Fe2+, and UV) for ex-situ Chemical Oxidation Processes (Ex-situ 화학적 산화처리 적용을 위하여 다양하게 활성화(heat, Fe2+, UV)된 persulfate를 이용한 TCE 분해에 대한 연구)

  • Kim, Han-Sol;Do, Si-Hyun;Park, Ki-Man;Jo, Young-Hoon;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.17 no.6
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    • pp.43-51
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    • 2012
  • Rreactivity of persulfate (PS) for oxidation of TCE under various conditions such as heat, $Fe^{2+}$, and UV was investigated. It was found that degradation rate of TCE increased with increasing temperature from 15 to $35^{\circ}C$. At pH 7.0, the rate constants (k) at 15, 25, 30, and $35^{\circ}C$ were 0.07, 0.30, 0.74, and $1.30h^{-1}$, respectively. For activation by $Fe^{2+}$, removal efficiency of TCE increased with increasing $Fe^{2+}$ concentration from 1.9 mM to 11 mM. The maximum removal efficiency of TCE was approximately 85% when pH of the solution dropped from 7.0 to 2.5. Degradation of TCE by UV-activated PS was the most effective, showing that the degradation rate of TCE increased with inreasing PS dosage; the rate constants (k) at 0.5, 2.5, and 10 mM were 34.2, 40.5, and $55.9h^{-1}$, respectively. Our results suggest that PS activation by UV/PS process could be the most effective in activation processes tested for TCE degradation. For oxidation process by PS, however, pH should be observed and adjusted to neutral conditions (i.e., 5.8-8.5) if necessary.

Degreasing of Impurities for a Web Strip Iron Mills (금속인발가공선의 협잡물 제거 (탈지)방법의 고찰(I))

  • 김주항
    • Journal of the Korean Professional Engineers Association
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    • v.31 no.1
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    • pp.74-84
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    • 1998
  • 본 지도업체인 쌍희금속은 1988년 2월 설립, 주생산제품은 닉켈합금선으로서 1997년 12월 현재 총매출액 7.4억원(수출 0.12억 포함) 당기순이익 0.32억원으로 종업원 9명을 포함한 개인기업 형태로 특히 총매출액의 6%를 기술투자비율에 할당하고 있는 유망 중소기업이다. 기술지도와 관련한 연선의 선재(線材)는 포항제철의 $^{ø}$8mm 태선(允線)이 주종이나 특수선(特殊線)인 경우는, 국내선재의 경우 멜팅(Melting)기술이 부족하여 독일국으로부터 $^{ø}$5.5 mm의 선재를 직수입에 의존하고 있었다. 한편 세선가공의 선재는 20여개의 Dies공구 가공공정을 통한 $^{ø}$1.3 mm의 선채를 사용하여 $^{ø}$0.6 mm의 세선(細線)을 가공하고 있었다. 그러나 인발(引拔) 기술과 관련함에 특히 Dies 공구로부터 세선(細線)을 제조한 후 마무리 공정에서의 탈지문제가 정립돼있지 못하여 End User로부터 불만사례가 종종 야기 되었다 이의 원인 규명을 기술지도를 통해 조사한 결과 소성가공유(습식형)의 인식 부족이 주원인이였다. 소성가공유의 조성은 일반적으로 식물성. 광물성, 계면활성제, 극압제 등으로 구성됨에 마무리공정에서의 탈지방법은 가공유제의 기재(Base oil)에 따라 다르다 즉 기유(基油)가 광물계인 경우는 탈지제가 용제형(TCE 등)이 양호하나 식물계인 경우는 Alkali계가 양호하다. 따라서 NaOH sol'n2~3%+분산제(기포방지제)로서 음이온인 노닐페놀 0.1~0.3%의 처방을 제시하고 설비로서는 8$0^{\circ}C$로 유지되는 조제된 알칼리 Vessel과 물중탕 설비(열풍설비 포함)등을 대입하는 공정개선으로 Dies를 통과한 중간제품의 세선 $\longrightarrow$ 탈지설비 $\longrightarrow$ 80~85$^{\circ}C$로 유지되는 열처리(Aniling)공정을 대입함에 세선의 가공경화가 없었으며 아울러 수용성 가공유의 관리 한계(사내표준화)를 설정 관리 하도록 지도함으로서 지도 전에 비해 제조원가의 절하 및 생산성 향상은 물론 세선의 신규 탈지제 개발과 공정 개선을 통하여 가열공정의 부하개선 과 최종제품인 절연선의 품질향상을 가져 왔다.

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Effect of Thin-Film Thickness on Electrical Performance of Indium-Zinc-Oxide Transistors Fabricated by Solution Process (용액 공정을 이용한 IZO 트랜지스터의 전기적 성능에 대한 박막 두께의 영향)

  • Kim, Han-Sang;Kyung, Dong-Gu;Kim, Sung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.8
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    • pp.469-473
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    • 2017
  • We investigated the effect of different thin-film thicknesses (25, 30, and 40 nm) on the electrical performance of solution-processed indium-zinc-oxide (IZO) thin-film transistors (TFTs). The structural properties of the IZO thin films were investigated by atomic force microscopy (AFM). AFM images revealed that the IZO thin films with thicknesses of 25 and 40 nm exhibit an uneven distribution of grains, which deforms the thin film and degrades the performance of the IZO TFT. Further, the IZO thin film with a thickness of 30 nm exhibits a homogeneous and smooth surface with a low RMS roughness of 1.88 nm. The IZO TFTs with the 30-nm-thick IZO film exhibit excellent results, with a field-effect mobility of $3.0({\pm}0.2)cm^2/Vs$, high Ion/Ioff ratio of $1.1{\times}10^7$, threshold voltage of $0.4({\pm}0.1)V$, and subthreshold swing of $0.7({\pm}0.01)V/dec$. The optimization of oxide semiconductor thickness through analysis of the surface morphologies can thus contribute to the development of oxide TFT manufacturing technology.

