• Title/Summary/Keyword: $S_2$

Search Result 158,467, Processing Time 0.116 seconds

Facile Synthesis of MoS2-C60 Nanocomposites and Their Application to Catalytic Reduction and Photocatalytic Degradation

  • Li, Jiulong;Ko, Weon Bae
    • Elastomers and Composites
    • /
    • v.51 no.4
    • /
    • pp.286-300
    • /
    • 2016
  • $MoS_2$ precursors were synthesized by reacting thioacetamide ($C_2H_5NS$) with sodium molybdate dihydrate ($Na_2MoO_4{\cdot}2H_2O$) in aqueous HCl solution. $MoS_2$ nanoparticles were prepared from dried $MoS_2$ precursors by calcination in an electric furnace at $700^{\circ}C$ for 2 h under an inert argon atmosphere. $MoS_2-C_{60}$ nanocomposites were obtained by heating $MoS_2$ nanoparticles and fullerene ($C_{60}$) together in an electric furnace at $700^{\circ}C$ for 2 h. Their morphological and the structural properties were characterized by powder X-ray diffraction and scanning electron microscopy. The $MoS_2$ nanoparticles and $MoS_2-C_{60}$ nanocomposites were used as catalysts in the reductions of 2-, 3-, and 4-nitrophenol in the presence of sodium borohydride. The photocatalytic activities of the $MoS_2$ nanoparticles and $MoS_2-C_{60}$ nanocomposites were evaluated in the degradation of organic dyes (brilliant green, methylene blue, methyl orange, and rhodamine B) under ultraviolet light (254 nm).

Synthesis and Biological Properties of l$\beta$-Methylcarbapenems with 5'- Ethoxycarbonylmethoxy(hydroxy )iminopyrrolidinylthio Group at C-2 Position (C-2 위치에 5'-Ethoxycarbonylmethoxy(hydroxy)iminopyrrolidinylthio Group을 가진 1$\beta$-Methylcarbapenems의 합성과 생물학적 성질)

  • 오창현;안수현;백대진;홍준희;고옥현
    • YAKHAK HOEJI
    • /
    • v.47 no.6
    • /
    • pp.450-455
    • /
    • 2003
  • Synthesis of (lR,5S,6S)-6-[(lR)-1-hydroxyethyl] -2-[(3S,5S)-5-(2-ethoxycarbonyl-1-moxy(hydroxy)iminoethyl)pyrrolidine-3-ylthio]-1-methylcarbapen-2-em-3-carboxylic acids (10a,l0b) were described. Methyl(2S,4S)-4-tritylthio-1-(allyloxycarbonyl)pyrrolidine-2-carboxyla late (I) was prepared from trans-4-hydroxy-L-proline with (2S,4R)-abs olute configuration as starting material. (2S,4S)-1-allyloxycarbonyl-2-(2-ethoxycarbonyl-hydroxy(methoxy )iminoethyl)-4-mercapto- pyrrolidines (6,7) were obtained from the tritylthio compound (I). (lR,5S,6S)-6-[(lR)-1-hydroxyethyl]-2-[(3S,5S)-5-(2-ethoxycarbonyl-1-methoxy(hydroxy)imino-ethyl)pyrrolidine-3-ylthio]-1-methylcarbapem-2-em-3-carboxylic acids (10a,10b) were obtained by the coupling reaction with carbapenem diphenylphosphates (8) and pyrrolidine-thiol moiety (6,7). Their in vitro antibacterial activities against both Gram-positive and Gram-negative were tested. Compounds ( 10a,10b) showed potent antibacterial activity except pseudomonas aerusinosa.

Enhancing the Thermoelectric Properties of Layered Bi2O2Q (Q = S, Se): the Effect of Mixed Chalcogen Net

  • Lee, Wang Ro;Lee, Changhoon
    • Journal of the Korean Physical Society
    • /
    • v.73 no.11
    • /
    • pp.1684-1690
    • /
    • 2018
  • The layered semiconductors $Bi_2O_2Q$ (Q = S, Se) consists of $Bi_2O_2$ layers sandwiched by Q square nets. On the basis of density functional theory calculations, we examined the thermoelectric properties of $Bi_2O_2S$, $Bi_2O_2Se$ as well as hypothetical structure of $Bi_2O_2$($S_{0.5}Se_{0.5}$) consisting of mixed chalcogen nets. The thermoelectric power factor of $Bi_2O_2S_{0.5}Se_{0.5}$ is much greater than those of $Bi_2O_2S$ and $Bi_2O_2Se$, suggesting that introducing mixed chalcogen net in $Bi_2O_2Q$ is a possible way of enhancing the thermoelectric property of $Bi_2O_2Q$.