Synthesis of TiO2 Fine Powder by Sol-Gel Process and Reaction Mechanism(I): Hydrolysis of Titanium Isopropoxide (졸-겔법에 의한 TiO2 미분말 합성과 반응메카니즘(I): Titanium isopropoxide의 가수분해)

  • Myung, Jung-Jae;Chung, Yong-Sun;Kyong, Jin-Bum;Kim, Ho-Kun
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.794-801
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    • 1996
  • $TiO_2$ fine powders were synthesized via hydrolysis reaction of titanium isopropoxide in isopropanol solvent and the reaction rates were studied by use of UV spectroscopic method. The reactions were controlled to proceed to pseudo-first-order reaction in the presence of excess water in isopropanol solvent. The rate constants which varied with temperature and concentration of water were calculated by Guggenheim method. Reactions using $D_2O$ were also carried out to determine the catalytic character of water. n value of water molecules in transition state and the thermodynamic parameters showed that the reaction proceeded by $S_N2$ mechanism. $TiO_2$ powders synthesized in this reaction were almost spheric forms and had average particle size of $0.3{\mu}m$ diameter.

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Preparation and Characterization of TPA Captured CL-SPEEK Polymer Composite Membranes for Water Electrolysis (수전해용 술폰화 폴리에테르 에테르 케톤과 고정된 TPA 고분자 복합막의 제조 및 특성)

  • CHA, JINSAN;YOON, YOUNGYO;KIM, MINJIN;KIM, BOYOUNG;MOON, SANG-BONG;CHUNG, JANG-HOON
    • Journal of Hydrogen and New Energy
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    • v.28 no.1
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    • pp.17-23
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    • 2017
  • Polyether ether ketone (PEEK) composite including tungstophosphoric acid(TPA) membranes have been intensively investigated for polymer electrolyte membrane water electrolysis (PEMWE) and thus covalently linked sulfonated polyether ether ketone (CL-SPEEK) with captured TPA composite membranes were prepared and characterized. Sulfonated polyether ether ketone (SPEEK) was prepared in sulfonation of PEEK and was cross-linked with 1,4 diiodobutane. The carbonyl group of SPEEK was reduced with $NaBH_4$ and 3-isocyanatepropyltriethoxysilane (ICPTES) was added. The TPA captured composite was prepared in reaction of TPA with 3-mercaptopropyltrime thoxysilane (MPTMS). The polymer composite membranes showed better thermostability and electrochemical properties than SPEEK. The membranes were prepared by sol-gel casting method. The polymer composite membrane featured 0.1285 S/cm of proton conductivity at $80^{\circ}C$ and outstanding durability.

Synthesis and characterization of polyamide thin-film nanocomposite membrane containing ZnO nanoparticles

  • AL-Hobaib, A.S.;El Ghoul, Jaber;El Mir, Lassaad
    • Membrane and Water Treatment
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    • v.6 no.4
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    • pp.309-321
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    • 2015
  • We report in this study the synthesis of mixed matrix reverse osmosis membranes by interfacial polymerization (IP) of thin film nanocomposite (TFNC) on porous polysulfone supports (PS). This paper investigates the synthesis of ZnO nanoparticles (NPs) using the sol-gel processing technique and evaluates the performance of mixed matrix membranes reached by these aerogel NPs. Aqueous m-phenyl diamine (MPD) and organic trimesoyl chloride (TMC)-NPs mixture solutions were used in the IP process. The reaction of MPD and TMC at the interface of PS substrates resulted in the formation of the thin film composite (TFC). NPs of ZnO with a size of about 25 nm were used for the fabrication of the TFNC membranes. These membranes were characterized and evaluated in comparison with neat TFC ones. Their performances were evaluated based on the water permeability and salt rejection. Experimental results indicated that the NPs improved membrane performance under optimal concentration of NPs. By changing the content of the filler, better hydrophilicity was obtained; the contact angle was decreased from $74^{\circ}$ to $32^{\circ}$. Also, the permeate water flux was increased from 26 to 49 L/m2.h when the content of NPs is 0.1 (wt.%) with the maintaining of lower salt passage of 1%.

Preparation of Field Effect Transistor with $(Bi,La)Ti_3O_{12}$ Ferroelectric Thin Film Gate ($(Bi,La)Ti_3O_{12}$ 강유전체 박막 게이트를 갖는 전계효과 트랜지스터 소자의 제작)

  • Suh Kang Mo;Park Ji Ho;Gong Su Cheol;Chang Ho Jung;Chang Young Chul;Shim Sun Il;Kim Yong Tae
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.11a
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    • pp.221-225
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    • 2003
  • The MFIS-FET(Field Effect Transistor) devices using $BLT/Y_2O_3$ buffer layer on p-Si(100) substrates were fabricated by the Sol-Gel method and conventional memory processes. The crystal structure, morphologies and electrical properties of prepared devices were investigated by using various measuring techniques. From the C-V(capacitance-voltage) data at 5V, the memory window voltage of the $Pt/BLT/Y_2O_3/si$ structure decreased from 1.4V to 0.6V with increasing the annealing temperature from $700^{\circ}C\;to\;750^{\circ}C$. The drain current (Ic) as a function of gate voltages $(V_G)$ for the $MFIS(Pt/BLT/Y_2O_3/Si(100))-FET$ devices at gate voltages $(V_G)$ of 3V, 4V and 5V, the memory window voltages increased from 0.3V to 0.8V as $V_G$ increased from 3V to 5V.

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