MoS2/Montmorillonite Nanocomposite: Preparation, Tribological Properties, and Inner Synergistic Lubrication

  • Cheng, Lehua;Hu, Enzhu;Chao, Xianquan;Zhu, Renfa;Hu, Kunhong;Hu, Xianguo
    • Nano
    • /
    • v.13 no.12
    • /
    • pp.1850144.1-1850144.13
    • /
    • 2018
  • A nano-$MoS_2$/montmorillonite K-10 (K10) composite was prepared and characterized. The composite contains two types of 2H-$MoS_2$ nanoparticles. One is the hollow spherical $MoS_2$ with a size range of 75 nm, and the other is the spherical nano cluster of $MoS_2$ with a size range of 30 nm. The two kinds of nano-$MoS_2$ were formed via assembly of numerous $MoS_2$ nano-platelets with a size of ~10 nm. A tribological comparison was then made among nano-$MoS_2$/K10, K10, nano-$MoS_2$ and a mechanical mixture of K10 and nano-$MoS_2$. K10 reduced the wear but slightly increased the friction. Nano-$MoS_2$ remarkably reduced both friction and wear. The mechanical mixture demonstrated better wear resistance than nano-$MoS_2$, indicating a synergistic anti-wear effect of nano-$MoS_2$ and K10. The synergistic effect was reinforced using nano-$MoS_2$/K10 instead of the mechanical mixture. A part of the $MoS_2$ in the contact region always lubricated the friction pair, and the rest formed a tribofilm. K10 segregated the friction pair to alleviate the ablation wear but magnified the abrasive wear. S-$MoS_2$ protects K10 and they together function as both a lubricant and an isolating agent to reduce the ablation and abrasive wear.

Synthesis and Antimicrobial Screening of Some Fluorinated Azoles Containing (2-(6-Methyl-2-P-tolyl-lH-imidazo[1,2-a]pyridin-3-yl) Nucleus ((2-(6-Methyl-2-P-tolyl-lH-imidazo[1,2-a]pyridin-3-yl)핵종을 가지고 있는 불소화된 아조화합물의 합성과 항균활성의 스크리닝)

  • Shelke, Sharad;Salunkhe, Nilesh;Sangale, Sandeep;Bhalerao, Swapnil;Naik, Nilesh;Mhaske, Ganesh;Jadhav, Ranjana;Karale, Bhausaheb
    • Journal of the Korean Chemical Society
    • /
    • v.54 no.1
    • /
    • pp.59-64
    • /
    • 2010
  • The synthesis of a series of fluorinated thiadiazoles 3, triazoles 4 and oxadiazoles 5 are synthesized from thiosemicarbazides 2 containing (2-(6-methyl-2-p-tolyl-lH-imidazo[1,2-a]pyridin-3-yl nucleus. These reactions were carried out by conventional method as well as ultra sound irradiation method. All products have been characterized by IR, 1H NMR, MS study and screened for their antimicrobial activity.

실란 개질제가 실리카충전고무 컴파운드에 미치는 영향

  • Kim, Gwang-Je
    • Rubber Technology
    • /
    • v.9 no.1
    • /
    • pp.1-12
    • /
    • 2008
  • Effects of silane modifier, bis(triethoxysilylpropyl) tetrasulfide (TESPT(S4)) and bis(triethoxysilylpropyl) disulfide (TESPD(S2)), on silica filled compound were investigated upon processability, dynamic, mechanical, heat build-up, blowout properties, and silica dispersion in natural rubber (NR). The temperature of the S2 treated silica compound generated higher than that of the S4 treated compound during internal mixer compounding. The shear viscosity of the S2 compound exhibited lower than that of the S4 compound and the viscosity measured in dynamic mode was close to each other. The elongation modulus of the S2 compound exhibited lower than that of the S4; however, the tear resistance strength of the S2 compound exhibited higher than that of the S4 compound. The loss tan$\delta$ values of the S2 compound exhibited higher than those of the S4 at room temperature. The augmentation of the test temperature lowered the tan$\delta$ values of each compound, which results in close tan$\delta$ values to each other at $100^{\circ}C$. The S2 compound deformed less than the S4 compound, and the blowout time of each compound was close to each other. The S2 compound generated more heat build-up than the S4 compound. The abrasion loss of the S2 compound was less than that of the S4 compound. The size of the silica agglomerate reduced on both S4 and S2 compounds upon vulcanization. The addition of the bifunctional silanes (S2 and S4) on silica filled NR compound improved the processability of each compound and their effects were more significant on the S2 compound than the S4 compound. After vulcanization the silica agglomerate size of each compound reduced compared with before vulcanization.

  • PDF

Experimental studies on anti-tumor and immunomodulatory effects according to it's (종양(腫瘍)의 치법(治法)에 관(關)한 실험적(實驗的) 연구(硏究) -부정법(扶正法), 부정거사법(扶正祛邪法), 공사법(攻邪法)의 비교연구(比較硏究)-)

  • Kim, Sun-Hee;Choi, Jong-Baek;Kim, Sang-Chan
    • Herbal Formula Science
    • /
    • v.5 no.1
    • /
    • pp.127-145
    • /
    • 1997
  • This study was aimed to investigate the anti-tumor and immune response effect of Samyongtang(S1; this medicine represents for 'ENERGIZER'), Yangjeongjejeoktang(S2; this is the 'INTERMEDIATE METHOD' of S1 and S3) and Onbeakwon(S3; this is 'ATTACK' the disease of mass) on the experimental rats induced by Sarcoma-180 and Methotrexate. And to observed the differences S1, S2, and S3 treatment groups. Tumor weight(TW) in vivo, interleukin-2(IL-2), hemagglutinin titer(H.A), hemolysin titer(HL), rossete forming cell(RFC), delayed type hypersensitivity(DTH), and natural killer cell activity(NKCA) in vivo were measured in rats. The obtained results were summarized as follows. 1. Tumor weight was decreased in all treatment groups (S2>S3>S1) as compared with control group, but the difference was not statistically significant each treatment groups. 2. Interleukin-2 was increased in all treatment groups (S1>S2>Ss) as compared with control group, but the difference was not statistically significant each treatment groups. 3. Hemagglutinin titer was increased in all treatment groups (S1>S2>S3) as compared with control group, but the difference was not statistically significant each treatment groups. 4. Hemolysin titer was increased in all treatment groups (S1>S2>S3) as compared with control group, but the difference was not statistically significant each treatment groups. 5. Rossete forming cell(RFC) was increased in all treatment groups (S1>S2>S3) as compared with control group, but the difference was not statistically significant each treatment groups. 6. Delayed type hyperseneitivity(DTH) was increased in S1, S2 treatment groups (S1>S2) as compared with control group, but it was decreased in S3 treatment group. Therefore, S1 group was statistically significant compared with S3 groups. 7. Natural killer cell activity(NKCA) was increased in all treatment groups (S2>S3>S1) as compared with control group, but the difference was not statistically significant each treatment groups. Based on the above mentioned results, it is suggested that S1, S2 and S3 will have anti-tumor substances and enhance effect of immune response. But the differences were not statistically significant in each treatment groups, except for delayed type hypersensitivity.

  • PDF

FACTORIZATION OF A HILBERT SPACE ON THE BIDISK

  • Yang, Mee-Hyea;Hong, Bum-Il
    • Honam Mathematical Journal
    • /
    • v.31 no.4
    • /
    • pp.479-487
    • /
    • 2009
  • Let $S(z_1,z_2),\;S_1(z_1,z_2)$ and $S_2(z_1,z_2)$ be power series with operator coefficients such that $S_(z_1,\;z_2)=S_1(z_1,z_2)S_2(z_1,z_2)$. Assume that the multiplications by $S_1(z_1,z_2)$ and $S_2(z_1,z_2)$ are contractive transformations in H($\mathbb{D}^2,\;\mathcal{C}$). Then the factorizations of spaces $\mathcal{D}(\mathbb{D},\;\tilde{S})$ and $\mathcal{D}(\mathbb{D}^2,\mathcal{S})$ are well-behaved.

Structural Interpretation on the Mechanism of High $La_2S_3$ Solubility in $GeS_2-Ga_2S_3-La_2S_3$Glasses ($GeS_2-Ga_2S_3-La_2S_3$ 유리 구조 분석을 통한 $La_2S_3$ 용융성 규명)

  • Yoon, Joong-Min;Heo, Jong;Ryou, Sun-Youn
    • Journal of the Korean Ceramic Society
    • /
    • v.34 no.8
    • /
    • pp.870-876
    • /
    • 1997
  • Ge-Ga-S glasses, contrary to other well-known chalcogenide glasses, show high rare-earth solubility. Raman spectra of GeS2-Ga2S3 glasses showed that two peaks at 260 cm-1 and 385 cm-1 increased in intensity with the addition of Ga2S3. These peaks are associated with the vibration of Ge-Ge bonds and edge-shared [GsS4] tetrahedra, respectively. In GeS2-Ga2S3-La2S3 glasses, the peak at 260 cm-1 decreased in intensity with addition of La2S3 and the one at 375 cm-1 due to the vibration of tetrahedra with non-bridging sulfurs increased. It indicated that La, or rare-earths in general, can easily be dissolved into the glass network as charge compensators for non-bridging sulfurs which were formed through the dissociation of Ge-Ge bonds and edge-shared [GaS4] tetrahedra. Since no such structural modification is expected in glasses as Ga-As-S, these peculiar transitions on the connection scheme in Ga-containing chalcogenide glasses seem to be playing the most important role on the enhanced rare-earth solubility.

  • PDF